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1. 发明授权

US5939589A Process and reactor for carrying out conversion with catalysts suspended in liquids 失效
标题翻译：用于悬浮在液体中的催化剂进行转化的工艺和反应器
公开(公告)号：US5939589A
公开(公告)日：1999-08-17
申请号：US820001
申请日：1997-03-18
申请人： Gerd Kaibel , Franz Josef Brocker , Manfred Stroezel
发明人： Gerd Kaibel , Franz Josef Brocker , Manfred Stroezel
IPC分类号： B01F5/06 , B01J8/00 , B01J8/06 , B01J8/18 , B01J8/20 , B01J8/22 , B01J8/34 , C07C45/62 , C07C49/00
CPC分类号： C07C45/62 , B01J8/0015 , B01J8/007 , B01J8/06 , B01J8/1863 , B01J8/20 , B01J8/22 , B01J8/34
摘要： Catalytic reactions are carried out in a reactor which contains a liquid phase in which at least one catalyst is suspended, and which may additionally contain a gas phase, by a process in which the liquid phase and, if present, also the gas phase are fed, at least partly, through an apparatus having orifices or channels in the reactor, the hydraulic diameter of which orifices or channels is from 0.5 to 20 mm, preferably from 1 to 10 mm, particularly preferably from 1 to 3 mm.
摘要翻译：催化反应在包含液相的反应器中进行，其中至少一种催化剂悬浮在其中，并且其可以另外含有气相，通过其中液相和（如果存在的话）气相被加料的方法至少部分地通过具有反应器中的孔或通道的装置，其孔径或通道的水力直径为0.5至20mm，优选为1至10mm，特别优选为1至3mm。

2. 发明授权

US6150564A Selective liquid-phase hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds 失效
标题翻译： α，β-不饱和羰基化合物的选择性液相氢化
公开(公告)号：US6150564A
公开(公告)日：2000-11-21
申请号：US275867
申请日：1999-03-25
申请人： Franz Josef Brocker , Gerd Kaibel , Werner Aquila , Hartwig Fuchs , Gunter Wegner , Manfred Stroezel
发明人： Franz Josef Brocker , Gerd Kaibel , Werner Aquila , Hartwig Fuchs , Gunter Wegner , Manfred Stroezel
IPC分类号： B01J23/44 , B01J8/20 , B01J8/22 , B01J19/24 , B01J23/46 , C07B61/00 , C07C45/62 , C07C49/04
CPC分类号： C07C45/62 , B01J19/2465 , B01J19/2495 , B01J8/20 , B01J8/22 , B01J2219/00103 , B01J2219/0011 , B01J2219/32
摘要： The invention relates to a process for the selective liquid-phase hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds of the formula I, ##STR1## where R.sub.1 is hydrogen or an organic radical, and R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or a C.sub.1 -- to C.sub.4 --alkyl group, to saturated carbonyl compounds of the formula II ##STR2## using hydrogen in the presence of a pulverulent palladium and/or rhodium catalyst and in the presence of an organic base. The process is carried out in a packed bubble column reactor (1, 2) with product recycling (11, 17) and circulating hydrogen gas (4, 15, 16). It is particularly suitable for the selective hydrogenation of citral to citronellal.
摘要翻译：本发明涉及用于式I的α，β-不饱和羰基化合物的选择性液相氢化的方法，其中R 1是氢或有机基团，并且R 2，R 3和R 4彼此独立地是氢或使用氢气在粉状钯和/或铑催化剂存在下并在有机碱的存在下，使C1至C4烷基与饱和的式II化合物反应。该方法在具有产品再循环（11,17）和循环氢气（4,15,16）的包装泡罩塔反应器（1,2）中进行。它特别适用于柠檬醛对香茅醛的选择性氢化。

