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1. 发明授权

US06197147B1 Process for continuous production of membrane-electrode composites 有权
标题翻译：连续生产膜 - 电极复合材料的方法
公开(公告)号：US06197147B1
公开(公告)日：2001-03-06
申请号：US09091659
申请日：1999-04-05
申请人： Harald Bönsel , Joachim Clauss , Gregor Deckers , Georg Frank , Arnold Schneller , Helmut Witteler , Mike Römmler , Michael Heine
发明人： Harald Bönsel , Joachim Clauss , Gregor Deckers , Georg Frank , Arnold Schneller , Helmut Witteler , Mike Römmler , Michael Heine
IPC分类号： B32B3100
CPC分类号： H01M4/926 , C25B9/10 , H01M4/90 , H01M4/92 , H01M8/0213 , H01M8/1004 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , Y02P70/56 , Y10T156/1084
摘要： A process for producing laminates which contain at least one centrally arranged, ion-conductive membrane which is, at least over a substantial part of its two mutually opposite flat faces, electrically conductively bonded to at least one catalytically active substance and to at least one two-dimensional, gas-permeable, electron-conductive contacting material, the bonding of at least two of the said components having been effected by lamination. The process comprises carrying out the bonding of the ion-conductive membrane, of the catalytically active substance and of the electron-conductive contacting material continuously. The ion-conductive membrane is brought together with at least the electron-conductive contacting material in the exact position by means of transport and feeding devices and the two components are laminated and bonded to one another by pressing them together. The range of variation in the a.c. resistances of the laminates produced by the process according to the invention is ±10%. The laminates are particularly suitable for use in fuel cells or electrolysers.
摘要翻译：一种制备层压体的方法，其包含至少一个中心布置的离子传导膜，其至少在其两个相互相对的平坦表面的至少大部分上与导电键合至至少一种催化活性物质和至少一种二三维，透气，电子传导的接触材料，至少两个所述组分的结合已通过层压实现。该方法包括连续地进行催化活性物质和电子传导性接触材料的离子传导膜的接合。离子传导膜通过输送和进料装置与至少电子传导接触材料在精确位置一起被带到一起，并且两个部件通过将它们压在一起而彼此层压并结合。 a.c.的变化范围。根据本发明的方法生产的层压体的电阻为±10％。层压板特别适用于燃料电池或电解槽。

2. 发明申请

US20070132128A1 Method of producing carbon fibers, and methods of making protective clothing and a filter module 失效
标题翻译：生产碳纤维的方法，以及制作防护服的方法和过滤器模块
公开(公告)号：US20070132128A1
公开(公告)日：2007-06-14
申请号：US11656259
申请日：2007-01-22
申请人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
发明人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
IPC分类号： D01F8/00
CPC分类号： D01F9/22
摘要： Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要翻译：多孔碳纤维，其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成，可通过有机或无机聚合物的碳化获得，其用于吸附或分离气态物质，特别是CO 2 2，以及其制备方法。首先，制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。接下来，将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。接着在非氧化条件下使混合纤维碳化或石墨化，使得聚合物B形成至少22重量％的碳和/或金属和/或金属碳化物残余物，残余物形成活性中心。

