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1. 发明授权

US4973399A Catalytic cracking of hydrocarbons 失效
标题翻译：碳氢化合物的催化裂化
公开(公告)号：US4973399A
公开(公告)日：1990-11-27
申请号：US454475
申请日：1989-12-21
申请人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
发明人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
IPC分类号： B01J29/072 , B01J37/04 , C10G11/05 , C10G11/18
CPC分类号： B01J37/04 , B01J29/072 , C10G11/05 , C10G11/18
摘要： Emission of noxious nitrogen oxides with the flue gas from the regenerator of a fluid catalytic cracking plant are reduced by incorporating into the circulating inventory of cracking catalyst separate additive particles that contain a copper-loaded zeolite. A particularly effective additive is provided, for example, by treating a ZSM-5 zeolite in a matrix consisting predominantly of titania, zirconia or a mixture thereof with a solution containing both copper and rare earth cations to incorporate both of these elements with the zeolitic composition.
摘要翻译：通过将含有负载铜的沸石的裂化催化剂分离的添加剂颗粒结合到循环库存中，减少了来自流化催化裂化装置的再生器的烟道气的有害氮氧化物的排放。提供了特别有效的添加剂，例如通过在主要由二氧化钛，氧化锆或其混合物组成的基质中处理ZSM-5沸石与含有铜和稀土阳离子的溶液以将这两种元素与沸石组合物结合。

2. 发明授权

US4980052A Catalytic cracking of hydrocarbons 失效
标题翻译：碳氢化合物的催化裂化
公开(公告)号：US4980052A
公开(公告)日：1990-12-25
申请号：US433407
申请日：1989-11-03
申请人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
发明人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
IPC分类号： B01J29/072 , B01J37/04 , C10G11/05 , C10G11/18
CPC分类号： C10G11/05 , B01J29/072 , B01J37/04 , C10G11/18
摘要： Emission of noxious nitrogen oxides with the flue gas from the regenerator of a fluid catalytic cracking plant are reduced by incorporating into the circulating inventory of cracking catalyst separate additive particles that contain a copper-loaded zeolite. A particularly effective additive is provided by ion-exchanging ZSM-5 zeolite with cupric ion. With such preferred additive, CO emissions also are reduced, and the recovered gasoline has enhanced octane number.
摘要翻译：通过将含有负载铜的沸石的裂化催化剂分离的添加剂颗粒结合到循环库存中，减少了来自流化催化裂化装置的再生器的烟道气的有害氮氧化物的排放。通过离子交换ZSM-5沸石与铜离子提供特别有效的添加剂。使用这种优选的添加剂，CO排放也减少，回收的汽油具有增强的辛烷值。

3. 发明授权

US4962075A Zeolitic copper catalyst 失效
标题翻译：沸石铜催化剂
公开(公告)号：US4962075A
公开(公告)日：1990-10-09
申请号：US279613
申请日：1988-12-05
申请人： Gary J. Green , David S. Shihabi
发明人： Gary J. Green , David S. Shihabi
IPC分类号： B01D53/94 , B01J29/072 , B01J29/46 , B01J29/72
CPC分类号： B01J29/46 , B01D53/945 , B01J29/072 , Y02T10/22
摘要： Improved zeolitic copper catalysts are prepared by incorporating with the catalyst a steam-stabilizing amount of titanium or zirconium compound. The novel compositions are particularly useful in treating wet exhaust gases to reduce the content of one or more pollutants such as nitrogen oxides, carbon monoxide and hydrocarbons.
摘要翻译：改进的沸石铜催化剂通过与催化剂掺入蒸汽稳定量的钛或锆化合物来制备。该新型组合物特别可用于处理湿废气以减少一种或多种污染物如氮氧化物，一氧化碳和碳氢化合物的含量。

