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1. 发明授权

US07393887B2 Stabilizer system for stabilizing halogen-containing polymers 有权
标题翻译：用于稳定含卤聚合物的稳定剂体系
公开(公告)号：US07393887B2
公开(公告)日：2008-07-01
申请号：US11395272
申请日：2006-04-03
申请人： Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner , Thomas Hopfmann
发明人： Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner , Thomas Hopfmann
IPC分类号： C08K3/16 , C08K5/17
CPC分类号： C08K5/17 , C08L57/08
摘要： A composition and process is disclosed for the stabilization of halogen-containing polymers. In particular, chlorine-containing polymers such as poly vinyl chloride (PVC) are stabilized by incorporating of a stabilizer mixture having at least a perchlorate salt and an alkanolamine.
摘要翻译：公开了用于稳定含卤聚合物的组合物和方法。特别地，通过加入至少含有高氯酸盐和链烷醇胺的稳定剂混合物来稳定含氯聚合物如聚氯乙烯（PVC）。

2. 发明授权

US07358286B2 Stabilizer system for stabilizing PVC 有权
标题翻译：稳定PVC系统
公开(公告)号：US07358286B2
公开(公告)日：2008-04-15
申请号：US10542562
申请日：2003-12-20
申请人： Thomas Hopfmann , Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner
发明人： Thomas Hopfmann , Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner
IPC分类号： C08K5/34
CPC分类号： C08K5/16 , C08K3/24 , C08L27/06
摘要： Disclosed are stabilizer mixtures comprising at least a) one alkanolamine or one reaction product of a monofunctional or polyfunctional epoxide and ammonia or a monofunctional or polyfunctional dialkyl(aryl)amine or monoalkyl(aryl)amine, and b) one uracil or one initial product and an optional perchlorate salt.
摘要翻译：公开了稳定剂混合物，其包含至少一种链烷醇胺或单官能或多官能环氧化物与氨或单官能或多官能二烷基（芳基）胺或单烷基（芳基）胺的一种反应产物，和b）一种尿嘧啶或一种初始产物和一种可选的高氯酸盐。

3. 发明申请

US20060235124A1 Stabilizer system for the stabilisation of halogenated polymers 审中-公开
公开(公告)号：US20060235124A1
公开(公告)日：2006-10-19
申请号：US10555021
申请日：2004-04-02
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Karl-Josef Kuhn , Thomas Hopfmann
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Karl-Josef Kuhn , Thomas Hopfmann
IPC分类号： C08K5/36
CPC分类号： C08K5/17 , C08K5/41 , C08L57/08
摘要： The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.

4. 发明申请

US20060183830A1 Stabilizer system for stabilizing halogen-containing polymers 有权
标题翻译：用于稳定含卤聚合物的稳定剂体系
公开(公告)号：US20060183830A1
公开(公告)日：2006-08-17
申请号：US11395272
申请日：2006-04-03
申请人： Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner , Thomas Hopfmann
发明人： Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner , Thomas Hopfmann
IPC分类号： C08K5/32
CPC分类号： C08K5/17 , C08L57/08
摘要： A composition and process is disclosed for the stabilization of halogen-containing polymers. In particular, chlorine-containing polymers such as poly vinyl chloride (PVC) are stabilized by incorporating of a stabilizer mixture having at least a perchlorate salt and an alkanolamine.
摘要翻译：公开了用于稳定含卤聚合物的组合物和方法。特别地，通过加入至少含有高氯酸盐和链烷醇胺的稳定剂混合物来稳定含氯聚合物如聚氯乙烯（PVC）。