3. 发明授权

US07105111B2 Process for producing hollow bodies comprising fibre-reinforced ceramic materials 有权
标题翻译：包含纤维增强陶瓷材料的中空体的制造方法
公开(公告)号：US07105111B2
公开(公告)日：2006-09-12
申请号：US10256492
申请日：2002-09-26
申请人： Moritz Bauer , Michael Heine , Udo Gruber , Ronald Huener , Andreas Kienzle , Andreas Rahn , Rainer Zimmermann-Chopin
发明人： Moritz Bauer , Michael Heine , Udo Gruber , Ronald Huener , Andreas Kienzle , Andreas Rahn , Rainer Zimmermann-Chopin
IPC分类号： C01B31/00
CPC分类号： F16D69/023 , B29C43/006 , B29C2043/3668 , C04B35/565 , C04B35/573 , C04B35/83 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/48 , C04B2235/5248 , C04B2235/526 , C04B2235/5268 , C04B2235/5272 , C04B2235/6028 , C04B2235/728 , C04B2235/80 , C04B2235/94 , F16D13/64 , F16D65/12 , F16D2200/0052
摘要： Process for producing hollow bodies comprising fibre-reinforced ceramic materials, where cores whose shape corresponds to that of the hollow spaces are produced in a first step, a green body is produced in a second step by introducing the abovementioned cores and a press moulding compound into a mould, where the press moulding compound comprises carbon fibres and/or carbon threads and pitch and/or resins, the green body is cured in a third step by heating under pressure, and then carbonised in a fourth step by heating in the absence of oxidants to form a C/C body, which latter can be infiltrated with liquid metal with retention of its shape in a fifth step, with at least partial formation of carbides, where the cores comprise a material which is non-meltable but undergoes at least sufficient shrinkage above the curing temperature of the shaping by pressing of the press moulding compound for the shrunken core to be able to be taken out from the carbonised body; hollow bodies produced by this process and also their use as brake disks, clutch disks and friction disks
摘要翻译：制造中空体的方法，其中纤维强化陶瓷材料的形状对应于中空空间的芯体在第一步骤中生产，在第二步骤中，通过将上述芯体和压模化合物引入模具，其中压模成型料包括碳纤维和/或碳线和沥青和/或树脂，生坯在第三步骤中通过在加压下加热固化，然后在第四步骤中通过在不存在氧化剂形成C / C体，后者可以用液态金属渗透，并在第五步中保持其形状，至少部分形成碳化物，其中芯包含不可熔化但经历至少通过压缩用于收缩芯的加压模塑料能够从碳化体中取出而使成形的固化温度以上的充分收缩; 通过该方法生产的中空体以及它们用作制动盘，离合器盘和摩擦盘

4. 发明申请

US20050179152A1 PROCESS FOR PRODUCING SHAPED BODIES COMPRISING FIBER-REINFORCED CERAMIC MATERIALS 有权
标题翻译：生产包含纤维增强陶瓷材料的成形体的方法
公开(公告)号：US20050179152A1
公开(公告)日：2005-08-18
申请号：US10328659
申请日：2002-12-23
申请人： Moritz Bauer , Michael Heine , Andreas Kienzle , Ronald Huener , Rainer Zimmermann-Chopin , Andreas Rahn
发明人： Moritz Bauer , Michael Heine , Andreas Kienzle , Ronald Huener , Rainer Zimmermann-Chopin , Andreas Rahn
IPC分类号： F16D13/64 , C04B35/573 , C04B35/64 , C04B35/80 , C04B35/83 , F16D65/12 , F16D69/02 , C01B31/02 , B32B5/00
CPC分类号： F16D65/125 , C04B35/573 , C04B35/806 , C04B35/83 , F16D69/023 , F16D2200/0039 , F16D2200/0052 , F16D2200/006 , Y10T428/249927 , Y10T428/249928
摘要： Process for producing shaped bodies comprising fiber-reinforced ceramic materials, where a green body is produced in a first step by introducing a press moulding composition into a mold, where the press moulding composition comprises carbon fibers and/or carbon filaments and pitch and/or resins which, when treated thermally and with the exclusion of oxidizing agents, form carbon-containing residues, the green body is cured in a second step by heating to a temperature of from 120° C. to 280° C. under pressure, the cured green body, also referred to as intermediate body, is carbonized in a third step by heating in a nonoxidizing atmosphere to a temperature of from about 750° C. to about 1100° C. to form a C/C body, wherein heating in the first, second and/or third step is at least partly effected by an electric current being passed through the pressable composition, the green body and/or the cured green body, shaped bodies produced according to this process and their use as brake disks, clutch disks and friction disks
摘要翻译：包括纤维增强陶瓷材料的成型体的制造方法，其中通过将压制成型组合物引入模具中，在第一步骤中生产生坯，其中所述压制成型组合物包含碳纤维和/或碳丝，沥青和/或在热处理和排除氧化剂的情况下，形成含碳残留物的树脂在第二步骤中通过在压力下加热至120℃至280℃的温度而固化，固化也称为中间体的生坯通过在非氧化气氛中加热至约750℃至约1100℃的温度而在第三步骤中碳化以形成C / C体，其中在第一，第二和/或第三步骤至少部分地通过通过可挤压组合物，生坯和/或固化的生坯体的电流，根据该方法制造的成形体及其作为制动器的用途 ks，离合器盘和摩擦盘

