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1. 发明授权

US09169449B2 Hydroprocessing catalysts and methods for making thereof 有权
标题翻译：加氢处理催化剂及其制备方法
公开(公告)号：US09169449B2
公开(公告)日：2015-10-27
申请号：US13330925
申请日：2011-12-20
申请人： Bruce E. Reynolds , Julie Chabot , Erin Maris , Sean Solberg , Kaidong Chen
发明人： Bruce E. Reynolds , Julie Chabot , Erin Maris , Sean Solberg , Kaidong Chen
IPC分类号： C10G47/26 , C10G49/00 , C10G49/02 , B01J37/20 , B01J35/00 , B01J23/883 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/02 , C10G49/12
CPC分类号： C10G49/02 , B01J23/883 , B01J35/0006 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1052 , B01J35/1066 , B01J35/1076 , B01J37/0036 , B01J37/0201 , B01J37/20 , C10G49/12 , C10G2300/208 , C10G2300/4056 , C10G2300/70 , C10G2300/708 , C10G2300/802
摘要： A method to upgrade heavy oil feedstock using an ebullated bed reactor and a novel catalyst system is provided. The ebullated bed reactor system includes two different catalyst with different characteristics: an expanded catalyst zone containing particulate catalyst having a particle size of greater than 0.65 mm; and a slurry catalyst having an average particle size ranging from 1 to 300 μm. The slurry catalyst is introduced to the ebullated bed system with the heavy oil feedstock, and entrained in the upflowing hydrocarbon liquid passing through the ebullated bed reaction zone. The slurry catalyst reduces the formation of sediment and coke precursors in the ebullating bed reactor system. The slurry catalyst is prepared from at least a water-soluble metal precursor and pre-sulfided prior to being introduced with the heavy oil feedstock to the reactor system, or sulfided in-situ in the ebullated bed reactor in another embodiment.
摘要翻译：提供了一种使用沸腾床反应器和新型催化剂体系升级重油原料的方法。沸腾床反应器系统包括具有不同特性的两种不同的催化剂：包含粒度大于0.65mm的颗粒催化剂的膨胀催化剂区; 和平均粒度为1〜300μm的浆料催化剂。将浆料催化剂与重油原料引入沸腾床系统，并夹带在通过沸腾床反应区的向上流动的烃液中。浆料催化剂减少沸腾床反应器系统中沉淀物和焦炭前体的形成。浆料催化剂由至少一种水溶性金属前体制备，并在将重油原料引入反应器系统之前进行预硫化，或在另一个实施方案中在沸腾床反应器中原位硫化。

2. 发明申请

US20120152805A1 Hydroprocessing Catalysts and Methods for Making Thereof 有权
标题翻译：加氢催化剂及其制备方法
公开(公告)号：US20120152805A1
公开(公告)日：2012-06-21
申请号：US13330910
申请日：2011-12-20
申请人： Julie Chabot , Bruce E. Reynolds , Erin Maris , Shuwu Yang
发明人： Julie Chabot , Bruce E. Reynolds , Erin Maris , Shuwu Yang
IPC分类号： C10G47/00 , B01J35/10 , B01J31/02 , B01J27/02 , C10G45/02 , B01J35/02
CPC分类号： C10G49/02 , B01J23/883 , B01J35/0006 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1052 , B01J35/1066 , B01J35/1076 , B01J37/0036 , B01J37/0201 , B01J37/20 , C10G49/12 , C10G2300/208 , C10G2300/4056 , C10G2300/70 , C10G2300/708 , C10G2300/802
摘要： A method to upgrade heavy oil feedstock using an ebullated bed reactor and a novel catalyst system is provided. The ebullated bed reactor system includes two different catalyst with different characteristics: an expanded catalyst zone containing particulate catalyst having a particle size of greater than 0.65 mm; and a slurry catalyst having an average particle size ranging from 1 to 300 μm. The slurry catalyst is provided to the ebullated bed system containing the heavy oil feedstock, and entrained in the upflowing hydrocarbon liquid passing through the ebullated bed reaction zone. The slurry catalyst reduces the formation of sediment and coke precursors in the ebullating bed reactor system. The slurry catalyst is prepared from rework materials, which form a slurry catalyst in-situ upon mixing with the heavy oil feedstock.
摘要翻译：提供了一种使用沸腾床反应器和新型催化剂体系升级重油原料的方法。沸腾床反应器系统包括具有不同特性的两种不同的催化剂：包含粒度大于0.65mm的颗粒催化剂的膨胀催化剂区; 和平均粒度为1〜300μm的浆料催化剂。将浆料催化剂提供给含有重油原料的沸腾床系统，并夹带在通过沸腾床反应区的向上流动的烃液中。浆料催化剂减少沸腾床反应器系统中沉淀物和焦炭前体的形成。浆料催化剂由返工材料制备，其在与重油原料混合时原位形成浆料催化剂。

