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1. 发明申请

WO2007003541A2 MIXTURES OF REACTIVE DYES AND THEIR USE 审中-公开
标题翻译：反应性染料的混合物及其使用
公开(公告)号：WO2007003541A2
公开(公告)日：2007-01-11
申请号：PCT/EP2006/063625
申请日：2006-06-28
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , TZIKAS, Athanassios , ROENTGEN, Georg , CHRISTNACHER, Hubert Jean Luc , CORTESE, Bruno
发明人： TZIKAS, Athanassios , ROENTGEN, Georg , CHRISTNACHER, Hubert Jean Luc , CORTESE, Bruno
IPC分类号： C09B67/22 , C09D11/00
CPC分类号： D06P3/66 , C09B67/0042 , C09B67/0045 , C09B67/0057 , C09B67/0059 , C09D11/037 , C09D11/17 , C09D11/18 , C09D11/32 , D06P1/38
摘要： Dye mixtures that comprise at least one dye of formula (1), together with at least one dye from the group of formulae (2), (3), (4) and (5), wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.
摘要翻译：包含式（1）的至少一种染料与至少一种式（2），（3），（4）和（5）的基团的染料的染料混合物，其中基团具有式对于染色或印刷含纤维素纤维材料，具有良好的聚集性能，并且产生具有深色度和良好牢度特性的染色。

2. 发明申请

WO2013017331A1 MIXTURES OF REACTIVE DYES AND THEIR USE 审中-公开
标题翻译：反应性染料的混合物及其用途
公开(公告)号：WO2013017331A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/061643
申请日：2012-06-19
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , ROENTGEN, Georg , TZIKAS, Athanassios , CHRISTNACHER, Hubert Jean-Luc , FEKETE, Laszlo
发明人： ROENTGEN, Georg , TZIKAS, Athanassios , CHRISTNACHER, Hubert Jean-Luc , FEKETE, Laszlo
IPC分类号： C09B62/44 , C09B62/513 , C09B62/533 , C09B67/00 , D06P1/651 , D06P1/90
CPC分类号： C09B62/533 , C09B62/4415 , C09B62/513 , C09B67/0055 , D06P1/38 , D06P3/248 , D06P3/66
摘要： Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH 2 , and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R 1 is hydrogen, hydroxy, sulfo, C 1 -C 4 alkyl or C 1 -C 4 alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R 2 is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino or ureido, R 3 is C 1 -C 4 alkyl, (R 4 ) 0-2 denotes 0 to 2 identical or different substituents selected from the group C 1 -C 4 alkyl, C 1 -C 4 alkoxy or sulfo, X1is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y 1 , Y 2 , Y 3 , Y 4 and Y 5 are each independently of the other vinyl or a radical -CH 2 CH 2 -U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-containing fibre materials.
摘要翻译：包含至少一种式（1）的活性染料与至少一种式（2）的活性染料的染料混合物，其中基团A和B中的一个表示NH 2，基团A和B中的另一个表示 OH，D是苯或萘基，R 1是氢，羟基，磺基，C 1 -C 4烷基或被烷基部分被羟基或硫酸酯取代的C 1 -C 4烷氧基，R 2是氢，C 1 -C 4烷基，C 1 -C 4烷氧基， C2-C4烷酰基氨基或脲基，R3是C1-C4烷基，（R4）0-2表示0至2个相同或不同的选自C1-C4烷基，C1-C4烷氧基或磺基，X1是卤素，3-羧基吡啶-1-基或3-氨基甲酰基吡啶-1-基，Y1，Y2，Y3，Y4和Y5各自独立地为其它乙烯基或基团-CH2CH2-U，U为在碱性条件下可除去的基团，h，k，l，m和 n各自独立于数字0,1或2中的另一个，p和q各自独立于数字0或1中的另一个，适用于染色和印花细胞含硅或含氮纤维材料。

