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1. 发明授权

US09279085B2 Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof 有权
标题翻译：用于制备单官能二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US09279085B2
公开(公告)日：2016-03-08
申请号：US13140555
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C07F9/02 , C07F9/22 , C07F9/28 , C08K5/53 , C09K21/12 , C07F9/30 , C07F9/32 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.
摘要翻译：本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。还公开了所述二烷基膦酸，酯和盐的用途。

2. 发明授权

US08592505B2 Hydrophosphorylation of phosphonous acid derivatives for flame retardants 有权
标题翻译：用于阻燃剂的膦酸衍生物的氢磷酸化
公开(公告)号：US08592505B2
公开(公告)日：2013-11-26
申请号：US13140563
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08K5/00 , C08K5/53 , C07F5/02 , C07F9/28
CPC分类号： C09K21/12 , A01N57/20 , A01N57/22 , B27K3/15 , B27K2240/30 , C07F9/4006 , C07F9/4093 , C07F9/505 , C07F9/5072 , C08K5/5393 , C08L77/00 , C08L97/02 , C09D5/086 , C09D5/185
摘要： Addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(═O)(OX)—H (I) and b) diester-forming olefins of formula (II) Methods for the production of the addition compounds and the use thereof are also disclosed.
摘要翻译： a）a）式AP（= O）（OX）-H（I）的烷基亚膦酸衍生物和b）式（II）的二酯形成烯烃的加成化合物加成化合物的制备方法及其用途也披露

3. 发明授权

US08293938B2 Alkylphosphonous acids, salts and esters, methods for the production thereof, and use of the same 有权
标题翻译：烷基亚磷酸，盐和酯，其制备方法及其用途
公开(公告)号：US08293938B2
公开(公告)日：2012-10-23
申请号：US12668814
申请日：2008-07-02
申请人： Michael Hill , Harald Bauer , Werner Krause
发明人： Michael Hill , Harald Bauer , Werner Krause
IPC分类号： C07F9/28
CPC分类号： C07F9/4866 , C07F9/4816 , C07F9/485 , C08K5/5393
摘要： The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(═O)(OX)—H (I) wherein A is C2-C20alkyl, C2-C20alkylene, and C8-C20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
摘要翻译：本发明涉及烷基亚磷酸，其中A是C 2 -C 20烷基，C 2 -C 20亚烷基和C 8 -C 20烷芳基的式（I）AP（= O）（OX）-H（I）的烷基亚磷酸，盐和酯，是烷基，芳基，烷基芳基，烯基，取代的烷基，芳基，烷芳基，烯基，铵，伯，仲，叔，季烷基和/或芳基铵，碱金属，碱土金属，第三和第四主要组和第二，第四和第八子组或镧系元素的金属。本发明还涉及其生产方法和所述化合物的用途。

4. 发明申请

US20100190901A1 Alkylphosphonous Acids, Salts and Esters, Methods for the Production Thereof, and Use of the Same 有权
标题翻译：烷基亚磷酸，盐和酯，其生产方法及其用途
公开(公告)号：US20100190901A1
公开(公告)日：2010-07-29
申请号：US12668814
申请日：2008-07-02
申请人： Michael Hill , Harald Bauer , Werner Krause
发明人： Michael Hill , Harald Bauer , Werner Krause
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C07F9/4866 , C07F9/4816 , C07F9/485 , C08K5/5393
摘要： The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(═O)(OX)—H (I) wherein A is C2-C20alkyl, C2-C20alkylene, and C8-C20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
摘要翻译：本发明涉及烷基亚磷酸，其中A是C 2 -C 20烷基，C 2 -C 20亚烷基和C 8 -C 20烷芳基的式（I）AP（= O）（OX）-H（I）的烷基亚磷酸，盐和酯，是烷基，芳基，烷基芳基，烯基，取代的烷基，芳基，烷芳基，烯基，铵，伯，仲，叔，季烷基和/或芳基铵，碱金属，碱土金属，第三和第四主要组和第二，第四和第八子组或镧系元素的金属。本发明还涉及其生产方法和所述化合物的用途。

