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    • 1. 发明申请
    • REACTIVE DYES, PROCESSES FOR THEIR PREPARATION AND THEIR USE
    • 反应性染料及其制备方法及其使用
    • WO2009053238A2
    • 2009-04-30
    • PCT/EP2008/063373
    • 2008-10-07
    • HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBHTZIKAS, AthanassiosVERDUGO, ThomasROENTGEN, Georg
    • TZIKAS, AthanassiosVERDUGO, ThomasROENTGEN, Georg
    • C09B62/503C09B62/465C09B67/00
    • C09B62/5033C09B62/465C09B67/004
    • Reactive dyes of the formula (1) in which Qi is hydrogen, halogen or a radical of the formula (2a) or (2b),R 1 , R 2 and R 3 independently of one another are hydrogen or C 1 -C 4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, and R 1 in formula (1) and R 1 in formula (2a) have identical or different meanings and R 2 in formula (1) and R 2 in formula (2a) have identical or different meanings, (R 4 ) 0-1 and (R 5 ) 0-1 independently of one another are 0 or 1 identical or different substituents from the group consisting of C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen and sulfo, A is hydrogen or C 1 -C 4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C 1 -C 2 alkylene which is unsubstituted or substituted in the phenyl ring by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl or halogen, or C 5 -C 7 cycloalkyl which is unsubstituted or substituted by C 1 -C 4 alkyl, B is a C 2 -C 12 alkylene radical which can be interrupted by 1, 2 or 3 members from the group consisting of -NH-, -N(CH 3 )- or -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, a C 5 -C 7 cycloalkylene radical or C 1 -C 2 alkylene-C 5 -C 7 cycloalkylene radical which are unsubstituted or substituted in the cycloalkylring by C 1 C 4 alkyl,C 1 C 2 alkylenephenylene radical or phenylene radical which are unsubstituted or substituted in the phenyl ring by C 1 C 4 alkyl, C 1 C 4 alkoxy, C 2 -C 4 alkanoylamino, sulfo, halogen or carboxyl, V 1 and V 2 independently of one another are halogen, T is a radical of the formula -CO-(CH 2 ) m -SO 2 -Y (3a), -CO-CH(HaI)-CH 2 -HaI (3b) or -CO-C(HaI)=CH 2 (3c), Hal is halogen, X is hydroxyl or Y, Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group which can be split off under alkaline conditions, and m is the number 2, 3 or 4. are suitable for dyeing widely varying fibre materials, in particular cellulosic fibre materials, and produce dyeings with good allround properties.
    • 其中Q 1是氢,卤素或式(2a)或(2b)的基团,其中R 1,R 2和R 3彼此独立的式(1)的反应性染料是氢或未被取代或被 羟基,磺基,羧基或硫酸根,式(1)中的R 1和式(2a)中的R 1具有相同或不同的含义,式(1)中的R 2和式(2a)中的R 2具有相同或不同的含义, 0-1和(R5)0-1彼此独立地是0或1个与C1-C4烷基,C1-C4烷氧基,卤素和磺基基团相同或不同的取代基,A是氢或未被取代的C 1 -C 4烷基 被羟基,磺基,羧基或硫酸根取代的苯基,未被取代或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,氨基甲酰基,磺基或卤素取代的苯基,未取代或取代的苯基-C 1 -C 2亚烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,磺基,氨基甲酰基的苯环 1或卤素,或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基,B为C2-C12亚烷基,其可以被-NH-,-N(CH 3) - 或-O-,并且是未取代的或被羟基,磺基,硫酸基,氰基或羧基取代的C 5 -C 7亚环烷基或C 1 -C 2亚烷基-C 5 -C 7亚环烷基,其未被取代或被被C 1 -C 4烷基,C 1 -C 2亚烷基亚苯基或亚苯基取代的环烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,磺基,卤素或羧基,V 1和V 2彼此独立地在苯环中被取代或取代的基团是卤素,T是式-CO-(CH 2)m - SO2-Y(3a),-CO-CH(HaI)-CH2-HaI(3b)或-CO-C(HaI)= CH2(3c),Hal是卤素,X是羟基或Y,Y是乙烯基或 基团-CH 2 -CH 2 -U和U是在碱性条件下可以分离的基团,m是2,3或4号,适用于广泛变化的纤维的染色 特别是纤维素纤维材料,并产生具有良好全面性能的染色。
    • 5. 发明申请
