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1. 发明授权

US4698357A 2,4-dichloro-5-nitro-thiazole 失效
标题翻译： 2,4-二氯-5-硝基 - 噻唑
公开(公告)号：US4698357A
公开(公告)日：1987-10-06
申请号：US863638
申请日：1986-05-15
申请人： Gunther Beck , Paul Reinecke , Wilfried Paulus , Hans-Georg Schmitt
发明人： Gunther Beck , Paul Reinecke , Wilfried Paulus , Hans-Georg Schmitt
IPC分类号： A61K31/425 , A01N43/78 , A61K31/426 , A61P31/04 , C07D277/20 , C07D277/58
CPC分类号： A01N43/78 , C07D277/58
摘要： The compound 2,4-dichloro-5-nitro-thiazole of the formula ##STR1## is microbicidally active.
摘要翻译：式“IMAGE”的化合物2,4-二氯-5-硝基 - 噻唑具有抗微生物活性。

2. 发明授权

US4521412A Pesticidal iodopropargylammonium salts 失效
标题翻译：杀虫碘炔丙基铵盐
公开(公告)号：US4521412A
公开(公告)日：1985-06-04
申请号：US490899
申请日：1983-05-02
申请人： Hans-Georg Schmitt , Paul Reinecke , Wilfried Paulus , Hermann Genth , Walter Radt
发明人： Hans-Georg Schmitt , Paul Reinecke , Wilfried Paulus , Hermann Genth , Walter Radt
IPC分类号： A01N33/02 , A01N33/12 , A01N43/90 , A01N55/02 , C07C51/00 , C07C55/02 , C07C67/00 , C07C209/00 , C07C209/12 , C07C211/63 , C07D487/18 , C07F17/02 , A01N43/64 , C07D487/12
CPC分类号： C07D487/18 , A01N33/12 , A01N43/90 , A01N55/02 , C07F17/02
摘要： The present invention relates to iodopropargyl-ammonium salts of the formula (I) ##STR1## in which R, R.sup.1, R.sup.2 and X.sup..phi. have the meanings given in the description.They are obtained, for example, by reacting tertiary amines with an iodopropargyl halide. In a second reaction step, the halogen anion can be exchanged for other anions, such as phosphate and sulphate. The iodopropargylammonium salts of the formula (I) are distinguished by high activity as pest-combating agents, in particular by a fungicidal as well as bactericidal activity.
摘要翻译：本发明涉及式（I）的化合物（I）的碘代炔丙基铵盐，其中R，R 1，R 2和X 6具有在说明书中给出的含义。它们例如通过使叔胺与碘代炔丙基卤反应获得。在第二反应步骤中，卤素阴离子可以与其它阴离子交换，例如磷酸盐和硫酸盐。式（I）的碘代炔丙基铵盐的特征在于作为防虫剂的高活性，特别是通过杀真菌剂和杀菌活性。

3. 发明授权

US4778511A Fluorine-containing N-sulphenylated indazoles for use as bactericides and fungicides 失效
标题翻译：含氟的N-磺基吲唑，用作杀菌剂和杀真菌剂
公开(公告)号：US4778511A
公开(公告)日：1988-10-18
申请号：US830593
申请日：1986-02-18
申请人： Gerhard Heywang , Bernd Baasner , Albrecht Marhold , Wilfried Paulus , Paul Reinecke , Hans-Georg Schmitt
发明人： Gerhard Heywang , Bernd Baasner , Albrecht Marhold , Wilfried Paulus , Paul Reinecke , Hans-Georg Schmitt
IPC分类号： C07D231/56 , C07D491/056 , C07D239/00 , C07D471/00 , C07D487/00
CPC分类号： C07D231/56
摘要： Novel fluorine-containing N-sulfenylated indazoles are prepared by reacting the corresponding indazoles with sulfenyl halides in the presence of a solvent and/or diluent and in the presence of an acid-binder. The novel fluorine-containing N-sulfenylated indazoles are useful in the protection of industrial materials against attack by microorganisms such as bacteria, fungi, yeast, algae, and slime as plant protection agents, and in combating insects and arachrids.
摘要翻译：通过在溶剂和/或稀释剂的存在下和在酸 - 粘合剂的存在下使相应的吲唑与硫化烯基卤化物反应来制备新的含氟N-亚磺酰基吲唑。新型含氟N-亚磺酰基吲唑可用于保护工业材料免受微生物如细菌，真菌，酵母，藻类和粘液作为植物保护剂的攻击，并可用于防治昆虫和蜘蛛。