3. 发明授权

US5750806A Preparation of alkenes by partial hydrogenation of alkynes over fixed-bed palladium catalysts 失效
标题翻译：通过固定床钯催化剂部分氢化制备烯烃
公开(公告)号：US5750806A
公开(公告)日：1998-05-12
申请号：US679118
申请日：1996-07-12
申请人： Franz Josef Brocker , Manfred Stroezel , Udo Rheude
发明人： Franz Josef Brocker , Manfred Stroezel , Udo Rheude
IPC分类号： B01J23/44 , B01J35/06 , B01J37/02 , C07B61/00 , C07C5/08 , C07C5/09 , C07C11/02 , C07C29/17 , C07C33/02
CPC分类号： B01J37/0238 , B01J23/44 , C07C5/09 , B01J37/0225 , C07C2523/44
摘要： Alkenes are prepared by partial hydrogenation of alkynes in the liquid phase over palladium catalysts by a process which comprises A. using a fixed-bed catalyst which is obtainable by heating the preferably metallic carrier in the air, cooling, coating under reduced pressure with metallic palladium, suitable molding and processing to a monolithic catalyst elements and B. adding from 10 to 180 ppm of CO to the hydrogen used for the hydrogenation.
摘要翻译：烯烃通过钯催化剂的液相中炔烃的部分氢化制备，该方法包括A.使用固定床催化剂，其可通过在空气中加热优选金属载体而获得，冷却，用金属钯在减压下涂覆，适合于整体催化剂元件的模塑和加工，以及将B加入到用于氢化的氢气中的10至180ppm的CO。

4. 发明授权

US06329554B1 Continuous preparation of unsaturated ketones 失效
标题翻译：连续制备不饱和酮
公开(公告)号：US06329554B1
公开(公告)日：2001-12-11
申请号：US09391619
申请日：1999-09-07
申请人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Bernhard Bockstiegel , Klaus Reimer , Gerd Kaibel , Hagen Jaedicke
发明人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Bernhard Bockstiegel , Klaus Reimer , Gerd Kaibel , Hagen Jaedicke
IPC分类号： C07C4500
CPC分类号： C07C45/676 , B01D3/009 , B01D3/14 , B01D3/141 , B01D3/322 , B01J19/24 , B01J2219/00103 , B01J2219/00162 , B01J2219/00777 , B01J2219/32268 , Y02P20/127 , Y02P20/582 , C07C49/203 , C07C49/255
摘要： Process for the continuous preparation of unsaturated ketones of the formula I where the dashed line can be an additional C—C bond, R1 is an alkyl, and R2 is an aliphatic hydrocarbon having from 1 to 37 carbons, a cycloalkyl or a cycloalkylalkyl, by reacting an unsaturated alcohol of the formula II with an alkyl acetoacetate of the formula III where R3 is an alkyl having from 1 to 5 carbons, in the presence or organic aluminum compounds as catalyst.
摘要翻译：用于连续制备式I的不饱和酮的方法，其中虚线可以是另外的CC键，R 1是烷基，R 2是具有1至37个碳的脂族烃，环烷基或环烷基烷基，通过使不饱和的式II的醇与式III的乙酰乙酸烷基酯反应，其中R 3是具有1至5个碳的烷基，在有机铝化合物作为催化剂存在下进行。

5. 发明授权

US06956141B1 Method for preparing acetylene alcohols and their secondary products 失效
标题翻译：乙炔醇及其次要产物的制备方法
公开(公告)号：US06956141B1
公开(公告)日：2005-10-18
申请号：US09913979
申请日：2000-02-22
申请人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
发明人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
IPC分类号： C07C29/17 , C07C29/42 , C07C33/042 , C07C33/04 , C07C33/044 , C07C33/046
CPC分类号： C07C29/42 , C07C29/172 , Y02P20/582 , C07C33/044 , C07C33/042 , C07C31/20
摘要： A process for preparing at least one unsaturated alcohol (B) comprises the steps (I) to (III) below: (I) reaction of at least one alkali metal hydroxide or alkaline earth metal hydroxide with at least one alcohol (A) in at least one organic solvent (L) to give a mixture (G-I) comprising at least the alcohol (A), the solvent (L) and an alkoxide (AL); (II) reaction of at least one carbonyl compound of the formula R—CO—R′ with at least one alkyne of the formula R″—C≡C—H and the mixture (G-I) obtained in step (I) to give a mixture (G-II) comprising at least the alcohol (A), the solvent (L) and an unsaturated alcohol (B); (III) distillation of the mixture (G-II) obtained in step (II) to give the alcohol or alcohols (B) and a mixture (G-III) comprising the solvent (L) and the alcohol (A), wherein the solvent (L) obtained in step (III) and the alcohol (A) obtained in step (III) are recycled as a mixture to step (I).
摘要翻译：一种制备至少一种不饱和醇（B）的方法包括下列步骤（I）至（III）：（I）至少一种碱金属氢氧化物或碱土金属氢氧化物与至少一种醇（A）在至少一种有机溶剂（L），得到至少包含醇（A），溶剂（L）和醇盐（AL）的混合物（GI）（II）至少一种式R-CO-R'的羰基化合物与至少一种式R'-C≡CH的炔和步骤（I）中获得的混合物（GI）的反应，得到混合物至少包含醇（A），溶剂（L）和不饱和醇（B）的化合物（G-II）; （II）中获得的混合物（G-II）的蒸馏（III），得到醇或醇（B）和包含溶剂（L）和醇（A）的混合物（G-III），其中将步骤（III）中获得的溶剂（L）和步骤（III）中获得的醇（A）作为步骤（I）的混合物再循环。