    • FIBRE-REACTIVE AZO DYES, THEIR PREPARATION AND THEIR USE
    • 纤维反应性AZO染色及其制备及其使用
    • WO2011018274A1
    • 2011-02-17
    • PCT/EP2010/059292
    • 2010-06-30
    • HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBHTZIKAS, AthanassiosKLIER, HerbertROENTGEN, Georg
    • TZIKAS, AthanassiosKLIER, HerbertROENTGEN, Georg
    • C09B62/44C09D11/00
    • C09B62/4415C09D11/328
    • Reactive dyes of the formula (1) wherein B is an aliphatic bridging member, G is a sulfo naphthalene group or a sulfo benzene group of the formula (2a) or a pyridone radical of the formula (2b), R 1 , R 2 , R 3 and R 4 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, (R 5 ) h denotes h identical or different substituents selected from the group sulfo, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 6 is hydrogen, sulfo, halogen, carboxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or a fibre-reactive group Z 1 of the formula -SO 2 -Y (3a), -NH-CO-(CH 2 ) l -SO 2 -Y (3b), -CONH-(CH 2 ) m -SO 2 -Y (3c), -NH-CO-CH(Hal)-CH 2 -Hal (3d) or -NH-CO-C(Hal)=CH 2 (3e), R 7 is amino, C 1 -C 4 alkyl or a fibre-reactive group Z 2 of the formula -NH-(CH 2 ) n -SO 2 -Y (3a), (R 8 ) j denotes j identical or different substituents selected from the group sulfo, C 2 -C 4 alkanoylamino, ureido, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 9 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy, R 10 is hydrogen or C 1 -C 4 alkyl, R 11 is hydrogen, cyano, carbamoyl or sulfomethyl, and R 12 is hydrogen, C 1 -C 4 alkyl, or phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, ureido, halogen or sulfo, X 1 and X 2 are halogen, Hal is chlorine or bromine, h and j are each independently of the other a number 0, 1 or 2; k is a number 1, 2 or 3; I, m and n are each independently of the other a number 2, 3 or 4, and Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, with the proviso that the dye of formula (1) contains at least one fibre-reactive group Z 1 or Z 2 are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    • 式(1)的活性染料其中B是脂族桥连构件,G是式(2a)的磺基萘基或磺基苯基或式(2b)的吡啶酮基,R1,R2,R3和 R 4各自独立地为氢或未取代的或取代的C 1 -C 4烷基,(R 5)h表示相同或不同的选自磺基,C 1 -C 4烷基和C 1 -C 4烷氧基的取代基,R 6为氢,磺基,卤素,羧基, C1-C4烷基,C1-C4烷氧基或式-SO2-Y(3a)的纤维反应性基团Z1,-NH-CO-(CH2)1-SO2-Y(3b),-CONH-(CH2)m- SO2-Y(3c),-NH-CO-CH(Hal)-CH2-Hal(3d)或-NH-CO-C(Hal)= CH2(3e),R7是氨基,C1-C4烷基或纤维 - 式-NH-(CH 2)n -SO 2 -Y(3a)的反应性基团Z 2,(R 8)j表示相同或不同的选自磺基,C 2 -C 4烷酰基氨基,脲基,C 1 -C 4烷基和C 1 -C 4烷氧基 R 9是氢,C 1 -C 4烷基或C 1 -C 4烷氧基,R 10是氢或C 1 -C 4烷基,R 11是氢,氰基,氨基甲酰基或磺基甲基,和 R 12是氢,C 1 -C 4烷基或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,脲基,卤素或磺基取代的苯基,X 1和X 2是卤素,Hal是氯或溴,h和j是 每个独立于另一个数字0,1或2; k是数字1,2或3; I,m和n各自独立地为数2,3或4,Y为乙烯基或基团-CH 2 -CH 2 -U,U为在碱性条件下可除去的基团,条件是式 (1)含有至少一种纤维反应性基团Z 1或Z 2适用于染色含纤维素或含酰胺基的纤维材料。
    • 6. 发明申请
    • REACTIVE DYES, PROCESSES FOR THEIR PREPARATION AND THEIR USE
    • 反应性染料及其制备方法及其使用
    • WO2009053238A3
    • 2009-12-17
    • PCT/EP2008063373
    • 2008-10-07
    • HUNTSMAN ADV MAT SWITZERLANDTZIKAS ATHANASSIOSVERDUGO THOMASROENTGEN GEORG
    • TZIKAS ATHANASSIOSVERDUGO THOMASROENTGEN GEORG
    • C09B62/503C09B62/465C09B67/22
    • C09B62/5033C09B62/465C09B67/004
