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    • 1. 发明授权
    • Method of producing carbon fibers, and methods of making protective clothing and a filter module
    • 生产碳纤维的方法,以及制作防护服的方法和过滤器模块
    • US07708805B2
    • 2010-05-04
    • US11656259
    • 2007-01-22
    • Michael HeineRichard NeuertRainer Zimmermann-Chopin
    • Michael HeineRichard NeuertRainer Zimmermann-Chopin
    • D01F9/12
    • D01F9/22
    • Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
    • 多孔碳纤维,其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成,可通过有机或无机聚合物的碳化获得,其用于吸附或分离气态物质 ,特别是二氧化碳,以及其制备方法。 首先,制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。 接下来,将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。 接着在非氧化条件下使混合纤维碳化或石墨化,使得聚合物B形成至少22重量%的碳和/或金属和/或金属碳化物残余物,残余物形成活性中心。
    • 5. 发明授权
    • Silicon carbide articles reinforced with short graphite fibers
    • 用短石墨纤维增强的碳化硅制品
    • US06030913A
    • 2000-02-29
    • US26347
    • 1998-02-19
    • Michael HeineUdo Gruber
    • Michael HeineUdo Gruber
    • C04B35/565C04B35/573C04B35/65C04B35/80F16D69/02C04B35/56
    • F16D69/023C04B35/573C04B35/806F16D2200/0047
    • A composite material article reinforced with high strength short graphite fibers and having a matrix substantially consisting of silicon carbide is prepared which has an elongation at break of 0.25 to 0.5% and thus exhibits quasi-ductile failure behavior. The short reinforcing graphite fibers are enclosed by at least two shells of graphitized carbon which have been obtained by impregnation with carbonizable impregnating agents and subsequent carbonization. The shell closest to the graphite fibers contains no cracks. The outermost shell is partially converted into silicon carbide. The starting material used comprises long or short fiber prepregs, which are first carbonized, then subjected at least once to an operation consisting of impregnation with a carbonizable impregnating agent and recarbonization, then graphitized at a temperature of up to maximum of 2400.degree. C. and then comminuted to yield a dry material for the production of a precursor article. This dry material is then mixed with a binder having a high carbon content and the mixture is compression molded to yield a green article. The green molding is then carbonized and afterwards infiltrated with liquid silicon, with the carbon matrix of the carbonized precursor article being converted into silicon carbide.
    • 制备用高强度短石墨纤维增强并具有基本上由碳化硅组成的基体的复合材料制品,其具有0.25至0.5%的断裂伸长率,因此显示出准韧性破坏行为。 短的增强石墨纤维被至少两个石墨化碳壳包围,这些石墨化碳通过用可碳化浸渍剂浸渍并随后进行碳化而获得。 最靠近石墨纤维的壳体不含裂纹。 最外壳被部分转化为碳化硅。 使用的起始原料包括长纤维或短纤维预浸料,其首先被碳化,然后至少进行一次操作,其中包括用可碳化浸渍剂的浸渍和再碳化,然后在最高达2400℃的温度下石墨化, 然后粉碎以产生用于制备前体制品的干材料。 然后将该干燥材料与具有高碳含量的粘合剂混合,并将该混合物压塑以产生绿色制品。 然后将绿色模制品碳化,然后用液态硅渗透,碳化前体制品的碳基体转化为碳化硅。
    • 6. 发明授权
    • Method for converting multidimensional sheet structures consisting of
polyacrylonitrile fibres into the thermally stabilized stage
    • 将由聚丙烯腈纤维组成的多维片材结构转化为热稳定化阶段的方法
    • US5853429A
    • 1998-12-29
    • US893737
    • 1997-07-11
    • Michael HeineDieter Kompalik
    • Michael HeineDieter Kompalik
    • D01F9/22
    • D01F9/225
    • Method for converting two-dimensional or three-dimensional sheet structures consisting of polyacrylonitrile fibres or substantially of polyacrylonitrile fibres, such as woven fabrics, layered materials, knitted fabrics, felts, or non-woven fabrics, into the thermally stabilized but non-carbonized state, by means of an oxygen-containing or oxygen-yielding gas flowing through the respective sheet fibre structure. This gas or gas mixture is used as a medium for the temperature control in the sheet fibre structure and as a means for supplying the oxygen carrier and also removing the gaseous reaction products. Temperature and flow velocity of the gas/gas mixture are matched to the stabilization characteristic of the respective sheet fibre structure and are controlled precisely. The device used for carrying out the method consists of a furnace (23) which consists of at least one chamber, through which furnace a web of the sheet fibre structure (18) is moved continuously. During this transportation the oxygen-containing or oxygen-emitting gas flows through the sheet fibre structure (18) in a controlled manner.
    • 将由聚丙烯腈纤维或基本上由纺织织物,层状材料,针织物,毡或无纺织物组成的聚丙烯腈纤维组成的二维或三维片材结构转化成热稳定但非碳化状态的方法 ,通过流过各个片材纤维结构的含氧或产氧气体。 该气体或气体混合物用作片材纤维结构中温度控制的介质,并用作供应氧载体并除去气态反应产物的方法。 气体/气体混合物的温度和流速匹配于各个片材纤维结构的稳定特性,并被精确地控制。 用于执行该方法的装置包括由至少一个室组成的炉(23),片状纤维结构(18)的纤维网通过该炉连续移动。 在该输送期间,含氧或发氧气体以受控的方式流过片状纤维结构(18)。