3. 发明申请

WO2008055805A1 MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 审中-公开
标题翻译：反应性染料的混合物及其在三色染色或印刷方法中的应用
公开(公告)号：WO2008055805A1
公开(公告)日：2008-05-15
申请号：PCT/EP2007/061642
申请日：2007-10-30
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , ROENTGEN, Georg , TZIKAS, Athanassios , CHRISTNACHER, Hubert Jean Luc
发明人： ROENTGEN, Georg , TZIKAS, Athanassios , CHRISTNACHER, Hubert Jean Luc
IPC分类号： C09B62/08 , C09B62/085 , C09B62/09 , C09B62/095 , C09B67/22
CPC分类号： C09B62/4407 , C09B62/4413 , C09B62/4415 , C09B67/005 , C09B67/0059
摘要： Dye mixtures, comprising at least one dye of formula (1) and at least one dye from the group of formulae (2) and (3) wherein Q 1 is C 1 -C 4 alkyl, halogen or a radical -SO 2 -Z, Q 2 and Q 3 are each independently of the other C 1 -C 4 alkoxy, Q 4 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, halogen or sulfo, Q 5 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, C 1 -C 4 alkanoylamino, ureido, halogen or sulfo, R 1 , R 2 and R 3 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X 1 , X 2 and X 3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3- carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T 1 , T 2 and T 3 are each independently of the others a non-fibre-reactive substituent or a fibre- reactive radical of formula (4a): -NH-(CH 2 ) 2-3 -SO 2 -Z, (4b): -NH-(CH 2 ) 2-3 -O-(CH 2 ) 2-3 -SO 2 -Z, (4c), (4d), (4e), (4f) or (4g),wherein (R 4 ) 0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, Q is a group -CH(Hal)-CH 2 -Hal or -C(Hal)=CH 2 , and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：包含至少一种式（1）的染料和至少一种式（2）和（3）基团的染料的染料混合物，其中Q 1是C 1〜 -C 4 - 烷基，卤素或-SO 2 -S-基团，Q 2和Q 3个基团各自为独立于其它C 1 -C 4烷氧基，Q 4是C 1 -C 4烷基 C 1 -C 4烷氧基，C 1 -C 4烷基，卤素或磺基，Q 5是C 1 -C 4烷基， -C 4烷氧基，C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基，烷基氨基，脲基，卤素或磺基，R 1，R 2和R 3各自独立地为氢或未取代或取代的 C 1 -C 4烷基，k和q各自独立地为0或1的另一个，n和p各自独立地为数个0,1或2的数个或2，m是数字0,1,2或3，t是数字1,2或3，X 1，X 2和X 3 各自独立于o 卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基或非纤维反应性取代基，T 1，T 2和T 2， -NH-（CH 2 2）2，其中R 1和R 3各自独立地为非纤维反应性取代基或式（4a）的纤维反应性基团： -3-SO 2 -Z，（4b）：-NH-（CH 2 2）2-3 - -O- （4c），（4d），（4e），（4f）或（4e）或（3）（4g），其中（R 4）0-2-2表示0-2个与卤素取代基相同或不同的取代基，C 1〜 C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基或基团-CH 2， -CH 2 -O-U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 -Hal或-C（Hal）= CH 2，Hal是卤素，特别适用于纤维素纤维材料的二色或三色染色或印花，并且具有良好重现性的产量染色或印花良好的全面坚牢性。

