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    • 4. 发明专利
    • JPH05290880A
    • 1993-11-05
    • JP8721892
    • 1992-04-08
    • SUMITOMO METAL INDTOKYO ELECTRIC POWER COHITACHI LTD
    • ANRAKU TOSHIROKUDO TAKEOOTSUKA NOBUOMORI SADAOMARUYAMA TADASHICHIKAZAKI MITSUOCHIBA YOSHITERUHATOU HISAMITSU
    • H01M10/39
    • PURPOSE:To provide a material for the positive electrode container of a sodium-sulfur battery and the manufacturing method thereof with the improved corrosion resistance against high-temperature sulfur and sodium polysulfide. CONSTITUTION:(1) This is a material for the positive pole of a sodium-sulfur battery with excellent corrosion resistance which is characterized by having a chromized layer of not less than 25mum thick including as main body chrome carbide on the outermost surface of a base material of low alloy steel containing carbon steel having C of not more than 0.55wt.% or additionally including Mo of not more than 5wt.% and/or Cr of not more than 12wt.%. (2) This is the manufacturing method for a material for the positive electrode of a sodium-sulfur battery with excellent corrosion resistance which is characterized by forming a coating film layer including as a main body chrome carbide on the surface to which the chromizing treatment is applied at the temperature of 1000 to 1150 deg.C after carbonizing treatment is applied in advance to the foregoing composition and then the carbon concentration on the surface layer part is set to 0.7 to 1.5wt.%. Thereby, the corrosion of a positive electrode container may be prevented, so that the durability of the positive pole container is remarkably increased.