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    • 6. 发明授权
    • Denitrification of flue gas from catalytic cracking
    • 烟气从催化裂化中脱氮
    • US5173278A
    • 1992-12-22
    • US669821
    • 1991-03-15
    • David O. MarlerAjit V. SapreDavid S. ShihabiRichard F. SochaScott A. Stevenson
    • David O. MarlerAjit V. SapreDavid S. ShihabiRichard F. SochaScott A. Stevenson
    • B01D53/86C10G11/18
    • B01D53/8625B01D53/8621C10G11/182B01D2257/408Y02P30/446
    • A flue gas that contains small amounts of both HCN and NO.sub.x, produced, for example, by catalyst regeneration in the fluid catalytic cracking of a petroleum gas oil, is readily denitrified by the catalyzed reaction that proceeds approximately according to:HCN+NO.fwdarw.N.sub.2 (gas)+CO+CO.sub.2 +H.sub.2 OIf the molar ratio of HCN to NO in the flue gas is about 1.0, e.g. in the range of about 0.8 to 1.2, effective denitrification is achieved without first changing the composition of the flue gas by contacting it with catalyst under conversion conditions including elevated temperature. If the molar ratio of HCN to NO exceeds 1.2, the ratio may be adjusted to about 1.0 to 1.1 by thermal or catalytic oxidation in the presence of oxygen gas, followed by catalytic denitrification. If the molar ratio is less than about 0.8, the effective molar ratio is adjusted to about 1.0 to 1.1 by adding NH.sub.3 gas, followed by denitirification. In all three instances an excessive content of carbon monoxide in the flue gas may be corrected by passing the denitrified flue gas to a CO-boiler.Catalysts for the denitrification reaction are described and exemplified by crystalline zeolites of the ZSM-5 type, and by vanadium oxide supported on titania.
    • 含有少量HCN和NOx的烟道气,例如通过在石油瓦斯油的流化催化裂化中的催化剂再生产生的烟气,可以通过大致按以下方式进行的催化反应脱氮:HCN + NO-> N2(气体)+ CO + CO2 + H2O如果烟气中HCN与NO的摩尔比为约1.0, 在约0.8至1.2的范围内,无需首先在包括升高的温度的转化条件下将催化剂与催化剂接触,而不改变烟道气的组成,实现有效的脱氮。 如果HCN与NO的摩尔比超过1.2,则在氧气存在下通过热或催化氧化将该比例调节至约1.0至1.1,然后进行催化反硝化。 如果摩尔比小于约0.8,则通过加入NH 3气体将有效摩尔比调节至约1.0-1.1,然后进行脱硝。 在所有三种情况下,可以通过将反硝化烟道气通过CO锅炉来校正烟道气中过量的一氧化碳。 用于脱氮反应的催化剂通过ZSM-5型的结晶沸石和负载在二氧化钛上的氧化钒来描述和例示。