5. 发明授权

US07219776B2 Friction disc and process for producing the same 有权
标题翻译：摩擦盘及其制造方法
公开(公告)号：US07219776B2
公开(公告)日：2007-05-22
申请号：US10125083
申请日：2002-04-18
申请人： Moritz Bauer , Bodo Benitsch , Martin Christ , Udo Gruber , Michael Heine , Andreas Kienzle , Jens Rosenlöcher , Rainer Zimmermann-Chopin
发明人： Moritz Bauer , Bodo Benitsch , Martin Christ , Udo Gruber , Michael Heine , Andreas Kienzle , Jens Rosenlöcher , Rainer Zimmermann-Chopin
IPC分类号： F16D66/00
CPC分类号： F16D66/02 , F16D65/126 , F16D2069/002 , F16D2200/0039 , F16D2200/0052 , F16D2200/006
摘要： A friction disc, in particular a brake or clutch disc, includes carbon fiber-reinforced ceramic composite material with at least one top surface formed as a friction surface. At least part of the friction surface is formed of a different material, in particular of a carbon-containing material. The different material exhibits lower wear and oxidation resistance than that of the rest of the friction surface and a supporting zone of the friction disc. A visual, audible or mechanical signal is produced under operating conditions due to comparatively greater wear. The signal provides a warning that the service life of the friction disc is being exceeded. A process for producing the friction disc is also provided.
摘要翻译：摩擦盘，特别是制动器或离合器盘，包括碳纤维增强陶瓷复合材料，其中至少一个顶表面形成为摩擦表面。摩擦表面的至少一部分由不同的材料形成，特别是含碳材料。不同的材料表现出比摩擦面的其余部分和摩擦盘的支撑区域更低的耐磨性和抗氧化性。由于相对较大的磨损，在操作条件下产生视觉，听觉或机械信号。该信号提示警告说摩擦盘的使用寿命被超过。还提供了制造摩擦盘的方法。

6. 发明授权

US06908667B2 Fiber-reinforced material composed, at least in a surface region, of a metal/ceramic composite, molding composed of the fiber-reinforced material and method of producing the fiber-reinforced material 失效
标题翻译：至少在表面区域中由金属/陶瓷复合材料构成的纤维增强材料，由纤维增强材料构成的成型体和制造纤维增强材料的方法
公开(公告)号：US06908667B2
公开(公告)日：2005-06-21
申请号：US10179481
申请日：2002-06-25
申请人： Martin Christ , Michael Heine , Andreas Kienzle , Rainer Zimmermann-Chopin
发明人： Martin Christ , Michael Heine , Andreas Kienzle , Rainer Zimmermann-Chopin
IPC分类号： C04B35/571 , C04B35/573 , C04B35/628 , C04B35/80 , C04B35/83 , C04B41/51 , C04B41/52 , C04B41/88 , C04B41/89 , F16D69/02 , D04H1/00
CPC分类号： C04B35/62884 , C04B35/565 , C04B35/571 , C04B35/573 , C04B35/62863 , C04B35/62873 , C04B35/806 , C04B35/83 , C04B41/009 , C04B41/4564 , C04B41/51 , C04B41/5127 , C04B41/52 , C04B41/88 , C04B41/89 , C04B2111/00362 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/40 , C04B2235/404 , C04B2235/405 , C04B2235/407 , C04B2235/408 , C04B2235/422 , C04B2235/428 , C04B2235/5224 , C04B2235/5232 , C04B2235/5236 , C04B2235/5244 , C04B2235/728 , C04B2235/75 , C04B2235/80 , F16D69/02 , Y10T428/213 , Y10T428/24273 , Y10T428/249924 , Y10T428/249927 , Y10T428/249951 , Y10T428/252 , Y10T428/2918 , Y10T428/2949 , Y10T428/31 , C04B41/5144 , C04B41/5133 , C04B41/522 , C04B41/5027 , C04B41/5022 , C04B38/00
摘要： A method is provided for producing a fiber-reinforced material which is composed, at least in a region of a surface layer, of a ceramic composite and has carbon-containing fibers reaction-bonded to a matrix containing the elements Si and C. In particular a method of producing fiber-reinforced silicon carbide is provided in which a structure of a matrix contains cracks and/or pores, at least at ambient temperature, because of a high thermal expansion coefficient compared with that of the fibers. Metals are selectively electrodeposited in the open pores and cracks of the matrix and, in particular, in a region of the electrically conductive reinforcing fibers. As a result, the open pores and cracks are filled and, in addition, metallic top layers are optionally formed that are firmly keyed to the ceramic composite and that may serve as an interlayer for glass top layers or ceramic top layers. A fiber-reinforced composite material, as well as moldings, in particular brake discs, brake linings or clutch plates, composed of such a composite material, are also provided.
摘要翻译：提供一种制造纤维增强材料的方法，所述纤维增强材料至少在陶瓷复合材料的表面层的区域中形成并具有与包含元素Si和C的基体反应结合的含碳纤维。特别地，提供了一种生产纤维增强碳化硅的方法，其中由于与纤维相比具有高的热膨胀系数，至少在环境温度下，基质的结构含有裂纹和/或孔。金属选择性地电沉积在基体的开孔和裂纹中，特别是在导电增强纤维的区域中。结果，填充了开放的孔和裂纹，此外，任选地形成金属顶层，其牢固地键合到陶瓷复合材料上，并且可以用作玻璃顶层或陶瓷顶层的中间层。还提供了由这种复合材料组成的纤维增强复合材料以及模制品，特别是制动盘，制动衬片或离合器片。