5. 发明申请

US20110251315A1 Method for the Production of Monofunctionalized Dialkylphosphinic Acids, Esters and Salts, and Use Thereof 有权
标题翻译：单官能二烷基次膦酸，酯和盐的制备方法及其用途
公开(公告)号：US20110251315A1
公开(公告)日：2011-10-13
申请号：US13140555
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/32 , C07F9/30
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.
摘要翻译：本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。还公开了所述二烷基膦酸，酯和盐的用途。

6. 发明申请

US20110213052A1 Method for Producing Dialkylphosphinic Acids and Esters and Salts Thereof by Means of Acrylic Acid Derivatives and Use Thereof 有权
标题翻译：通过丙烯酸衍生物生产二烷基次膦酸及其酯及其盐的方法及用途
公开(公告)号：US20110213052A1
公开(公告)日：2011-09-01
申请号：US13127102
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08L63/00 , C07F9/30 , C07F9/32 , C07F5/06 , C07F7/28 , C08G63/183 , C08L67/02 , C08G59/02 , C08G69/26 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the alkylphosphonic acid thus obtained, salt or ester (II) thereof is reacted with an α,β-unsaturated carboxylic acid derivative (V) to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应得到烷基膦酸，盐或酯（Ⅱ）在催化剂A存在下，将所得的烷基膦酸，其盐或酯（II）与α，β-不饱和羧酸衍生物（V）反应，得到单羧基官能化的二烷基次膦酸衍生物（ III）在催化剂B存在下，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同，彼此独立地表示H，C 1 -C 18烷基， C18芳基，C6-C18芳烷基，C6-C18烷基芳基，X和Y相同或不同，并且H，C1-C18烷基，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱催化剂A由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

7. 发明授权

US08664418B2 Method for producing dialkylphosphinic acids and esters and salts thereof by means of acrylic acid derivatives and use thereof 有权
标题翻译：通过丙烯酸衍生物及其用途制备二烷基次膦酸及其酯及其盐的方法
公开(公告)号：US08664418B2
公开(公告)日：2014-03-04
申请号：US13127102
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C07F9/30 , C07F5/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the alkylphosphonic acid thus obtained, salt or ester (II) thereof is reacted with an α,β-unsaturated carboxylic acid derivative (V) to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸，盐或酯（II）在催化剂A存在下，b）将由此得到的烷基膦酸，其盐或酯（II）与α，β-不饱和羧酸衍生物（V）反应，得到单羧基官能化的二烷基次膦酸衍生物（III ），其中R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同并且彼此独立地表示，其中，H，C 1 -C 18烷基，C 6 -C 18 芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X和Y相同或不同并且独立地为H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基， Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱，并且催化剂A由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

