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1. 发明申请

US20120165473A1 PREPARATION OF DERIVATIVES OF ISOBUTENE COPOLYMERS 有权
标题翻译： ISOBUTENE共聚物衍生物的制备
公开(公告)号：US20120165473A1
公开(公告)日：2012-06-28
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

2. 发明授权

US09458262B2 Process for preparing isobutene homopolymers or copolymers 有权
标题翻译：制备异丁烯均聚物或共聚物的方法
公开(公告)号：US09458262B2
公开(公告)日：2016-10-04
申请号：US13655839
申请日：2012-10-19
申请人： Hannah Maria Koenig , Rainer Urban , Klaus Muehlbach , Thomas Wettling , Uwe Rachwalsky , Stefan Hirsch , Anne Berg , Helmut Mach
发明人： Hannah Maria Koenig , Rainer Urban , Klaus Muehlbach , Thomas Wettling , Uwe Rachwalsky , Stefan Hirsch , Anne Berg , Helmut Mach
IPC分类号： C08F10/10 , C08F210/10 , C08F110/10
CPC分类号： C08F10/10 , C08F110/10 , C08F210/10 , C08F4/00 , C08F2500/01 , C08F2500/02 , C08F2500/03 , C08F212/08
摘要： Preparation of isobutene homopolymers or copolymers having a number average molecular weight of from 500 to 5 000 000 by polymerization of isobutene or an isobutene-comprising monomer mixture in the presence of a Lewis acid or a complex comprising a Lewis acid as polymerization catalyst, wherein the polymerization is carried out in the presence of at least one hemiacetal or full acetal which can be obtained by protic acid-catalyzed reaction of at least one C1-C12-hydrocarbyl alcohol with at least one aldehyde or ketone having from 1 to 12 carbon atoms.
摘要翻译：在路易斯酸或包含路易斯酸作为聚合催化剂的络合物存在下，通过异丁烯或含异丁烯的单体混合物的聚合制备数均分子量为500-500,000的异丁烯均聚物或共聚物，其中，在至少一种半缩醛或全缩醛的存在下进行聚合，所述半缩醛或全缩醛可以通过至少一种C 1 -C 12烃基醇与至少一种具有1至12个碳原子的醛或酮的质子酸催化反应而获得。

3. 发明申请

US20130102748A1 PROCESS FOR PREPARING ISOBUTENE HOMOPOLYMERS OR COPOLYMERS 有权
标题翻译：制备异丁烯共聚物或共聚物的方法
公开(公告)号：US20130102748A1
公开(公告)日：2013-04-25
申请号：US13655839
申请日：2012-10-19
申请人： Hannah Maria Koenig , Rainer Urban , Klaus Muehlbach , Thomas Wettling , Uwe Rachwalsky , Stefan Hirsch , Anne Berg , Helmut Mach
发明人： Hannah Maria Koenig , Rainer Urban , Klaus Muehlbach , Thomas Wettling , Uwe Rachwalsky , Stefan Hirsch , Anne Berg , Helmut Mach
IPC分类号： C08F4/00 , C08F10/10
CPC分类号： C08F10/10 , C08F110/10 , C08F210/10 , C08F4/00 , C08F2500/01 , C08F2500/02 , C08F2500/03 , C08F212/08
摘要： Preparation of isobutene homopolymers or copolymers having a number average molecular weight of from 500 to 5 000 000 by polymerization of isobutene or an isobutene-comprising monomer mixture in the presence of a Lewis acid or a complex comprising a Lewis acid as polymerization catalyst, wherein the polymerization is carried out in the presence of at least one hemiacetal or full acetal which can be obtained by protic acid-catalyzed reaction of at least one C1-C12-hydrocarbyl alcohol with at least one aldehyde or ketone having from 1 to 12 carbon atoms.
摘要翻译：在路易斯酸或包含路易斯酸作为聚合催化剂的络合物存在下，通过异丁烯或含异丁烯的单体混合物的聚合制备数均分子量为500-500,000的异丁烯均聚物或共聚物，其中，在至少一种半缩醛或全缩醛的存在下进行聚合，所述半缩醛或全缩醛可以通过至少一种C 1 -C 12烃基醇与至少一种具有1至12个碳原子的醛或酮的质子酸催化反应而获得。

