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1. 发明授权

US06531533B1 Stabilized halogen-containing polymers 失效
标题翻译：稳定的含卤聚合物
公开(公告)号：US06531533B1
公开(公告)日：2003-03-11
申请号：US08799174
申请日：1997-02-12
申请人： Karl Josef Kuhn , Wolfgang Wehner , Rolf Drewes
发明人： Karl Josef Kuhn , Wolfgang Wehner , Rolf Drewes
IPC分类号： C08K322
CPC分类号： C08K5/56 , C08K3/34 , C08K5/57 , C08L57/08
摘要： Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.
摘要翻译：通过加入（a）含卤聚合物或其回收物，使含卤聚合物或其回收物稳定化;（b）至少一种形式为钠，钾和/或锂的沸石，特别是至少除了沸石A，Na12Al12Si12O48.27H2O和斜发沸石Na6Al6Si30O72.2H2O，（c）至少一种有机物，除了M，其中一种沸石是Na，K或Li，x是2至12，y是1至15 锌，铝或稀土化合物，和/或（d）至少一种有机锡化合物，如权利要求1中更详细描述的。

2. 发明授权

US5925696A Stabilizer combinations for chlorine-containing polymers 失效
标题翻译：含氯聚合物的稳定剂组合
公开(公告)号：US5925696A
公开(公告)日：1999-07-20
申请号：US728870
申请日：1996-10-10
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
IPC分类号： C09K15/30 , C08K3/00 , C08K3/16 , C08K3/22 , C08K3/24 , C08K3/26 , C08K3/34 , C08K5/00 , C08K5/05 , C08K5/06 , C08K5/07 , C08K5/09 , C08K5/10 , C08K5/1515 , C08K5/34 , C08K5/3432 , C08K5/3462 , C08K5/3477 , C08K5/39 , C08K5/52 , C08K5/524 , C08K5/57 , C08L27/04 , C08L27/06 , C08L57/08 , C08L101/00
CPC分类号： C08K5/1515 , C08K3/0041 , C08K3/34 , C08K5/005 , C08K5/3462 , C08K5/39
摘要： A stabilizer combination, mainly for PVC, is described, comprisingA) at least one compound of formula I ##STR1## wherein R*.sub.1 and R*.sub.2 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.6 lkenyl, C.sub.5 -C.sub.8 cycloalkyl that is unsubstituted or substituted by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or by chlorine atoms, or C.sub.7 -C.sub.9 phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.8 cycloalkyl or by hydroxy groups or chlorine atoms,and R*.sub.1 and R*.sub.2 may additionally be hydrogen and C.sub.1 -C.sub.12 alkyl, and Y is S or O, andB) at least one compound from the following groups:B1) perchlorate compounds,B2) glycidyl compounds,B3) beta-diketones and beta-keto esters,B4) dihydropyridines and polydihydropyridines,B5) polyols and disaccharide alcohols,B6) sterically hindered amines (tetraalkylpiperidine compounds),B7) alkali aluminosilicates (zeolites),B8) hydrotalcites,B9) alkali aluminocarbonates (dawsonites),B10) alkali- (or alkaline earth-) carboxylates,-(bi)carbonates or -hydroxides,B11) antioxidants and lubricants andB12) organotin stabilizers.
摘要翻译：描述了主要用于PVC的稳定剂组合物，其包含A）至少一种式I化合物，其中R * 1和R * 2各自独立地为未取代的其它C 1 -C 12烷基，C 3 -C 6烯基，C 5 -C 8环烷基，被1至3个C 1 -C 4烷基，C 1 -C 4烷氧基，C 5 -C 8环烷基或被羟基或氯原子取代的C 7 -C 9苯基烷基，或未被取代或在苯环上被1至3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基， C4烷氧基，C5-C8环烷基或羟基或氯原子，R * 1和R * 2可以另外是氢和C 1 -C 12烷基，Y是S或O，和B）至少一种下列化合物：B1 ）高级氯酸酯化合物，B2）缩水甘油化合物，B3）β-二酮和β-酮酯，B4）二氢吡啶和聚二氢吡啶，B5）多元醇和二糖醇，B6）空间位阻胺（四烷基哌啶化合物），B7）碱铝硅酸盐（沸石），B8）水滑石，B9）碱金属铝酸盐（片钠土），B10）碱（或碱土金属）羧酸盐， - （双）碳酸盐或氢氧化物，B11）抗氧化剂和润滑剂以及B12）有机锡稳定剂。