4. 发明授权

US5085762A Catalytic cracking of hydrocarbons 失效
标题翻译：碳氢化合物的催化裂化
公开(公告)号：US5085762A
公开(公告)日：1992-02-04
申请号：US548349
申请日：1990-07-05
申请人： Robert P. L. Absil , Emmerson Bowes , Gary J. Green , David O. Marler , David S. Shihabi , Richard F. Socha
发明人： Robert P. L. Absil , Emmerson Bowes , Gary J. Green , David O. Marler , David S. Shihabi , Richard F. Socha
IPC分类号： B01J29/70 , B01J29/86 , C10G11/05
CPC分类号： B01J29/7038 , B01J29/86 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： Emission of noxious nitrogen oxides with the flue gas from the regenerator of a fluid catalytic cracking plant are reduced by incorporating into the circulating inventory of cracking catalyst separate additive particles that contain a copper-loaded zeolite material having a characteristic structure with a defined X-ray diffraction pattern. The preferred material of this type is zeolite MCM-22. The copper may be exchanged onto the zeolite or impregnated into the catalyst. In addition, the catalyst may include titanium or zirconium to provide stability and further improvements in stability may be obtained with the addition of rareearth metal cations, especially cerium or yttrium. NOX and CO emissions from the regenerator are reduced, and the gasoline produced in the unit may have an improved octane number.
摘要翻译：流化催化裂化装置的再生器的废气中的有害氮氧化物的排放通过将含有具有特定结构的含铜负载沸石材料的裂化催化剂的分开的添加剂颗粒加入循环库存中来减少，所述添加剂颗粒具有规定的X射线衍射图案。这种类型的优选材料是沸石MCM-22。铜可以交换到沸石上或浸入催化剂中。此外，催化剂可以包括钛或锆以提供稳定性，并且通过添加乳剂金属阳离子，特别是铈或钇，可以获得稳定性的进一步改善。来自再生器的NO x和CO排放减少，并且在该单元中产生的汽油可能具有改善的辛烷值。

5. 发明授权

US5830346A FCC regenerator in partial CO burn with downstream air addition 失效
标题翻译： FCC再生器部分CO燃烧与下游空气添加
公开(公告)号：US5830346A
公开(公告)日：1998-11-03
申请号：US521177
申请日：1995-08-30
申请人： Mohsen N. Harandi , Paul H. Schipper , David S. Shihabi , Scott A. Stevenson
发明人： Mohsen N. Harandi , Paul H. Schipper , David S. Shihabi , Scott A. Stevenson
IPC分类号： B01D53/86 , C10G11/18 , C10G11/00 , B01J21/20 , C01B21/02
CPC分类号： C10G11/182 , B01D53/8625
摘要： Oxides of nitrogen (NO.sub.x) emissions from an FCC regenerator are reduced by operating the regenerator in partial CO burn mode to produce flue gas with more CO than O.sub.2 and with NO.sub.x precursors. This flue gas is then enriched with controlled amounts of oxygen and charged over catalyst, preferably Group VIII noble metal on a support, to convert most NO.sub.x precursors to nitrogen. Flue gas may then be charged to a CO boiler. Eliminating more than 90% of NO.sub.x emissions is possible by operating the FCC regenerator in partial CO burn mode, then adding air and catalytically converting NO.sub.x precursors at substoichiometric conditions. Conversion of NO.sub.x, if formed in the regenerator, may be achieved as well.
摘要翻译：通过在部分CO燃烧模式下操作再生器来减少来自FCC再生器的氮（NOx）排放的氧化物，以产生具有比O 2和NO x前体更多的CO的烟道气。然后，该烟道气用受控量的氧气富集，并通过催化剂，优选载体上的VIII族贵金属加入，以将大部分NOx前体转化为氮气。然后将烟道气充入CO锅炉。通过在部分CO燃烧模式下操作FCC再生器，然后在亚化学计量条件下添加空气和催化转化NOx前体，可以消除超过90％的NOx排放。也可以在再生器中形成NOx的转化。

