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    • 2. 发明申请
    • MIXTURES OF FIBRE-REACTIVE DYES AND THEIR USE IN A METHOD FOR DI- OR TRICHROMATIC DYEING OR PRINTING
    • 纤维反应性染料的混合物及其在二色或三色染色或印刷方法中的用途
    • WO2011101185A1
    • 2011-08-25
    • PCT/EP2011/050397
    • 2011-01-13
    • HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBHTZIKAS, AthanassiosROENTGEN, GeorgCASARTELLI, MarcoCODEMO, RemoLANDRE, Jean-François
    • TZIKAS, AthanassiosROENTGEN, GeorgCASARTELLI, MarcoCODEMO, RemoLANDRE, Jean-François
    • C09B67/22D06P3/66D06P1/38C09B62/513
    • C09B62/513C09B62/4413C09B62/4415C09B67/0042C09B67/0047C09B67/0052D06P1/38D06P3/663Y10S8/917Y10S8/918Y10S8/919Y10S8/924Y10S8/926
    • Dye mixtures, comprising at least one red dyeing dye of the formula (1) and at least one blue, yellow, orange or brown dyeing dye from the group of the formulae (2), (3), (4), (5) and (6), wherein B is an aliphatic bridging member, R 1 , R 3 and R 8 are each independently of the others hydrogen or C 1 -C 4 alkyl, R 2 , R 4 , R 5 , R 9 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 are each independently of the others hydrogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or sulfo, R 6 and R 10 are each independently of the other amino or C 1 -C 4 alkyl, (R 7 ) j denotes j identical or different substituents selected from the group C 2 -C 4 alkanoylamino, ureido, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, (R 17 ) i denotes i identical or different substituents selected from the group C 2 -C 4 alkanoylamino, ureido, sulfo, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, X 1 , X 2 , X 3 , X 4 , X 5 and X 6 are each independently of the others halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Z 1 , Z 2 and Z 3 are each independently of the others a fibre-reactive group of the formula -SO 2 -Y 8 , (7a) or -NH-CO-(CH 2 ) 2-3 -SO 2 -Y 9 (7b), Y 1 , Y 2 , Y 3 , Y 4 , Y 5 , Y 6 , Y 7 , Y 8 and Y 9 are each independently of the others vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, i, j, k and l are each independently of the other the number 0, 1 or 2, m is the number 1 or 2, n and u are each independently of the other the number 1, 2 or 3, p and q are each independently of the other the number 0 or 1, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    • 包含至少一种式(1)的红染色剂和至少一种式(2),(3),(4),(5)的基团的蓝,黄,橙或棕染色染料的染料混合物, 和(6)其中B是脂族桥连构件,R 1,R 3和R 8各自独立地为氢或C 1 -C 4烷基,R 2,R 4,R 5,R 9,R 11,R 12,R 13,R 14,R 15和R 16为 各自独立地为氢,C 1 -C 4烷基,C 1 -C 4烷氧基或磺基,R 6和R 10各自独立地为其它氨基或C 1 -C 4烷基,(R 7)j表示相同或不同的选自C 2 -C 4烷酰基氨基, 脲基,C 1 -C 4烷基和C 1 -C 4烷氧基,(R 17)i表示相同或不同的选自C 2 -C 4烷酰基氨基,脲基,磺基,C 1 -C 4烷基和C 1 -C 4烷氧基,X 1,X 2,X 3,X 4,X 5和 X 6各自独立地为卤素,3-羧基吡啶-1-基或3-氨基甲酰基吡啶-1-基,Z1,Z2和Z3各自独立地为式-SO2-Y8的纤维反应性基团( 7A) 或-NH-CO-(CH2)2-3-SO2-Y9(7b),Y1,Y2,Y3,Y4,Y5,Y6,Y7,Y8和Y9各自独立地为乙烯基或基团-CH2- CH2-U和U是在碱性条件下可除去的基团,i,j,k和l各自独立于数字0,1或2中的另一个,m是数字1或2,n和u各自独立地为 数字1,2或3中的另一个,p和q各自独立于数字0或1中的另一个,r和s各自独立于数字0或1中的另一个,并且t是数字0,1或2, r,s和t的总和为2或3,特别适用于纤维素纤维材料的二色或三色染色或印花,并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。