3. 发明授权

US06841062B2 Crude oil desulfurization 失效
标题翻译：原油脱硫
公开(公告)号：US06841062B2
公开(公告)日：2005-01-11
申请号：US09896224
申请日：2001-06-28
申请人： Bruce E. Reynolds
发明人： Bruce E. Reynolds
IPC分类号： C10G7/06 , C10G45/08 , C10G47/02 , C10G65/00 , C10G65/12 , C10G65/14 , C10G67/02 , C10G69/02
CPC分类号： C10G65/12 , C10G65/00 , C10G65/14
摘要： This invention relates to a crude oil desulfurization process which comprises hydrodesulfurizing a crude oil feed in a crude desulfurization unit. The desulfurized crude oil is then separated into a light gas oil fraction, a vacuum gas oil fraction and a vacuum residuum fraction. The vacuum gas oil is hydrocracked to form at least one low sulfur fuel product. The light gas oil fraction is hydrotreated. The vacuum gas oil may be hydrocracked in one or more stages. Hydrocracking in the second stage, if present, will convert of at least 20% of the first zone effluent, to create a low sulfur light gas oil fraction. The light gas oil fraction may then be hydrotreated.
摘要翻译：本发明涉及一种原油脱硫方法，其包括对粗脱硫装置中的原油进料进行加氢脱硫。然后将脱硫的原油分离成轻瓦斯油馏分，减压瓦斯油馏分和真空渣油馏分。减压瓦斯油被加氢裂化以形成至少一种低硫燃料产物。轻油馏分被加氢处理。减压瓦斯油可以在一个或多个阶段加氢裂化。第二阶段的加氢裂化（如果存在）将转化至少20％的第一区流出物，以产生低硫轻瓦斯油馏分。然后轻油馏分可以进行加氢处理。

4. 发明授权

US06554994B1 Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks 有权
标题翻译：具有分层催化剂床的上流式反应器系统用于加氢处理重质原料
公开(公告)号：US06554994B1
公开(公告)日：2003-04-29
申请号：US09290448
申请日：1999-04-13
申请人： Bruce E. Reynolds , Fred W. Lam , Julie Chabot , Fernando J. Antezana , Robert Bachtel , Kirk R. Gibson , Richard Threlkel , Pak C. Leung
发明人： Bruce E. Reynolds , Fred W. Lam , Julie Chabot , Fernando J. Antezana , Robert Bachtel , Kirk R. Gibson , Richard Threlkel , Pak C. Leung
IPC分类号： C10G6502
CPC分类号： B01J8/0492 , B01J8/0453 , B01J2208/025 , C10G49/002 , C10G65/04
摘要： A reactor system and process for hydrotreating a heavy feedstock contaminated with metals sulfur and carbon residue using an upflow fixed bed reactor with at least two catalyst layers having different hydrogenation activity.
摘要翻译：一种用于使用具有不同氢化活性的至少两个催化剂层的上流固定床反应器加氢处理被金属硫和碳残余物污染的重质原料的反应器系统和方法。

5. 发明授权

US5082551A Hydroconversion effluent separation process 失效
标题翻译：加氢转化废水分离过程
公开(公告)号：US5082551A
公开(公告)日：1992-01-21
申请号：US560223
申请日：1990-07-25
申请人： Bruce E. Reynolds , Donald A. Bea , Robert W. Bachtel
发明人： Bruce E. Reynolds , Donald A. Bea , Robert W. Bachtel
IPC分类号： C10G49/00 , C10G49/22
CPC分类号： C10G49/22 , C10G49/007
摘要： A hydroconversion effluent separation process is provided.The effluent from the hydroconversion zone is passed to a hot high pressure separation zone. The gas phase from that zone is then passed to a cold high pressure separation zone while the liquid hydrocarbon bottoms is passed to a hot low pressure separation zone. The gas phase is partially condensed in the cold high pressure separation zone to obtain a hydrogen-rich gas and a liquid hydrocarbon bottoms. A portion of the hydrogen-rich gas is recycled to the hydroconversion zone. A second portion is sent to a hydrogen purification step, most preferably by membrane separation, and the purified gas is recycled to the hydroconversion zone. The overhead from the hot low pressure separation is fed to a cold low pressure separation zone. The gas phase from the cold low pressure separation zone is recycled to the hydroconversion zone. Preferably, two cold low pressure separation zones are utilized in the process.
摘要翻译：提供加氢转化废水分离过程。来自加氢转化区的流出物被传递到热的高压分离区。然后将来自该区域的气相传递到冷的高压分离区，同时液体烃底部通入热的低压分离区。气相在冷高压分离区中部分冷凝，得到富氢气体和液态烃底物。一部分富氢气体被再循环到加氢转化区。将第二部分送至氢气净化步骤，最优选通过膜分离，并将纯化的气体再循环至加氢转化区。来自热低压分离的塔顶馏出物被送入冷的低压分离区。来自冷低压分离区的气相再循环到加氢转化区。优选地，在该过程中使用两个冷的低压分离区。

