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1. 发明授权

US6015504A Method for increasing the SPF rating of textile fibers by treatment with triazinyldiamino stilbene compounds 失效
标题翻译：通过用三嗪基二氨基二苯乙烯化合物处理提高纺织纤维的SPF等级的方法
公开(公告)号：US6015504A
公开(公告)日：2000-01-18
申请号：US13657
申请日：1998-01-26
申请人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
发明人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
IPC分类号： D06L1/00 , C07D251/48 , C07D251/50 , C07D251/68 , C07D251/70 , C09K3/00 , C11D1/02 , C11D1/66 , C11D1/83 , C11D3/00 , C11D3/28 , C11D3/39 , C11D3/42 , C12S11/00 , D06L3/11 , D06L3/12 , D06L3/16 , D06M13/02 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/332 , D06M13/345 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/10 , D06M101/16 , D06M101/18 , D21H19/10 , D06M13/262 , D06P1/62
CPC分类号： C11D3/28 , C07D251/48 , C07D251/50 , C07D251/68 , C11D3/42 , D06L3/1207 , D06L3/1214 , D06L3/1228 , D06L3/125 , D06L3/16 , D06M13/358 , C11D3/39 , C11D3/3905 , D06M2101/06 , D06M2101/12 , D06M2101/34 , D06M2200/25
摘要： The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fiber material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
摘要翻译：本发明涉及可用作紫外线吸收剂（UVA）和荧光增白剂（FWA）的新化合物，以及改善纺织纤维材料，特别是棉花，聚酰胺和羊毛的防晒因子（SPF）的方法用新化合物和某些已知化合物处理。

2. 发明授权

US5965506A Fabric bleaching composition 失效
标题翻译：织物漂白组合物
公开(公告)号：US5965506A
公开(公告)日：1999-10-12
申请号：US967318
申请日：1997-10-28
申请人： Jean-Pierre Bacher , Claude Eckhardt , Dieter Reinehr
发明人： Jean-Pierre Bacher , Claude Eckhardt , Dieter Reinehr
IPC分类号： D06L3/02 , C07F13/00 , C11D3/39 , C01B15/055 , C11D3/395
CPC分类号： C11D3/3932
摘要： A fabric bleaching composition comprising a peroxy compound and a specified manganese complex is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
摘要翻译：公开了包含过氧化合物和特定锰络合物的织物漂白组合物，以及通过使其与所述织物漂白组合物接触来漂白和/或清洁织物的方法。

3. 发明授权

US5945396A Compounds 失效
标题翻译：化合物
公开(公告)号：US5945396A
公开(公告)日：1999-08-31
申请号：US996895
申请日：1997-12-23
申请人： Claude Eckhardt , Georges Metzger , Dieter Reinehr , Hanspeter Sauter , Mario Dubini
发明人： Claude Eckhardt , Georges Metzger , Dieter Reinehr , Hanspeter Sauter , Mario Dubini
IPC分类号： C07D251/68 , C07D251/50 , C07D251/54 , C09K3/00 , C11D1/62 , C11D3/42 , D06L3/12 , D06M13/07 , D06M13/355 , D06M13/358 , D06M11/00 , C07D251/38
CPC分类号： C07D251/50 , C07D251/54 , C11D1/62 , C11D3/42 , D06L3/1214 , D06L3/1257 , D06M13/07 , D06M13/355 , D06M13/358 , D06M2200/25 , D06M2200/50
摘要： The present invention provides a compound having the formula: ##STR1## in which each R.sub.d is the same or different and each is --NH--Z--N(R.sub.a)(R.sub.b) or --N--�Z--N(R.sub.a)(R.sub.b)!.sub.2 in which Z is C.sub.2 -C.sub.14 alkylene or optionally substituted arylene, R.sub.a and R.sub.b are the same or different and each is C.sub.1 -C.sub.12 alkyl, or R.sub.a and R.sub.b, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; each R.sub.c is the same or different and is NH.sub.2, NH(C.sub.1 -C.sub.4 alkyl), N(C.sub.1 -C.sub.4 alkyl).sub.2, N(CH.sub.2 CH.sub.2 OH).sub.2, O--C.sub.1 -C.sub.4 alkyl, ##STR2## alkali metal atom, ammonium or a cation formed from an amine; or a quaternized form thereof. The present invention also relates to a composition for the treatment of textiles, in particular to a composition containing the new ultra-violet absorbing agents; and to a method for the improvement of both the sun protection factor (UPF) and the whiteness of textile fiber material, comprising treating the material with the composition according to the present invention.
摘要翻译：本发明提供具有下式的化合物：其中每个R d相同或不同，各自为-NH-ZN（Ra）（Rb）或-N- [ZN（Ra）（Rb）] 2，其中Z为 C 2 -C 14亚烷基或任选取代的亚芳基，R a和R b相同或不同，各自为C 1 -C 12烷基，或者R a和R b与它们各自连接的氮原子一起形成吗啉代，哌啶子基或哌嗪基环; 每个Rc相同或不同，是NH 2，NH（C 1 -C 4烷基），N（C 1 -C 4烷基）2，N（CH 2 CH 2 OH）2，O-C 1 -C 4烷基，碱金属原子，铵或由胺形成的阳离子 ; 或其季铵化形式。本发明还涉及用于处理纺织品的组合物，特别涉及含有新的紫外线吸收剂的组合物; 以及用于改善防晒因子（UPF）和纺织纤维材料的白度的方法，包括用根据本发明的组合物处理该材料。

