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1. 发明申请

US20110160415A1 Method for manufacturing fluoropolymers 有权
标题翻译：氟聚合物的制造方法
公开(公告)号：US20110160415A1
公开(公告)日：2011-06-30
申请号：US13002781
申请日：2009-07-06
申请人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
发明人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
IPC分类号： C08F14/26 , C07D317/42
CPC分类号： C07D317/34 , C07D317/42 , C08F14/18 , C08F114/26 , C08F2/24
摘要： The invention pertains to a method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein said aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I): wherein X1, X2, X3, equal or different from each other are independently selected among H, F, and C1-6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; RF is a divalent fluorinated C1-3 bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
摘要翻译：本发明涉及一种制备含氟聚合物的方法，该方法包括一种或多种含氟单体的水乳液聚合，其中所述水乳液聚合在至少一种下式（I）的环状氟化合物的存在下进行：其中X1，X2 各自独立地选自H，F和C 1-6（全）氟烷基，任选地包含一个或多个悬链或非链状氧原子的X 3相同或不同。 L表示键或二价基团; RF是二价氟化C1-3桥联基团; Y是选自阴离子官能团，阳离子官能团和非离子官能团的亲水性功能。

2. 发明授权

US08703889B2 Method for manufacturing fluoropolymers 有权
标题翻译：氟聚合物的制造方法
公开(公告)号：US08703889B2
公开(公告)日：2014-04-22
申请号：US13002781
申请日：2009-07-06
申请人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
发明人： Giuseppe Marchionni , Vito Tortelli , Ivan Wlassics , Valeri Kapeliouchko
IPC分类号： C08F14/26
CPC分类号： C07D317/34 , C07D317/42 , C08F14/18 , C08F114/26 , C08F2/24
摘要： A method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein the aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I): wherein X1, X2, X3, equal to or different from each other are independently selected among H, F, and C1-6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; RF is a divalent fluorinated C1-3 bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
摘要翻译：一种制备含氟聚合物的方法，其包含一种或多种氟化单体的水乳液聚合，其中所述水乳液聚合在至少一种下式（I）的环状氟化合物的存在下进行：其中X1，X2，X3等于彼此独立地选自H，F和C 1-6（全）氟烷基，任选地包含一个或多个悬链或非链状氧原子; L表示键或二价基团; RF是二价氟化C1-3桥联基团; Y是选自阴离子官能团，阳离子官能团和非离子官能团的亲水性功能。

3. 发明申请

US20120283383A1 Method for Manufacturing Fluoropolymers 有权
标题翻译：氟聚合物的制造方法
公开(公告)号：US20120283383A1
公开(公告)日：2012-11-08
申请号：US13515973
申请日：2010-12-16
申请人： Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
发明人： Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
IPC分类号： C08L27/18 , C07C51/42 , C08K5/06 , C09K3/00
CPC分类号： C08F6/14 , C08F14/18 , C08L27/12 , C08F2/24 , C08F2/32
摘要： The invention pertains to a process for manufacturing a (per)fluoropolymer, said process comprising polymerizing one or more fluorinated monomers in the presence of a multi-phase medium, said medium comprising: (A) a water phase [phase (W)]; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: Rf—(OCF2CF2)k-1—O—CF2—COOXa (I) wherein Rf is a C1-C3 perfluoroalkyl group comprising, optionally, one or more ether oxygen atoms, k is 2 or 3 and Xa is a selected from a monovalent metal and an ammonium group of formula NRN4, wherein RN, equal or different at each occurrence, is a hydrogen atom or a C1-C3 alkyl group; (C) an oil phase [phase (O)] comprising: at least one non-functional (per)fluoropolyether (non-functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (RF)] and at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R′F)] and having a number average molecular weight of at least 1000 and a solubility of less than 1% by weight in water at 25° C.
摘要翻译：本发明涉及制备（全）含氟聚合物的方法，所述方法包括在多相介质存在下聚合一种或多种氟化单体，所述介质包括：（A）水相[相（W）]; （B）至少一种具有式（I）的氟化表面活性剂（表面活性剂（FS））：Rf-（OCF2CF2）k-1-O-CF2-COOXa（Ⅰ）其中Rf是C1-C3全氟烷基，任选地，一个或多个醚氧原子，k为2或3，Xa为选自式NRN4的一价金属和铵基团，其中每次出现时相同或不同的RN为氢原子或C1-C3 烷基; （C）油相[相（O）]，其包含：至少一种包含至少一种（全）氟聚氧亚烷基链[链（RF）]的至少一种非官能（全）氟聚醚（非功能性PFPE）包含至少一种（全）氟聚氧亚烷基链[链（R'F）]并且具有至少1000的数均分子量和小于1重量％在水中的溶解度为25的（全）氟聚醚（功能性PFPE） C。