6. 发明授权

US4744888A Process for the removal of sodium from a hydrocarbon feedstock employing a catalyst system 失效
标题翻译：使用催化剂体系从烃原料中除去钠的方法
公开(公告)号：US4744888A
公开(公告)日：1988-05-17
申请号：US915457
申请日：1986-10-06
申请人： Chi-Wen Hung , Bruce E. Reynolds
发明人： Chi-Wen Hung , Bruce E. Reynolds
IPC分类号： B01J23/85 , B01J35/10 , C10G45/08 , C10G45/04 , C10G29/04
CPC分类号： B01J35/10 , B01J23/85 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/108 , C10G45/08
摘要： We disclose a catalyst system which is capable of removing sodium from a hydrocarbon feed having at least 1 ppm oil-soluble sodium. It comprises a catalyst layer characterized as a fixed bed of catalyst particles having a low volume percent of their pore volume percent in the form of macropores above 1000 .ANG. in diameter, high surface area, and high hydrogenation activity. We also disclose a process of using the system.
摘要翻译：我们公开了能够从具有至少1ppm油溶性钠的烃进料中除去钠的催化剂体系。它包括催化剂层，其特征在于催化剂颗粒的固定床，其具有孔体积百分比的低体积百分比，其直径大于1000，高表面积和高氢化活性的大孔形式。我们还披露了使用该系统的过程。

7. 发明授权

US09206361B2 Hydroprocessing catalysts and methods for making thereof 有权
标题翻译：加氢处理催化剂及其制备方法
公开(公告)号：US09206361B2
公开(公告)日：2015-12-08
申请号：US13330910
申请日：2011-12-20
申请人： Julie Chabot , Bruce E. Reynolds , Erin Maris , Shuwu Yang
发明人： Julie Chabot , Bruce E. Reynolds , Erin Maris , Shuwu Yang
IPC分类号： C10G47/26 , C10G49/02 , B01J37/20 , B01J35/00 , B01J23/883 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/02 , C10G49/12
CPC分类号： C10G49/02 , B01J23/883 , B01J35/0006 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1052 , B01J35/1066 , B01J35/1076 , B01J37/0036 , B01J37/0201 , B01J37/20 , C10G49/12 , C10G2300/208 , C10G2300/4056 , C10G2300/70 , C10G2300/708 , C10G2300/802
摘要： A method to upgrade heavy oil feedstock using an ebullated bed reactor and a novel catalyst system is provided. The ebullated bed reactor system includes two different catalyst with different characteristics: an expanded catalyst zone containing particulate catalyst having a particle size of greater than 0.65 mm; and a slurry catalyst having an average particle size ranging from 1 to 300 μm. The slurry catalyst is provided to the ebullated bed system containing the heavy oil feedstock, and entrained in the upflowing hydrocarbon liquid passing through the ebullated bed reaction zone. The slurry catalyst reduces the formation of sediment and coke precursors in the ebullating bed reactor system. The slurry catalyst is prepared from rework materials, which form a slurry catalyst in-situ upon mixing with the heavy oil feedstock.
摘要翻译：提供了一种使用沸腾床反应器和新型催化剂体系升级重油原料的方法。沸腾床反应器系统包括具有不同特性的两种不同的催化剂：包含粒度大于0.65mm的颗粒催化剂的膨胀催化剂区; 和平均粒度为1〜300μm的浆料催化剂。将浆料催化剂提供给含有重油原料的沸腾床系统，并夹带在通过沸腾床反应区的向上流动的烃液中。浆料催化剂减少沸腾床反应器系统中沉淀物和焦炭前体的形成。浆料催化剂由返工材料制备，其在与重油原料混合时原位形成浆料催化剂。