7. 发明授权

US06703117B2 Friction body or sliding body formed from composite materials reinforced with fiber bundles and containing a ceramics matrix and process for the production of a friction or sliding body 有权
标题翻译：由用纤维束增强并含有陶瓷基体的复合材料形成的摩擦体或滑动体以及用于生产摩擦或滑动体的方法
公开(公告)号：US06703117B2
公开(公告)日：2004-03-09
申请号：US10156535
申请日：2002-05-28
申请人： Udo Gruber , Michael Heine , Andreas Kienzle
发明人： Udo Gruber , Michael Heine , Andreas Kienzle
IPC分类号： D04H100
CPC分类号： C04B35/573 , B82Y30/00 , C04B35/63424 , C04B35/63444 , C04B35/63448 , C04B35/63452 , C04B35/63476 , C04B35/63496 , C04B35/806 , C04B37/008 , C04B2235/5212 , C04B2235/5224 , C04B2235/5228 , C04B2235/5244 , C04B2235/5248 , C04B2235/526 , C04B2235/5276 , C04B2235/5284 , C04B2237/341 , C04B2237/343 , C04B2237/348 , C04B2237/361 , C04B2237/363 , C04B2237/365 , C04B2237/368 , C04B2237/38 , C04B2237/385 , C04B2237/582 , C04B2237/584 , C04B2237/61 , F16C33/043 , F16D65/125 , F16D69/02 , F16D2069/001 , F16D2069/009 , Y10T428/249924 , Y10T428/249928 , Y10T428/24993 , Y10T428/249945 , Y10T428/30
摘要： A friction or sliding body includes at least two composite materials reinforced with fiber bundles and containing a ceramics matrix. A first composite material forms the outside of the sliding body as a friction layer and a second composite material forms a supporting body joined areally to the friction layer. The fiber bundle lengths of the friction layer are significantly shorter than the fiber bundle lengths of the supporting body. The fiber bundles of the friction layer have a clear alignment perpendicular to the surface. The surface of the friction layer is formed substantially only of small regions of free carbon with a diameter of at most 1.2 mm, and a total fraction of the area of free carbon on the surface is at most 35%. The surface has an extremely fine crack structure and the friction layer exhibits virtually no stresses in the vicinity of the surface. A process for producing a friction or sliding body and a brake disc or brake lining are also provided.
摘要翻译：摩擦或滑动体包括由纤维束增强并含有陶瓷基体的至少两种复合材料。第一复合材料形成滑动体的外部作为摩擦层，第二复合材料形成与摩擦层接合的支撑体。摩擦层的纤维束长度明显短于支撑体的纤维束长度。摩擦层的纤维束具有与表面垂直的清晰取向。摩擦层的表面基本上仅形成直径为1.2mm以下的游离碳的小区域，表面上的游离碳面积的总分数为35％以下。该表面具有非常细小的裂纹结构，摩擦层在表面附近几乎没有表现出应力。还提供了用于生产摩擦或滑动体以及制动盘或制动衬片的方法。

