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1. 发明授权

US06818205B2 Use of fluorescent whitening agents 失效
标题翻译：使用荧光增白剂
公开(公告)号：US06818205B2
公开(公告)日：2004-11-16
申请号：US10149396
申请日：2002-06-11
申请人： Dieter Reinehr , Helmut Luther , Georges Metzger
发明人： Dieter Reinehr , Helmut Luther , Georges Metzger
IPC分类号： A61K742
CPC分类号： A61Q19/02 , A61K8/466 , A61K8/49 , A61K8/494 , A61K8/4966 , A61K8/498 , A61K8/731 , A61K8/732 , A61K8/8147 , A61K8/8158 , A61K2800/434 , A61Q17/04
摘要： The use of a polymeric carrier material treated with a fluorescent whitening agent, for lightening human skin and for protecting human skin against UV radiation, is described.
摘要翻译：描述了使用用荧光增白剂处理的聚合物载体材料，用于减轻人体皮肤和保护人体皮肤免受紫外线辐射。

2. 发明授权

US06193960B1 Triazine derivatives 失效
标题翻译：三嗪衍生物
公开(公告)号：US06193960B1
公开(公告)日：2001-02-27
申请号：US09544852
申请日：2000-04-06
申请人： Georges Metzger , Dieter Reinehr , Helmut Luther
发明人： Georges Metzger , Dieter Reinehr , Helmut Luther
IPC分类号： A61K742
CPC分类号： C07D251/52 , A61K8/4966 , A61K8/4993 , A61Q17/04 , C07D251/48 , C07D251/50 , C07D251/70
摘要： The present invention relates to novel s-triazine compounds, processes for their preparation and the use of these novel compounds as UV filters in sunscreen compositions. The novel compounds are those of the formula The triazine compounds of the formula (1) according to the invention are distinguished by a high UV absorption and are particularly suitable as UV filters, i.e. for protecting ultra-violet-sensitive organic materials, in particular the skin and the hair of man and animals, from the harmful action of UV radiation.
摘要翻译：本发明涉及新型的三嗪化合物，它们的制备方法以及这些新化合物作为防晒组合物中的紫外线过滤剂的用途。新化合物是下式的那些：根据本发明的式（1）的三嗪化合物是其特征在于高的紫外线吸收，并且特别适用于紫外线过滤器，即用于保护紫外线有害的紫外线辐射有害作用的紫外线敏感有机材料，特别是人和动物的皮肤和头发。

3. 发明授权

US07476699B2 Amino- and hydroxysubstituted triphenyl-s-triazines as stabilizers 失效
标题翻译：氨基和羟基取代的三苯基-s-三嗪作为稳定剂
公开(公告)号：US07476699B2
公开(公告)日：2009-01-13
申请号：US11891554
申请日：2007-08-10
申请人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
发明人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
IPC分类号： C08K5/3492
CPC分类号： A61K8/4966 , A61K31/785 , A61K2800/52 , A61Q17/04 , C07D251/24 , C07D265/22 , Y10S514/972
摘要： The present invention provides compounds having the formula: in which R is hydrogen, hydroxy, halogen, C1-C20-alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy or C7-C13aralkyl; R1 and R2, independently, are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C7-C13 aralkyl, —C(═O)—R4 (in which R4 is C1-C20alkyl, C2-C20alkyl interrupted by 1 to 6 oxygen atoms, hetero-substituted C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, C6-C12 aryl, C6-C12 aryloxy or C7-C13 aralkyl), or —C(═O)—NH—R1 in which R1 has its previous significance; and R3 is hydrogen, halogen, hydroxy, C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, phenyl, C7-C13 aralkyl or —N(R1)(R2) in which R1 and R2 have their previous significance, or R1 and R2 together form a C4-C12 membered ring. The new triphenyltriazine compounds have improved absorption spectrum characteristics and superior resistance to exposure to UV light, relative to known triphenyltriazine compounds.
摘要翻译：本发明提供具有下式的化合物：其中R是氢，羟基，卤素，C 1 -C 20烷基，C 4 -C 12环烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基或C 7 -C 13芳烷基; R 1和R 2独立地是氢，C 1 -C 20烷基，C 4 -C 12环烷基，C 7 -C 13芳烷基，-C（-O）-R 4（其中R 4是C 1 -C 20烷基，被1至6个氧原子间断的C 2 -C 20烷基， C 1 -C 20烷基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20烯烃氧基，C 2 -C 20炔氧基，C 6 -C 12芳基，C 6 -C 12芳氧基或C 7 -C 13 芳烷基）或-C（-O）-NH-R 1，其中R 1具有其先前的含义; 并且R 3是氢，卤素，羟基，C 1 -C 20烷基，C 4 -C 12环烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，苯基，C 7 -C 13芳烷基或 -N（R 1）（R 2），其中R 1和R 2具有其先前的含义，或者R 1和R 2一起形成C 4 -C 12元环。相对于已知的三苯基三嗪化合物，新的三苯基三嗪化合物具有改善的吸收光谱特性和对UV光的暴露性优异的抗性。

