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1. 发明授权

US08697820B2 Process for preparing high-reactivity isobutene homo- or copolymers 有权
标题翻译：制备高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US08697820B2
公开(公告)日：2014-04-15
申请号：US13568421
申请日：2012-08-07
申请人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
发明人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
IPC分类号： C08F4/06 , C08F2/00 , C08F10/00
CPC分类号： C08F110/10 , C08F10/10 , C08F4/00 , C08F4/06 , C08F2500/02 , C08F2500/03
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % by polymerization of isobutene or isobutene-comprising monomer mixtures in the presence of Lewis acids suitable as polymerization catalysts or of complexes which are effective as polymerization catalysts and are formed from Lewis acids and donors, and in the presence of initiators, wherein the initiators used are organic sulfonic acids Z—SO3H in which the variable Z denotes an alkyl radical, haloalkyl radical, cycloalkyl radical, aryl radical or arylalkyl radical.
摘要翻译：通过在适合作为聚合催化剂的路易斯酸存在下异丁烯或含异丁烯的单体混合物的聚合制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键含量的高反应性异丁烯均聚物或共聚物，或者作为聚合催化剂有效并且由路易斯酸和供体形成的络合物，并且在引发剂的存在下，其中所用的引发剂是有机磺酸Z-SO 3 H，其中变量Z表示烷基，卤代烷基，环烷基，芳基或芳基烷基。

2. 发明申请

US20120165473A1 PREPARATION OF DERIVATIVES OF ISOBUTENE COPOLYMERS 有权
标题翻译： ISOBUTENE共聚物衍生物的制备
公开(公告)号：US20120165473A1
公开(公告)日：2012-06-28
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

3. 发明申请

US20130041121A1 PROCESS FOR PREPARING HIGH-REACTIVITY ISOBUTENE HOMO- OR COPOLYMERS 有权
标题翻译：制备高反应性异丁基苯酚或共聚物的方法
公开(公告)号：US20130041121A1
公开(公告)日：2013-02-14
申请号：US13568421
申请日：2012-08-07
申请人： Hannah Maria KÖNIG , Klaus Mühlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
发明人： Hannah Maria KÖNIG , Klaus Mühlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
IPC分类号： C08F110/10 , C08F4/14 , C08F4/26
CPC分类号： C08F110/10 , C08F10/10 , C08F4/00 , C08F4/06 , C08F2500/02 , C08F2500/03
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % by polymerization of isobutene or isobutene-comprising monomer mixtures in the presence of Lewis acids suitable as polymerization catalysts or of complexes which are effective as polymerization catalysts and are formed from Lewis acids and donors, and in the presence of initiators, wherein the initiators used are organic sulfonic acids Z—SO3H in which the variable Z denotes an alkyl radical, haloalkyl radical, cycloalkyl radical, aryl radical or arylalkyl radical.
摘要翻译：通过在适合作为聚合催化剂的路易斯酸存在下异丁烯或含异丁烯的单体混合物的聚合制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键含量的高反应性异丁烯均聚物或共聚物，或者作为聚合催化剂有效并且由路易斯酸和供体形成的络合物，并且在引发剂的存在下，其中所用的引发剂是有机磺酸Z-SO 3 H，其中变量Z表示烷基，卤代烷基，环烷基，芳基或芳基烷基。