6. 发明授权

US5520895A Method for the reduction of nitrogen oxides using iron impregnated zeolites 失效
标题翻译：使用铁浸渍沸石还原氮氧化物的方法
公开(公告)号：US5520895A
公开(公告)日：1996-05-28
申请号：US271693
申请日：1994-07-07
申请人： Sanjay B. Sharma , David S. Shihabi
发明人： Sanjay B. Sharma , David S. Shihabi
IPC分类号： B01D53/86 , B01D53/94 , B01J29/072 , B01J37/02 , C01B21/00
CPC分类号： B01J37/0203 , B01D53/8621 , B01D53/865 , B01D53/9418 , B01J29/072 , B01D2251/2062 , B01D2255/20738 , B01D2255/50
摘要： There is provided a process for the treatment of exhaust gas, which process uses a specially prepared catalyst composition, for the selective catalytic reduction of NO.sub.x contained in the exhaust gas. An embodiment of the process of this invention comprises a catalytic stage to selectively catalytically reduce NO.sub.x over a catalyst composition comprising an intermediate pore size zeolite catalyst that has been treated with a water soluble iron salt or salt precursor in a way effective to maximize iron dispersion. The intermediate pore size zeolite of this invention preferably has a silica:alumina molar ratio of between about 20 and about 1000. The catalyst of this invention typically comprises a silica, titania, or zirconia binder, preferably a binder including a high molecular weight, hydroxyl functional silicone resin. The catalyst of this invention is preferably formed, e.g., extruded, and then simultaneously calcined and hydrothermally treated.
摘要翻译：提供了一种处理废气的方法，该方法使用特别制备的催化剂组合物来选择性催化还原废气中所含的NOx。本发明方法的一个实施方案包括催化阶段，以催化还原催化剂还原催化剂组合物，该催化剂组合物包含中和孔径的沸石催化剂，该催化剂已经以有效使铁分散最大化的方式用水溶性铁盐或盐前体处理。本发明的中等孔径沸石优选具有约20至约1000的二氧化硅：氧化铝摩尔比。本发明的催化剂通常包含二氧化硅，二氧化钛或氧化锆粘合剂，优选包含高分子量羟基的粘合剂功能硅树脂。本发明的催化剂优选形成例如挤出，然后同时进行煅烧和水热处理。

7. 发明授权

US5451387A Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst 失效
标题翻译：使用铁浸渍的沸石催化剂选择性还原氮氧化物
公开(公告)号：US5451387A
公开(公告)日：1995-09-19
申请号：US271692
申请日：1994-07-07
申请人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
发明人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
IPC分类号： B01D53/86 , B01D53/94 , B01J29/072 , B01J29/46 , B01J37/02 , C01B21/20
CPC分类号： B01J37/0203 , B01D53/8621 , B01D53/8628 , B01D53/865 , B01D53/9418 , B01J29/072 , B01J29/46 , B01D2251/2062 , B01D2255/20738 , B01D2255/50
摘要： An exhaust gas treatment process useful for the removal of nitrogen oxides using an iron containing zeolite as the catalyst and ammonia as a reducing agent. It is desired to extend the effective temperature range for the selective catalytic reduction (SCR) of nitrogen oxides below about 400.degree. C. This is accomplished in the instant invention through the use of an intermediate pore size zeolite, such as ZSM-5, based catalyst which has been treated to incorporate iron into its pores.
摘要翻译：用于使用含铁沸石作为催化剂除去氮氧化物的废气处理方法和氨作为还原剂。期望将氮氧化物的选择性催化还原（SCR）的有效温度范围延伸到低于约400℃。这在本发明中通过使用中等孔径的沸石，例如ZSM-5，基于已经处理以将铁掺入其孔中的催化剂。