4. 发明申请

US20070274933A1 Amino- and hydroxysubstituted triphenyl-S-triazines as stabilizers 失效
公开(公告)号：US20070274933A1
公开(公告)日：2007-11-29
申请号：US11891554
申请日：2007-08-10
申请人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
发明人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
IPC分类号： A61K31/785 , A61K47/22 , A61K8/00 , A61Q17/04
CPC分类号： A61K8/4966 , A61K31/785 , A61K2800/52 , A61Q17/04 , C07D251/24 , C07D265/22 , Y10S514/972
摘要： The present invention provides compounds having the formula: in which R is hydrogen, hydroxy, halogen, C1-C20-alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy or C7-C13aralkyl; R1 and R2, independently, are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C7-C13 aralkyl, —C(═O)—R4 (in which R4 is C1-C20alkyl, C2-C20alkyl interrupted by 1 to 6 oxygen atoms, hetero-substituted C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, C6-C12 aryl, C6-C12 aryloxy or C7-C13 aralkyl), or —C(═O)—NH—R1 in which R1 has its previous significance; and R3 is hydrogen, halogen, hydroxy, C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, phenyl, C7-C13 aralkyl or —N(R1)(R2) in which R1 and R2 have their previous significance, or R1 and R2 together form a C4-C12 membered ring. The new triphenyltriazine compounds have improved absorption spectrum characteristics and superior resistance to exposure to UV light, relative to known triphenyltriazine compounds.

5. 发明授权

US06929667B2 Method for the fluorescent whitening of cotton 有权
公开(公告)号：US06929667B2
公开(公告)日：2005-08-16
申请号：US10333258
申请日：2001-07-12
申请人： Fabienne Cuesta , Dieter Reinehr , Hans Kramer , Georges Metzger , Bernd Wockenfuss
发明人： Fabienne Cuesta , Dieter Reinehr , Hans Kramer , Georges Metzger , Bernd Wockenfuss
IPC分类号： C07D251/68 , D06L3/12 , D06M13/358 , D06P5/06
CPC分类号： D06P5/06 , C07D251/68 , D06L4/621 , D06M13/358 , D06M2101/06 , Y10S8/918
摘要： A method for the fluorescent whitening of cotton in a discontinuous process comprising contacting the cotton, I an aqueous bath having a pH value of 6 or less, with one or more compounds of the Formula (I) wherein R1 represents an —SO2R3, —SOR3, CO2M, —CO2R3, —CONR3R4, —CN or —NO2 substituent, R2 is —NH2, —NH(C1-C4alkyl), —N(C1-C4alkyl)2, —NH(C2-C4hydroxyalkyl), —N(C2-C4hydroxyalkyl)2, —NH(C1-C4alkoxy)(C1-C4alkyl), —N[(C1-C4alkoxy)(C1-C4alkyl)]2, NHC2—C4alkylsulphonic acid, morpholineo, piperidino pyrrolidino, an amino acid or amino acid amide residue from which a hydrogen atom on the amino group has been removed, —OC1-C4alkyl or —OC1-C4hydroxyalkyl, R3 and R4 each, independently, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl or C1-C4alkoxyC1-C4alkyl and M is H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubsituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof, some of which are new

