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1. 发明申请

US20050038245A1 Naphthyltriazines as stabilizers for organic material 审中-公开
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050038245A1
公开(公告)日：2005-02-17
申请号：US10492721
申请日：2002-10-10
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48
CPC分类号： C07D251/24
摘要： Novel compounds of formula (I) are described, wherein E corresponds to the formula (a) or to the formula (b) and the radicals R1, R2, R11, R22, R′22, R33, and R′33 are as defined in claim 1. Compounds of formula (I) are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式（I）化合物，其中E对应于式（a）或式（b），基团R 1，R 2，R 11，R 22，R 22，R 33和R 33如上定义式（I）化合物适于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

2. 发明申请

US20050169859A1 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050169859A1
公开(公告)日：2005-08-04
申请号：US11098640
申请日：2005-04-04
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48 , G03C1/005 , G03C1/494
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33a和R 33如权利要求1中所定义。式I化合物适用于稳定化有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，防止光，氧和/或热的损害。

3. 发明授权

US07087753B2 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US07087753B2
公开(公告)日：2006-08-08
申请号：US11098640
申请日：2005-04-04
申请人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： C07D251/24 , A61K7/42 , G03C1/005
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilizing organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33和R 33如权利要求1中所定义。式I化合物适用于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

4. 发明授权

US07476699B2 Amino- and hydroxysubstituted triphenyl-s-triazines as stabilizers 失效
标题翻译：氨基和羟基取代的三苯基-s-三嗪作为稳定剂
公开(公告)号：US07476699B2
公开(公告)日：2009-01-13
申请号：US11891554
申请日：2007-08-10
申请人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
发明人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
IPC分类号： C08K5/3492
CPC分类号： A61K8/4966 , A61K31/785 , A61K2800/52 , A61Q17/04 , C07D251/24 , C07D265/22 , Y10S514/972
摘要： The present invention provides compounds having the formula: in which R is hydrogen, hydroxy, halogen, C1-C20-alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy or C7-C13aralkyl; R1 and R2, independently, are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C7-C13 aralkyl, —C(═O)—R4 (in which R4 is C1-C20alkyl, C2-C20alkyl interrupted by 1 to 6 oxygen atoms, hetero-substituted C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, C6-C12 aryl, C6-C12 aryloxy or C7-C13 aralkyl), or —C(═O)—NH—R1 in which R1 has its previous significance; and R3 is hydrogen, halogen, hydroxy, C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, phenyl, C7-C13 aralkyl or —N(R1)(R2) in which R1 and R2 have their previous significance, or R1 and R2 together form a C4-C12 membered ring. The new triphenyltriazine compounds have improved absorption spectrum characteristics and superior resistance to exposure to UV light, relative to known triphenyltriazine compounds.
摘要翻译：本发明提供具有下式的化合物：其中R是氢，羟基，卤素，C 1 -C 20烷基，C 4 -C 12环烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基或C 7 -C 13芳烷基; R 1和R 2独立地是氢，C 1 -C 20烷基，C 4 -C 12环烷基，C 7 -C 13芳烷基，-C（-O）-R 4（其中R 4是C 1 -C 20烷基，被1至6个氧原子间断的C 2 -C 20烷基， C 1 -C 20烷基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20烯烃氧基，C 2 -C 20炔氧基，C 6 -C 12芳基，C 6 -C 12芳氧基或C 7 -C 13 芳烷基）或-C（-O）-NH-R 1，其中R 1具有其先前的含义; 并且R 3是氢，卤素，羟基，C 1 -C 20烷基，C 4 -C 12环烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，苯基，C 7 -C 13芳烷基或 -N（R 1）（R 2），其中R 1和R 2具有其先前的含义，或者R 1和R 2一起形成C 4 -C 12元环。相对于已知的三苯基三嗪化合物，新的三苯基三嗪化合物具有改善的吸收光谱特性和对UV光的暴露性优异的抗性。

5. 发明申请

US20070274933A1 Amino- and hydroxysubstituted triphenyl-S-triazines as stabilizers 失效
公开(公告)号：US20070274933A1
公开(公告)日：2007-11-29
申请号：US11891554
申请日：2007-08-10
申请人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
发明人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
IPC分类号： A61K31/785 , A61K47/22 , A61K8/00 , A61Q17/04
CPC分类号： A61K8/4966 , A61K31/785 , A61K2800/52 , A61Q17/04 , C07D251/24 , C07D265/22 , Y10S514/972
摘要： The present invention provides compounds having the formula: in which R is hydrogen, hydroxy, halogen, C1-C20-alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy or C7-C13aralkyl; R1 and R2, independently, are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C7-C13 aralkyl, —C(═O)—R4 (in which R4 is C1-C20alkyl, C2-C20alkyl interrupted by 1 to 6 oxygen atoms, hetero-substituted C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, C6-C12 aryl, C6-C12 aryloxy or C7-C13 aralkyl), or —C(═O)—NH—R1 in which R1 has its previous significance; and R3 is hydrogen, halogen, hydroxy, C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, phenyl, C7-C13 aralkyl or —N(R1)(R2) in which R1 and R2 have their previous significance, or R1 and R2 together form a C4-C12 membered ring. The new triphenyltriazine compounds have improved absorption spectrum characteristics and superior resistance to exposure to UV light, relative to known triphenyltriazine compounds.