4. 发明授权

US4808212A Oxime esters of substituted quinoline-8-carboxylic acids and use thereof as herbicides 失效
标题翻译：取代喹啉-8-羧酸的肟酯及其作为除草剂的用途
公开(公告)号：US4808212A
公开(公告)日：1989-02-28
申请号：US944519
申请日：1986-12-22
申请人： Peter Plath , Karl Eicken , Bernd Zeeh , Ulrich Eichenauer , Helmut Hagen , Rolf-Dieter Kohler , Norbert Meyer , Bruno Wuerzer
发明人： Peter Plath , Karl Eicken , Bernd Zeeh , Ulrich Eichenauer , Helmut Hagen , Rolf-Dieter Kohler , Norbert Meyer , Bruno Wuerzer
IPC分类号： C07D333/00 , A01N43/42 , A01N43/48 , A01N43/653 , C07D215/32 , C07D215/48 , C07D335/00 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00
CPC分类号： C07D231/12 , A01N43/42 , A01N43/653 , C07D215/32 , C07D233/56 , C07D249/08 , C07D405/12 , C07D409/12
摘要： Oxime esters of substituted quinoline-8-carboxylic acids of the formula ##STR1## where X is hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, Z is hydrogen or methyl, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkoxyethyl, C.sub.1 -C.sub.4 -alkylthiomethyl, C.sub.1 -C.sub.4 -alkylthioethyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.5 -C.sub.8 -cycloalkyl, each of which is unsubstituted or bears up to 3 methyl substituents, hydrogen, cyano, acetyl, benzoyl, unsubstituted benzyl or phenyl, or benzyl or phenyl bearing up to 3 substitutents selected from the group consisting of halogen, cyano, trifluoromethyl, C.sub.1 -C.sub.4 -haloalkyloxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkyl, hydroxy, dimethylamino or acetamino, R.sup.2 is hydrogen if R.sup.1 is not hydrogen, R.sup.2 further denotes C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, chloromethyl, azolylmethyl, 1,1-dimethoxymethyl, cyano, C.sub.1 -C.sub.4 -alkoxycarbony, C.sub.1 -C.sub.4 -alkoxy, phenyl if R.sup.1 is H, CH.sub.3 or acetyl, or R.sup.2 denotes, when R.sup.1 is H or methyl, furyl, tetrahydrofuryl, thienyl, tetrahydropyranyl, tetrahydrothiopyranyl, dihydro-.DELTA..sup.3 -pyranyl or dihydro-.DELTA..sup.3 -thiopyranyl; further, R.sup.1 and R.sup.2, together with the carbon atom to which they are linked, denote C.sub.1 -C.sub.12 -cycloalkylidene, C.sub.5 -C.sub.6 -cycloalkenylidene or 4-oxacyclohexadienylidene, each of which is unsubstituted or bears up to 3 methyl substituents, it being possible, where the ring is 5-membered or 6-membered, or doubly unsaturated 6-membered, for it to contain an oxygen or sulfur atom, their preparation, and their use as herbicides.
摘要翻译：其中X是氢，C 1 -C 4烷基或卤素，Z是氢或甲基的取代喹啉-8-羧酸的肟酯，R 1是C 1 -C 6烷基，C 1 -C 4烷氧基甲基， C 1 -C 4 - 烷氧基乙基，C 1 -C 4 - 烷硫基甲基，C 1 -C 4 - 烷硫基乙基，C 1 -C 4 - 烷氧基羰基，C 3 -C 6 - 烯基或C 5 -C 8 - 环烷基，其各自为未取代的或至多含有3个甲基取代基，氰基，乙酰基，苯甲酰基，未取代的苄基或苯基，或带有至多3个选自卤素，氰基，三氟甲基，C 1 -C 4卤代烷氧基，C 1 -C 6 - 烷硫基，C 1 -C 4 - 烷氧基的取代基的苄基或苯基 C1-C4烷基，羟基，二甲基氨基或乙酰氨基，如果R1不是氢，R2是氢，R2还表示C1-C6-烷基，C1-C4-烷氧基甲基，氯甲基，唑基甲基，1,1-二甲氧基甲基，氰基，C1 -C 1-4烷氧基羰基，C 1 -C 4 - 烷氧基，如果R 1为H，CH 3或乙酰基，则为苯基，或R 2表示当R 1为H或甲基时，呋喃基，四氢呋喃基，噻吩基，四氢吡喃基，四氢噻喃基，二水合-3β-吡喃基或二氢-D-3,3-噻喃基; 此外，R 1和R 2与它们所连接的碳原子一起表示C 1 -C 12 - 亚环烷基，C 5 -C 6 - 环亚烯基或4-氧杂环己二亚苯基，其各自是未取代的或最多含有3个甲基取代基，可能是，其中环为5元或6元，或双不饱和6元，含有氧或硫原子，其制备及其作为除草剂的用途。