8. 发明授权

US5173278A Denitrification of flue gas from catalytic cracking 失效
标题翻译：烟气从催化裂化中脱氮
公开(公告)号：US5173278A
公开(公告)日：1992-12-22
申请号：US669821
申请日：1991-03-15
申请人： David O. Marler , Ajit V. Sapre , David S. Shihabi , Richard F. Socha , Scott A. Stevenson
发明人： David O. Marler , Ajit V. Sapre , David S. Shihabi , Richard F. Socha , Scott A. Stevenson
IPC分类号： B01D53/86 , C10G11/18
CPC分类号： B01D53/8625 , B01D53/8621 , C10G11/182 , B01D2257/408 , Y02P30/446
摘要： A flue gas that contains small amounts of both HCN and NO.sub.x, produced, for example, by catalyst regeneration in the fluid catalytic cracking of a petroleum gas oil, is readily denitrified by the catalyzed reaction that proceeds approximately according to:HCN+NO.fwdarw.N.sub.2 (gas)+CO+CO.sub.2 +H.sub.2 OIf the molar ratio of HCN to NO in the flue gas is about 1.0, e.g. in the range of about 0.8 to 1.2, effective denitrification is achieved without first changing the composition of the flue gas by contacting it with catalyst under conversion conditions including elevated temperature. If the molar ratio of HCN to NO exceeds 1.2, the ratio may be adjusted to about 1.0 to 1.1 by thermal or catalytic oxidation in the presence of oxygen gas, followed by catalytic denitrification. If the molar ratio is less than about 0.8, the effective molar ratio is adjusted to about 1.0 to 1.1 by adding NH.sub.3 gas, followed by denitirification. In all three instances an excessive content of carbon monoxide in the flue gas may be corrected by passing the denitrified flue gas to a CO-boiler.Catalysts for the denitrification reaction are described and exemplified by crystalline zeolites of the ZSM-5 type, and by vanadium oxide supported on titania.
摘要翻译：含有少量HCN和NOx的烟道气，例如通过在石油瓦斯油的流化催化裂化中的催化剂再生产生的烟气，可以通过大致按以下方式进行的催化反应脱氮：HCN + NO-> N2（气体）+ CO + CO2 + H2O如果烟气中HCN与NO的摩尔比为约1.0，在约0.8至1.2的范围内，无需首先在包括升高的温度的转化条件下将催化剂与催化剂接触，而不改变烟道气的组成，实现有效的脱氮。如果HCN与NO的摩尔比超过1.2，则在氧气存在下通过热或催化氧化将该比例调节至约1.0至1.1，然后进行催化反硝化。如果摩尔比小于约0.8，则通过加入NH 3气体将有效摩尔比调节至约1.0-1.1，然后进行脱硝。在所有三种情况下，可以通过将反硝化烟道气通过CO锅炉来校正烟道气中过量的一氧化碳。用于脱氮反应的催化剂通过ZSM-5型的结晶沸石和负载在二氧化钛上的氧化钒来描述和例示。

9. 发明授权

US5043307A Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效
标题翻译：改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US5043307A
公开(公告)日：1991-08-27
申请号：US402716
申请日：1989-09-05
申请人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
发明人： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
IPC分类号： C10G50/02
CPC分类号： C10G50/02
摘要： The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:a) steaming the as synthesized crystalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom.
摘要翻译：本发明提供了一种修饰约约至约12约束指数的结晶硅铝酸盐沸石的方法，该方法包括：a）蒸煮含有有机模板材料的合成的结晶硅铝酸盐沸石以分解所述模板材料的至少一部分，以及提取沸石铝; 和b）将由步骤（a）得到的沸石以铵，碱金属或氢的形式与脱铝剂接触，脱铝剂与铝形成水溶性络合物以从其中除去另外量的沸石铝。

10. 发明授权

US4851604A Toluene disproportionation 失效
标题翻译：甲苯歧化
公开(公告)号：US4851604A
公开(公告)日：1989-07-25
申请号：US92842
申请日：1987-09-02
申请人： Robert P. L. Absil , Scott Han , David O. Marler , David S. Shihabi
发明人： Robert P. L. Absil , Scott Han , David O. Marler , David S. Shihabi
IPC分类号： B01J29/65 , B01J29/40 , C07B61/00 , C07C1/00 , C07C6/12 , C07C15/02 , C07C67/00
CPC分类号： C07C6/123 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52
摘要： An improved process is provided for vapor-phase disproportionation of toluene over catalyst comprising a molecular sieve having a high lattice aluminum content whereby its silica/alumina mole ratio is less than 55 and a diffusion rate constant of less than about 150 sec.sup.-1.

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