6. 发明授权

US5077321A Process for the preparation of polyurethane substances using specific stabilizer systems 失效
标题翻译：使用特定稳定系统制备聚氨酯物质的方法
公开(公告)号：US5077321A
公开(公告)日：1991-12-31
申请号：US709689
申请日：1991-06-03
申请人： Peter Michaelis
发明人： Peter Michaelis
IPC分类号： C08G18/08 , C08G18/65 , C08K5/13 , C08K5/17 , C08K5/18 , C08K5/36 , C08K5/375 , C08K5/46 , C08L75/00 , C08L75/04
CPC分类号： C08K5/375 , C08K5/13 , C08K5/18 , C08K5/46
摘要： A process for the preparation of polyurethane substances in any desired form by reaction ofa) polyisocyanates withb) compounds comprising at least two hydrogen atoms that are reactive towards isocyanates, in the presence ofc) catalysts known per se andd) specific stabilizer systems,wherein there is used as component d) a stabilizer system comprising at least two compounds of at least two structurally different stabilizer types of formulae (1), (2), (3) and (4), in which formula (1) represents formulae (1a), (1b), (1c), (1d) or (1e) ##STR1## and the other formulae (2), (3) and (4) are as follows: ##STR2## wherein R.sub.1 each independently of the other is C.sub.1 -C.sub.4 alkyl, R.sub.2 and R.sub.5 each independently of the other are C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.7 cycloalkyl, benzyl, phenyl or a group of the formula --CH.sub.2 COO--C.sub.6 -C.sub.18 alkyl, R.sub.3 is --H or --CH.sub.3, and R.sub.4 is C.sub.1 -C.sub.12 alkyl, R.sub.6 and R.sub.8 each independently of the other are C.sub.1 -C.sub.18 alkyl or C.sub.5 -C.sub.7 cycloalkyl, R.sub.7 each independently of the other is --H, C.sub.1 -C.sub.4 alkyl or C.sub.5 -C.sub.7 cycloalkyl, n is the number 1, 2 or 3, R.sub.9 is C.sub.6 -C.sub.18 alkyl and R.sub.10 is methyl or ethyl, and Ar and Ar' ech independently of the other are a radical of the formula ##STR3## wherein R.sub.17 and R.sub.17 ' each independently of the other are --H or C.sub.4 -C.sub.18 alkyl, R.sub.11 and R.sub.12 each independently of the other are C.sub.1 -C.sub.4 alkyl, R.sub.13 and R.sub.14 each independently of the other are C.sub.4 -C.sub.18 alkyl, and R.sub.15 and R.sub.16 each independently of the other are --H or C.sub.1 -C.sub.12 alkyl.
摘要翻译：通过a）多异氰酸酯与b）包含至少两个对异氰酸酯反应的氢原子的化合物在c）本身已知的催化剂和d）特定稳定剂体系的反应中制备聚氨酯物质的方法其中使用组分d）稳定剂体系，其包含至少两种至少两种结构不同的式（1），（2），（3）和（4）稳定剂的化合物，其中式（1）代表公式（1a），（1b），（1c），（1d）或（1e）和其他公式（2），（3）和（4）如下：其中R 1各自独立地为C 1 -C 4烷基，R 2和R 5各自独立地为C 1 -C 18烷基，C 5 -C 7环烷基，苄基，苯基或式-CH 2 COO-C 6 -C 18烷基的基团，R 3 是-H或-CH 3，R 4是C 1 -C 12烷基，R 6和R 8各自独立地是C 1 -C 18烷基或C 5 -C 7环烷基，R 7各自独立地是-H，C 1 -C 4个烷基或C 5 -C 7环烷基，n是数字1,2或3，R 9是C 6 -C 18烷基，R 10是甲基或乙基，Ar和Ar'独立地是下式的基团或者ArNHAr 其中R 17和R 17'各自独立地为-H或C 4 -C 18烷基，R 11和R 12各自独立地为C 1 -C 4烷基，R 13和R 14各自独立地为C 4 -C 18烷基，R 15和R 16各自独立地为-H或C 1 -C 12烷基。