4. 发明申请

WO2007017425A2 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：反应性染料及其制备及其使用
公开(公告)号：WO2007017425A2
公开(公告)日：2007-02-15
申请号：PCT/EP2006/064937
申请日：2006-08-02
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , CHRISTNACHER, Hubert, Jean Luc , TZIKAS, Athanassios , ROENTGEN, Georg
发明人： CHRISTNACHER, Hubert, Jean Luc , TZIKAS, Athanassios , ROENTGEN, Georg
CPC分类号： C09B62/043 , C09B62/4416 , Y10S8/918
摘要： Reactive dyes of formula (1), wherein B is an aliphatic bridging member, R 1 is C 1 -C 4 alkyl, halogen or an -SO 2 -Z radical, R 2 and R 3 are each independently of the other C 1 -C 4 alkoxy, R 4 , R 5 and R 6 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number O or 1 , p is the number O, 1 or 2, X 1 and X 2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e) or (2f), wherein (R 7 ) 0-2 denotes from O to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH 2 -HaI or -C(Hal)=CH 2 group and Hal is halogen, or T is a radical of formula (3), wherein R 1 , R 2 , R 3 , R 4 , k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
摘要翻译：式（1）的活性染料，其中B是脂族桥连构件，R 1是C 1 -C 4烷基，卤素或 -SO 2 -Z基，R 2和R 3各自独立地为C 1 -C 3 - 4个烷氧基，R 4，R 5和R 6各自独立地为氢或未取代或取代的 C 1 -C 4烷基，k和q各自独立地为O或1的另一个，p是数字O 1或2，X 1， 1和X 2各自独立地为其它卤素，T为卤素，非纤维反应性取代基或式（2a），（2b）的纤维反应性基团，，（2c），（2d），（2e）或（2f），其中（R 7）0-2表示0至2个相同或不同的取代基，卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基或 -CH 2 - ， - CH 2 -O-u基团，U是基团在碱性条件下可以除去，Q是-CH（Hal）-CH 2 -H 2或-C（Hal）= CH 2 H 2基，Hal是卤素，或T是式（3）的基团，其中R 1，R 2，R 3，R 4，k ，p和q各自具有上述定义，特别适用于染色棉和具有良好全面坚牢性的产量染色。

5. 发明申请

WO2009053238A2 REACTIVE DYES, PROCESSES FOR THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：反应性染料及其制备方法及其使用
公开(公告)号：WO2009053238A2
公开(公告)日：2009-04-30
申请号：PCT/EP2008/063373
申请日：2008-10-07
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , TZIKAS, Athanassios , VERDUGO, Thomas , ROENTGEN, Georg
发明人： TZIKAS, Athanassios , VERDUGO, Thomas , ROENTGEN, Georg
IPC分类号： C09B62/503 , C09B62/465 , C09B67/00
CPC分类号： C09B62/5033 , C09B62/465 , C09B67/004
摘要： Reactive dyes of the formula (1) in which Qi is hydrogen, halogen or a radical of the formula (2a) or (2b),R 1 , R 2 and R 3 independently of one another are hydrogen or C 1 -C 4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, and R 1 in formula (1) and R 1 in formula (2a) have identical or different meanings and R 2 in formula (1) and R 2 in formula (2a) have identical or different meanings, (R 4 ) 0-1 and (R 5 ) 0-1 independently of one another are 0 or 1 identical or different substituents from the group consisting of C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen and sulfo, A is hydrogen or C 1 -C 4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C 1 -C 2 alkylene which is unsubstituted or substituted in the phenyl ring by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl or halogen, or C 5 -C 7 cycloalkyl which is unsubstituted or substituted by C 1 -C 4 alkyl, B is a C 2 -C 12 alkylene radical which can be interrupted by 1, 2 or 3 members from the group consisting of -NH-, -N(CH 3 )- or -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, a C 5 -C 7 cycloalkylene radical or C 1 -C 2 alkylene-C 5 -C 7 cycloalkylene radical which are unsubstituted or substituted in the cycloalkylring by C 1 C 4 alkyl,C 1 C 2 alkylenephenylene radical or phenylene radical which are unsubstituted or substituted in the phenyl ring by C 1 C 4 alkyl, C 1 C 4 alkoxy, C 2 -C 4 alkanoylamino, sulfo, halogen or carboxyl, V 1 and V 2 independently of one another are halogen, T is a radical of the formula -CO-(CH 2 ) m -SO 2 -Y (3a), -CO-CH(HaI)-CH 2 -HaI (3b) or -CO-C(HaI)=CH 2 (3c), Hal is halogen, X is hydroxyl or Y, Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group which can be split off under alkaline conditions, and m is the number 2, 3 or 4. are suitable for dyeing widely varying fibre materials, in particular cellulosic fibre materials, and produce dyeings with good allround properties.
摘要翻译：其中Q 1是氢，卤素或式（2a）或（2b）的基团，其中R 1，R 2和R 3彼此独立的式（1）的反应性染料是氢或未被取代或被羟基，磺基，羧基或硫酸根，式（1）中的R 1和式（2a）中的R 1具有相同或不同的含义，式（1）中的R 2和式（2a）中的R 2具有相同或不同的含义， 0-1和（R5）0-1彼此独立地是0或1个与C1-C4烷基，C1-C4烷氧基，卤素和磺基基团相同或不同的取代基，A是氢或未被取代的C 1 -C 4烷基被羟基，磺基，羧基或硫酸根取代的苯基，未被取代或被C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，羟基，羧基，氨基甲酰基，磺基或卤素取代的苯基，未取代或取代的苯基-C 1 -C 2亚烷基 C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，羟基，羧基，磺基，氨基甲酰基的苯环 1或卤素，或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基，B为C2-C12亚烷基，其可以被-NH-，-N（CH 3） - 或-O-，并且是未取代的或被羟基，磺基，硫酸基，氰基或羧基取代的C 5 -C 7亚环烷基或C 1 -C 2亚烷基-C 5 -C 7亚环烷基，其未被取代或被被C 1 -C 4烷基，C 1 -C 2亚烷基亚苯基或亚苯基取代的环烷基 C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，磺基，卤素或羧基，V 1和V 2彼此独立地在苯环中被取代或取代的基团是卤素，T是式-CO-（CH 2）m - SO2-Y（3a），-CO-CH（HaI）-CH2-HaI（3b）或-CO-C（HaI）= CH2（3c），Hal是卤素，X是羟基或Y，Y是乙烯基或基团-CH 2 -CH 2 -U和U是在碱性条件下可以分离的基团，m是2,3或4号，适用于广泛变化的纤维的染色特别是纤维素纤维材料，并产生具有良好全面性能的染色。

