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    • 1. 发明授权
    • Method of producing carbon fibers, and methods of making protective clothing and a filter module
    • 生产碳纤维的方法,以及制作防护服的方法和过滤器模块
    • US07708805B2
    • 2010-05-04
    • US11656259
    • 2007-01-22
    • Michael HeineRichard NeuertRainer Zimmermann-Chopin
    • Michael HeineRichard NeuertRainer Zimmermann-Chopin
    • D01F9/12
    • D01F9/22
    • Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
    • 多孔碳纤维,其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成,可通过有机或无机聚合物的碳化获得,其用于吸附或分离气态物质 ,特别是二氧化碳,以及其制备方法。 首先,制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。 接下来,将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。 接着在非氧化条件下使混合纤维碳化或石墨化,使得聚合物B形成至少22重量%的碳和/或金属和/或金属碳化物残余物,残余物形成活性中心。
    • 5. 发明授权
    • Production of fibers or films using specific forming solutions and the
fibers of films obtainable thereby
    • 使用特定的成形溶液生产纤维或薄膜以及由此获得的薄膜的纤维
    • US5646234A
    • 1997-07-08
    • US416148
    • 1995-04-04
    • Holger JungRichard NeuertPeter KleinGeorg-Emerich Miess
    • Holger JungRichard NeuertPeter KleinGeorg-Emerich Miess
    • B29C55/02B29K77/00B29L7/00C08G69/32C08G69/42C08J5/18C08L77/00C08L77/10D01F6/60D01F6/80D01F6/90C08G69/12
    • C08J5/18C08G69/32C08G69/42D01F6/805C08J2377/10Y10T428/2969Y10T428/2971Y10T428/31725
    • A process for producing fibers or films by the steps of:a) preparing an aromatic polyamide by polycondensation of dicarbonyl dihalides or mixtures thereof with at least two diamines in N-alkyllactams as a solvent, the polycondensation being of at least 90 mol %, based on the total amount of dicarbonyl dihalides in the reaction mixture, of compounds of the formula I or mixtures of such compoundsHal--OC--Ar.sup.1 --CO--Hal (I)with at least 90 mol%, based on the total amount of diamines in the reaction mixture, of compounds of the formula II and optionally III or mixtures of such compoundsH.sub.2 N--Ar.sup.2 --NH.sub.2 (II), H.sub.2 N--Ar.sup.3 --NH.sub.2 (III)where Ar.sup.1, Ar.sup.2 and Ar.sup.3 are independently of each other a bivalent aromatic radical, the proportion of structural repeat units in the aromatic polyamide derived from the compounds of the formula II, based on the proportion of the structural repeat units derived from the compounds of the formulae II and III, being at least 50 mol %, and said aromatic polyamide is soluble in organic solvents,b) forcing the solution of the aromatic polyamide obtained in step a) through dies of the desired cross-sectional shape at temperatures from 40.degree. to 120.degree. C. to form fibers or films,c) removing the organic solvent in a conventional manner to produce solvent-leaner or -free fibers or films sufficiently mechanically stable and nontacky for further processing.The process of the invention omits the customary neutralization after the aromatic polyamide has been prepared.
    • 一种通过以下步骤制备纤维或薄膜的方法:a)通过二羰基二卤化物或其混合物与N-烷基内酰胺中的至少两种二胺作为溶剂进行缩聚来制备芳族聚酰胺,所述缩聚为至少90mol%,基于 对于反应混合物中二羰基二卤化物的总量,式I化合物或这些化合物Hal-OC-Ar1-CO-Hal(I)的混合物与至少90mol%的二胺的总量相比, 反应混合物,式II和任选III的化合物或这些化合物H 2 N-Ar 2 -NH 2(II),H 2 N-Ar 3 -NH 2(III)的混合物,其中Ar 1,Ar 2和Ar 3彼此独立地是二价芳族基团 衍生自式II化合物的芳族聚酰胺中结构重复单元的比例基于衍生自式II和III的化合物的结构重复单元的比例为至少50mol%,所述芳族 聚酰胺可溶于或 粗制溶剂,b)在40℃至120℃的温度下,将步骤a)中获得的芳族聚酰胺溶液强迫所需的横截面形状,以形成纤维或膜,c)将 以常规的方式制备足够机械稳定和非粘性以进行进一步处理的溶剂稀的或无 - 纤维或薄膜。 在制备芳族聚酰胺之后,本发明的方法省略了常规中和。
    • 7. 发明授权
    • Process and apparatus for guiding a tow
    • 过程和设备指导
    • US5214828A
    • 1993-06-01
    • US679224
    • 1991-04-02
    • Richard NeuertBernd Huber
    • Richard NeuertBernd Huber
    • B65H57/00D02G1/12D02J1/18G01N33/36
    • D02J1/18G01N33/365
    • A process and apparatus for guiding a continuous moving tow in synthetic fiber manufacture. The profile (the thickness distribution and width) and the position of the tow are continuously sensed in a non-contact manner and an appropriate electrical signal is generated. This electrical signal is used to control the profile and the position of the tow in such a way that its profile and position stay within predetermined target value ranges. The tow geometry is preferably sensed using a CCD camera, while the tow geometry is controlled using tow-engaging deflecting means. In this way it is possible to optimize tow profile and position, for example for entry into a stuffer box (FIG. 1).
    • 用于在合成纤维制造中引导连续移动的丝束的方法和装置。 轮廓(厚度分布和宽度)和丝束的位置以非接触的方式连续感测,并产生适当的电信号。 该电信号用于控制丝束的轮廓和位置,使得其轮廓和位置保持在预定目标值范围内。 优选地,使用CCD照相机感测丝束几何形状,而使用牵引接合偏转装置来控制丝束几何形状。 以这种方式,可以优化丝束轮廓和位置,例如用于进入填塞箱(图1)。