7. 发明授权

US5412008A Stabilized methylmethacrylate polymers 失效
标题翻译：稳定的甲基丙烯酸甲酯聚合物
公开(公告)号：US5412008A
公开(公告)日：1995-05-02
申请号：US143240
申请日：1993-10-22
申请人： Peter Michaelis
发明人： Peter Michaelis
IPC分类号： C08J3/20 , C08J5/18 , C08K5/00 , C08K5/17 , C08K5/3492 , C08L33/04 , C08L33/12
CPC分类号： C08K5/3492
摘要： Hydroxyphenyltriazines of formula I ##STR1## wherein R is hydrogen, C.sub.1 -C.sub.18 alkyl, halogen- or C.sub.1 -C.sub.12 alkoxy-substituted C.sub.2 -C.sub.6 alkyl, or benzyl, andR' is hydrogen or methyl, are particularly suitable stabilizers for polymethylmethacrylate and copolymers thereof.
摘要翻译：式I的羟基苯基三嗪其中R是氢，C 1 -C 18烷基，卤素 - 或C 1 -C 12烷氧基取代的C 2 -C 6烷基或苄基，R'是氢或甲基是聚甲基丙烯酸甲酯及其共聚物的特别合适的稳定剂。

8. 发明授权

US4260503A Mercaptan as an additive for lubricants 失效
标题翻译：硫醇作为润滑剂的添加剂
公开(公告)号：US4260503A
公开(公告)日：1981-04-07
申请号：US97296
申请日：1979-11-26
申请人： Peter Michaelis
发明人： Peter Michaelis
IPC分类号： C10M135/26 , C07C67/00 , C07C313/00 , C07C323/12 , C07C323/25 , C07C323/52 , C07D331/02 , C10M135/00 , C10M135/22 , C10M135/24 , C10M169/00 , C10M1/20 , C07C149/06 , C07C149/20 , C10M1/38
CPC分类号： C10M135/00 , C07C323/00 , C07D331/02 , C10M2205/00 , C10M2205/026 , C10M2205/22 , C10M2207/023 , C10M2207/024 , C10M2207/025 , C10M2207/026 , C10M2207/027 , C10M2207/123 , C10M2207/129 , C10M2207/16 , C10M2207/22 , C10M2207/289 , C10M2209/084 , C10M2211/08 , C10M2215/04 , C10M2215/044 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/028 , C10M2217/06 , C10M2219/024 , C10M2219/044 , C10M2219/068 , C10M2219/082 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/089 , C10M2219/09 , C10M2219/108 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/043 , C10M2223/045 , C10M2223/065 , C10N2210/02 , C10N2210/05
摘要： Epithio compounds or mercaptans of the formula I ##STR1## wherein X is an oxygen or sulfur atom, --CH.sub.2 --, --CH(R.sub.1)--, --COO--, --NH-- or --NR.sub.1 --, each of Y and Z is hydrogen or together they are a direct bond, Q is hydrogen if Y and Z together are a direct bond, or is --OH, --SH, --OR.sub.1, --SR.sub.1, --OOCR.sub.1, --S--CH.sub.2).sub.n OH, --S--CH.sub.2).sub.n COOR.sub.1, --NHR.sub.1 or --N(R.sub.1).sub.2, n is an integer from 1 to 10, each of R and R.sub.1 independently is a cyclic or acyclic hydrocarbon radical of aliphatic or aromatic character containing 4 to 30 carbon atoms which can be interrupted by oxygen or sulfur, with the proviso that the groups R and R.sub.1 contain a total number of 8 to 30 carbon atoms. These compounds have excellent suitability for use as additives for lubricants, especially as extreme pressure and antiwear additives.
摘要翻译：式I的（I）的硫代化合物或硫醇，其中X是氧或硫原子，-CH 2 - ， - CH（R 1） - ， - COO - ， - NH-或-NR 1 - ，每个Y 并且Z是氢或一起它们是直接键，如果Y和Z一起是直接键，则Q是氢，或者是-OH，-SH，-OR1，-SR1，-OOCR1，-S-CH2）n OH， -S-CH 2）n COOR 1，-NHR 1或-N（R 1）2，n是1至10的整数，R和R 1各自独立地是含有4至30个碳的脂族或芳族的环状或非环状烃基可以被氧或硫中断的原子，条件是基团R和R 1含有总共8-30个碳原子。这些化合物具有优异的适用性，可用作润滑剂的添加剂，特别是作为极压和抗磨添加剂。