8. 发明授权

US06537654B1 Protection products and armored products made of fiber-reinforced composite material with ceramic matrix 失效
标题翻译：保护产品和由陶瓷基体纤维增强复合材料制成的装甲产品
公开(公告)号：US06537654B1
公开(公告)日：2003-03-25
申请号：US09547684
申请日：2000-04-12
申请人： Udo Gruber , Michael Heine , Andreas Kienzle , Reinhard Nixdorf
发明人： Udo Gruber , Michael Heine , Andreas Kienzle , Reinhard Nixdorf
IPC分类号： B32B1800
CPC分类号： F41H5/0435 , C04B35/573 , C04B35/806 , Y10S428/911 , Y10T428/166 , Y10T428/249924 , Y10T428/249928 , Y10T428/24993 , Y10T428/249937 , Y10T428/25 , Y10T428/252 , Y10T428/26 , Y10T428/2904 , Y10T428/2918 , Y10T428/2927 , Y10T428/2933 , Y10T428/2967 , Y10T428/298 , Y10T428/2995 , Y10T428/30 , Y10T428/31717
摘要： Protection products and armored products made of a fiber-reinforced composite material with a ceramic matrix, include a protection element for partial or complete absorption of at least one impact-like load focussed at a point. The protection element has a body having at least one dimension at least equal to 3 cm, in a direction perpendicular to a load to be absorbed. The body includes a fiber-reinforced composite material having a ceramic matrix with at least 10% by weight of silicon carbide and having reinforcing fibers. At least 5% by weight of the reinforcing fibers are carbon fibers and/or graphite fibers.
摘要翻译：由具有陶瓷基体的纤维增强复合材料制成的防护产品和装甲产品包括用于部分或完全吸收至少一个集中在一点上的冲击状载荷的保护元件。保护元件具有在垂直于要被吸收的负载的方向上具有至少一个尺寸至少一个尺寸的主体。本体包括具有至少10重量％的碳化硅并具有增强纤维的陶瓷基体的纤维增强复合材料。至少5重量％的增强纤维是碳纤维和/或石墨纤维。

9. 发明授权

US07708805B2 Method of producing carbon fibers, and methods of making protective clothing and a filter module 失效
标题翻译：生产碳纤维的方法，以及制作防护服的方法和过滤器模块
公开(公告)号：US07708805B2
公开(公告)日：2010-05-04
申请号：US11656259
申请日：2007-01-22
申请人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
发明人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
IPC分类号： D01F9/12
CPC分类号： D01F9/22
摘要： Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要翻译：多孔碳纤维，其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成，可通过有机或无机聚合物的碳化获得，其用于吸附或分离气态物质，特别是二氧化碳，以及其制备方法。首先，制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。接下来，将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。接着在非氧化条件下使混合纤维碳化或石墨化，使得聚合物B形成至少22重量％的碳和/或金属和/或金属碳化物残余物，残余物形成活性中心。

10. 发明授权

US07309609B2 Detection of oxidation of carbon-containing fibers or fiber bundles in composites 有权
标题翻译：检测复合材料中含碳纤维或纤维束的氧化
公开(公告)号：US07309609B2
公开(公告)日：2007-12-18
申请号：US10624697
申请日：2003-07-22
申请人： Martin Christ , Michael Heine
发明人： Martin Christ , Michael Heine
IPC分类号： G01N25/18 , G01N27/00 , G01R31/26 , G01R31/28 , H01L23/58 , H01L29/10
CPC分类号： C04B35/83 , C04B35/565 , C04B35/573 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/5248 , C04B2235/526 , C04B2235/5264 , C04B2235/728 , C04B2235/80 , G01N27/9046
摘要： The invention relates to the detection of oxidation of carbon-containing fibers or fiber bundles embedded in a nonconductive or semiconducting ceramic matrix in composites wherein use is made of the eddy current method.
摘要翻译：本发明涉及检测复合材料中嵌入非导电或半导体陶瓷基体中的含碳纤维或纤维束的氧化，其中使用涡流法。

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