6. 发明授权

US06427985B1 Structured packing for heat exchange and mass transfer 失效
标题翻译：用于热交换和传质的结构填料
公开(公告)号：US06427985B1
公开(公告)日：2002-08-06
申请号：US09625486
申请日：2000-07-25
申请人： Gerd Kaibel , Manfred Stroezel , Achim Stammer
发明人： Gerd Kaibel , Manfred Stroezel , Achim Stammer
IPC分类号： B01F304
CPC分类号： F28C3/08 , B01J19/32 , B01J2219/3221 , B01J2219/32213 , B01J2219/32227 , B01J2219/32258 , B01J2219/32272 , B01J2219/32408 , B01J2219/32466 , Y10S261/72
摘要： A structured packing for heat exchange and mass transfer between a liquid and a gas in a column having at least one packing layer with a first, lower end and a second, upper end is described, the packing layer having an internal geometry which varies over its height so that by suitably setting the liquid and gas flow rates in a first, in particular lower, region of the packing layer a bubbling layer having a predominantly disperse gas phase forms in a targeted manner and simultaneously in a second, in particular upper, region of the packing layer a film flow of the liquid having a predominantly continuous gas phase forms in a targeted manner.
摘要翻译：描述了一种用于在具有至少一个具有第一，下端和第二上端的填料层的塔中的液体和气体之间的热交换和质量传递的规整填料，所述填料层具有内部几何形状高度，使得通过适当地将液体和气体流速设定在填料层的第一个，特别是较低的区域中，具有主要分散气相的起泡层以目标方式形成，同时在第二特别是上部区域的填料层，以目标的方式形成具有主要连续气相的液体的膜流。

7. 发明授权

US06365790B2 Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts 失效
标题翻译：通过固定床负载的钯催化剂上的炔进行部分氢化制备C10-C30-烯烃
公开(公告)号：US06365790B2
公开(公告)日：2002-04-02
申请号：US09734024
申请日：2000-12-12
申请人： Klaus Reimer , Gerd Kaibel , Ulrich Kammel , Franz Josef Bröcker , Andreas Ansmann , Heinz Etzrodt , Manfred Stroezel , Mathias Haake , Lothar Laupichler , Bernhard Bockstiegel
发明人： Klaus Reimer , Gerd Kaibel , Ulrich Kammel , Franz Josef Bröcker , Andreas Ansmann , Heinz Etzrodt , Manfred Stroezel , Mathias Haake , Lothar Laupichler , Bernhard Bockstiegel
IPC分类号： C07C2900
CPC分类号： C07C29/17 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0217 , B01J37/0225 , B01J37/08 , C07C5/09 , C07C2523/44 , C07C11/02 , C07C33/025 , C07C33/02
摘要： Alkenes are prepared by partial hydrogenation of alkynes in the liquid phase at from 20 to 250° C. and hydrogen partial pressures of from 0.3 to 200 bar over fixed-bed supported palladium catalysts which are obtainable by heating the support material in the air, cooling, applying a palladium compound and, if required, additionally other metal ions for doping purposes, molding and processing to give monolithic catalyst elements, by a process in which A) alkynes of 10 to 30 carbon atoms are used as starting compounds, B) the palladium compound and, if required, the other metal ions are applied to the support material by impregnation of the heated and cooled support material with a solution containing palladium salts and, if required, other metal ions and subsequent drying, and C) from 10 to 2000 ppm of carbon monoxide (CO) are added to the hydrogenation gas or a corresponding amount of CO is allowed to form in the liquid phase by slight decomposition of a compound which is added to the reaction mixture and eliminates CO under the reaction conditions. The process is particularly advantageous if the partial hydrogenation is carried out in a tube reactor by the trickle-bed or liquid phase procedure with product recycling at cross-sectional loadings of from 20 to 500 m3/m2*h. The process is particularly suitable for the preparation of 3,7,11,15-tetramethyl-1-hexadecen-3-ol (isophytol), 3,7,11-trimethyl-l-dodecen-3-ol (tetrahydronerolidol), 3,7,11-trimethyl-1,4-dodecadien-3-ol, 3,7,11-trimethyl-1,6-dodecadien-3-ol (dihydronerolidol), 3,7-dimethyloct-1,6-dien-3-ol or 3,7-dimethyloct-1-en-3-ol from the corresponding alkynes.
摘要翻译：烯烃通过液相中炔烃在20至250℃的部分氢化和固定床负载的钯催化剂的0.3至200巴的氢分压来制备，其可通过加热空气中的载体材料，冷却使用钯化合物，另外还需要另外的金属离子用于掺杂目的，通过使用10-30个碳原子的炔烃作为起始化合物的方法，模塑和加工以得到整体式催化剂元素，B）钯如果需要，另外的金属离子通过用含有钯盐的溶液浸渍加热和冷却的载体材料以及如果需要的话其它金属离子并随后干燥而被施加到载体材料上，C）为10-2000ppm 的一氧化碳（CO）加入到氢化气体中，或者相应量的CO在液相中形成，通过轻微分解添加到真空中的化合物并且在反应条件下消除CO。如果部分氢化在管式反应器中通过滴流床或液相方法进行，则该方法是特别有利的，其中产物回收的横截面负荷为20-500m 3 / m2 * h。该方法特别适用于制备3,7,11,15-四甲基-1-十六碳烯-3-醇（异山梨糖醇），3,7,11-三甲基-1-十二碳烯-3-醇（四氢化吗啉醇），3 ，7,11-三甲基-1,4-十二碳二烯-3-醇，3,7,11-三甲基-1,6-十二碳二烯-3-醇（二氢吗啉醇），3,7-二甲基辛-1,6-二烯 - 3-醇或3,7-二甲基辛-1-烯-3-醇。