8. 发明申请

US20110251310A1 Hydrophosphorylation of Phosphonous Acid Derivatives for Flame Retardants 有权
公开(公告)号：US20110251310A1
公开(公告)日：2011-10-13
申请号：US13140563
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08K5/1539 , C07F9/655 , C08K5/5393 , C07F9/48
CPC分类号： C09K21/12 , A01N57/20 , A01N57/22 , B27K3/15 , B27K2240/30 , C07F9/4006 , C07F9/4093 , C07F9/505 , C07F9/5072 , C08K5/5393 , C08L77/00 , C08L97/02 , C09D5/086 , C09D5/185
摘要： The invention relates to addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(═O)(OX)—H (I) in which A represents C2-C18-alkyl, C2-C18-alkylene, C6-C18-arylalkyl, C6-C18-arylalkyl, optionally substituted, and X represents H, C1-C18-alkyl, C6-C18-aryl, C6-C18-arylalkyl, C6-C18-alkylaryl, optionally substituted C2-C18-alkylene, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H and/or a protonated nitrogenous base, and b) diester-forming olefins of formula (II) in which R2, R4 are identical or different from each other and represent CO2H, CO2R5, R6—CO2H, R6—CO2R5 and R1, R3 are identical or different from each other and represent H, R5; or R1, R4 are identical or different from each other and represent CO2H, CO2R5, R6—CO2H, R6—CO2R5 and R2, R3 are identical or different from each other and represent H, R5; or R2, R4 are identical or different from each other and represent —CO—O—CO—, —CO—S—CO—, —CO—NR1—CO—, —CO—PR1—CO— and R1, R3 are identical or different from each other and represent H, R5; or R1, R2 are identical or different from each other and represent CO2H, CN, CO2R5, R6—CO2H, R6—CO2R5 and R3, R4 are identical or different from each other and represent H, R5; or R1, R2 are identical or different from each other and represent —CR23—CO—O—CO—, —CR23—CO—NR1—CO—, —CR23—CO—O—CO-CR23, —CR23—CO—NR1—CO—CR23 and R3, R4 are identical or different from each other and represent H, R5; or R2 and R4 each represent —CO—CR5═CR5—CO— and R1, R3 are identical or different from each other and represent H, R5; R5═C1-C18-alkyl, C6-C18-aryl, C6-C18-arylalkyl, C6-C18-alkylaryl; R6═C2-C18-alkylene, C6-C18-arylene, C6-C18-alkarylene and/or C6-C18-aralkylene. Methods for the production of said addition compounds and the use thereof are also disclosed.

9. 发明申请

US20080214708A1 Asymmetrically substituted phosphinic acids 审中-公开
标题翻译：不对称取代的次膦酸
公开(公告)号：US20080214708A1
公开(公告)日：2008-09-04
申请号：US11904902
申请日：2007-09-28
申请人： Harald Bauer , Michael Hill , Werner Krause
发明人： Harald Bauer , Michael Hill , Werner Krause
IPC分类号： C07F9/141 , C08K5/5317
CPC分类号： C09K21/12 , C07F9/301 , C08K5/5313
摘要： The invention relates to asymmetrically substituted phosphinic acids of the formula (I) R1R2C(OH)—P(═O)(OX)—C(OH)R3R4 (I) in which X is hydrogen R1, R2, R3, and R4 are identical or different and are hydrogen, alkyl, alkenyl, alkynyl, aralkyl, aryl and/or alkaryl, with the proviso that the respective R1R2C(OH)— and —C(OH)R3R4 groups are always different, to a process for their preparation, and to their use.
摘要翻译：本发明涉及式（I）的不对称取代的次膦酸：<？in-line-formula description =“In-line Formulas”end =“lead”→> R＆lt; 1＆lt; 2＆gt; C（OH）-P（-O）（OX）-C（OH）R 3 R 4（I）<β在线式 description =“In-line Formulas”end =“tail”？>其中X是氢R 1，R 2，R 3，和R 4相同或不同，为氢，烷基，烯基，炔基，芳烷基，芳基和/或烷芳基，条件是相应的R 1 R > 2个C（OH） - 和-C（OH）R 3 R 4个4个基团总是不同于其制备方法，以及它们使用。

10. 发明授权

US08987489B2 Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether and the use thereof 有权
标题翻译：使用乙烯基醚制备单羧基官能化二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US08987489B2
公开(公告)日：2015-03-24
申请号：US13132196
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C07F9/30 , C07F9/48 , C08K5/5313 , C09K21/12 , C08L21/00
CPC分类号： C07F9/30 , C07F9/301 , C07F9/32 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C08L21/00 , C09K21/12
摘要： A method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ether of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting this derivative (VI) with an oxidant or in the presence of a catalyst C to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein the catalysts A and C are transition metals and/or transition metal compounds, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound.
摘要翻译：使用乙烯基醚制备单羧基官能化的二烷基次膦酸，酯和盐的方法。该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使所得的烷基亚磷酸，其盐或其酯（II）与式（V）的乙烯基醚在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（VI），和c）使该衍生物 VI）与氧化剂或催化剂C的存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III），其中催化剂A和C为过渡金属和/或过渡金属化合物，催化剂B为过氧化物形成化合物和/或过氧化合物和/或偶氮化合物。

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