4. 发明申请

US20100170636A1 SEMI-INTERPENETRATING NETWORK HAVING A PHASE OF A LINEAR NONCROSSLINKED ISOBUTENE POLYMER 审中-公开
标题翻译：具有线性非交联ISOBUTENE聚合物相的半互连网络
公开(公告)号：US20100170636A1
公开(公告)日：2010-07-08
申请号：US12664527
申请日：2008-06-19
申请人： Phillip Hanefeld , Nicole Hildebrandt , Klaus Muehlbach , Helmut Mach , Hans-Michael Walter , Dominique Teyssie , Odile Fichet , Cedric Vancaeyzeele , Benjamin Davion
发明人： Phillip Hanefeld , Nicole Hildebrandt , Klaus Muehlbach , Helmut Mach , Hans-Michael Walter , Dominique Teyssie , Odile Fichet , Cedric Vancaeyzeele , Benjamin Davion
IPC分类号： C08L23/00 , C08L25/02 , C08L83/04 , C08L75/04 , C08L75/02 , B32B37/12 , B05D3/02 , B05D3/06
CPC分类号： C08J3/246 , C08F255/08 , C08J2323/22 , C08L23/22 , C08L33/08 , C08L2205/04 , C08L2205/22 , C08L2666/06
摘要： A description is given of a semi-interpenetrating network having a first phase of a linear noncrosslinked isobutene polymer and a second phase of a crosslinked polymer, wherein the crosslinked polymer is obtained by crosslinking molecular enlargement reaction in the presence of the isobutene polymer. The crosslinked polymer is preferably obtained by free-radical polymerization of ethylenically unsaturated monomers comprising at least one polyethylenically unsaturated monomer. The networks are suitable as molding compounds having gas and moisture barrier effect or as adhesives.
摘要翻译：给出了具有线性非交联异丁烯聚合物的第一相和交联聚合物的第二相的半互穿网络的描述，其中交联聚合物通过在异丁烯聚合物存在下进行分子扩增反应而获得。交联聚合物优选通过包含至少一种多烯属不饱和单体的烯属不饱和单体的自由基聚合而获得。网络适合作为具有气体和水分阻隔作用的模制化合物或作为粘合剂。

5. 发明授权

US09296841B2 Preparation of isobutene homo- or copolymer derivatives 有权
标题翻译：异丁烯均聚物或共聚物衍生物的制备
公开(公告)号：US09296841B2
公开(公告)日：2016-03-29
申请号：US13305283
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F4/14 , C08F4/26 , C08F10/10 , C08F8/30 , C08F8/32 , C08F8/46 , C08F8/00 , C08F8/34 , C08F110/10 , C08F210/10
CPC分类号： C08F4/14 , C08F4/26 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/46 , C08F10/10 , C08F110/10 , C08F210/10 , C08F4/12 , C08F210/08
摘要： A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250,000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
摘要翻译：（i）在卤化铁 - 给体络合物，三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法（ ii）使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应，和（iii）在与亚结构反应的情况下，进一步反应以完成低分子量的形成极地组。均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团，硝基，羟基，硫醇基，羧酸或羧酸衍生物功能，磺酸或磺酸衍生物功能，醛官能团和/或甲硅烷基。

6. 发明授权

US09562117B2 Preparation of derivatives of isobutene copolymers 有权
标题翻译：异丁烯共聚物衍生物的制备
公开(公告)号：US09562117B2
公开(公告)日：2017-02-07
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10 , C08F8/32 , C08F8/46 , C08F8/30 , C08F8/14 , C08F290/04 , C08F8/42
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

7. 发明申请

US20120142868A1 PREPARATION OF ISOBUTENE HOMO- OR COPOLYMER DERIVATIVES 有权
标题翻译： ISOBUTENE共聚物衍生物的制备
公开(公告)号：US20120142868A1
公开(公告)日：2012-06-07
申请号：US13305283
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10 , C08F8/32 , C08F8/00 , C08F8/28 , C08F8/08 , C08F8/34 , C08F8/42
CPC分类号： C08F4/14 , C08F4/26 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/46 , C08F10/10 , C08F110/10 , C08F210/10 , C08F4/12 , C08F210/08
摘要： A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
摘要翻译：（i）在卤化铁 - 给体络合物，三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法（ ii）使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应，和（iii）在与亚结构反应的情况下，进一步反应以完成低分子量的形成极地组。均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团，硝基，羟基，硫醇基，羧酸或羧酸衍生功能，磺酸或磺酸衍生物功能，醛官能团和/或甲硅烷基。

8. 发明授权

US07956156B2 Method for the removal of isobutene oligomers from an isobutene polymer 失效
标题翻译：从异丁烯聚合物中除去异丁烯低聚物的方法
公开(公告)号：US07956156B2
公开(公告)日：2011-06-07
申请号：US12514899
申请日：2007-11-13
申请人： Hans Peter Rath , Phillip Hanefeld , Helmut Mach
发明人： Hans Peter Rath , Phillip Hanefeld , Helmut Mach
IPC分类号： C08G63/02 , C08G63/00
CPC分类号： C08F6/001 , C08F6/04 , C08L23/20
摘要： A process is described for removing isobutene oligomers from an isobutene polymer by stripping the isobutene polymer with vapors of a saturated hydrocarbon having at least 8 carbon atoms and at least partly driving out the isobutene oligomers. Troublesome isobutene oligomers are substantially removed without impairing the reactivity of the isobutene polymer (expressed as the content of the methylidene double bonds).
摘要翻译：描述了通过用具有至少8个碳原子的饱和烃的蒸气汽提异丁烯聚合物并且至少部分驱除异丁烯低聚物来从异丁烯聚合物中除去异丁烯低聚物的方法。基本上除去麻烦的异丁烯低聚物，而不损害异丁烯聚合物的反应性（以亚甲基双键的含量表示）。