4. 发明授权

US5744599A Triazinyldiaminostilbene compounds useful as ultraviolet absorbers and as fluorescent whitening agents 失效
标题翻译：可用作紫外线吸收剂的三嗪基二氨基芪化合物和荧光增白剂
公开(公告)号：US5744599A
公开(公告)日：1998-04-28
申请号：US604536
申请日：1996-02-21
申请人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
发明人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
IPC分类号： D06L1/00 , C07D251/48 , C07D251/50 , C07D251/68 , C07D251/70 , C09K3/00 , C11D1/02 , C11D1/66 , C11D1/83 , C11D3/00 , C11D3/28 , C11D3/39 , C11D3/42 , C12S11/00 , D06L3/11 , D06L3/12 , D06L3/16 , D06M13/02 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/332 , D06M13/345 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/10 , D06M101/16 , D06M101/18 , D21H19/10 , C07D251/00
CPC分类号： C11D3/28 , C07D251/48 , C07D251/50 , C07D251/68 , C11D3/42 , D06L3/1207 , D06L3/1214 , D06L3/1228 , D06L3/125 , D06L3/16 , D06M13/358 , C11D3/39 , C11D3/3905 , D06M2101/06 , D06M2101/12 , D06M2101/34 , D06M2200/25
摘要： The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
摘要翻译：本发明涉及可用作紫外线吸收剂（UVA）和荧光增白剂（FWA）的新化合物，以及改善纺织纤维材料，特别是棉花，聚酰胺和羊毛的防晒因子（SPF）的方法用新化合物和某些已知化合物处理。

5. 发明授权

US5462564A Inhibition of re-absorption of migrating dyes in the wash liquor 失效
标题翻译：在洗涤液中抑制迁移染料的再吸收
公开(公告)号：US5462564A
公开(公告)日：1995-10-31
申请号：US259651
申请日：1994-06-14
申请人： Claude Eckhardt , Dieter Reinehr
发明人： Claude Eckhardt , Dieter Reinehr
IPC分类号： C07F13/00 , C11D3/00 , C11D3/16 , C11D3/26 , C11D3/34 , C11D3/39 , C11D3/395 , D06L3/02 , D06M13/02 , D06M13/50 , D06M13/503 , C11D3/30 , C11D7/10
CPC分类号： C11D3/3932 , C11D3/0021
摘要： A process for inhibiting the re-absorption of migrating dyes in the wash liquor comprises introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg, per liter of wash liquor, of one or more manganese compounds having the formula (1), (2), (3), (4), (5), (6) or (7) as defined in the specification. The manganese compounds do not exhaust at all on to cotton, polyamide or polyester fibres so that the compounds cannot lead to fibre discoloration problems.
摘要翻译：用于抑制洗涤液中迁移染料的再吸收的方法包括将含有过氧化物的洗涤剂的洗涤液引入每升洗涤液0.5至150mg的一种或多种具有式（ 1），（2），（3），（4），（5），（6）或（7）。锰化合物根本不排放到棉，聚酰胺或聚酯纤维上，使得化合物不会导致纤维变色问题。

