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1. 发明申请

US20130190432A1 Flame Retardant-Stabilizer Combination For Thermoplastic Polymers 审中-公开
标题翻译：阻燃稳定剂组合热塑性聚合物
公开(公告)号：US20130190432A1
公开(公告)日：2013-07-25
申请号：US13878145
申请日：2011-09-30
申请人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K5/5313 , C08K5/3492 , C08K5/10 , C08K3/22 , C08K5/5317 , C08K5/56 , C08K5/52 , C08K3/38
CPC分类号： C08K5/5313 , C08K3/22 , C08K3/38 , C08K5/0008 , C08K5/10 , C08K5/34922 , C08K5/34924 , C08K5/52 , C08K5/5317 , C08K5/56
摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
摘要翻译：一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

2. 发明申请

US20090137707A1 Mixed salts of diorganylphosphinic acids and carboxylic acids 有权
标题翻译：二有机基次膦酸和羧酸的混合盐
公开(公告)号：US20090137707A1
公开(公告)日：2009-05-28
申请号：US12313523
申请日：2008-11-21
申请人： Harald Bauer , Werner Krause , Wolfgang Wanzke
发明人： Harald Bauer , Werner Krause , Wolfgang Wanzke
IPC分类号： C09K21/12 , C07F19/00
CPC分类号： C07F9/301 , C07C63/28 , C08K5/0066 , C08K5/5313 , C08L21/00
摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.
摘要翻译：本发明涉及二有机基次膦酸和羧酸的混合物，其结构式为：α-in-line-formula description =“In-line Formulas”end =“lead”→[cationn +（phosphinate-）x（carboxylic acid anionz-1 / z）y] <？in-line-formula description =“In-line Formulas”end =“tail”？>其中n = 1至4 x =从0.01到n-0.01 y = nx z =从1到4 其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素，第五主元素和/或过渡基团的元素和/ 或过渡组，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子，其中R 1和R 2相同或不同且彼此独立地为H，C 1 -C 6 - 烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸a 国王本发明还涉及其生产方法及其用途。

3. 发明授权

US08221658B2 Mixed salts of diorganylphosphinic acids and carboxylic acids 有权
标题翻译：二有机基次膦酸和羧酸的混合盐
公开(公告)号：US08221658B2
公开(公告)日：2012-07-17
申请号：US12313523
申请日：2008-11-21
申请人： Harald Bauer , Werner Krause , Wolfgang Wanzke
发明人： Harald Bauer , Werner Krause , Wolfgang Wanzke
IPC分类号： C09K21/00 , C09K21/04 , C07F9/28
CPC分类号： C07F9/301 , C07C63/28 , C08K5/0066 , C08K5/5313 , C08L21/00
摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.
摘要翻译：本发明涉及二有机基次膦酸和具有式[阳离子+（次膦酸盐））x（羧酸阴离子z-1 / z）y]的羧酸的混合物，其中n = 1至4×= 0.01至n-0.01y = n -xz =从1到4，其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素，第五主转移组和/或过渡组的元素，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子其中R 1和R 2相同或不同，并且彼此独立地为H，C 1 -C 6烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸阴离子本发明还涉及其生产方法及其用途。