6. 发明授权

US06528469B2 Fabric bleaching composition 失效
标题翻译：织物漂白组合物
公开(公告)号：US06528469B2
公开(公告)日：2003-03-04
申请号：US09077047
申请日：1998-10-13
申请人： Dieter Reinehr , Georges Metzger
发明人： Dieter Reinehr , Georges Metzger
IPC分类号： C11D300
CPC分类号： C11D3/3932 , D06L4/12
摘要： A fabric bleaching composition comprising a peroxy compound and a specified manganese compound is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
摘要翻译：公开了包含过氧化合物和特定锰化合物的织物漂白组合物，以及通过使其与所述织物漂白组合物接触来漂白和/或清洁织物的方法。

7. 发明授权

US06458169B2 Fluorescent whitening agents 失效
标题翻译：荧光增白剂
公开(公告)号：US06458169B2
公开(公告)日：2002-10-01
申请号：US09767112
申请日：2001-01-22
申请人： Peter Rohringer , Georges Metzger , Dieter Reinehr
发明人： Peter Rohringer , Georges Metzger , Dieter Reinehr
IPC分类号： C07D25100
CPC分类号： C09B23/148 , C07D251/68 , C11D3/42 , D06L4/621 , D06L4/657 , D06L4/75 , D06M13/07 , D06M13/358 , D06P1/6426 , D21H21/30 , Y10S8/919
摘要： The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine, L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.
摘要翻译：本发明提供了新的具有下式的化合物：其中X为O或优选为NH; M是氢，碱金属原子，铵或由胺形成的阳离子; 每个R 1独立地是氨基酸被除去的氨基酸残基; n为1或2; 并且每个R 2独立地是氢，C 1 -C 3烷基，卤素，氰基，其中R是氢或C 1 -C 3烷基的COOR，其中R具有其先前含义的CONH-R，其中R具有其先前含义的SO 2 NH- 其中R具有其先前意义的NH-COR，其中M具有其先前含义的SO 3 M，或当n为1时，R 2也可以是其中R 3为C 1 -C 3烷基或苯基的CO-R 3;条件是将这些化合物排除在哪一个）X是NH，n是1，R2是SO3M，其中M具有其先前的意义; 环）X是NH，n是2，一个R2是SO3M，其中M具有其先前的意义，另一个R 2是氢，甲基或卤素; orc）X是NH，n是1，R1是甘氨酸，R2是H或CO2H; ord）X是NH，n是2，每个R2是SO3M，其中M具有其先前的意义，SO3M基团在苯环中是2,5位，R1是D，L-丙氨酸，L-缬氨酸，L L-亮氨酸，L-异亮氨酸，L-苏氨酸，L-天冬氨酸，L-谷氨酸，L-苯丙氨酸，L-脯氨酸，D，L-甲硫氨酸或甘氨酸。新的4,4'-二氨基芪 - 2,2'-二磺酸化合物可用作荧光增白剂，特别是用于纸。

