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1. 发明申请

US20120142868A1 PREPARATION OF ISOBUTENE HOMO- OR COPOLYMER DERIVATIVES 有权
标题翻译： ISOBUTENE共聚物衍生物的制备
公开(公告)号：US20120142868A1
公开(公告)日：2012-06-07
申请号：US13305283
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10 , C08F8/32 , C08F8/00 , C08F8/28 , C08F8/08 , C08F8/34 , C08F8/42
CPC分类号： C08F4/14 , C08F4/26 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/46 , C08F10/10 , C08F110/10 , C08F210/10 , C08F4/12 , C08F210/08
摘要： A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
摘要翻译：（i）在卤化铁 - 给体络合物，三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法（ ii）使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应，和（iii）在与亚结构反应的情况下，进一步反应以完成低分子量的形成极地组。均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团，硝基，羟基，硫醇基，羧酸或羧酸衍生功能，磺酸或磺酸衍生物功能，醛官能团和/或甲硅烷基。

2. 发明授权

US09562117B2 Preparation of derivatives of isobutene copolymers 有权
标题翻译：异丁烯共聚物衍生物的制备
公开(公告)号：US09562117B2
公开(公告)日：2017-02-07
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10 , C08F8/32 , C08F8/46 , C08F8/30 , C08F8/14 , C08F290/04 , C08F8/42
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

3. 发明授权

US09296841B2 Preparation of isobutene homo- or copolymer derivatives 有权
标题翻译：异丁烯均聚物或共聚物衍生物的制备
公开(公告)号：US09296841B2
公开(公告)日：2016-03-29
申请号：US13305283
申请日：2011-11-28
申请人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria König , Klaus Mühlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F4/14 , C08F4/26 , C08F10/10 , C08F8/30 , C08F8/32 , C08F8/46 , C08F8/00 , C08F8/34 , C08F110/10 , C08F210/10
CPC分类号： C08F4/14 , C08F4/26 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/46 , C08F10/10 , C08F110/10 , C08F210/10 , C08F4/12 , C08F210/08
摘要： A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250,000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
摘要翻译：（i）在卤化铁 - 给体络合物，三卤化铝 - 供体络合物或烷基铝卤化物 - 供体络合物存在下聚合异丁烯或含异丁烯的单体混合物来制备异丁烯均聚物或共聚物衍生物的方法（ ii）使所得高反应性异丁烯聚合物与引入低分子量极性基团或其下结构的化合物反应，和（iii）在与亚结构反应的情况下，进一步反应以完成低分子量的形成极地组。均聚物或共聚物衍生物包括数均分子量为110至250,000的疏水聚异丁烯聚合物基团和包括氨基官能团的低分子量极性基团，硝基，羟基，硫醇基，羧酸或羧酸衍生物功能，磺酸或磺酸衍生物功能，醛官能团和/或甲硅烷基。

4. 发明申请

US20110201772A1 PROCESS FOR PREPARING HIGH-REACTIVITY ISOBUTENE HOMO- OR COPOLYMERS 有权
标题翻译：制备高反应性异丁基苯酚或共聚物的方法
公开(公告)号：US20110201772A1
公开(公告)日：2011-08-18
申请号：US13029413
申请日：2011-02-17
申请人： Hannah Maria König , Klaus Mühlbach , Matthias Kiefer , Sergei V. Kostjuk , Irina Vasilenko , Alexander Frolov
发明人： Hannah Maria König , Klaus Mühlbach , Matthias Kiefer , Sergei V. Kostjuk , Irina Vasilenko , Alexander Frolov
IPC分类号： C08F4/14 , C08F112/12 , C08F110/10
CPC分类号： C08F10/10 , C08F110/10 , C08F210/12 , C08F4/14 , C08F2500/01 , C08F212/08
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % and a polydispersity of preferably 1.05 to less than 3.5, by polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, especially of an aluminum trichloride-donor complex, said complex comprising, as the donor, an organic compound with at least one ether function or a carboxylic ester function.
摘要翻译：通过将异丁烯或含异丁烯的单体混合物聚合，制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键的含量，优选1.05至小于3.5的多分散性的高反应性异丁烯均聚物或共聚物作为聚合催化剂或卤化烷基铝供体络合物，特别是三氯化铝 - 供体络合物有效的铝三卤化铝 - 供体络合物的存在，所述复合物包含作为供体的具有至少一个醚官能团的有机化合物或羧酸酯官能团。