6. 发明申请

WO2005090484A1 FIBRE-REACTIVE DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：纤维反应性染料及其制备及其使用
公开(公告)号：WO2005090484A1
公开(公告)日：2005-09-29
申请号：PCT/EP2005/051044
申请日：2005-03-09
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , TZIKAS, Athanassios , ROENTGEN, Georg , CHRISTNACHER, Hubert Jean Luc
发明人： TZIKAS, Athanassios , ROENTGEN, Georg , CHRISTNACHER, Hubert Jean Luc
IPC分类号： C09B62/09
CPC分类号： C09B62/09 , C09B62/475 , C09B62/513
摘要： Reactive dyes of formula (I), wherein Q 1 and Q 2 are each independently of the other hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, D 1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D 2 has the same definition as D 1 or is a radical of formula (II), wherein (Q 3 ) 0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, carboxy and sulfo and Z 1 is a radical of formula -SO 2 -Y (3a), -NH-CO-(CH 2 ) m -SO 2 -Y (3b), -CONH-(CH 2 ) n -SO 2 -Y (3c), -NH-CO-CH(Hal)-CH 2 -Hal (3d) or -NH-CO-C(Hal)=CH 2 (3e), Y is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
摘要翻译：式（I）的活性染料，其中Q1和Q2各自独立于另一个氢或未取代或取代的C1-C4烷基，D1是重氮组分的基团，其本身是单或二偶氮染料或含有染料D2具有与D1相同的定义或者是式（II）的基团，其中（Q3）0-3表示0至3个相同或不同的选自卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，Z1是式-SO2-Y（3a），-NH-CO-（CH2）m-SO2-Y（3b），-CONH-（CH2）n-SO2-Y（3c） -NH-CO-CH（Hal）-CH2-Hal（3d）或-NH-CO-C（Hal）= CH2（3e），Y是乙烯基或-CH2-CH2-U基，U是在碱性条件下是可除去的，m和n各自独立地为数2，3或4，Hal为卤素，适用于染色含纤维素或含酰胺基的纤维材料。