4. 发明申请

US20050101704A1 Flame retardant additive for polymers compounds with improved hydro-thermal stability 审中-公开
标题翻译：具有改善的水热稳定性的聚合物化合物的阻燃添加剂
公开(公告)号：US20050101704A1
公开(公告)日：2005-05-12
申请号：US10839991
申请日：2004-05-06
申请人： Frank Eisentraeger , Werner Krause , Sebastian Hoerold , Wolfgang Wanzke , Peter Anna , Gyoergy Bertalan , Gyoergy Marosi , Andrea Marton , Emese Zimonyi
发明人： Frank Eisentraeger , Werner Krause , Sebastian Hoerold , Wolfgang Wanzke , Peter Anna , Gyoergy Bertalan , Gyoergy Marosi , Andrea Marton , Emese Zimonyi
IPC分类号： C09K21/04 , C08K3/32 , C08K5/54 , C08L101/00 , C09K21/12 , C09K21/14 , C08K5/34 , C08K5/49
CPC分类号： C08K3/32 , C09K21/12
摘要： The invention relates to a flame retardant polymer compound comprising from 50-95 wt % polymer matrix related to the total amount of the flame retardant polymeric compound and 5-50 wt % of flame retardant additive system related to the total amount of the flame retardant polymeric compound.
摘要翻译：本发明涉及一种阻燃聚合物化合物，其包含与阻燃聚合物的总量相关的50-95重量％的聚合物基质和5-50重量％的与阻燃聚合物总量相关的阻燃添加剂体系复合。

5. 发明申请

US20100190901A1 Alkylphosphonous Acids, Salts and Esters, Methods for the Production Thereof, and Use of the Same 有权
标题翻译：烷基亚磷酸，盐和酯，其生产方法及其用途
公开(公告)号：US20100190901A1
公开(公告)日：2010-07-29
申请号：US12668814
申请日：2008-07-02
申请人： Michael Hill , Harald Bauer , Werner Krause
发明人： Michael Hill , Harald Bauer , Werner Krause
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C07F9/4866 , C07F9/4816 , C07F9/485 , C08K5/5393
摘要： The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(═O)(OX)—H (I) wherein A is C2-C20alkyl, C2-C20alkylene, and C8-C20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
摘要翻译：本发明涉及烷基亚磷酸，其中A是C 2 -C 20烷基，C 2 -C 20亚烷基和C 8 -C 20烷芳基的式（I）AP（= O）（OX）-H（I）的烷基亚磷酸，盐和酯，是烷基，芳基，烷基芳基，烯基，取代的烷基，芳基，烷芳基，烯基，铵，伯，仲，叔，季烷基和/或芳基铵，碱金属，碱土金属，第三和第四主要组和第二，第四和第八子组或镧系元素的金属。本发明还涉及其生产方法和所述化合物的用途。

6. 发明授权

US07420007B2 Dialkylphosphinic salts 有权
标题翻译：二烷基次膦酸盐
公开(公告)号：US07420007B2
公开(公告)日：2008-09-02
申请号：US11015195
申请日：2004-12-17
申请人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
发明人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
IPC分类号： C08K5/5313
CPC分类号： C07F9/301 , C08K5/34928 , C08K5/5313 , C08L21/00
摘要： The invention relates to dialkylphosphinic salts of the formula (I) where R1, R2 identical or different, are C1-C6-alkyl, linear or branched M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or is a protonated nitrogen base; m is from 1 to 4; wherein the telomer content is from 0.01 to 6% by weight. The invention also relates to glare use in flame retardant compositions, and to flame-retardant polymer molding compositions and flame-retardant polymer moldings which comprise these dialkylphosphinic salts.
摘要翻译：本发明涉及式（I）的二烷基次膦酸盐，其中R 1，R 2，R 2相同或不同，为C 1 -C 3 直链或支链M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/ 是质子化的氮基; m为1〜4; 其中调聚物含量为0.01至6重量％。本发明还涉及阻燃组合物中的眩光用途，以及包含这些二烷基次膦酸盐的阻燃聚合物模塑组合物和阻燃聚合物模制品。