    • Reactive dyes of the formula (1) in which Q1 is hydrogen, halogen or a radical of the formula (2a) or (2b),R1, R2 and R3 independently of one another are hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, and R1 in formula (1) and R1 in formula (2a) have identical or different meanings and R2 in formula (1) and R2 in formula (2a) have identical or different meanings, (R4)0-1 and (R5)0-1 independently of one another are 0 or 1 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, halogen and sulfo, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl which is unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C2alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B is a C2-C12alkylene radical which can be interrupted by 1, 2 or 3 members from the group consisting of -NH-, -N(CH3)- or -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, a C5-C7cycloalkylene radical or C1-C2alkylene-C5-C7cycloalkylene radical which are unsubstituted or substituted in the cycloalkylring by C1C4alkyl,C1C2alkylenephenylene radical or phenylene radical which are unsubstituted or substituted in the phenyl ring by C1C4alkyl, C1C4alkoxy, C2-C4alkanoylamino, sulfo, halogen or carboxyl, V1 and V2 independently of one another are halogen, T is a radical of the formula -CO-(CH2)m-SO2-Y (3a), -CO-CH(HaI)-CH2-HaI (3b) or -CO-C(HaI)=CH2 (3c), Hal is halogen, X is hydroxyl or Y, Y is vinyl or a radical -CH2-CH2-U and U is a group which can be split off under alkaline conditions, and m is the number 2, 3 or 4. are suitable for dyeing widely varying fibre materials, in particular cellulosic fibre materials, and produce dyeings with good allround properties.
    • 其中Q1是氢,卤素或式(2a)或(2b)的基团的式(1)的反应性染料是R 1,R 2和R 3彼此独立的氢或C 1 -C 4烷基,其未被取代或被 羟基,磺基,羧基或硫酸根,式(1)中的R 1和式(2a)中的R 1具有相同或不同的含义,式(1)中的R 2和式(2a)中的R 2具有相同或不同的含义, 0-1和(R5)0-1彼此独立地是0或1个与C1-C4烷基,C1-C4烷氧基,卤素和磺基基团相同或不同的取代基,A是氢或未被取代的C 1 -C 4烷基 被羟基,磺基,羧基或硫酸根取代的苯基,未被取代或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,氨基甲酰基,磺基或卤素取代的苯基,未取代或取代的苯基-C 1 -C 2亚烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,磺基,氨基甲酰基的苯环 1或卤素,或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基,B为C2-C12亚烷基,其可以被-NH-,-N(CH 3) - 或-O-,并且是未取代的或被羟基,磺基,硫酸基,氰基或羧基取代的C 5 -C 7亚环烷基或C 1 -C 2亚烷基-C 5 -C 7亚环烷基,其未被取代或被被C 1 -C 4烷基,C 1 -C 2亚烷基亚苯基或亚苯基取代的环烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,磺基,卤素或羧基,V 1和V 2彼此独立地在苯环中被取代或取代的基团是卤素,T是式-CO-(CH 2)m - SO2-Y(3a),-CO-CH(HaI)-CH2-HaI(3b)或-CO-C(HaI)= CH2(3c),Hal是卤素,X是羟基或Y,Y是乙烯基或 基团-CH 2 -CH 2 -U和U是在碱性条件下可以分离的基团,m是2,3或4号,适用于广泛变化的纤维的染色 特别是纤维素纤维材料,并产生具有良好全面性能的染色。
    • 8. 发明申请
    • REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 活性染料,它们的制备和它们的用途
    • WO2007017425A3
    • 2007-04-05
    • PCT/EP2006064937
    • 2006-08-02
    • HUNTSMAN ADV MAT SWITZERLANDCHRISTNACHER HUBERT JEAN LUCTZIKAS ATHANASSIOSROENTGEN GEORG
    • CHRISTNACHER HUBERT JEAN LUCTZIKAS ATHANASSIOSROENTGEN GEORG
    • C09B62/04C09B62/515C09D11/02
    • C09B62/043C09B62/4416Y10S8/918
    • Reactive dyes of formula (1), wherein B is an aliphatic bridging member, R 1 is C 1 -C 4 alkyl, halogen or an -SO 2 -Z radical, R 2 and R 3 are each independently of the other C 1 -C 4 alkoxy, R 4 , R 5 and R 6 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number O or 1 , p is the number O, 1 or 2, X 1 and X 2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e) or (2f), wherein (R 7 ) 0-2 denotes from O to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH 2 -HaI or -C(Hal)=CH 2 group and Hal is halogen, or T is a radical of formula (3), wherein R 1 , R 2 , R 3 , R 4 , k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