7. 发明申请

WO2011018274A1 FIBRE-REACTIVE AZO DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：纤维反应性AZO染色及其制备及其使用
公开(公告)号：WO2011018274A1
公开(公告)日：2011-02-17
申请号：PCT/EP2010/059292
申请日：2010-06-30
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , TZIKAS, Athanassios , KLIER, Herbert , ROENTGEN, Georg
发明人： TZIKAS, Athanassios , KLIER, Herbert , ROENTGEN, Georg
IPC分类号： C09B62/44 , C09D11/00
CPC分类号： C09B62/4415 , C09D11/328
摘要： Reactive dyes of the formula (1) wherein B is an aliphatic bridging member, G is a sulfo naphthalene group or a sulfo benzene group of the formula (2a) or a pyridone radical of the formula (2b), R 1 , R 2 , R 3 and R 4 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, (R 5 ) h denotes h identical or different substituents selected from the group sulfo, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 6 is hydrogen, sulfo, halogen, carboxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or a fibre-reactive group Z 1 of the formula -SO 2 -Y (3a), -NH-CO-(CH 2 ) l -SO 2 -Y (3b), -CONH-(CH 2 ) m -SO 2 -Y (3c), -NH-CO-CH(Hal)-CH 2 -Hal (3d) or -NH-CO-C(Hal)=CH 2 (3e), R 7 is amino, C 1 -C 4 alkyl or a fibre-reactive group Z 2 of the formula -NH-(CH 2 ) n -SO 2 -Y (3a), (R 8 ) j denotes j identical or different substituents selected from the group sulfo, C 2 -C 4 alkanoylamino, ureido, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 9 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy, R 10 is hydrogen or C 1 -C 4 alkyl, R 11 is hydrogen, cyano, carbamoyl or sulfomethyl, and R 12 is hydrogen, C 1 -C 4 alkyl, or phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, ureido, halogen or sulfo, X 1 and X 2 are halogen, Hal is chlorine or bromine, h and j are each independently of the other a number 0, 1 or 2; k is a number 1, 2 or 3; I, m and n are each independently of the other a number 2, 3 or 4, and Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, with the proviso that the dye of formula (1) contains at least one fibre-reactive group Z 1 or Z 2 are suitable for dyeing cellulosic or amide-group-containing fibre materials.
摘要翻译：式（1）的活性染料其中B是脂族桥连构件，G是式（2a）的磺基萘基或磺基苯基或式（2b）的吡啶酮基，R1，R2，R3和 R 4各自独立地为氢或未取代的或取代的C 1 -C 4烷基，（R 5）h表示相同或不同的选自磺基，C 1 -C 4烷基和C 1 -C 4烷氧基的取代基，R 6为氢，磺基，卤素，羧基， C1-C4烷基，C1-C4烷氧基或式-SO2-Y（3a）的纤维反应性基团Z1，-NH-CO-（CH2）1-SO2-Y（3b），-CONH-（CH2）m- SO2-Y（3c），-NH-CO-CH（Hal）-CH2-Hal（3d）或-NH-CO-C（Hal）= CH2（3e），R7是氨基，C1-C4烷基或纤维 - 式-NH-（CH 2）n -SO 2 -Y（3a）的反应性基团Z 2，（R 8）j表示相同或不同的选自磺基，C 2 -C 4烷酰基氨基，脲基，C 1 -C 4烷基和C 1 -C 4烷氧基 R 9是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 10是氢或C 1 -C 4烷基，R 11是氢，氰基，氨基甲酰基或磺基甲基，和 R 12是氢，C 1 -C 4烷基或被C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，脲基，卤素或磺基取代的苯基，X 1和X 2是卤素，Hal是氯或溴，h和j是每个独立于另一个数字0,1或2; k是数字1,2或3; I，m和n各自独立地为数2，3或4，Y为乙烯基或基团-CH 2 -CH 2 -U，U为在碱性条件下可除去的基团，条件是式（1）含有至少一种纤维反应性基团Z 1或Z 2适用于染色含纤维素或含酰胺基的纤维材料。