5. 发明授权

US09562117B2 Preparation of derivatives of isobutene copolymers 有权
标题翻译：异丁烯共聚物衍生物的制备
公开(公告)号：US09562117B2
公开(公告)日：2017-02-07
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10 , C08F8/32 , C08F8/46 , C08F8/30 , C08F8/14 , C08F290/04 , C08F8/42
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

6. 发明授权

US5008472A Preparation of 4,4"-dihydroxyterphenyl 失效
标题翻译：制备4,4“ - 二羟基苯基
公开(公告)号：US5008472A
公开(公告)日：1991-04-16
申请号：US400932
申请日：1989-08-31
申请人： Ulrich Eichenauer
发明人： Ulrich Eichenauer
IPC分类号： C07C37/04 , C07C39/15 , C07C303/06 , C07C303/08
CPC分类号： C07C303/08 , C07C303/06 , C07C37/04
摘要： 4,4'-Dihydroxyterphenyl is prepared by sulfonating terphenyl with sulfuric acid, sulfur trioxide, a mixture thereof or chlorosulfonic acid and then treating the resulting terphenyl-4,4'-disulfonic acid, which may be first converted into a dialkali metal salt, with an alkali metal hydroxide.
摘要翻译：通过用硫酸，三氧化硫，其混合物或氯磺酸磺化三联苯然后处理所得的三联苯-4,4'-二磺酸（其可以首先转化成二碱金属盐）制备4,4'-二羟基苯基苯基，与碱金属氢氧化物反应。

7. 发明授权

US4982005A Preparation of benzophenones 失效
标题翻译：二苯甲酮的制备
公开(公告)号：US4982005A
公开(公告)日：1991-01-01
申请号：US397873
申请日：1989-08-23
申请人： Peter Neumann , Ulrich Eichenauer
发明人： Peter Neumann , Ulrich Eichenauer
IPC分类号： C07C45/46 , C07C49/83 , C07C49/84
CPC分类号： C07C45/46 , C07C49/83 , C07C49/84
摘要： Benzophenones are prepared by condensing benzoic acids and aromatics of the benzene series by means of boron trifluoride in nitrobenzene as reaction medium.
摘要翻译：苯甲酮通过在硝基苯中作为反应介质将苯系列的苯甲酸和芳族化合物通过三氟化硼冷凝来制备。

8. 发明授权

US09296841B2 Preparation of isobutene homo- or copolymer derivatives 有权
标题翻译：异丁烯均聚物或共聚物衍生物的制备
公开(公告)号：US09296841B2
公开(公告)日：2016-03-29
申请号：US13305283
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F4/14 , C08F4/26 , C08F10/10 , C08F8/30 , C08F8/32 , C08F8/46 , C08F8/00 , C08F8/34 , C08F110/10 , C08F210/10
CPC分类号： C08F4/14 , C08F4/26 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/46 , C08F10/10 , C08F110/10 , C08F210/10 , C08F4/12 , C08F210/08
摘要： A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250,000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
摘要翻译：（i）在卤化铁 - 给体络合物，三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法（ ii）使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应，和（iii）在与亚结构反应的情况下，进一步反应以完成低分子量的形成极地组。均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团，硝基，羟基，硫醇基，羧酸或羧酸衍生物功能，磺酸或磺酸衍生物功能，醛官能团和/或甲硅烷基。

