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    • 5. 发明授权
    • Blocked polyisocyanates and their use in stoving lacquers
    • 封闭的多异氰酸酯及其在烘烤漆中的用途
    • US5691438A
    • 1997-11-25
    • US633940
    • 1996-04-17
    • Eberhard KonigTheodor Engbert
    • Eberhard KonigTheodor Engbert
    • C08G18/79C08G18/28C08G18/42C08G18/78C08G18/80C09D175/00C09D175/04
    • C08G18/8058C08G18/2865C08G18/4238C08G18/4277C08G18/807C08G18/808C08G2105/02
    • Polyisocyanates which have 1,2,4,-triazole-blocked isocyanate groups and a blocked isocyanate group content of 7 to 14 wt. % and which are reaction products of A) a polyisocyanate component selected from (i) lacquer polyisocyanates based on (cyclo)aliphatic diisocyanates or (ii) mixtures of these lacquer polyisocyanates with cycloaliphatic diisocyanates of a maximum molecular weight of 300, B) 50 to 80 equivalent-%, based on the isocyanate groups of component A), of a monofunctional isocyanate group blocking agent containing at least 90 wt. % of 1,2,4-triazole, C) 10 to 30 equivalent-%, based on the isocyanate groups of component A), of a polyester component having an OH number of 56 to 250 and D) 0 to 20 equivalent-%, based on the isocyanate groups of component A), of selected hydrazine derivatives. The present invention is also directed to the use of these blocked polyisocyanates as crosslinking agents in one-component polyurethane stoving lacquers.
    • 具有1,2,4,4-三唑封端异氰酸酯基和封端异氰酸酯基含量为7-14重量%的聚异氰酸酯 %,并且其是A)多异氰酸酯组分的反应产物,所述多异氰酸酯组分选自(i)基于(环)脂族二异氰酸酯的漆多异氰酸酯或(ii)这些漆多异氰酸酯与最大分子量为300的脂环族二异氰酸酯的混合物,B)50至 80当量%,基于组分A)的异氰酸酯基团,含有至少90重量%的单官能异氰酸酯基封端剂。 %的1,2,4-三唑,C)10至30当量%,基于组分A)的异氰酸酯基团,其中OH数为56至250的聚酯组分和D为0至20当量% 基于组分A)的异氰酸酯基团,选择的肼衍生物。 本发明还涉及这些封端多异氰酸酯作为单组分聚氨酯烘烤漆中的交联剂的用途。