4. 发明授权

US4457930A Todopropargylsulphamides, microbicidal compositions and use 失效
标题翻译：叔丙炔酰胺，杀微生物剂及用途
公开(公告)号：US4457930A
公开(公告)日：1984-07-03
申请号：US526930
申请日：1983-08-26
申请人： Hans-Georg Schmitt , Wilfried Paulus , Hermann Genth , Wilhelm Brandes , Paul Reinecke , Hans Scheinpflug
发明人： Hans-Georg Schmitt , Wilfried Paulus , Hermann Genth , Wilhelm Brandes , Paul Reinecke , Hans Scheinpflug
IPC分类号： A01N41/08 , A01N43/08 , A01N43/36 , A01N43/84 , A01N47/02 , C07C67/00 , C07C301/00 , C07C307/06 , C07C307/08 , C07C307/10 , C07C313/00 , C07C323/49 , C07D295/22 , C07D295/26 , C07D307/52 , A01N41/02 , C07C161/00
CPC分类号： C07D295/26 , A01N41/08 , A01N43/08 , A01N47/02
摘要： 3-Iodopropargyl-sulphamides of the formula ##STR1## in which R represents hydrogen, alkyl, optionally substituted cycloalkyl, optionally substituted phenylalkyl, optionally substituted heterocyclylalkyl or optionally substituted phenyl, andR.sup.1 and R.sup.2 are identical or different and represent alkyl, orR.sup.1 and R.sup.2 represent an alkylene bridge which, together with the nitrogen atom at which they are located, form a ring which can be interrupted by further hetero atoms,which are microbicidally active.
摘要翻译：其中R表示氢，烷基，任选取代的环烷基，任选取代的苯基烷基，任选取代的杂环基烷基或任选取代的苯基，并且R 1和R 2相同或不同，表示烷基，或R 1和 R2表示亚烷基桥，其与它们所位于的氮原子一起形成可被另外的具有杀微生物活性的杂原子中断的环。

5. 发明授权

US4663327A 1-heteroaryl-4-aryl-pyrazolin-5-ones 失效
标题翻译： 1-杂芳基-4-芳基 - 吡唑啉-5-酮
公开(公告)号：US4663327A
公开(公告)日：1987-05-05
申请号：US733450
申请日：1985-05-10
申请人： Klaus Sasse , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke , Hans-Georg Schmitt , Wilfried Paulus
发明人： Klaus Sasse , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke , Hans-Georg Schmitt , Wilfried Paulus
IPC分类号： C07D251/46 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/56 , A01N43/66 , A01N47/02 , C07D213/77 , C07D215/38 , C07D215/42 , C07D217/22 , C07D239/42 , C07D239/47 , C07D251/16 , C07D251/22 , C07D317/00 , C07D401/04 , C07D401/12 , C07D403/04 , C07D405/14 , A61K31/53 , A61K31/44 , A61K31/505
CPC分类号： C07D401/04 , A01N43/56 , A01N43/66 , A01N47/02 , C07D403/04
摘要： Microbicidally active novel 1-heteroaryl-4-aryl-pyrazolin-5-ones of the formula ##STR1## in which R represents hydrogen or alkyl,R.sup.1 represents halogen, hydroxyl, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted phenoxy, a radical --S(O).sub.p -- alkyl which is optionally substituted in the alkyl part, nitro, optionally substituted amino or a fused-on carbocyclic or heterocyclic radical,p represents an integer 0, 1 or 2,R.sup.2 represents halogen or optionally substituted alkyl, or represents alkoxy, alkylmercapto, nitro, cyano, carboxamide or a fused-on carbocyclic radical,m represents an integer from 0 to 5,n represents an integer from 0 to 4, it being possible for the substituents to be identical or different when m and/or n represent a number greater than 1, andX, Y and Z are identical or different and represent a nitrogen atom or the radical .dbd.CH or ##STR2## wherein R.sup.2 has the meaning given above, with the proviso that at least one of the radicals X, Y and Z denotes a nitrogen atom.
摘要翻译：具有式“IMAGE”的杀微生物活性的新颖的1-杂芳基-4-芳基 - 吡唑啉-5-酮，其中R表示氢或烷基，R1表示卤素，羟基，任选取代的烷基，任选取代的烷氧基，任选取代的苯氧基，在烷基部分任选取代的-S（O）p-烷基，硝基，任选取代的氨基或稠合的碳环或杂环基，p表示整数0,1或2，R 2表示卤素或任选取代的烷基，或表示烷氧基，烷基巯基，硝基，氰基，甲酰胺或稠合的碳环基团，m表示0至5的整数，n表示0至4的整数，当m取代时，取代基可以相同或不同和/或n表示大于1的数，X，Y和Z相同或不同，表示氮原子或基团= CH或，其中R2具有上述含义，条件是至少一个的基团X，Y和 Z表示氮原子。