8. 发明申请

WO2011101185A1 MIXTURES OF FIBRE-REACTIVE DYES AND THEIR USE IN A METHOD FOR DI- OR TRICHROMATIC DYEING OR PRINTING 审中-公开
标题翻译：纤维反应性染料的混合物及其在二色或三色染色或印刷方法中的用途
公开(公告)号：WO2011101185A1
公开(公告)日：2011-08-25
申请号：PCT/EP2011/050397
申请日：2011-01-13
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , TZIKAS, Athanassios , ROENTGEN, Georg , CASARTELLI, Marco , CODEMO, Remo , LANDRE, Jean-François
发明人： TZIKAS, Athanassios , ROENTGEN, Georg , CASARTELLI, Marco , CODEMO, Remo , LANDRE, Jean-François
IPC分类号： C09B67/22 , D06P3/66 , D06P1/38 , C09B62/513
CPC分类号： C09B62/513 , C09B62/4413 , C09B62/4415 , C09B67/0042 , C09B67/0047 , C09B67/0052 , D06P1/38 , D06P3/663 , Y10S8/917 , Y10S8/918 , Y10S8/919 , Y10S8/924 , Y10S8/926
摘要： Dye mixtures, comprising at least one red dyeing dye of the formula (1) and at least one blue, yellow, orange or brown dyeing dye from the group of the formulae (2), (3), (4), (5) and (6), wherein B is an aliphatic bridging member, R 1 , R 3 and R 8 are each independently of the others hydrogen or C 1 -C 4 alkyl, R 2 , R 4 , R 5 , R 9 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 are each independently of the others hydrogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or sulfo, R 6 and R 10 are each independently of the other amino or C 1 -C 4 alkyl, (R 7 ) j denotes j identical or different substituents selected from the group C 2 -C 4 alkanoylamino, ureido, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, (R 17 ) i denotes i identical or different substituents selected from the group C 2 -C 4 alkanoylamino, ureido, sulfo, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, X 1 , X 2 , X 3 , X 4 , X 5 and X 6 are each independently of the others halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Z 1 , Z 2 and Z 3 are each independently of the others a fibre-reactive group of the formula -SO 2 -Y 8 , (7a) or -NH-CO-(CH 2 ) 2-3 -SO 2 -Y 9 (7b), Y 1 , Y 2 , Y 3 , Y 4 , Y 5 , Y 6 , Y 7 , Y 8 and Y 9 are each independently of the others vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, i, j, k and l are each independently of the other the number 0, 1 or 2, m is the number 1 or 2, n and u are each independently of the other the number 1, 2 or 3, p and q are each independently of the other the number 0 or 1, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：包含至少一种式（1）的红染色剂和至少一种式（2），（3），（4），（5）的基团的蓝，黄，橙或棕染色染料的染料混合物，和（6）其中B是脂族桥连构件，R 1，R 3和R 8各自独立地为氢或C 1 -C 4烷基，R 2，R 4，R 5，R 9，R 11，R 12，R 13，R 14，R 15和R 16为各自独立地为氢，C 1 -C 4烷基，C 1 -C 4烷氧基或磺基，R 6和R 10各自独立地为其它氨基或C 1 -C 4烷基，（R 7）j表示相同或不同的选自C 2 -C 4烷酰基氨基，脲基，C 1 -C 4烷基和C 1 -C 4烷氧基，（R 17）i表示相同或不同的选自C 2 -C 4烷酰基氨基，脲基，磺基，C 1 -C 4烷基和C 1 -C 4烷氧基，X 1，X 2，X 3，X 4，X 5和 X 6各自独立地为卤素，3-羧基吡啶-1-基或3-氨基甲酰基吡啶-1-基，Z1，Z2和Z3各自独立地为式-SO2-Y8的纤维反应性基团（ 7A）或-NH-CO-（CH2）2-3-SO2-Y9（7b），Y1，Y2，Y3，Y4，Y5，Y6，Y7，Y8和Y9各自独立地为乙烯基或基团-CH2- CH2-U和U是在碱性条件下可除去的基团，i，j，k和l各自独立于数字0,1或2中的另一个，m是数字1或2，n和u各自独立地为数字1,2或3中的另一个，p和q各自独立于数字0或1中的另一个，r和s各自独立于数字0或1中的另一个，并且t是数字0,1或2， r，s和t的总和为2或3，特别适用于纤维素纤维材料的二色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。