    • 式(1)的活性染料,其中B是脂族桥连成员,R 1是C 1 -C 4烷基,卤素或 -SO 2 -Z基团,R 2 SUB 3和R 3各自独立于另一个C 1 -C 1 -C R 4,R 5,R 5,和R 6各自独立地为氢或未被取代的或被取代的 C 1 -C 4烷基,k和q各自独立地是数字0或1,p是数字0,1或2,X (2a),(2b)的非纤维反应性取代基或纤维反应性基团的卤素,其中R 1和X 2各自独立于其它卤素,并且T为卤素, ,(2c),(2d),(2e)或(2f),其中(R 7)0-2表示O至2个相同或不同的 基团卤素,C 1 -C 4烷基,C 1 -C 4烷氧基和磺基,Z为乙烯基或 -CH 2 SUB-2 -U基团,并且U是基团 在碱性条件下可除去,Q为-CH(Hal)-CH 2 -Hal或-C(Hal)= CH 2 SUB基团,Hal为卤素或T为 式(3)的基团,其中R 1,R 2,R 3,R 4,k,k, ,p和q各自具有上面给出的定义,特别适用于具有良好的全面牢度性能的染色棉和产量染色。
    • 9. 发明申请
    • ADSORBENTS COMPRISING ANTHRAQUINONE DYE-LIGANDS FOR THE SEPARATION OF BIOLOGICAL MATERIALS
    • 包含用于分离生物材料的蒽醌衍生物的吸附剂
    • WO2006108760A2
    • 2006-10-19
    • PCT/EP2006/061121
    • 2006-03-29
    • CIBA SPECIALTY CHEMICALS HOLDING INC.EKKUNDI, Vadiraj, SubbannaPUNEKAR, Narayan, S.FONDEKAR, Kamalesh, PaiROENTGEN, GeorgKORDE, Shilpa, S.SHINDE, Ajit, B.MOORTHY, Masana
    • EKKUNDI, Vadiraj, SubbannaPUNEKAR, Narayan, S.FONDEKAR, Kamalesh, PaiROENTGEN, GeorgKORDE, Shilpa, S.SHINDE, Ajit, B.MOORTHY, Masana
    • C09B1/20C09B1/26C09B62/04
    • C09B69/101C09B62/06
    • A process for the separation of biological materials, wherein an adsorbent is used, which comprises a reaction product of a compound of formula and a substrate having a group capable of reaction with a reactive group in said compound of formula (1) to form a covalent bond, in which B is C 2 -C 12 alkylene radical, which can be interrupted by 1, 2 or 3 members from the group consisting of -NR 1 - or -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, R 1 is hydrogen or C 1 -C 4 alkyl, or B is a C 5 -C 9 cycloalkylene radical, C 1 -C 4 alkylene-C 5 -C 9 cycloalkylene radical or C 1 -C 4 alkylene-C 5 -C 9 cycloalkylene-C 1 -C 4 alkylene radical, which are unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, sulfo, halogen or carboxyl, or a phenylene radical, C 1 -C 4 alkylene-phenylene radical or C 1 -C 4 alkylene-phenylene-C 1 -C 4 alkylene radical, which are unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, sulfo, halogen or carboxyl, V is a non-fibre-reactive substituent or is a fibre-reactive substituent of formula wherein R 2 is hydrogen or unsubstituted or substituted C 1 -C 4 alkyl or a radical , R 3 is hydrogen, hydroxy, sulfo, sulfato, carboxy, cyano, halogen, C 1 -C 4 alkoxycarbonyl, C 1 -C 4 - alkanoyloxy, carbamoyl or a group -SO 2 -Y, R 4 is hydrogen or C 1 -C 4 alkyl, alk and alk 1 are each independently of the other linear or branched C 1 -C 6 alkylene, arylene is a phenylene or naphthylene radical which is unsubstituted or substituted by sulfo, carboxy, hydroxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or by halogen, Y is vinyl or a radical -CH 2 -CH 2 -U and U is a leaving group, Y 1 is a group -CH(Hal)-CH 2 (Hal) or -C(Hal)=CH 2 wherein Hal is chlorine or bromine, W is a group -SO 2 -NR 4 -, -CONR 4 - or -NR 4 CO- wherein R 4 is as defined above, Q is a radical -O- or -NR 4 - wherein R 4 is as defined above, and n is a number 0 or 1, X is halogen, and k and m are each independently of the other a number 0 or 1 and the sum of k+m is 1 or 2, with the exception of an adsorbent, comprising a compound of formula wherein Q is sulfo or carboxy, provides various dye-ligand structures available for screening in dye-ligand affinity chromatography.