6. 发明授权

US5449477A Bleach dispersion of long shelf life 失效
标题翻译：漂白分散长保质期
公开(公告)号：US5449477A
公开(公告)日：1995-09-12
申请号：US991661
申请日：1992-12-16
申请人： Claude Eckhardt
发明人： Claude Eckhardt
IPC分类号： C11D3/395 , C11D3/39 , C11D3/42 , C11D7/54 , D06L3/02 , D06L3/12 , C01B15/00 , C09K11/06
CPC分类号： C11D3/42 , C11D3/3947 , D06L3/025 , D06L3/1228
摘要： A bleach dispersion of long shelf life comprising, apart from at least one peracid or salts thereof, one or more fluorescent whiteners of the bis(benzofuranyl) type and the preparation and use of this bleach dispersion for the simultaneous bleaching and whitening of household and industrial fabrics at temperatures starting from +10.degree. C. or higher are described.
摘要翻译：长保质期的漂白分散体除了至少一种过酸或其盐以外还包含一种或多种双（苯并呋喃基）型荧光增白剂以及该漂白分散体用于家庭和工业同时漂白和增白的制备和用途描述了从+ 10℃或更高温度开始的织物。

7. 发明授权

US5434275A Dibenzofuranylbiphenyls 失效
标题翻译：二苯并呋喃基联苯
公开(公告)号：US5434275A
公开(公告)日：1995-07-18
申请号：US221733
申请日：1994-04-01
申请人： Kurt Weber , Claude Eckhardt , Hans R. Meyer
发明人： Kurt Weber , Claude Eckhardt , Hans R. Meyer
IPC分类号： C07D307/79 , C07D307/82 , C11D3/42 , D21H21/30 , C07D307/80
CPC分类号： C07D307/79 , C07D307/82 , C11D3/42 , D21H21/30
摘要： Novel dibenzofuranylbiphenyl compounds of the formula (I) ##STR1## which are unsubstituted or are monosubstituted or polysubstituted by radicals R=hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, phenoxy and benzyloxy and in which R.sub.3 is C.sub.1 -C.sub.4 alkyl, halogen or phenyl and M is hydrogen and/or one equivalent of a non-chromophoric cation and the preparation and use thereof for fluorescent whitening are described.
摘要翻译：式（I）的新型二苯并呋喃基联苯化合物（I）其为未取代的或被基团R 1 =氢，C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，苯氧基和苄氧基单取代或多取代，其中R 3为C 1 -C 4烷基，卤素或苯基，M是氢和/或一当量的非发色阳离子，并且其荧光增白的制备和用途被描述。

8. 发明授权

US5279772A Liquid detergents containing specifically disulfonated dibenzofuranyl-biphenyls as flourescent whitening agents 失效
标题翻译：含有二磺酸二苯并呋喃基 - 联苯的液体洗涤剂作为荧光增白剂
公开(公告)号：US5279772A
公开(公告)日：1994-01-18
申请号：US13482
申请日：1993-02-01
申请人： Claude Eckhardt , Kurt Weber
发明人： Claude Eckhardt , Kurt Weber
IPC分类号： C11D3/42 , C11D1/83 , C11D3/40
CPC分类号： C11D3/42
摘要： The present patent application describes novel liquid detergent compositions containing specifically disulfonated dibenzofuranylbiphenyls of the formula ##STR1## in which X is a sulfonic acid radical, hydrogen or C.sub.1 -C.sub.4 alkyl and Y and Z independently of the other are a sulfonic acid radical, hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogeno, CN, phenoxy or benzyloxy, with the proviso that either X or Y or Z is a sulfonic acid radical and the remaining substituents are not a sulfonic acid radical, and the preparation and use thereof; these detergent compositions prevent spotting on textile fabric when it comes into direct contact with the liquid detergent composition.
摘要翻译：本专利申请描述了新颖的液体洗涤剂组合物，其特征在于，其中X是磺酸基，氢或C 1 -C 4烷基，Y和Z（X）是具有下式（*化学结构*）（I）（*化学结构*）的二磺化二苯并呋喃基联苯独立于磺酸基，氢，C 1 -C 4烷基，C 1 -C 4烷氧基，卤代，CN，苯氧基或苄氧基，条件是X或Y或Z是磺酸基，其余取代基是不是磺酸基，其制备和使用; 这些洗涤剂组合物在与液体洗涤剂组合物直接接触时防止织物上的斑点。

