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    • 7. 发明授权
    • Hydroconversion effluent separation process
    • 加氢转化废水分离过程
    • US5082551A
    • 1992-01-21
    • US560223
    • 1990-07-25
    • Bruce E. ReynoldsDonald A. BeaRobert W. Bachtel
    • Bruce E. ReynoldsDonald A. BeaRobert W. Bachtel
    • C10G49/00C10G49/22
    • C10G49/22C10G49/007
    • A hydroconversion effluent separation process is provided.The effluent from the hydroconversion zone is passed to a hot high pressure separation zone. The gas phase from that zone is then passed to a cold high pressure separation zone while the liquid hydrocarbon bottoms is passed to a hot low pressure separation zone. The gas phase is partially condensed in the cold high pressure separation zone to obtain a hydrogen-rich gas and a liquid hydrocarbon bottoms. A portion of the hydrogen-rich gas is recycled to the hydroconversion zone. A second portion is sent to a hydrogen purification step, most preferably by membrane separation, and the purified gas is recycled to the hydroconversion zone. The overhead from the hot low pressure separation is fed to a cold low pressure separation zone. The gas phase from the cold low pressure separation zone is recycled to the hydroconversion zone. Preferably, two cold low pressure separation zones are utilized in the process.
    • 提供加氢转化废水分离过程。 来自加氢转化区的流出物被传递到热的高压分离区。 然后将来自该区域的气相传递到冷的高压分离区,同时液体烃底部通入热的低压分离区。 气相在冷高压分离区中部分冷凝,得到富氢气体和液态烃底物。 一部分富氢气体被再循环到加氢转化区。 将第二部分送至氢气净化步骤,最优选通过膜分离,并将纯化的气体再循环至加氢转化区。 来自热低压分离的塔顶馏出物被送入冷的低压分离区。 来自冷低压分离区的气相再循环到加氢转化区。 优选地,在该过程中使用两个冷的低压分离区。
    • 9. 发明授权
    • Catalyst, method and apparatus for an on-stream particle replacement
system for countercurrent contact of a gas and liquid feed stream with
a packed bed
    • 用于气体和液体进料流与填充床的逆流接触的在线颗粒更换系统的催化剂,方法和装置
    • US5733440A
    • 1998-03-31
    • US748942
    • 1996-11-14
    • Bruce E. StangelandDavid C. KramerDavid S. SmithJames T. McCallGeorgieanna L. ScheuermanRobert W. BachtelDavid R. Johnson
    • Bruce E. StangelandDavid C. KramerDavid S. SmithJames T. McCallGeorgieanna L. ScheuermanRobert W. BachtelDavid R. Johnson
    • B01J8/00B01J8/12B01J8/18B01J8/22C10G35/10C10G45/00C10G49/00C10G49/14C10G35/14
    • B01J8/003B01J8/008B01J8/125B01J8/1881B01J8/22C10G49/002C10G49/14B01J2208/00884
    • This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid (i.e. a mixture of liquid hydrocarbon and a hydrogen-containing gas) at a rate insufficient to levitate or ebullate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion, such as in a large pilot plant run, with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed. At the desired flow rate, such catalyst continually flows in a plug-like manner downwardly through the reactor vessel by introducing fresh catalyst at the top of the catalyst bed by laminarly flowing such catalyst in a liquid stream on a periodic or semicontinuous basis. Catalyst is similarly removed by laminarly flowing catalyst particles in a liquid stream out of the bottom of the catalyst bed. Intake for such flow is out of direct contact with the stream of gas flowing through the bed and the flow path is substantially constant in cross-sectional area and greater in diameter by several times than the diameter of the catalyst particles. The catalyst of this invention produces a plug-flowing substantially packed bed of hydroprocessing catalyst which occupies at least about 75% by volume of the reactor volume.
    • 本发明使得均匀分布的氢气和烃液体可以在密集填充的催化剂床上基本连续地流动,以通过将流体作为气体和液体的替代环​​形环(即液体烃和液体烃的混合物)引入反应器容器的基本整个体积 含氢气体),其速率不足以使催化剂床漂浮或沸腾。 在液体和气体的设计进料速率下,通过密度,形状和尺寸选择催化剂,以防止填料床以设计进料速率进行沸腾。 通过在设计压力和流速下测量床膨胀,例如在大型中试设备运行中与烃,氢气和催化剂进行选择。 进料床的液体和气体组分在床的整个区域内以交替的环形环流入床中。 以期望的流速,这种催化剂以塞子状方式向下延伸穿过反应器容器,通过在催化剂床的顶部引入新鲜的催化剂,通过在液体流中以周期性或半连续的方式层流流动这种催化剂。 催化剂类似地通过层流流动的催化剂颗粒在催化剂床底部的液体流中除去。 这种流动的吸入不与流过床的气体流直接接触,并且流动通道在横截面积上基本上恒定,并且直径大于催化剂颗粒直径的几倍。 本发明的催化剂产生占据反应器体积的至少约75体积%的加氢处理催化剂的堵塞流动基本上填充的床。
    • 10. 发明授权
    • Hydrocarbon hydroconversion process
    • 烃加氢转化过程
    • US5522983A
    • 1996-06-04
    • US832170
    • 1992-02-06
    • Dennis R. CashRobert W. Bachtel
    • Dennis R. CashRobert W. Bachtel
    • C10G65/10C10G65/12
    • C10G65/12C10G65/10
    • A process is provided for converting a hydrocarbon feedstock comprising the steps of introducing the hydrocarbon feedstock to a first hydroconversion zone at superatmospheric pressure and at a temperature between about 450.degree. F. and about 850.degree. F. in the presence of hydrogen, the hydrogen flowing in a countercurrent relationship to the hydrocarbon feedstock, to form a hydrogen-rich vapor effluent and a hydrocarbon-rich liquid effluent; reacting the hydrogen-rich vapor effluent in a second hydroconversion zone to form a converted vapor effluent; and introducing a portion of the hydrocarbon-rich liquid effluent to the second hydroconversion zone in countercurrent relationship to the hydrogen-rich vapor effluent. By recycling to the second hydroconversion zone a stream having sufficiently high boiling range that it remains a liquid, a greater range of operating conditions are possible in the second hydroconversion zone, thus allowing for higher conversions and product yields.
    • 提供了一种用于转化烃原料的方法,包括以下步骤:在氢气存在下,在超大气压和约450°F至约850°F的温度下将烃原料引入第一加氢转化区,氢气流动 与烃原料逆流关系,形成富氢蒸汽流出物和富烃液体流出物; 使富氢蒸汽流出物在第二加氢转化区中反应以形成转化的蒸汽流出物; 并将富含烃的液体流出物的一部分与富氢蒸气流出物逆流地引入第二加氢转化区。 通过再循环到第二加氢转化区,具有足够高沸点范围的物流,其保持液体,在第二加氢转化区可能有更大范围的操作条件,从而允许更高的转化率和产物产率。