9. 发明授权

US06509403B1 Moulding materials with a polyarylene ether sulfone and aliphatic polyamide base 失效
标题翻译：具有聚芳醚砜和脂肪族聚酰胺基的成型材料
公开(公告)号：US06509403B1
公开(公告)日：2003-01-21
申请号：US09763698
申请日：2001-02-26
申请人： Martin Weber , Joachim Queisser , Ulrich Eichenauer
发明人： Martin Weber , Joachim Queisser , Ulrich Eichenauer
IPC分类号： C08K310
CPC分类号： C08L77/00 , C08K3/16 , C08L77/06 , C08L81/06 , C08L81/00 , C08L2666/04 , C08L2666/02 , C08L2666/08
摘要： Molding compositions comprise A) at least one polyarylene ether sulfone, B) at least one aliphatic polyamide, C) at least one filler, and also if desired D) an impact-modifying rubber or a mixture of various impact-modifying rubbers, and E) an additive or a mixture of various additives wherein the viscosity number of the polyamides B (measured in 0.5% strength by weight solution in 96% strength by weight sulfuric acid to DIN 53 727) is at least 180 ml/g, and the molding compositions comprise F) from 100 ppm to 0.5% by weight, based on the total weight of A to E, of copper bromide or copper iodide or a mixture of these.
摘要翻译：成型组合物包含A）至少一种聚亚芳基醚砜，B）至少一种脂肪族聚酰胺，C）至少一种填料，以及如果需要D）冲击改性橡胶或各种冲击改性橡胶的混合物，和E）添加剂或各种添加剂的混合物，其中聚酰胺B的粘度数（以按重量百分比计的硫酸按重量计按DIN 53727标准的重量百分比为0.5％的溶液）为至少180ml / g，模塑组合物包含F）基于A至E的总重量，从100ppm至0.5重量％的溴化铜或碘化铜或其混合物。

10. 发明授权

US4990660A Preparation of aromatic hydroxycarboxylic acids 失效
标题翻译：芳香族羟基羧酸的制备
公开(公告)号：US4990660A
公开(公告)日：1991-02-05
申请号：US287034
申请日：1988-12-21
申请人： Peter Neumann , Ulrich Eichenauer
发明人： Peter Neumann , Ulrich Eichenauer
IPC分类号： C07B61/00 , C07C51/09 , C07C51/255 , C07C51/367 , C07C65/03 , C07C65/105 , C07C65/11 , C07C65/24 , C07C315/04 , C07C317/44 , C07C317/46 , C07C319/20 , C07C323/62
CPC分类号： C07C323/62 , C07C317/44 , C07C51/09 , C07C51/255
摘要： Aromatic hydroxycarboxylic acids of the formula(HO--).sub.n A--COOHwhere n is 1 or 2 and A is a radical from the benzene, naphthalene, biphenyl, diphenyl ether, diphenyl sulfide or diphenyl sulfone series, are prepared by a process in which an acylated aromatic compound of the formula(R.sup.1 --CO--O--).sub.n A--CO--R.sup.2where R.sup.1 and R.sup.2 independently of one another are each unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl and n and A each have the abovementioned meanings, is oxidized with oxygen in the presence of a catalyst and of a solvent at from 20.degree. to 250.degree. C. to give a carboxylic acid of the formula(R.sup.1 --CO--O--).sub.n A--COOHwhere R.sup.1, n and A have the abovementioned meanings, and the acyl group or groups is or are then eliminated.
摘要翻译：式（HO-）nA-COOH的芳族羟基羧酸，其中n为1或2，A为来自苯，萘，联苯，二苯醚，二苯硫醚或二苯砜系列的基团，其通过以下方法制备：式（R1-CO-O-）nA-CO-R2的酰化芳族化合物，其中R 1和R 2彼此独立地各自为未取代或取代的C 1 -C 4 - 烷基，n和A各自具有上述含义，被氧化为在催化剂和溶剂存在下，在20-250℃下加入氧，得到式（R1-CO-O-）nA-COOH的羧酸，其中R1，n和A具有上述含义，酰基或酰基被除去或被除去。

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