5. 发明授权

US09234098B2 Method for the production of composite materials 有权
标题翻译：复合材料生产方法
公开(公告)号：US09234098B2
公开(公告)日：2016-01-12
申请号：US13262755
申请日：2010-04-01
申请人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
发明人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
IPC分类号： B82Y30/00 , C08L83/02 , C08J5/00 , H01B1/04 , C08K3/36
CPC分类号： C08L83/02 , B82Y30/00 , C08J5/005 , C08K3/36
摘要： The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e. a conventional monomer which does not have a monomer unit A and is copolymerizable with the monomer unit B (embodiment 2).
摘要翻译：本发明涉及从a）至少一种无机或有机金属金属相制备纳米复合材料的方法; 和b）有机聚合物相; 包括至少一种单体M的聚合，所述单体M具有至少一个具有金属或半金属M的第一可聚合单体单元A和至少一个第二可聚合有机单体单元B，其通过共价化学键连接到可聚合单元A 在可聚合单体单元A和可聚合单元B两者都聚合并且A和B之间的键断裂聚合的聚合条件下，待聚合的单体M包含第一单体M1和至少一个第二单体M2，其至少不同在单体M1（实施方案1）的单体单元A和B中的一种中，或要聚合的单体以及至少一种单体M至少一种除单体M以外的其它单体，即常规不具有单体单元A并且可与单体单元B共聚的单体（实施方案2）。

6. 发明授权

US09006158B2 Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive 有权
标题翻译：聚四氢苯并恶嗪和双四氢苯并恶嗪及其作为燃料添加剂或润滑剂添加剂的用途
公开(公告)号：US09006158B2
公开(公告)日：2015-04-14
申请号：US13313400
申请日：2011-12-07
申请人： Arno Lange , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel , Ivette Garcia Castro
发明人： Arno Lange , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel , Ivette Garcia Castro
IPC分类号： C10L1/233 , C10M169/04 , C07D265/14 , C07D265/16 , C10L1/238 , C10L10/04 , C10M133/48 , C10M149/14
CPC分类号： C10L10/04 , C07D265/16 , C10L1/233 , C10L1/238 , C10L2200/0259 , C10L2230/22 , C10L2270/026 , C10M133/48 , C10M149/14 , C10M2215/225 , C10M2217/041 , C10N2220/021
摘要： Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines, obtainable by (A) reacting at least one diamine of the formula H2N-A-NH2 with a C1- to C12-aldehyde and a C1- to C8-alkanol at 20 to 80° C. with elimination and removal of water, (B) reacting the condensation product from (A) with a phenol which bears a long-chain substituent at 30 to 120° C., and optionally (C) heating the reaction product from (B) to 125 to 280° C. The resulting polytetrahydrobenzoxazines and bistetrahydrobenzoxazines are suitable as fuel or lubricant additives, especially as detergent additives for diesel fuels.
摘要翻译：可通过（A）使式H2N-A-NH2的至少一种二胺与C 1 -C 12 - 醛和C 1 -C 8烷醇在20至80℃下反应得到的聚四氢苯并恶嗪和双四氢苯并恶嗪，同时除去和除去水，（B）使来自（A）的缩合物与长链取代基的苯酚在30〜120℃下反应，任选（C）将反应产物从（B）加热至125〜280℃ 所得聚四氢苯并恶嗪和双四氢苯并恶嗪适用作燃料或润滑剂添加剂，特别是作为柴油燃料的洗涤剂添加剂。

7. 发明申请

US20130133243A1 QUATERNIZED NITROGEN COMPOUNDS AND USE THEREOF AS ADDITIVES IN FUELS AND LUBRICANTS 审中-公开
公开(公告)号：US20130133243A1
公开(公告)日：2013-05-30
申请号：US13535847
申请日：2012-06-28
申请人： Cornelia Röger-Göpfert , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel
发明人： Cornelia Röger-Göpfert , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel
IPC分类号： C10L1/22
CPC分类号： C10L1/221 , C10L1/2383 , C10L10/04 , C10L10/06 , C10L10/14 , C10L2200/0259 , C10L2270/023 , C10L2270/026 , C10M133/58 , C10M2215/28 , C10N2230/04 , C10N2270/00 , C10N2260/00
摘要： The present invention relates to novel quaternized nitrogen compounds, to the preparation thereof and to the use thereof as a fuel and lubricant additive, more particularly as a detergent additive; to additive packages which comprise these compounds; and to fuels and lubricants thus additized. The present invention further relates to the use of these quaternized nitrogen compounds as a fuel additive for reducing or preventing deposits in the injection systems of direct-injection diesel engines, especially in common-rail injection systems, for reducing the fuel consumption of direct-injection diesel engines, especially of diesel engines with common-rail injection systems, and for minimizing power loss in direct-injection diesel engines, especially in diesel engines with common-rail injection systems.