3. 发明授权

US06174941B1 NH2-modified 6-aminouracils as stabilizers for halogenated polymers 失效
标题翻译： NH2改性的6-氨基尿嘧啶作为卤化聚合物的稳定剂
公开(公告)号：US06174941B1
公开(公告)日：2001-01-16
申请号：US09336079
申请日：1999-06-18
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
IPC分类号： C08K534
CPC分类号： C07D239/545 , C08K5/3462 , C08L27/06
摘要： A description is given of compounds of the general formula I where Y is oxygen or sulfur, and R1 and R2 independently of one another are C1-C18-alkyl, C3-C6-alkenyl, unsubstituted or C1-C4-alkoxy-, C5-C8-cycloalkyl-, —OH— and/or Cl-substituted C1-C18-alkyl, C5-C8-cycloalkyl, phenyl or C7-C9-phenylalkyl which is unsubstituted or substituted on the phenyl ring by C1-C4-alkyl, C1-C4-alkoxy, C5-C8-cycloalkyl, —OH and/or Cl, and R3 is unsubstituted C9-C18-alkyl or is C1-C18-alkyl substituted by —OH, C1-C12-alkoxy, phenoxy, C6-C8-alkylphenoxy, C7-C9-alkoxyphenyl, —C═O(OR4) and/or —O—COR4, or is C3-C6-alkenyl, C5-C8-cycloalkyl, or mono- to tri-OH—, —C1-C4-alkyl-, —C1-C4-alkoxy-, —C═O(OR4)— and/or —O—COR4-substituted phenyl or naphthyl, and where R4 is C1-C12-alkyl, which are suitable for stabilizing chlorine-containing polymers, especially PVC.
摘要翻译：描述了通式I的化合物，其中Y是氧或硫，R 1和R 2彼此独立地是C 1 -C 18烷基，C 3 -C 6 - 烯基，未取代的或C 1 -C 4 - 烷氧基 - ，C 5 -C 8 - 环烷基 - ， - C 1 -C 4 - 烷基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 5 -C 8 - 环烷基，-OH和/或Cl，R 3为未取代的C 9 -C 18 - 烷基或被-OH，C 1 -C 12烷氧基，苯氧基，C 6 -C 8烷基苯氧基，C 7 -C 18 - 烷基取代的C 1 -C 18烷基 -C9-烷氧基苯基，-C = O（OR4）和/或-O-COR4，或为C3-C6-烯基，C5-C8-环烷基或一至三-OH-，-C1-C4-烷基 - ，-C 1 -C 4 - 烷氧基 - ， - C = O（OR 4） - 和/或-O-COR 4 - 取代的苯基或萘基，其中R 4是适用于稳定含氯聚合物的C 1 -C 12烷基， PVC。

4. 发明授权

US6002004A Pyrrolodiazine derivatives as stabilizers for chilorine-containing polymers 失效
标题翻译：吡咯并嗪衍生物作为含Chilorine的聚合物的稳定剂
公开(公告)号：US6002004A
公开(公告)日：1999-12-14
申请号：US007196
申请日：1998-01-14
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
IPC分类号： C07D487/04 , C08K5/3462
CPC分类号： C07D487/04 , C08K5/3462
摘要： The invention relates to compositions comprisinga) a chlorine-containing polymer andb) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.
摘要翻译：本发明涉及包含a）含氯聚合物和b）至少一种含有至少一个式I基团的化合物，其中A是形成未取代或取代的六元杂环所需的其它基团或原子含有两个氮环原子。