6. 发明授权

US5177090A Microbicidal agents 失效
标题翻译：杀菌剂
公开(公告)号：US5177090A
公开(公告)日：1993-01-05
申请号：US878794
申请日：1992-05-05
申请人： Hans-Joachim Diehr , Karl-Heinz Kuck , Wilfried Paulus , Hans-Georg Schmitt
发明人： Hans-Joachim Diehr , Karl-Heinz Kuck , Wilfried Paulus , Hans-Georg Schmitt
IPC分类号： A01N43/82 , B27K3/34 , C07D285/12 , C07D285/125
CPC分类号： C07D285/125 , A01N43/82
摘要： The invention relates to the use of 2,5-substituted 1,3,4-thiadiazoles of the formula ##STR1## in which R.sup.1 stands for straight-chain or branched halogenoalkyl,R.sup.2 stands for straight-chain or branched alkyl andn stands for the numbers 1 or 2,as microbicides for protecting industrial materials.
摘要翻译：本发明涉及式（Ⅰ）的2,5-取代的1,3,4-噻二唑，其中R1代表直链或支链卤代烷基，R2代表直链或支链烷基， n代表数字1或2，作为用于保护工业材料的杀菌剂。

7. 发明授权

US5175176A 1-[pyri(mi)dyl-(2)]-hydroxy-pyrazole microbicides 失效
标题翻译： 1-（PYRI（MI）DYL-（2）） - 羟基吡唑微生物
公开(公告)号：US5175176A
公开(公告)日：1992-12-29
申请号：US731680
申请日：1991-07-17
申请人： Klaus Sasse , Michael Schwamborn , Peter Wachtler , Monika Frie , Georg-Wilhelm Ludwig , Wilfried Paulus , Hans-Georg Schmitt
发明人： Klaus Sasse , Michael Schwamborn , Peter Wachtler , Monika Frie , Georg-Wilhelm Ludwig , Wilfried Paulus , Hans-Georg Schmitt
IPC分类号： A01N43/56 , C07D401/04 , C07D403/04 , C07D405/14
CPC分类号： C07D401/04 , A01N43/56 , C07D403/04
摘要： The invention relates to the use of certain 1-[2-pyri(mi)dyl]-5-hydroxy-pyrazoles which are characterized by formula (I) given in the description, as microbicides for the protection of industrial materials, and to certain novel 1-[2-pyri(mi)dyl]-5-hydroxy-pyrazoles which are characterized by formula (II) given in the description.
摘要翻译：本发明涉及以描述中给出的式（I）为特征的某些1- [2-吡啶（mi）Dyl] -5-羟基 - 吡唑作为用于保护工业材料的杀微生物剂以及某些由描述中给出的式（II）表征的新颖的1- [2-吡啶（mi）dyl] -5-羟基 - 吡唑。

8. 发明授权

US4966974A 2-phenylsulphinyl-nitro-pyridines, and their use as fungicides 失效
标题翻译： 2-苯基亚磺酰基 - 硝基吡啶，以及它们作为杀真菌剂的用途
公开(公告)号：US4966974A
公开(公告)日：1990-10-30
申请号：US332853
申请日：1989-04-03
申请人： Alexander Klausener , Wilfried Paulus , Hans-Georg Schmitt , Wilhelm Brandes
发明人： Alexander Klausener , Wilfried Paulus , Hans-Georg Schmitt , Wilhelm Brandes
IPC分类号： C07D213/71 , C07D213/61 , C09D5/14
CPC分类号： C07D213/61
摘要： The invention relates to 2-phenylsulphinyl-nitro-pyridines of the formula ##STR1## in which R.sub.1 denotes hydrogen, alkyl or halogen andR.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another represent hydrogen, halogen, alkyl, haloalkyl, alkyoxy, haloalkoxy, cyano, nitro, carboxyl, alkoxycarbonyl, carboxamido, N-alkyl- or N,N-dialkylcarboxamido, acyl or primary, secondary or tertiary amino.processes for their preparation, and their use as microbicides for the protection of materials and fungicides in plant protection.
摘要翻译：本发明涉及式（I）的2-苯基亚磺酰基 - 硝基吡啶，其中R 1表示氢，烷基或卤素，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，氰基，硝基，羧基，烷氧基羰基，甲酰胺基，N-烷基 - 或N，N-二烷基甲酰胺基，酰基或伯，仲或叔氨基。它们的制备方法，以及它们作为杀微生物剂用于保护植物保护中的材料和杀真菌剂的用途。