4. 发明申请

US20070015888A1 Polymerization process 失效
标题翻译：聚合过程
公开(公告)号：US20070015888A1
公开(公告)日：2007-01-18
申请号：US11476560
申请日：2006-06-29
申请人： Marco Apostolo , Valeri Kapeliouchko , Alessandro Galia , Onofrio Scialdone , Giuseppe Filardo
发明人： Marco Apostolo , Valeri Kapeliouchko , Alessandro Galia , Onofrio Scialdone , Giuseppe Filardo
IPC分类号： C08F16/24
CPC分类号： C08F14/18 , C08F2/04 , C08F2/08
摘要： The invention pertains to a polymerization process including polymerizing at least one fluorinated monomer in the presence of a radical initiator and a surfactant in a polymerization medium containing carbon dioxide to provide a polymer product, characterized in that the surfactant is a functional (per)fluoropolyether, which is a polymer comprising recurring units (R1) and at least one functional group having a heteroatom other than fluorine, said recurring units having at least one ether linkage in the main chain and at least one fluorine atom (fluoropolyoxyalkene chain).
摘要翻译：本发明涉及一种聚合方法，其包括在自由基引发剂和表面活性剂存在下，在含有二氧化碳的聚合介质中聚合至少一种氟化单体以提供聚合物产物，其特征在于表面活性剂是功能性（全）氟聚醚，其是包含重复单元（R1）和至少一个具有除了氟以外的杂原子的官能团的聚合物，所述重复单元在主链中具有至少一个醚键和至少一个氟原子（氟代聚氧亚烷基链）。

5. 发明授权

US09803036B2 Method for manufacturing fluoropolymers 有权
公开(公告)号：US09803036B2
公开(公告)日：2017-10-31
申请号：US13515973
申请日：2010-12-16
申请人： Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
发明人： Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
IPC分类号： C08F6/14 , C08F14/18
CPC分类号： C08F6/14 , C08F14/18 , C08L27/12 , C08F2/24 , C08F2/32
摘要： The invention pertains to a process for manufacturing a (per)fluoropolymer, said process comprising polymerizing one or more fluorinated monomers in the presence of a multi-phase medium, said medium comprising: (A) a water phase [phase (W)]; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: Rf—(OCF2CF2)k-1—O—CF2—COOXa (I) wherein Rf is a C1-C3 perfluoroalkyl group comprising, optionally, one or more ether oxygen atoms, k is 2 or 3 and Xa is a selected from a monovalent metal and an ammonium group of formula NRN4, wherein RN, equal or different at each occurrence, is a hydrogen atom or a C1-C3 alkyl group; (C) an oil phase [phase (O)] comprising: at least one non-functional (per)fluoropolyether (non-functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (RF)] and at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R′F)] and having a number average molecular weight of at least 1000 and a solubility of less than 1% by weight in water at 25° C.

6. 发明授权

US07915356B2 Polymerisation process 有权
标题翻译：聚合过程
公开(公告)号：US07915356B2
公开(公告)日：2011-03-29
申请号：US12296216
申请日：2007-04-06
申请人： Vincenzo Arcella , Valeri Kapeliouchko , Stefano Ferrero , Aniello Gargiulo
发明人： Vincenzo Arcella , Valeri Kapeliouchko , Stefano Ferrero , Aniello Gargiulo
IPC分类号： C08F2/18 , C08F2/00 , C08J5/00 , B01J19/18
CPC分类号： C08F2/01 , B01F7/00975 , B01F7/166 , B01F7/1665 , C08F14/18 , C08F14/26 , Y10S526/918 , C08F2/02
摘要： A fluoropolymer [polymer (F)], a polymerisation process for its manufacture, and a molding process using such fluoropolymer [polymer (F)].The polymerisation process comprises polymerising at least one fluorinated monomer in a polymerization medium, in which the polymerization medium is mixed by means of a stirring system comprising at least two counter-rotating impellers. Surprisingly and advantageously, the polymerization occurs without fouling or deposit formation on the reactor walls, and moreover, occurs with improved homogeneity, without composition, pressure or temperature gradients, thus enabling obtaining homogeneous polymer composition with no risk of local overheating.A polymer (F) obtained from such process has improved morphology (percentage of organized structures, i.e. of particles of regular shape) and, hence, has good free flowing properties which make it suitable for being processed by compression molding with no need of intermediate milling or grinding process or other size reduction process.
摘要翻译：含氟聚合物[聚合物（F）]，其制造的聚合方法和使用这种含氟聚合物[聚合物（F）]的成型方法。聚合方法包括在聚合介质中聚合至少一种氟化单体，其中聚合介质通过包括至少两个反向旋转叶轮的搅拌系统混合。令人惊奇和有利地，聚合反应发生在反应器壁上没有结垢或沉积物形成，此外，在没有组成，压力或温度梯度的情况下，具有改进的均匀性发生，从而能够获得均匀的聚合物组合物，而没有局部过热的风险。从这种方法获得的聚合物（F）具有改善的形态（有组织的结构的百分比，即规则形状的颗粒的百分比），因此具有良好的自由流动性，使其适于通过压缩加工而不需要中间研磨或研磨过程或其他尺寸缩小过程。