5. 发明授权

US5543449A Stabilized flexible PVC 失效
标题翻译：稳定的柔性PVC
公开(公告)号：US5543449A
公开(公告)日：1996-08-06
申请号：US419310
申请日：1995-04-10
申请人： Rolf Drewes , Markus Kolb , Karl J. Kuhn , Hans-J urgen Sander , Wolfgang Wehner
发明人： Rolf Drewes , Markus Kolb , Karl J. Kuhn , Hans-J urgen Sander , Wolfgang Wehner
IPC分类号： C08K3/00 , C08G59/20 , C08K3/16 , C08K3/24 , C08K5/00 , C08K5/15 , C08K5/1515 , C08L27/06 , C08L63/00 , C08L63/02 , C08L63/06
CPC分类号： C08K3/16 , C08K5/1515
摘要： A high degree of stabilization of flexible PVC is achieved by using a perchlorate and a terminal epoxide compound.
摘要翻译：通过使用高氯酸盐和末端环氧化合物可实现柔性PVC的高度稳定化。

6. 发明授权

US5492949A Stabilized polyvinyl chloride 失效
标题翻译：稳定的聚氯乙烯
公开(公告)号：US5492949A
公开(公告)日：1996-02-20
申请号：US226620
申请日：1994-04-12
申请人： Rolf Drewes , Markus Kolb , Karl Kuhn , Wolfgang Wehner
发明人： Rolf Drewes , Markus Kolb , Karl Kuhn , Wolfgang Wehner
IPC分类号： A01G13/02 , C08J5/18 , C08K3/00 , C08K3/10 , C08K5/00 , C08K5/09 , C08K5/098 , C08K5/13 , C08K5/1515 , C08K13/02 , C08L27/06 , C08L63/02 , H01B3/44 , C08K5/15
CPC分类号： C08K5/098 , C08K3/0041 , C08K5/1515 , C08L27/06 , C08L63/00
摘要： Use of an inorganic or organic zinc compound and a terminal epoxide compound, optionally with chalk, gives a high level of stabilization of PVC.
摘要翻译：无机或有机锌化合物和末端环氧化合物（任选用白垩）的使用给出了PVC的高水平稳定性。

7. 发明授权

US06194494B1 Stabiliser combinations for chlorine-containing polymers 失效
标题翻译：含氯聚合物的稳定剂组合
公开(公告)号：US06194494B1
公开(公告)日：2001-02-27
申请号：US09107848
申请日：1998-06-30
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
IPC分类号： C08K534
CPC分类号： C08K5/1515 , C08K3/014 , C08K3/34 , C08K5/005 , C08K5/3462 , C08K5/39 , C08L27/06 , C08L11/00 , C08L57/08
摘要： A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonites), B10) alkali- (or alkaline earth-) carboxylates,-(bi)carbonates or -hydroxides, B11) antioxidants and lubricants and B12) organotin stabilisers.
摘要翻译：描述了主要用于PVC的稳定剂组合物，其包含A）至少一种式I化合物，其中R * 1和R * 2各自独立地为未取代或取代的其它C 1 -C 12烷基，C 3 -C 6烯基，C 5 -C 8环烷基 C1-C4烷基，C1-C4烷氧基，C5-C8环烷基或羟基或氯原子，或未被取代或在苯环被1至3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基，C 1 -C 4烷氧基，C 5 -C 8环烷基或羟基或氯原子，R * 1和R * 2可以另外是氢和C 1 -C 12烷基，Y是S或O，和B）至少一种下列化合物：B1）高氯酸盐化合物，B2）缩水甘油基化合物，B3）β-二酮和β-酮酯，B4）二氢吡啶和聚二氢吡啶，B5）多元醇和二糖醇，B6）空间位阻胺（四烷基哌啶化合物），B7）碱铝硅酸盐（沸石），B8）水滑石，B9）碱金属铝酸盐（片钠铝石），B10）碱 - （或碱）（b）抗氧化剂和润滑剂和B12）有机锡稳定剂。