5. 发明申请

US20060052497A1 Stabilizer system for stabilizing pvc 有权
标题翻译：用于稳定pvc的稳定剂系统
公开(公告)号：US20060052497A1
公开(公告)日：2006-03-09
申请号：US10542562
申请日：2003-12-20
申请人： Thomas Hopfmann , Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner
发明人： Thomas Hopfmann , Hans-Helmut Friedrich , Karl-Josef Kuhn , Wolfgang Wehner
IPC分类号： C08K5/32
CPC分类号： C08K5/16 , C08K3/24 , C08L27/06
摘要： Disclosed are stabilizer mixtures comprising at least a) one alkanolamine or one reaction product of a monofunctional or polyfunctional epoxide and ammonia or a monofunctional or polyfunctional dialkyl(aryl)amine or monoalkyl(aryl)amine, and b) one uracil or one initial product and an optional perchlorate salt
摘要翻译：公开了稳定剂混合物，其包含至少一种链烷醇胺或单官能或多官能环氧化物与氨或单官能或多官能二烷基（芳基）胺或单烷基（芳基）胺的一种反应产物，和b）一种尿嘧啶或一种初始产物和任选的高氯酸盐

6. 发明授权

US06531533B1 Stabilized halogen-containing polymers 失效
标题翻译：稳定的含卤聚合物
公开(公告)号：US06531533B1
公开(公告)日：2003-03-11
申请号：US08799174
申请日：1997-02-12
申请人： Karl Josef Kuhn , Wolfgang Wehner , Rolf Drewes
发明人： Karl Josef Kuhn , Wolfgang Wehner , Rolf Drewes
IPC分类号： C08K322
CPC分类号： C08K5/56 , C08K3/34 , C08K5/57 , C08L57/08
摘要： Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.
摘要翻译：通过加入（a）含卤聚合物或其回收物，使含卤聚合物或其回收物稳定化;（b）至少一种形式为钠，钾和/或锂的沸石，特别是至少除了沸石A，Na12Al12Si12O48.27H2O和斜发沸石Na6Al6Si30O72.2H2O，（c）至少一种有机物，除了M，其中一种沸石是Na，K或Li，x是2至12，y是1至15 锌，铝或稀土化合物，和/或（d）至少一种有机锡化合物，如权利要求1中更详细描述的。

7. 发明授权

US6136900A Stabilized polyvinyl chloride 失效
标题翻译：稳定的聚氯乙烯
公开(公告)号：US6136900A
公开(公告)日：2000-10-24
申请号：US121471
申请日：1998-07-23
申请人： Karl Josef Kuhn , Wolfgang Wehner
发明人： Karl Josef Kuhn , Wolfgang Wehner
IPC分类号： C08K3/34 , C08K5/053 , C08K5/098 , C08K5/3432 , C08K5/34 , C08K3/10 , C08K5/05
CPC分类号： C08K5/098 , C08K3/34 , C08K5/053 , C08K5/3432
摘要： The invention relates to a PVC composition comprising a stabilizer combination of (b) polyDHP of the formula I ##STR1## where the radicals T, L, R, R', R" are as defined in claim 1, (c) a subtance from the group consisting of crystalline hydrotalcites,crystalline or amorphous zeolites,crystalline or amorphous dawsonites, magadiites or kenyaites, disaccharide alcohols and sterically hindered amines containing the structural unit ##STR2## in which R.sup.0 is hydrogen or methyl, and (d) at least one zinc, aluminium or lanthanoid compound.
摘要翻译：本发明涉及一种PVC组合物，其包含（b）式I的聚DHP的稳定剂组合，其中基团T，L，R，R'，R“如权利要求1所定义，（c）由结晶水滑石，结晶或无定形沸石，结晶或无定形片钠钙石，马达加斯特或肯尼亚，含有其中R 0为氢或甲基的结构单元的二糖醇和空间位阻胺，和（d）至少一种锌，铝或镧系元素化合物。