8. 发明申请

US20120149617A1 POLYTETRAHYDROBENZOXAZINES AND BISTETRAHYDROBENZOXAZINES AND USE THEREOF AS A FUEL ADDITIVE OR LUBRICANT ADDITIVE 有权
标题翻译：聚四氢呋喃并苯并噻唑并二苯并噻唑并作为燃料添加剂或润滑剂添加剂使用
公开(公告)号：US20120149617A1
公开(公告)日：2012-06-14
申请号：US13313400
申请日：2011-12-07
申请人： Arno LANGE , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel , Ivette Garcia Castro
发明人： Arno LANGE , Harald Böhnke , Wolfgang Grabarse , Hannah Maria König , Markus Hansch , Ludwig Völkel , Ivette Garcia Castro
IPC分类号： C10L1/233 , C10M169/04 , C07D265/14
CPC分类号： C10L10/04 , C07D265/16 , C10L1/233 , C10L1/238 , C10L2200/0259 , C10L2230/22 , C10L2270/026 , C10M133/48 , C10M149/14 , C10M2215/225 , C10M2217/041 , C10N2220/021
摘要： Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines, obtainable by (A) reacting at least one diamine of the formula H2N-A-NH2 with a C1- to C12-aldehyde and a C1- to C8-alkanol at 20 to 80° C. with elimination and removal of water, (B) reacting the condensation product from (A) with a phenol which bears a long-chain substituent at 30 to 120° C., and optionally (C) heating the reaction product from (B) to 125 to 280° C. The resulting polytetrahydrobenzoxazines and bistetrahydrobenzoxazines are suitable as fuel or lubricant additives, especially as detergent additives for diesel fuels.
摘要翻译：可通过（A）使式H2N-A-NH2的至少一种二胺与C 1 -C 12 - 醛和C 1 -C 8烷醇在20至80℃下反应得到的聚四氢苯并恶嗪和双四氢苯并恶嗪，同时除去和除去水，（B）使来自（A）的缩合物与长链取代基的苯酚在30〜120℃下反应，任选（C）将反应产物从（B）加热至125〜280℃ 所得聚四氢苯并恶嗪和双四氢苯并恶嗪适用作燃料或润滑剂添加剂，特别是作为柴油燃料的洗涤剂添加剂。

9. 发明授权

US08992801B2 Electroactive material, and use thereof in anodes for lithium-ion cells 有权
标题翻译：电活性材料及其在锂离子电池阳极中的应用
公开(公告)号：US08992801B2
公开(公告)日：2015-03-31
申请号：US13262453
申请日：2010-04-01
申请人： Hannah Maria König , Kirill Bramnik , Arno Lange , Phillip Hanefeld
发明人： Hannah Maria König , Kirill Bramnik , Arno Lange , Phillip Hanefeld
IPC分类号： H01B1/04 , H01M4/587 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/36 , H01M4/38 , H01M4/48 , H01M4/485 , H01M10/0525
CPC分类号： H01M4/587 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/362 , H01M4/38 , H01M4/48 , H01M4/485 , H01M10/0525 , Y02E60/122
摘要： The present invention relates to a novel electroactive material which comprises a graphitic carbon phase C and a (semi)metal phase and/or a (semimetal) oxide phase (MOx phase) and also to the use of the electroactive material in anodes for lithium ion cells. The invention further relates to a process for producing such materials. The electroactive material comprises: a) a carbon phase C; b) at least one MOx phase, where M is a metal or semimetal, x is from 0 to
摘要翻译：本发明涉及一种新型的电活性材料，其包括石墨碳相C和（半）金属相和/或（半金属）氧化物相（MOx相），以及锂阳离子阳极中电活性材料的使用细胞。本发明还涉及一种生产这种材料的方法。电活性材料包括：a）碳相C; b）至少一个MOx相，其中M是金属或半金属，x为0至

10. 发明申请

US20120271003A1 Block Copolymers As Thermoplastic Elastomers Made Of Polyisobutene Blocks And Oligoamide Blocks 审中-公开
标题翻译：嵌段共聚物作为由聚异丁烯嵌段和低聚酰胺嵌段制成的热塑性弹性体
公开(公告)号：US20120271003A1
公开(公告)日：2012-10-25
申请号：US13502184
申请日：2010-10-12
申请人： Hannah Maria König , Arno Lange , Holger Frauenrath , Jan Gebers , Emmanuel Croisier , Su Liang , Katalin Feher , Roman Niklaus Marty
发明人： Hannah Maria König , Arno Lange , Holger Frauenrath , Jan Gebers , Emmanuel Croisier , Su Liang , Katalin Feher , Roman Niklaus Marty
IPC分类号： C08L53/00
CPC分类号： C08G81/028
摘要： Aspects of the invention relate to block copolymers having the properties of thermoplastic elastomers made of blocks on the basis of isobutene monomer units as the soft segment and blocks on the basis of oligoamides composed of at least two base units, each of which comprises an amino or a carbonyl group in the α, β, γ or δ position to each other or directly bound to each other, as the hard segment. Such block copolymers are suited for producing fibers, microfibers, and films.
摘要翻译：本发明的方面涉及具有基于由异丁烯单体单元作为软链段的嵌段的热塑性弹性体的特性的嵌段共聚物和基于由至少两个碱基单元组成的低聚酰胺基的嵌段，其各自包含氨基或作为硬链段，α，bgr，γ或δ位置中的羰基彼此相互直接结合。这种嵌段共聚物适用于生产纤维，微纤维和薄膜。

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