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    • 2. 发明授权
    • Process for preparing a catalyst for aromatic production
    • 制备芳香族生产催化剂的方法
    • US06617275B1
    • 2003-09-09
    • US10022107
    • 2001-12-13
    • Sanjay B. SharmaJohn KulachAaron James Imrie
    • Sanjay B. SharmaJohn KulachAaron James Imrie
    • B01J2906
    • B01J29/061B01J29/405B01J2229/20B01J2229/42
    • A novel process for converting C2 to C6 aliphatic hydrocarbons to aromatics and catalyst for use in this process are disclosed. The catalyst that contains a zeolite having a silica to alumina molar ratio greater than about 20 and a pore diameter from about 5 Å to about 6 Å, an essentially non-acidic binder, and a gallium component. The binder is selected from silica, zirconia, titania, and mixtures thereof and results in a catalyst formulation having both enhanced selectivity to desired C6-C9 aromatic products and improved stability compared to prior art compositions. Preferred zeolites that can be used include those of the MFI structure type, with ZSM-5 being a specific example.
    • 公开了一种用于将C2转化为C6脂族烃到用于该方法中的芳族化合物和催化剂的新方法。 含有二氧化硅与氧化铝摩尔比大于约20,孔直径为约5至约6的沸石,基本上非酸性粘合剂和镓组分的沸石的催化剂。 粘合剂选自二氧化硅,氧化锆,二氧化钛及其混合物,并且导致与现有技术组合物相比,具有对期望的C 6 -C 9芳香族产物的增强的选择性和改善的稳定性的催化剂制剂。 可以使用的优选的沸石包括MFI结构类型的沸石,ZSM-5是具体实例。
    • 4. 发明授权
    • Process for exhaust gas NO.sub.x, CO, and hydrocarbon removal
    • 废气NOx,CO和烃的去除方法
    • US5676912A
    • 1997-10-14
    • US391859
    • 1995-02-22
    • Sanjay B. SharmaDavid S. Shihabi
    • Sanjay B. SharmaDavid S. Shihabi
    • B01D53/94B01D53/92B01D53/56B01D53/62B01D53/72
    • B01D53/945Y02T10/22
    • There is provided a multizone catalytic process for the treatment of exhaust gas comprising nitrogen oxides, hydrocarbons, and carbon monoxide. In the multizone catalytic process, the exhaust gas is directed through a first zone, a second zone, and a third zone. The first zone comprises a catalyst that is effective for the three-way conversion of nitrogen oxides, hydrocarbons, and carbon monoxide. The second zone comprises materials effective to sorb hydrocarbons, e.g., zeolites ZSM-5 and Beta, particularly iron modified zeolites ZSM-5 and Beta. The second zone is effective for the adsorption of hydrocarbons from the exhaust gas during the cold-start period of operation of an internal combustion engine. The third zone comprises a catalyst that is effective for the oxidation of hydrocarbons and carbon monoxide.
    • 提供了一种用于处理包含氮氧化物,碳氢化合物和一氧化碳的废气的多区域催化方法。 在多区域催化过程中,废气被引导通过第一区域,第二区域和第三区域。 第一区域包含对氮氧化物,碳氢化合物和一氧化碳三元转化有效的催化剂。 第二区域包括有效吸附烃的材料,例如沸石ZSM-5和β,特别是铁改性沸石ZSM-5和β。 第二区域对于在内燃机的冷启动期间从排气中吸附碳氢化合物是有效的。 第三区域包含对烃和一氧化碳的氧化有效的催化剂。