8. 发明授权

US08765622B2 Recovery of slurry unsupported catalyst 有权
标题翻译：浆料无载体催化剂的回收
公开(公告)号：US08765622B2
公开(公告)日：2014-07-01
申请号：US12004015
申请日：2007-12-20
申请人： Lalit S. Shah , Christopher A. Powers , James R. Stoy , Fred D. Brent , Bruce E. Reynolds , Andre R. Da Costa
发明人： Lalit S. Shah , Christopher A. Powers , James R. Stoy , Fred D. Brent , Bruce E. Reynolds , Andre R. Da Costa
IPC分类号： B01J38/48 , B01D61/14 , C10G31/09 , C10G31/11 , B01J27/051
CPC分类号： B01J38/48 , B01D61/142 , B01D61/147 , B01D2311/06 , B01D2315/10 , B01D2321/2058 , B01J27/051 , B01J27/0515 , B01J38/72 , C10G31/09 , C10G31/11
摘要： A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. Filtering in the deoiling zone can comprise filtering the slurry and solvent through a cross-flow microfiltration unit, recovering a retentate stream of the cross-flow microfiltration unit, combining the retentate stream of the cross-flow microfiltration unit with solvent to form a combined retentate-solvent stream, and filtering the combined retentate-solvent stream through a cross-flow microfiltration unit.
摘要翻译：从重油中回收未负载的细催化剂的方法包括将包含重油中的无载体细催化剂的浆料与溶剂组合以形成组合的浆料 - 溶剂流。将合并的浆料 - 溶剂流在脱油区中过滤。从脱油区回收包含未负载的细催化剂和溶剂的料流。将不负载的细催化剂与包含无载体的细催化剂和溶剂的流分离。在除油区域中的过滤可以包括通过交叉流微量过滤单元过滤浆料和溶剂，回收交叉流微量过滤单元的滞留物流，将交联流微量微滤单元的滞留物流与溶剂组合以形成组合的滞留物并通过交叉流微量过滤装置过滤组合的滞留物 - 溶剂流。

9. 发明授权

US07678732B2 Highly active slurry catalyst composition 有权
标题翻译：高活性浆料催化剂组合物
公开(公告)号：US07678732B2
公开(公告)日：2010-03-16
申请号：US12212483
申请日：2008-09-17
申请人： Kaidong Chen , Bruce E. Reynolds , Darush Farshid
发明人： Kaidong Chen , Bruce E. Reynolds , Darush Farshid
IPC分类号： B01J27/051
CPC分类号： B01J23/85 , B01J27/049 , B01J27/0515 , B01J37/03 , B01J37/20 , C10G49/04
摘要： The instant invention is directed to the preparation of a slurry catalyst composition. The slurry catalyst composition is prepared in a series of steps, involving mixing a Group VIB metal oxide and aqueous ammonia to form an aqueous mixture and sulfiding the mixture to form a slurry. The slurry is then promoted with a Group VIII metal. Subsequent steps involve mixing the slurry with a hydrocarbon oil, and combining the resulting mixture with hydrogen gas (under conditions which maintain the water in a liquid phase) to produce the active slurry catalyst.
摘要翻译：本发明涉及制备淤浆催化剂组合物。浆料催化剂组合物是以一系列步骤制备的，包括将VIB族金属氧化物与氨水混合以形成含水混合物并硫化混合物以形成浆料。然后用VIII族金属促进该浆料。随后的步骤包括将浆料与烃油混合，并将所得混合物与氢气（在将水保持在液相中的条件下）组合以产生活性淤浆催化剂。

10. 发明申请

US20090163347A1 Recovery of slurry unsupported catalyst 有权
标题翻译：浆料无载体催化剂的回收
公开(公告)号：US20090163347A1
公开(公告)日：2009-06-25
申请号：US12004015
申请日：2007-12-20
申请人： Lalit S. Shah , Christopher A. Powers , James R. Stoy , Fred D. Brent , Bruce E. Reynolds , Andre R. Da Costa
发明人： Lalit S. Shah , Christopher A. Powers , James R. Stoy , Fred D. Brent , Bruce E. Reynolds , Andre R. Da Costa
IPC分类号： B01J38/72
CPC分类号： B01J38/48 , B01D61/142 , B01D61/147 , B01D2311/06 , B01D2315/10 , B01D2321/2058 , B01J27/051 , B01J27/0515 , B01J38/72 , C10G31/09 , C10G31/11
摘要： A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. Filtering in the deoiling zone can comprise filtering the slurry and solvent through a cross-flow microfiltration unit, recovering a retentate stream of the cross-flow microfiltration unit, combining the retentate stream of the cross-flow microfiltration unit with solvent to form a combined retentate-solvent stream, and filtering the combined retentate-solvent stream through a cross-flow microfiltration unit.
摘要翻译：从重油中回收未负载的细催化剂的方法包括将包含重油中的无载体的细催化剂的浆料与溶剂组合以形成组合的浆料 - 溶剂流。将合并的浆料 - 溶剂流在脱油区中过滤。从脱油区回收包含未负载的细催化剂和溶剂的料流。将不负载的细催化剂与包含无载体的细催化剂和溶剂的流分离。在脱油区中的过滤可以包括通过交叉流微量过滤单元过滤浆料和溶剂，回收交叉流微量过滤单元的滞留物流，将交联流微量过滤单元的滞留物流与溶剂组合以形成组合的滞留物并通过交叉流微量过滤装置过滤组合的滞留物 - 溶剂流。

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