9. 发明授权

US4217233A Epithio compounds as additives for lubricants 失效
标题翻译： Epithio化合物作为润滑剂的添加剂
公开(公告)号：US4217233A
公开(公告)日：1980-08-12
申请号：US935815
申请日：1978-08-22
申请人： Peter Michaelis
发明人： Peter Michaelis
IPC分类号： C10M135/26 , C07C67/00 , C07C313/00 , C07C323/12 , C07C323/25 , C07C323/52 , C07D331/02 , C10M135/00 , C10M135/22 , C10M135/24 , C10M169/00 , C10M1/20 , C07D327/02 , C10M1/38
CPC分类号： C10M135/00 , C07C323/00 , C07D331/02 , C10M2205/00 , C10M2205/026 , C10M2205/22 , C10M2207/023 , C10M2207/024 , C10M2207/025 , C10M2207/026 , C10M2207/027 , C10M2207/123 , C10M2207/129 , C10M2207/16 , C10M2207/22 , C10M2207/289 , C10M2209/084 , C10M2211/08 , C10M2215/04 , C10M2215/044 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/028 , C10M2217/06 , C10M2219/024 , C10M2219/044 , C10M2219/068 , C10M2219/082 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/089 , C10M2219/09 , C10M2219/108 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/043 , C10M2223/045 , C10M2223/065 , C10N2210/02 , C10N2210/05
摘要： Epithio compounds or mercaptans of the formula I ##STR1## wherein X is an oxygen or sulfur atom, --CH.sub.2 --, --CH(R.sub.1)--, --COO--, --NH-- or --NR.sub.1 --, each of Y and Z is hydrogen or together they are a direct bond, Q is hydrogen if Y and Z together are a direct bond, or is --OH, --SH, --OR.sub.1, --SR.sub.1, --OOCR.sub.1, --S--CH.sub.2).sub.n OH, --S--CH.sub.2).sub.n COOR.sub.1, --NHR.sub.1 or --N(R.sub.1).sub.2, n is an integer from 1 to 10, each of R and R.sub.1 independently is a cyclic or acyclic hydrocarbon radical of aliphatic or aromatic character containing 4 to 30 carbon atoms which can be interrupted by oxygen or sulfur, with the proviso that the groups R and R.sub.1 contain a total number of 8 to 30 carbon atoms. These compounds have excellent suitability for use as additives for lubricants, especially as extreme pressure and antiwear additives.
摘要翻译：式I的（I）的硫代化合物或硫醇，其中X是氧或硫原子，-CH 2 - ， - CH（R 1） - ， - COO - ， - NH-或-NR 1 - ，每个Y 并且Z是氢或一起它们是直接键，如果Y和Z一起是直接键，则Q是氢，或者是-OH，-SH，-OR1，-SR1，-OOCR1，-S-CH2）nOH， - S-CH 2）n COOR 1，-NHR 1或-N（R 1）2，n为1〜10的整数，R和R 1各自独立地为含有4〜30个碳原子的脂肪族或芳香族的环状或非环状烃基，可以被氧或硫中断，条件是基团R和R 1含有总共8-30个碳原子。这些化合物具有优异的适用性，可用作润滑剂的添加剂，特别是作为极压和抗磨添加剂。

10. 发明授权

US5422415A Polyether polyol and polyurethane compositions protected against oxidation and core scorching 失效
标题翻译：聚醚多元醇和聚氨酯组合物防止氧化和烧焦
公开(公告)号：US5422415A
公开(公告)日：1995-06-06
申请号：US191577
申请日：1994-02-03
申请人： Peter Michaelis
发明人： Peter Michaelis
IPC分类号： C08G18/48 , C08J9/02 , C08J9/14 , C08K5/00 , C08K5/04 , C08K5/1535 , C08L71/00 , C08L71/02 , C08L75/00 , C08L75/08 , C08G18/32 , C08G18/40
CPC分类号： C08K5/1535
摘要： Described are compositions protected against thermal and oxidative degradation that compriseA) a polyether polyol or mixtures of such polyols,B) at least one benzofuranone derivative of formula I, ##STR1## wherein L, G, m, R.sub.1 to R.sub.5 and R.sub.21 to R.sub.24 are as defined in claim 1,C) at least one compound from the group of the phenolic anti-oxidants, and/orD) at least one compound from the group of the amino anti-oxidants of the secondary amine type. Also polyurethane(s) (foam(s)) prepared therefrom are protected against thermal and oxidative degradation, especially against core scorching.
摘要翻译：描述了保护免受热和氧化降解的组合物，其包含A）聚醚多元醇或这种多元醇的混合物，B）至少一种式I的苯并呋喃酮衍生物，R 24如权利要求1所定义，C）至少一种酚类抗氧化剂组，和/或D）至少一种来自仲胺型氨基抗氧化剂的化合物。由其制备的聚氨酯（泡沫）也可防止热和氧化降解，特别是防止烧焦。

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