8. 发明授权

US5914012A Dividing wall column for continuous fractionation of multicomponent mixtures by distillation 失效
$Dividing wall column for continuous fractionation of multicomponent mixtures by distillation$
标题翻译：分隔壁柱，用于通过蒸馏连续分馏多组分混合物
公开(公告)号：US5914012A
公开(公告)日：1999-06-22
申请号：US845226
申请日：1997-04-21
申请人： Gerd Kaibel , Manfred Stroezel , Udo Rheude
发明人： Gerd Kaibel , Manfred Stroezel , Udo Rheude
IPC分类号： B01D3/14 , B01D3/16 , B01D3/32 , B01J19/32
CPC分类号： B01D3/141 , B01D3/14 , B01D3/16 , B01J19/325 , Y10S159/41 , Y10S159/42 , Y10S261/72
摘要： A dividing wall column for separating a mixture into 3 or more fractions by distillation is described, where at least one dividing wall is detachably attached within the dividing wall column.
摘要翻译：描述了用于通过蒸馏将混合物分离成3个或更多个馏分的分隔壁塔，其中至少一个分隔壁可拆卸地附接在分隔壁塔内。

9. 发明授权

US07576246B1 Isothermal operation of heterogeneously catalyzed three phase reactions 失效
标题翻译：异相催化三相反应的等温运行
公开(公告)号：US07576246B1
公开(公告)日：2009-08-18
申请号：US09629482
申请日：2000-07-31
申请人： Franz Josef Bröcker , Mathias Haake , Gerd Kaibel , Gerd Rohrbacher , Ekkehard Schwab , Manfred Stroezel
发明人： Franz Josef Bröcker , Mathias Haake , Gerd Kaibel , Gerd Rohrbacher , Ekkehard Schwab , Manfred Stroezel
IPC分类号： C07C5/10
CPC分类号： F28D9/04 , B01J10/007 , B01J19/2405 , B01J19/2465 , B01J19/249 , B01J19/26 , B01J35/04 , B01J2208/00212 , B01J2219/00094 , B01J2219/00103 , B01J2219/0011 , B01J2219/1944 , B01J2219/1945 , B01J2219/2453 , B01J2219/2454 , B01J2219/2462 , B01J2219/2479 , B01J2219/2485 , B01J2219/2497 , C07C5/10 , C07C2601/14 , Y10S585/911 , Y10S585/914 , C07C13/18
摘要： The invention relates to a process and apparatus for the isothermal operation of heterogeneously catalyzed reactions involving at least three phases in the form of a gaseous phase, a liquid phase and a solid phase. The invention provides apparatus for carrying out reactions involving a gaseous phase, a liquid phase and a solid phase, comprising (i) a dispersing element for dispersing a gas phase in a liquid phase to generate a reaction fluid, (ii) at least one reactor which possesses an inlet, an outlet and a reactor space bounded by heat-removing walls which are spaced apart substantially uniformly along the main flow axis of the reaction fluid, and which is fitted with catalyst-coated metal fabric, and (iii) a feed line which routes the reaction fluid from the dispersing element to the reactor inlet and is sufficiently short that the degree of dispersion of the reaction fluid does not substantially change in the course of the passage through the feed line.
摘要翻译：本发明涉及用于等温操作的非均相催化反应的方法和装置，所述反应涉及气相，液相和固相形式的至少三相。本发明提供了用于进行涉及气相，液相和固相的反应的装置，其包括（i）用于将气相分散在液相中以产生反应流体的分散元件，（ii）至少一个反应器其具有通过除热壁界定的入口，出口和反应器空间，其沿反应流体的主流动轴线基本上均匀间隔开，并且装配有催化剂涂覆的金属织物，和（iii）进料将反应流体从分散元件引导到反应器入口的管线，并且足够短，使得在通过进料管线的通道过程中反应流体的分散度基本上不改变。