8. 发明授权

US5519077A Stabilized polyvinyl chloride 失效
标题翻译：稳定的聚氯乙烯
公开(公告)号：US5519077A
公开(公告)日：1996-05-21
申请号：US419313
申请日：1995-04-10
申请人： Rolf Drewes , Markus Kolb , Karl J. Kuhn , Hans-Jurgen Sander , Wolfgang Wehner
发明人： Rolf Drewes , Markus Kolb , Karl J. Kuhn , Hans-Jurgen Sander , Wolfgang Wehner
IPC分类号： C08K3/00 , C08G59/20 , C08K3/16 , C08K3/24 , C08K5/00 , C08K5/13 , C08K5/15 , C08K5/1515 , C08L27/06 , C08L63/00
CPC分类号： C08K3/16 , C08K5/1515
摘要： A high degree of stabilization of polyvinyl chloride is achieved by using a perchlorate, a terminal epoxide compound and an antioxidant.
摘要翻译：通过使用高氯酸盐，末端环氧化合物和抗氧化剂来实现聚氯乙烯的高度稳定化。

9. 发明授权

US5859100A Rigid PVC stabilised with N,N-dimethyl-6-aminouracils 失效
标题翻译：用N，N-二甲基-6-氨基尿嘧啶稳定的刚性PVC
公开(公告)号：US5859100A
公开(公告)日：1999-01-12
申请号：US934986
申请日：1997-09-22
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes , Kornelia Malzacher
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes , Kornelia Malzacher
IPC分类号： B29D23/00 , B29K27/06 , C08K5/3462 , C08K5/524 , C08L27/06 , C08K5/34
CPC分类号： C08K5/3462
摘要： Compositions are described, comprisingA) rigid or semi-rigid PVC having a plasticiser content of up to 20%, andB) at least one compound of formula 1, ##STR1## wherein X is O or S, and R is H or phenyl, with the proviso that compounds from the groups of the perchlorate compounds, glycidyl compounds, beta-diketones, beta-keto esters, dihydropyridines, polydihydro-pyridines, polyols, disaccharide alcohols, sterically hindered amines (tetraalkylpiperidine compounds), alkali alumosilicates (zeolites), hydrotalcites, alkali alumocarbonates (dawsonites) are not present.
摘要翻译：描述了组合物，其包括A）具有高达20％的增塑剂含量的刚性或半刚性PVC，和B）至少一种式1化合物，其中X是O或S，R是H或苯基条件是来自高氯酸盐化合物，缩水甘油基化合物，β-二酮，β-酮酯，二氢吡啶，聚二氢吡啶，多元醇，二糖醇，空间位阻胺（四烷基哌啶化合物），碱铝硅酸盐（沸石），水滑石，碱性碳酸铝（片钠土）不存在。

10. 发明授权

US5770643A Pyrrolodiazine derivatives as stabilizers for chlorine-containing polymers 失效
标题翻译：吡咯并嗪衍生物作为含氯聚合物的稳定剂
公开(公告)号：US5770643A
公开(公告)日：1998-06-23
申请号：US618591
申请日：1996-03-20
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Rolf Drewes
IPC分类号： C07D487/04 , C08K5/1515 , C08K5/34 , C08K5/3415 , C08K5/3462 , C08K5/52 , C08K5/524 , C08L27/06 , C08K5/04 , C08K5/09
CPC分类号： C07D487/04 , C08K5/3462
摘要： The invention relates to compositions comprising a) a chlorine-containing polymer and b) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.
摘要翻译：本发明涉及包含a）含氯聚合物和b）至少一种含至少一个式I（I）的基团的化合物，其中A是形成未取代的或含有两个氮环原子的取代的六元杂环。

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