9. 发明授权

US5139695A Stable bleaching compositions containing fluorescent whitening agents 失效
标题翻译：含有荧光增白剂的稳定漂白组合物
公开(公告)号：US5139695A
公开(公告)日：1992-08-18
申请号：US678164
申请日：1991-03-28
申请人： Claude Eckhardt
发明人： Claude Eckhardt
IPC分类号： C11D3/395 , C11D3/42 , D06L3/06 , D06L3/12
CPC分类号： D06L3/068 , C11D3/3956 , C11D3/42 , D06L3/1257
摘要： The present invention relates to a stable aqueous hypochlorite solution which contains at least one specific fluroescent whitening agent of the bis(benzofuranyl) type, to the preparation thereof, and to the use of said composition for simultaneously bleaching and whitening materials in the home and in industry. These bleach solutions are stable for several months.
摘要翻译：本发明涉及一种稳定的次氯酸钠溶液，其含有至少一种双（苯并呋喃基）型特异性荧光增白剂及其制备方法，以及所述组合物在家中同时漂白和增白材料的用途行业。这些漂白剂溶液稳定数月。

10. 发明授权

US06482241B1 Asymmetric stilbene compounds 失效
标题翻译：不对称二苯乙烯化合物
公开(公告)号：US06482241B1
公开(公告)日：2002-11-19
申请号：US09657737
申请日：2000-09-08
申请人： Georges Metzger , Dieter Reinehr , Claude Eckhardt , Fabienne Cuesta
发明人： Georges Metzger , Dieter Reinehr , Claude Eckhardt , Fabienne Cuesta
IPC分类号： C07D25108
CPC分类号： C07D251/68 , C11D3/42 , D06M13/07 , D06M13/358 , D06M2101/04 , D06M2101/06 , D06M2101/10 , D06M2101/12 , D06M2101/16 , D06M2101/28 , D06M2101/32 , D06M2101/34 , D06M2200/25
摘要： The present invention provides, as a first aspect, an asymmetric compound having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; Xa and Xb are the same or different and each is NH2; NH(C1-C4alkyl); NH(C2-C4alkoxyalkyl); N(C1-C4alkyl)2; N(CH2CH2OH)2; a group NH—Z—NR1R2 in which Z is C2-C14alkylene or optionally substituted arylene, and R1 and R2 are the same or different and each is C1-C12alkyl or R1 and R2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C1-C4alkoxy; hydroxy-substituted-C2-C4alkoxy; and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: in which R3 is CN; SO2R5 in which R5 is, C1-C12alkyl, C1-C12alkoxy, NH2, NH(C1-C4alkyl), N(C1-C4alkyl)2, N(CH2CH2OH)2, C1-C4alkoxy or hydroxy-substituted-C2-C4alkoxy; COR5 in which R5 has its previous significance; COOM in which M has its previous significance or NHCOR5 in which R5 has its previous significance and in which R4 has the same significance as R3 or is H, OH, C1-C4alkyl or C1-C4alkoxy and one of Xa and Xb can be identical to one of Ya and Yb, provided that one of Xa and Xb is different from the other and/or one of Ya and Yb is different from the other. The present invention also relates to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, comprising treating them with the new compounds.
摘要翻译：作为第一方面，本发明提供具有下式的不对称化合物：其中M是氢，碱金属原子，铵或由胺形成的阳离子; Xa和Xb相同或不同，各自为NH 2; NH（C 1 -C 4烷基）; NH（C 2 -C 4烷氧基烷基）; N（C 1 -C 4烷基）2; N（CH 2 CH 2 OH）2; 其中Z为C 2 -C 14亚烷基或任选取代的亚芳基的基团NH-Z-NR 1 R 2，并且R 1和R 2相同或不同，并且各自为C 1 -C 12烷基或R 1和R 2以及它们各自连接的氮原子形成吗啉代，哌啶子基或哌嗪基环; 氨基酸残基; C1-C4烷氧基; 羟基取代的C 2 -C 4烷氧基; Ya和Yb相同或不同，并且各自为具有下式的UVA和UVB吸收性质的取代氨基：其中R3为CN; 其中R 5为C 1 -C 12烷基，C 1 -C 12烷氧基，NH 2，NH（C 1 -C 4烷基），N（C 1 -C 4烷基）2，N（CH 2 CH 2 OH）2，C 1 -C 4烷氧基或羟基取代的C 2 -C 4烷氧基的SO 2 R 5; COR5其中R5具有以前的意义; 其中M具有其先前意义的COOM或其中R5具有其先前意义的NHCOR5，并且其中R 4与R 3具有相同的含义或为H，OH，C 1 -C 4烷基或C 1 -C 4烷氧基，X a和X b中的一个可以相同 Ya和Yb中的一个，其中Xa和Xb中的一个与另一个不同，和/或Ya和Yb中的一个与另一个不同。本发明还涉及一种改善防晒因子（SPF）的方法纺织纤维材料，特别是棉花，聚酰胺和羊毛，包括用新化合物处理它们。

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