9. 发明授权

US07932332B2 Isobutene polymerisation in the presence of a donor and fluorinated acids complex 有权
标题翻译：在供体和氟化酸络合物存在下，异丁烯聚合
公开(公告)号：US07932332B2
公开(公告)日：2011-04-26
申请号：US11597274
申请日：2005-05-11
申请人： Mirjam Herrlich-Loos , Christian Drohmann , Darijo Mijolovic , Thomas Wettling , Helmut Mach
发明人： Mirjam Herrlich-Loos , Christian Drohmann , Darijo Mijolovic , Thomas Wettling , Helmut Mach
IPC分类号： C08F2/00
CPC分类号： C08F10/10 , C08F4/12 , C08F4/06
摘要： The invention relates to a method for producing mainly ethylenically unsaturated isobutene polymers, wherein the sum of proportions of molecules with a double bond in an α position and molecules with a double bond in a position β is increased to 75% mol by polymerising isobutene in a liquid phase in the presence of a diluted or dispersed catalyst complex which comprises (i) an electron donor and (ii) a compound of general formula (I) Ha Meb [MFx]c, wherein Me is a metal with oxidation state m, M is an element selected from elements of the groups 2, 3, 4, 5, 10, 11, 13, 14 or 15 of the periodic table according to the IUPAC notation of an element oxidation number n, a is an integer ≧1, b is an integer ≧0, x is an integer ≧2 and c is [(a+mb)/(x−n)]. The catalyst is preferably embodied in the form of HBF4 O(CH3)2. The inventive method makes it possible to obtain an isobutene polymer having a low fluorine-content even using technical C4 hydrocarbon portions as an isobutene source.
摘要翻译：本发明涉及一种主要生产烯键式不饱和异丁烯聚合物的方法，其中α位上具有双键的分子和位置上具有双键的分子的比例之和< 通过在稀释或分散的催化剂配合物存在下在液相中聚合异丁烯而增加至75％摩尔，其包括（i）电子给体和（ii）通式（I）的化合物Ha Meb [MF x] c，其中Me是具有氧化态m的金属，M是根据元素氧化的IUPAC符号从元素周期表的第2,3,4,5,10,11,13,14或15族的元素中选出的元素数n，a为整数≥1，b为整数≥0，x为整数≥2，c为[（a + mb）/（x-n）]。催化剂优选以HBF 4 O（CH 3）2的形式实施。本发明的方法使得即使使用工业C4烃部分作为异丁烯源，也可以获得具有低含氟量的异丁烯聚合物。

10. 发明申请

US20090023882A1 PROCESS FOR PREPARATION OF POLYISOBUTYLENE WHOSE CONTENT OF TERMINAL DOUBLE BONDS IS MORE THAN 50% FROM AN INDUSTRIAL C4 HYDROCARBON STREAM COMPRISING 1-BUTENE, 2-BUTENE AND ISOBUTENE 审中-公开
标题翻译：用于制备聚异丁烯的方法包含1-BOTENE，2-BOTENE和ISOBUTENE的端子双重含量的含量超过了工业C4烃类流体的50％以上
公开(公告)号：US20090023882A1
公开(公告)日：2009-01-22
申请号：US12278590
申请日：2007-02-15
申请人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
发明人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C08F110/10
CPC分类号： C10G57/02 , C08F110/10 , C10G25/00 , C10G2300/1044 , C10G2300/1092 , C08F2/00
摘要： Preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene using a polymerization catalyst customary therefor from a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream which may comprise up to 3000 ppm by weight, of 1,3-butadiene, by reducing the content of oxygenates in the C4 hydrocarbon stream before the polymerization of the isobutene by contacting it with an inorganic adsorbent at a pressure of from 1 to 20 bar and a temperature of from 20 to 220° C.
摘要翻译：通过聚合催化剂制备具有大于50％的末端双键的聚异丁烯，所用的聚合催化剂通常来自可以包含高达3000ppm的1-丁烯，2-丁烯和异丁烷的C4烃流通过在异丁烯聚合之前通过将其与无机吸附剂在1至20巴的压力和20至20℃的温度下接触来降低C4烃流中的含氧化合物的含量，从而降低1,3-丁二烯的含量 220°C

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