    • 一种用于分离生物材料的方法,其中使用吸附剂,其包含式(1)化合物与具有能与所述式(1)化合物中的反应性基团反应的基团的底物的反应产物,以形成共价 键,其中B是C 2 -C 12亚烷基,其可以被1,2或3个成员所组成的组中断,其由-NR 1 - 或-O-,并且是未取代的或被羟基,磺基,硫酸基,氰基或羧基取代,R 1是氢或C 1 -C 3 > C 1-4烷基,或B是C 5 -C 9亚环烷基,C 1 -C 4烷基, /亚烷基-C 5亚烷基亚环烷基或C 1 -C 4亚烷基-C 亚烷基-C 1 -C 3亚烷基-C 1 -C 4亚烷基,其未被取代或被C 如上所定义,Q是基团-O-或-NR 4 - ,其中R 4如上定义,并且n是数字0或1,X 是卤素,并且k和m各自彼此独立地为0或1,并且k + m的和为1或2,除了吸附剂外,其中Q为磺基或羧基的式 可用于染料 - 配体亲和层析中筛选的各种染料 - 配体结构。
    • 10. 发明申请
    • FIBRE-REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 纤维反应性染料及其制备及其使用
    • WO2005090484A1
    • 2005-09-29
    • PCT/EP2005/051044
    • 2005-03-09
    • CIBA SPECIALTY CHEMICALS HOLDING INC.TZIKAS, AthanassiosROENTGEN, GeorgCHRISTNACHER, Hubert Jean Luc
    • TZIKAS, AthanassiosROENTGEN, GeorgCHRISTNACHER, Hubert Jean Luc
    • C09B62/09
    • C09B62/09C09B62/475C09B62/513
    • Reactive dyes of formula (I), wherein Q 1 and Q 2 are each independently of the other hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, D 1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D 2 has the same definition as D 1 or is a radical of formula (II), wherein (Q 3 ) 0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, carboxy and sulfo and Z 1 is a radical of formula -SO 2 -Y (3a), -NH-CO-(CH 2 ) m -SO 2 -Y (3b), -CONH-(CH 2 ) n -SO 2 -Y (3c), -NH-CO-CH(Hal)-CH 2 -Hal (3d) or -NH-CO-C(Hal)=CH 2 (3e), Y is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    • 式(I)的活性染料,其中Q1和Q2各自独立于另一个氢或未取代或取代的C1-C4烷基,D1是重氮组分的基团,其本身是单或二偶氮染料或含有 染料D2具有与D1相同的定义或者是式(II)的基团,其中(Q3)0-3表示0至3个相同或不同的选自卤素,C 1 -C 4烷基,C 1 -C 4烷氧基, 羧基和磺基,Z1是式-SO2-Y(3a),-NH-CO-(CH2)m-SO2-Y(3b),-CONH-(CH2)n-SO2-Y(3c) -NH-CO-CH(Hal)-CH2-Hal(3d)或-NH-CO-C(Hal)= CH2(3e),Y是乙烯基或-CH2-CH2-U基,U是 在碱性条件下是可除去的,m和n各自独立地为数2,3或4,Hal为卤素,适用于染色含纤维素或含酰胺基的纤维材料。