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    • 3. 发明申请
    • Stabilizer system for the stabilisation of halogenated polymers
    • US20060235124A1
    • 2006-10-19
    • US10555021
    • 2004-04-02
    • Wolfgang WehnerHans-Helmut FriedrichKarl-Josef KuhnThomas Hopfmann
    • Wolfgang WehnerHans-Helmut FriedrichKarl-Josef KuhnThomas Hopfmann
    • C08K5/36
    • C08K5/17C08K5/41C08L57/08
    • The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.