7. 发明申请

US20080146708A1 Salts of asymmetrically substituted bis (1-hydroxymethyl)phosphinic acids 审中-公开
标题翻译：不对称取代的双（1-羟甲基）次膦酸的盐
公开(公告)号：US20080146708A1
公开(公告)日：2008-06-19
申请号：US12002136
申请日：2007-12-14
申请人： Harald Bauer , Werner Krause , Wiebke Maas
发明人： Harald Bauer , Werner Krause , Wiebke Maas
IPC分类号： C08K5/51 , C07F9/30
CPC分类号： C09K21/12 , C07F9/301 , C08K5/5313
摘要： The invention relates to salts of asymmetrically substituted bis(1-hydroxymethyl)phosphinic acids, of the formula (I) A-P(═O)(OX)—B (I) in whichA is R1R2C(OH)— and B is R3R4C(OH)—, with the proviso that the respective groups R1R2C(OH)— and —C(OH)R3R4 are always different, and where R1, R2, R3, and R4 are hydrogen, alkyl, alkenyl, alkynyl, aralkyl, aryl and/or substituted aryl, andX is an element of the first main group, an element of the second main or transition group, an element of the third main or transition group, an element of the fourth main or transition group, an element of the eighth transition group and/ora nitrogen base.
摘要翻译：本发明涉及不对称取代的双（1-羟甲基）次膦酸的式（I）的化合物<？in-line-formula description =“In-line formula”end =“lead”？> AP（-O）（OX）-B（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A是R 1 R 2 C（OH） - 和B是R 3 R 4 C（OH） - ，条件是各个基团R 1， R 2 C（OH） - 和-C（OH）R 3 R 4 R 3总是不同的，并且其中R 1， R 2，R 3，R 3和R 4是氢，烷基，烯基，炔基，芳烷基，芳基和/或取代的芳基，X是第一主要组分的元素，第二主要或转移基团的元素，第三主要或转移基团的元素，第四主体或转移基团的元素，第八过渡组的元素和/或氮碱。

8. 发明授权

US07259200B2 Phosphorus-containing flame retardant agglomerates 有权
标题翻译：含磷阻燃剂
公开(公告)号：US07259200B2
公开(公告)日：2007-08-21
申请号：US10959515
申请日：2004-10-06
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313
CPC分类号： C08K5/0066 , C08J3/223 , C08J2367/02 , C08J2377/02 , C08J2377/06 , C08K5/5313
摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.
摘要翻译：本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基，直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，和b）0.01至20重量％的助剂。本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

9. 发明申请

US20060214144A1 Phosphorus-containing thermally stabilized flame retardant agglomerates 审中-公开
标题翻译：含磷热稳定阻燃剂团聚体
公开(公告)号：US20060214144A1
公开(公告)日：2006-09-28
申请号：US11388916
申请日：2006-03-24
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause
IPC分类号： C09K21/00
CPC分类号： C08K5/5313 , C08K5/3492
摘要： The invention relates to phosphorus-containing thermally stabilized flame retardant agglomerates, comprising as component A from 6 to 99.99% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II), and/or of their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Zn, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4; as component B from 0 to 90% by weight of a synergist which comprises a nitrogen compound or which comprises a phosphorus compound, or which comprises a phosphorus-nitrogen compound; as component C from 0 to 20% by weight of compounds of the elements of the second main and transition group; and as component D from 0.01 to 20% by weight of auxiliary. The invention also relates to a process for their production, and to their use.
摘要翻译：本发明涉及含磷热稳定的阻燃附聚物，其包含作为组分A的6至99.99重量％的由式（I）的次膦酸盐和/或由式（I）的次膦酸盐组成的聚集体和/或一次颗粒和/ 式（II）和/或它们的聚合物，其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基，和 /或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Zn，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1〜4; 作为组分B的0至90重量％的增效剂，其包含氮化合物或包含磷化合物，或包含磷 - 氮化合物; 作为组分C的0至20重量％的第二主要和过渡基团的元素的化合物; 并且作为组分D为辅助剂的0.01至20重量％。本发明还涉及其生产方法及其用途。

10. 发明授权

US09279085B2 Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof 有权
标题翻译：用于制备单官能二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US09279085B2
公开(公告)日：2016-03-08
申请号：US13140555
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C07F9/02 , C07F9/22 , C07F9/28 , C08K5/53 , C09K21/12 , C07F9/30 , C07F9/32 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.
摘要翻译：本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。还公开了所述二烷基膦酸，酯和盐的用途。

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