8. 发明授权

US6013703A Stabilizer combination for chlorine-containing polymers 失效
标题翻译：含氯聚合物的稳定剂组合
公开(公告)号：US6013703A
公开(公告)日：2000-01-11
申请号：US822563
申请日：1997-03-19
申请人： Karl Josef Kuhn , Wolfgang Wehner , Horst Zinke
发明人： Karl Josef Kuhn , Wolfgang Wehner , Horst Zinke
IPC分类号： C07D401/04 , C07D401/12 , C07D401/14 , C08K3/22 , C08K3/24 , C08K3/34 , C08K5/05 , C08K5/07 , C08K5/09 , C08K5/098 , C08K5/10 , C08K5/13 , C08K5/138 , C08K5/15 , C08K5/1515 , C08K5/17 , C08K5/3432 , C08K5/3435 , C08K5/3492 , C08K5/36 , C08K5/524 , C08K5/56 , C08L27/06 , C08L67/02 , C08K5/34
CPC分类号： C08K5/138 , C08K5/07 , C08K5/098 , C08K5/3435
摘要： A stabilizer combination, principally for PVC, is described which essentially comprisesA) at least one zinc compound of the formula IZn(R.sup.1 R.sup.2) (I)andB) at least one metal compound of the formula IIMe.sup.n+ (R.sup.3.sub.a R.sup.4.sub.b R.sup.5.sub.c) (II)in which Me is Al, Mg, Na or K,a, b and c are 0, 1, 2 or 3,n=a+b+c and can be from 1 to 3, and at least one radical R.sup.1 to R.sup.5 independently of one another are C.sub.1 -C.sub.22 carboxylates, C.sub.2 -C.sub.21 alkenyl-CO.sub.2 --, phenyl-CO.sub.2 --, naphthyl-CO.sub.2 --, C.sub.5 -C.sub.12 cycloalkyl-CO.sub.2 --, C.sub.7 -C.sub.18 alkylphenyl-CO.sub.2 --, C.sub.7 -C.sub.18 alkylphenyl-O--, C.sub.7 -C.sub.9 phenylalkyl-CO.sub.2 --, C.sub.1 -C.sub.21 -alkyl-O--, R.sup.8 --O--CO--[CH.sub.2 ].sub.p --S-- or a radical of the formula R.sup.6 --CO--CH.dbd.CR.sup.7 --O.sup..crclbar. -- and can be Cl-- or HO--, where the aforementioned alkyl or alkenyl radical can be branched, interrupted one or more times by oxygen or substituted by one or more OH groups, and the abovementioned phenyl radical can be substituted by one or more methyl, ethyl, propyl, butyl and/or OH groups,R.sub.6 and R.sub.7 are C.sub.1 -C.sub.8 alkyl-, C.sub.1 -C.sub.8 alkenyl-, C.sub.5 -C.sub.8 cycloalkyl-, benzyl- or phenyl-,p is 1 to 6,R.sup.8 is C.sub.4 -C.sub.22 alkyl that is uninterrupted or interrupted by oxygen, andC) at least one sterically hindered amine comprising the group ##STR1## in which A and Y independently of one another are C.sub.1-8 alkyl-, C.sub.3-8 alkenyl-, C.sub.5-8 cycloalkyl-, or C.sub.7-9 phenylalkyl- or together are C.sub.2-5 alkylene that is uninterrupted or interrupted by O, NH or CH.sub.3 --N.
摘要翻译：描述了主要用于PVC的稳定剂组合物，其基本上包含A）至少一种式I Zn（R1R2）（I）的锌化合物和B）至少一种式II的金属化合物Men +（R3a R4b R5c）（ II）其中Me为Al，Mg，Na或K，a，b和c分别为0,1,2或3，n = a + b + c，并且可以为1至3，并且至少一个基团R 1至 C 2 -C 21烷基-CO 2 - ，C 5 -C 12环烷基-CO 2 - ，C 7 -C 18烷基苯基-CO 2 - ，C 7 -C 18烷基苯基-O-，C 7 -C 18烷基苯基， C 9苯基烷基-CO 2 - ，C 1 -C 21烷基-O-，R 8 -O-CO- [CH 2] p S-或式R 6 -CO-CH = CR 7 -O（ - ） - 的基团，并且可以是Cl - 或 HO-，其中上述烷基或烯基可以被支化，被氧中断一次或多次或被一个或多个OH基取代，并且上述苯基可以被一个或多个甲基，乙基，丙基，丁基和 /或OH基，R 6和R 7是C 1 -C 8烷基 - ，C 1 -C 8烯基 - ，C 5 -C 8环烷基 - ，苄基或苯基 - ，p是 1至6中，R 8为不间断或被中断的C 4 -C 22烷基，和C）至少一个空间位阻胺，其中A和Y彼此独立地为C1-8烷基，C3-8烯基，C5 -8环烷基 - 或C7-9苯基烷基 - 或一起是不间断或被O，NH或CH3-N中断的C2-5亚烷基。