9. 发明申请

WO2012025279A1 MIXTURES OF FIBRE-REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 审中-公开
标题翻译：纤维反应性染料的混合物及其在三色染色或印刷方法中的应用
公开(公告)号：WO2012025279A1
公开(公告)日：2012-03-01
申请号：PCT/EP2011/060442
申请日：2011-06-22
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GmbH , TZIKAS, Athanassios , ROENTGEN, Georg , LANDRE, Jean-François , CODEMO, Remo
发明人： TZIKAS, Athanassios , ROENTGEN, Georg , LANDRE, Jean-François , CODEMO, Remo
IPC分类号： D06P1/38 , D06P3/66 , C09B67/22
CPC分类号： D06P1/0096 , C09B67/0057 , C09B67/0073 , D06P1/0032 , D06P1/38 , D06P1/382 , D06P1/384 , D06P3/66 , D06P3/663 , D06P3/666
摘要： Dye mixtures, comprising least one yellow dye of the formula (1), at least one yellow dye of the formula (2), at least one red dye of the formula (3), at least one blue dye of the formula (4), wherein the radicals have the definitions given in the claims, are suitable especially for the trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：包含式（1）的至少一种黄色染料，至少一种式（2）的黄色染料，至少一种式（3）的红色染料，至少一种式（4）的蓝色染料的染料混合物，其中基团具有权利要求中给出的定义，特别适用于纤维素纤维材料的三色染色或印刷，并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。

10. 发明申请

WO2007062958A1 MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 审中-公开
标题翻译：反应性染料的混合物及其在三色染色或印刷方法中的应用
公开(公告)号：WO2007062958A1
公开(公告)日：2007-06-07
申请号：PCT/EP2006/068123
申请日：2006-11-06
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , SIRE, Jean-Marie , TZIKAS, Athanassios , ROENTGEN, Georg
发明人： SIRE, Jean-Marie , TZIKAS, Athanassios , ROENTGEN, Georg
IPC分类号： C09B67/22 , C09B62/08 , C09B31/057
CPC分类号： C09B62/4416 , C09B31/057 , C09B62/043 , C09B62/095 , C09B62/4413 , C09B62/4415 , C09B67/0047 , Y10S8/918
摘要： Dye mixtures, comprising at least one dye of formula (1) and at least one dye from the group of formulae (2) and (3), wherein B 1 , B 2 and B 3 are each independently of the others an organic bridging member, Q 1 is C 1 -C 4 alkyl, halogen or a radical -SO 2 -Z, Q 2 and Q 3 are each independently of the other C 1 -C 4 alkoxy, Q 4 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, halogen or sulfo, Q 5 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, C 1 -C 4 alkanoylamino, ureido, halogen or sulfo, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X 1 , X 2 , X 3 , X 4 , X 5 and X 6 are each independently of the others halogen, and T 1 , T 2 and T 3 are each independently of the others a non-fibre-reactive substituent or a fibre- reactive radical of formula -NH-(CH 2 ) 2-3 -SO 2 -Z (4a), -NH-(CH 2 ) 2-3 -O-(CH 2 ) 2-3 -SO 2 -Z (4b), (4c), (4d), (4e) or (4f) wherein (R 10 ) 0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, Q is a group -CH(Hal)-CH 2 -Hal or -C(Hal)=CH 2 , and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：包含至少一种式（1）染料和至少一种式（2）和（3）基团的染料的染料混合物，其中B 1，B 2， >和B 3 3各自独立地为有机桥连体，Q 1是C 1 -C 4 烷基，卤素或基团-SO 2 -Z，Q 2和Q 3各自独立地为另一个C 1 C 4 -C 4烷氧基，Q 4是C 1 -C 4烷氧基，C _{2 ）_{2-3 -O-（CH _{2 ）_{2-3 -SO}}}}

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