10. 发明授权

US06300524B1 Process for preparing higher unsaturated ketones 失效
标题翻译：制备高级不饱和酮的方法
公开(公告)号：US06300524B1
公开(公告)日：2001-10-09
申请号：US09440281
申请日：1999-11-15
申请人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Udo Rheude , Gerd Kaibel , Thomas Krug , Luise Spiske , Hagen Jaedicke
发明人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Udo Rheude , Gerd Kaibel , Thomas Krug , Luise Spiske , Hagen Jaedicke
IPC分类号： C07C4500
CPC分类号： C07C45/676 , Y02P20/582 , C07C49/255 , C07C49/203
摘要： The present invention relates to an improved process for preparing higher unsaturated ketones by reacting the corresponding &agr;,&bgr;-unsaturated alcohols with alkyl acetoacetates in a Carroll reaction , in a reactor system with fitted fractionation column, wherein A the &agr;,&bgr;-unsaturated alcohol is introduced into the reaction vessel together with the organic aluminum compound in the absence of effective amounts of a solvent, and the alkyl acetoacetate is metered into this mixture, B a reaction temperature which is as constant as possible at between 175° C. and 220° C., preferably between 180° C. and 200° C., is adjusted and C during the reaction the content of alkyl acetoacetate in the reaction mixture is adjusted to a value which is as constant as possible at between 1 and 3% by weight. It is advantageous in this process for the reaction temperature defined under B to be controlled by suitable variation of the heat input and/or by variation of the rate of addition of the alkyl acetoacetate, and for adequate mixing of the reaction mixture in the reaction vessel to be ensured This can be achieved with the aid of a stirrer, by pumping the reaction mixture through an external liquid circulation, by introducing the alkyl acetoacetate by means of a mixing nozzle or else by passing in a stream of inert gas. The process according to the invention is particularly suitable for the Carroll reaction of higher alcohols such as 3,7-dimethyl-1,6-octadien-3-ol (linalool), 3,7-dimethyl-1-octen-3-ol, 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol (nerolidol), 3,7,11-trimethyl-1-dodecen-3-ol or 3,7,11-trimethyl-1,6-dodecadien-3-ol (dihydronerolidol).
摘要翻译：本发明涉及一种改进的制备高级不饱和酮的方法，该方法通过在具有合适分馏塔的反应器系统中，在卡罗尔反应中使相应的α，β-不饱和醇与烷基乙酰乙酸酯反应，其中引入α，β-不饱和醇在没有有效量的溶剂的情况下，将有机铝化合物与有机铝化合物一起加入到反应容器中，并将乙酰乙酸烷基酯计量加入到该混合物中，B在175℃和220℃之间的反应温度尽可能恒定在反应过程中，优选在180℃和200℃之间调节和C，将反应混合物中乙酰乙酸烷基酯的含量调节至1至3重量％之间尽可能恒定的值。在该方法中，通过适当变化的热输入和/或通过烷基的加成速率的变化来控制在B下限定的反应温度，乙酰乙酸酯，并使反应混合物在反应容器中充分混合以确保这可以借助于搅拌器，通过泵送反应混合物通过外部液体循环，通过引入烷基乙酰乙酸酯通过混合喷嘴或者通过流入惰性气体流。根据本发明的方法特别适用于高级醇如3,7-二甲基-1,6-辛二烯-3-醇（芳樟醇），3， 7,7-二甲基-1-辛烯-3-醇，3,7,11-三甲基-1,6,10-十二碳三烯-3-醇（橙花叔醇），3,7,11-三甲基-1-十二碳烯-3-醇或3,7,11-三甲基-1,6-十二碳二烯-3-醇（二氢吗啉醇）。

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