9. 发明授权

US5814691A Stabilized polyvinyl chloride 失效
标题翻译：稳定的聚氯乙烯
公开(公告)号：US5814691A
公开(公告)日：1998-09-29
申请号：US566772
申请日：1995-12-04
申请人： Karl Josef Kuhn , Wolfgang Wehner
发明人： Karl Josef Kuhn , Wolfgang Wehner
IPC分类号： C07D211/10 , C07D211/90 , C07D401/14 , C08K3/24 , C08K3/34 , C08K5/053 , C08K5/098 , C08K5/17 , C08K5/34 , C08K5/3432 , C08L27/06 , C08L67/00 , C08L67/02 , C08K5/04
CPC分类号： C08K5/098 , C08K3/34 , C08K5/053 , C08K5/3432
摘要： The invention relates to a PVC composition comprising a stabilizer combination of (b) polyDHP of the formula I ##STR1## where the radicals T, L, R, R', R" are as defined in claim 1, (c) a substance from the group consisting of crystalline hydrotalcites, crystalline or amorphous zeolites, crystalline or amorphous dawsonites, magadiites or kenyaites, disaccharide alcohols and sterically hindered amines containing the structural unit ##STR2## in which R.degree. is hydrogen or methyl, and (d) at least one zinc, aluminium or lanthanoid compound.
摘要翻译：本发明涉及一种PVC组合物，其包含（b）式I的聚DHP（I）＆lt; IMAGE＆gt;的稳定剂组合，其中基团T，L，R，R'，R'如权利要求1所定义，（c）由结晶水滑石，结晶或无定形沸石，结晶或无定形片钠钙石，马达加斯特或肯尼亚组成的组中的物质，含有R DEG为氢的结构单元（II）的二糖醇和空间位阻胺或甲基，和（d）至少一种锌，铝或镧系元素化合物。

10. 发明授权

US5804622A Monomeric N-piperidinylmelamines as stabilizers for chlorine-containing polymers 失效
标题翻译：单体N-哌啶基三聚氰胺作为含氯聚合物的稳定剂
公开(公告)号：US5804622A
公开(公告)日：1998-09-08
申请号：US819224
申请日：1997-03-17
申请人： Horst Zinke , Wolfgang Wehner , Karl Josef Kuhn , Valerio Borzatta , Gerhard Rytz
发明人： Horst Zinke , Wolfgang Wehner , Karl Josef Kuhn , Valerio Borzatta , Gerhard Rytz
IPC分类号： C07D401/12 , C07D401/14 , C08K3/10 , C08K5/00 , C08K5/098 , C08K5/3492 , C08L27/04 , C08L101/04
CPC分类号： C07D401/14 , C07D401/12 , C08K5/005 , C08K5/098 , C08K5/34926
摘要： A stabilizer combination, principally for PVC, is described, comprising A at least one zinc carboxylate B at least one compound of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in claim 1.
摘要翻译：描述了主要用于PVC的稳定剂组合物，其包含至少一种羧酸锌B至少一种式（I）的化合物，其中R 1至R 6如权利要求1所定义。

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