9. 发明授权

US4599427A Microbicidal azolylmethylamines 失效
标题翻译：杀菌唑类甲基胺
公开(公告)号：US4599427A
公开(公告)日：1986-07-08
申请号：US536929
申请日：1983-09-28
申请人： Siegfried Oeckl , Hans-Georg Schmitt , Wilfried Paulus , Hermann Genth
发明人： Siegfried Oeckl , Hans-Georg Schmitt , Wilfried Paulus , Hermann Genth
IPC分类号： A01N43/50 , A01N43/653 , A01N43/78 , A01N43/80 , B27K3/34 , C07D209/00 , C07D231/12 , C07D233/00 , C07D233/61 , C07D249/00 , C07D249/08 , C07D249/10 , C07D275/00 , C07D275/04 , C07D275/06 , C07D403/06 , C07D417/06 , C07D521/00 , C09D5/14
CPC分类号： C07D275/06 , A01N43/50 , A01N43/653 , A01N43/80 , C07D231/12 , C07D233/56 , C07D249/08 , C09D5/14 , B27K3/343
摘要： The new azolylmethylamines can be prepared by reaction of amines and azoles with formaldehyde. They can be used in microbicidal agents.
摘要翻译：新的唑基甲胺可以通过胺和吡唑与甲醛的反应来制备。它们可用于杀菌剂。

10. 发明授权

US4806540A 1-heteroaryl-4-aryl-pyrazole microbicides 失效
标题翻译： 1-杂芳基-4-芳基 - 吡唑杀微生物剂
公开(公告)号：US4806540A
公开(公告)日：1989-02-21
申请号：US99928
申请日：1987-09-23
申请人： Klaus Sasse , Gerd Hanssler , Hans-Georg Schmitt , Wilfried Paulus
发明人： Klaus Sasse , Gerd Hanssler , Hans-Georg Schmitt , Wilfried Paulus
IPC分类号： A01N43/40 , A01N43/56 , A01N47/06 , A01N47/16 , A01N47/22 , C07D401/04 , C07D403/04 , C07D405/14 , A61K31/44 , A61K31/47 , A61K31/505 , C07D215/20 , C07D215/36 , C07D215/38
CPC分类号： C07D401/04 , A01N43/56 , A01N47/06 , A01N47/16 , A01N47/22 , C07D403/04 , C07D405/14
摘要： Novel microbicidally active 1-heteroaryl-4-arylpyrazole derivatives of the formulae (I) and/or (1A) ##STR1## in which R represents hydrogen or alkyl,R.sup.1 represents halogen, hydroxyl, optionally substituted alkyl, optionally substituted alkoxy, a radical --S(O).sub.p -alkyl which is optionally substituted in the alkyl part, nitro or optionally substituted amino, or represents a fused-on carbocyclic or heterocyclic radicalp represents the integer 0, 1 or 2,n represents an integer from 0 to 5,X represents .dbd.CH--, or represents a nitrogen atom,Y represents CO or SO.sub.2 andR.sup.2 represents hydrogen, in each case optionaly substituted alkyl, cycloalkyl or aryl or a heterocyclic radical, or represents OR.sup.3, or also represents SR.sup.3, if Y is CO,whereinR.sup.3 represents optionally substituted alkyl or aryl, orR.sup.2 represents a radical ##STR2## wherein R.sup.4 represents hydrogen or saturated or unsaturated optionally substituted alkyl and optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or an optionally substituted heterocyclic radical, orR.sup.4 and R.sup.5, together with the nitrogen atom on which they are located, form a heterocyclic ring which optionally contains further hetero atoms and can optionally be mono- or polysubstituted by identical or different substituents.
摘要翻译：式（I）和/或（1A）的新型杀微生物活性1-杂芳基-4-芳基吡唑衍生物其中R表示氢或烷基，R 1表示卤素，羟基，任选地取代的烷基，任选取代的烷氧基，在烷基部分任选取代的-S（O）对 - 烷基，硝基或任选取代的氨基，或表示稠合的碳环或杂环基p表示整数0,1或 2，n表示0〜5的整数，X表示= CH-，或表示氮原子，Y表示CO或SO2，R2表示氢，各自为任选取代的烷基，环烷基或芳基或杂环基，或表示 OR 3，或者也表示SR 3，如果Y是CO，其中R 3表示任选取代的烷基或芳基，或R 2表示基团，其中R 4表示氢或饱和或不饱和的任选取代的烷基和任选取代的烷基，任选取代的环烷或任选取代的芳基或任选取代的杂环基，或者R 4和R 5与它们所位于的氮原子一起形成任选含有其它杂原子的杂环，并且可任选地被相同或不同的单取代或多取代取代基。

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