8. 发明授权

US6040443A Process for the production of benzoxazinones 失效
标题翻译：生产苯并恶嗪酮的方法
公开(公告)号：US6040443A
公开(公告)日：2000-03-21
申请号：US119300
申请日：1998-07-20
申请人： Georges Metzger , Dieter Reinehr , Serge Hauger
发明人： Georges Metzger , Dieter Reinehr , Serge Hauger
IPC分类号： C07D265/22 , C07D265/02
CPC分类号： C07D265/22
摘要： There is described a process for the production of a 1,3-benzoxazin-4-one having the formula: ##STR1## in which R.sub.1 and R.sub.2, independently, are hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl, NH--CO--C.sub.1 -C.sub.20 alkyl, N(R.sub.3).sub.2, SO.sub.2 N(R.sub.3).sub.2, COOR.sub.3 or CON(R.sub.3).sub.2 in which R.sub.3 is hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl or NH--CO--C.sub.1 -C.sub.20 alkyl, comprising reacting, at elevated temperature, 1 molar equivalent of an o-hydroxybenzamide of formula: ##STR2## in which R.sub.1 has its previous significance, with 2 to 6 molar equivalents of a benzoyl chloride of formula: ##STR3## in which R.sub.2 has its previous significance. The 1,3-benzoxazin-4-ones having the formula (1) so obtained are important intermediates for the production of triazine compounds having excellent absorption spectrum characteristics and good resistance to exposure to UV light.
摘要翻译：描述了制备具有下式的1,3-苯并恶嗪-4-酮的方法：其中R 1和R 2独立地是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基，苯基，NH-CO-C 1 -C 20烷基，N（R 3）2，SO 2 N（R 3）2，COOR 3或CON（R 3）2，其中R 3是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基苯基或NH-CO-C 1 -C 20烷基，其包括在升高的温度下，将1摩尔当量的具有其先前意义的式的邻羟基苯甲酰胺与2至6摩尔当量的下式的苯甲酰氯反应：其中R2具有以前的意义。具有式（1）的1,3-苯并恶嗪-4-酮是制备具有优异的吸收光谱特性和良好的耐紫外线性的三嗪化合物的重要中间体。

9. 发明授权

US5733341A Inhibition of dye migration in a wash liquor 失效
标题翻译：在洗液中抑制染料迁移
公开(公告)号：US5733341A
公开(公告)日：1998-03-31
申请号：US572417
申请日：1995-12-14
申请人： Claude Eckhardt , Dieter Reinehr , Georges Metzger
发明人： Claude Eckhardt , Dieter Reinehr , Georges Metzger
IPC分类号： C07D213/38 , C07D213/53 , C07D255/04 , C07D257/10 , C07D487/22 , C07F13/00 , C11D3/00 , C11D3/16 , C11D3/28 , C11D3/32 , C11D3/34 , C11D3/37 , C11D3/39 , C11D3/30 , C11D3/395 , C11D7/10 , D06L3/02
CPC分类号： C07D213/53 , C07D213/38 , C07D255/04 , C07D257/10 , C07F13/005 , C11D3/0021 , C11D3/168 , C11D3/28 , C11D3/32 , C11D3/349
摘要： A process is described for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13) or (14) as defined in the specification. The compounds of formula (1), (2), (3), (4), (5), (6), (8), (9) (10), (11), (12), (13) or (14) are new compounds. The compounds used do not exhaust at all on to cotton, polyamide or polyester fibers, so that the compounds cannot lead to fiber discoloration problems.
摘要翻译：描述了一种用于抑制洗涤液中迁移染料的再吸收的方法，包括将含有过氧化物的洗涤剂的洗涤液从0.5至150，优选1.5至75，特别是7.5至40mg，一种或多种具有式（1），（2），（3），（4），（5），（6），（7），（8），（9） 10），（11），（12），（13）或（14）。式（1），（2），（3），（4），（5），（6），（8），（9）（10），（11），（12）或（14）是新化合物。所使用的化合物根本不排放到棉，聚酰胺或聚酯纤维上，使得化合物不会导致纤维变色问题。

10. 发明申请

US20050038245A1 Naphthyltriazines as stabilizers for organic material 审中-公开
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050038245A1
公开(公告)日：2005-02-17
申请号：US10492721
申请日：2002-10-10
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48
CPC分类号： C07D251/24
摘要： Novel compounds of formula (I) are described, wherein E corresponds to the formula (a) or to the formula (b) and the radicals R1, R2, R11, R22, R′22, R33, and R′33 are as defined in claim 1. Compounds of formula (I) are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式（I）化合物，其中E对应于式（a）或式（b），基团R 1，R 2，R 11，R 22，R 22，R 33和R 33如上定义式（I）化合物适于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

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