7. 发明申请

US20110040039A1 TETRAFLUOROETHYLENE POLYMER PARTICLES 审中-公开
标题翻译：四氢氟乙烯聚合物颗粒
公开(公告)号：US20110040039A1
公开(公告)日：2011-02-17
申请号：US11739145
申请日：2007-04-24
申请人： Giovanna Palamone , Tiziana Poggio , Valeri Kapeliouchko , Michele Laus
发明人： Giovanna Palamone , Tiziana Poggio , Valeri Kapeliouchko , Michele Laus
IPC分类号： C08L27/18 , B32B5/00 , B82Y99/00
CPC分类号： C08F259/08 , Y10T428/2998 , C08F220/10
摘要： Core-shell particles having a core of at least one tetrafluoroethylene (TFE) polymer and having an average primary particle size of less than 50 nm; and a shell of at least one acrylic polymer having recurring units, more than 50% by moles of which being derived from at least one ethylenically unsaturated monomer having directly bonded to one of the sp2 carbon atoms of the ethylenic unsaturation at least one group of formula: Process for manufacturing core-shell particles. Use as ingredients/additives in polymer compositions, polymer composition and articles containing the same.
摘要翻译：具有至少一种四氟乙烯（TFE）聚合物的芯并且具有小于50nm的平均一次粒径的核 - 壳颗粒; 和具有重复单元的至少一种丙烯酸类聚合物的壳，大于50摩尔％的至少一种烯键式不饱和单体，其至少一种烯属不饱和单体直接键合到烯属不饱和键的一个sp2碳原子上，至少一个式制造核 - 壳粒子的方法。用作聚合物组合物中的成分/添加剂，聚合物组合物和含有它们的物品。

8. 发明授权

US07678848B2 Process for preparing fluoropolymer dispersions 失效
标题翻译：氟聚合物分散体的制备方法
公开(公告)号：US07678848B2
公开(公告)日：2010-03-16
申请号：US11319804
申请日：2005-12-29
申请人： Marco Malvasi , Valeri Kapeliouchko
发明人： Marco Malvasi , Valeri Kapeliouchko
IPC分类号： C08L1/00
CPC分类号： C08F6/16 , C08J3/03 , C08J2327/12 , C08L27/12
摘要： A process to substantially remove fluorinated anionic surfactants from fluoropolymer dispersions comprising the following steps: a) addition to the fluoropolymer dispersion of one or more non fluorinated surfactants; b) contact of the dispersion with an anionic exchanger; c) separation of the dispersion from the anionic exchanger and recovery of the dispersion substantially fluorinated anionic surfactant free.
摘要翻译：从含氟聚合物分散体中大量除去氟化阴离子表面活性剂的方法，包括以下步骤：a）加入一种或多种非氟化表面活性剂的含氟聚合物分散体; b）分散体与阴离子交换剂的接触; c）从阴离子交换剂分离分散体并回收分散体基本氟化的阴离子表面活性剂。

9. 发明授权

US07294276B2 Process for preparing fluoropolymer dispersions 有权
标题翻译：氟聚合物分散体的制备方法
公开(公告)号：US07294276B2
公开(公告)日：2007-11-13
申请号：US11319802
申请日：2005-12-29
申请人： Marco Malvasi , Tiziana Poggio , Valeri Kapeliouchko
发明人： Marco Malvasi , Tiziana Poggio , Valeri Kapeliouchko
IPC分类号： C02P1/42 , C08L27/12
CPC分类号： C08F6/16 , C08J3/03 , C08J2327/12 , Y10S210/915 , C08L27/12
摘要： A process to substantially remove the fluorinated anionic surfactants from fluoropolymer dispersions comprising the following steps: a) addition to the fluoropolymer dispersion of an anionic polyelectrolyte; b) contact of the dispersion with an anionic exchanger; c) separation of the dispersion from the anionic exchanger and recovery of the dispersion substantially fluorinated anionic surfactant free.
摘要翻译：从含氟聚合物分散体中大量除去氟化阴离子表面活性剂的方法，包括以下步骤：a）加入阴离子聚电解质的氟聚合物分散体; b）分散体与阴离子交换剂的接触; c）从阴离子交换剂分离分散体并回收分散体基本氟化的阴离子表面活性剂。

10. 发明授权

US07691936B2 Fine fluoropolymer powders 失效
标题翻译：精细含氟聚合物粉末
公开(公告)号：US07691936B2
公开(公告)日：2010-04-06
申请号：US11488022
申请日：2006-07-18
申请人： Marco Malvasi , Stefano Ferrero , Valeri Kapeliouchko
发明人： Marco Malvasi , Stefano Ferrero , Valeri Kapeliouchko
IPC分类号： C08L27/12
CPC分类号： C08F6/22 , C08F6/16 , C08F6/18 , C08J3/12 , C08J3/128 , C08J2327/12 , C08L27/12 , C08L2666/04
摘要： Fine fluoropolymer powders substantially fluorinated surfactant free, in particular fluorinated ionic surfactants, preferably perfluorooctanoic acid or its salts, comprising an anionic polyelectrolyte.
摘要翻译：基本上不含氟表面活性剂的精细含氟聚合物粉末，特别是包含阴离子聚电解质的氟化离子表面活性剂，优选全氟辛酸或其盐。

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