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1. 发明授权

US4777284A Continuous preparation of carbalkoxy-containing aliphatic compounds 失效
标题翻译：连续制备含有烷氧基的脂族化合物
公开(公告)号：US4777284A
公开(公告)日：1988-10-11
申请号：US116877
申请日：1987-11-05
申请人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
发明人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
IPC分类号： B01J31/20 , B01J31/00 , C07B61/00 , C07C67/30 , C07C67/38 , C07C69/003 , C07C69/34 , C07C69/44 , C07C69/533 , C07C69/593
CPC分类号： C07C67/38
摘要： Carbalkoxy-containing aliphatic compounds are prepared continuously by reacting an olefinically unsaturated aliphatic compound with carbon monoxide and an alkanol in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at from 80.degree. to 200.degree. C. and under from 100 to 1,200 bar by an improved process in which carbon monoxide is circulated, and a carbon dioxide content of from 0.1 to 2% by volume is maintained in the carbon monoxide fed to the reaction.
摘要翻译：在羰基催化剂和叔氮碱的存在下，在80〜200℃，100〜1200巴下，使烯属不饱和脂肪族化合物与一氧化碳和链烷醇反应制备含有链烷烃基的脂肪族化合物通过一氧化碳循环的改进方法，并且在进料到反应中的一氧化碳中维持二氧化碳含量为0.1-2体积％。

2. 发明授权

US4861895A Treatment of aqueous solutions obtained in the carbalkoxylation of olefinically unsaturated compounds 失效
标题翻译：处理在烯属不饱和化合物的碳烷基化反应中获得的水溶液
公开(公告)号：US4861895A
公开(公告)日：1989-08-29
申请号：US77630
申请日：1987-07-24
申请人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
发明人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
IPC分类号： C07C67/38 , C07C67/00 , C07C67/48 , C07C67/54 , C07C67/60 , C07C69/02 , C07C69/34 , C07C69/44 , C07C69/533 , C07D211/70 , C07D213/06
CPC分类号： C07C67/38 , C07C67/60
摘要： Aqueous solutions which are obtained in the carbalkoxylation of olefinically unsaturated compounds and contain heterocyclic aromatic nitrogen bases, their transformation products and lower fatty acids and/or their salts are treated by a process in which (a) the aqueous solution is heated to 150.degree.-300.degree. C. under from 10 to 300 bar and (b) heterocyclic aromatic nitrogen bases which are formed again from the transformation products are then separated off.
摘要翻译：通过以下方法处理在烯属不饱和化合物的碳烷基氧化中含有杂环芳族氮碱，它们的转化产物和低级脂肪酸和/或其盐的水溶液，其中（a）将水溶液加热至150℃， 300℃，10-300巴，（b）从转化产物再次形成的杂环芳基氮碱分离出来。

3. 发明授权

US4894474A Preparation of alkyl pentenoates 失效
标题翻译：戊烯酸烷基酯的制备
公开(公告)号：US4894474A
公开(公告)日：1990-01-16
申请号：US225823
申请日：1988-07-29
申请人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
发明人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
IPC分类号： C07C67/38 , B01J31/20 , C07B61/00 , C07C69/533
CPC分类号： C07C69/533
摘要： Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen, based on the amount of carbon monoxide used.
摘要翻译：烷基戊烯酸酯是通过使丁二烯与一氧化碳和链烷醇在羰基钴配合物和叔芳族杂环氮碱存在下，在80-160℃，100-1,000巴下，存在0.1当量至10体积％的氢气，基于所用一氧化碳的量。

4. 发明授权

US4755625A Preparation of 1,1,2-trialkoxyethanes 失效
标题翻译： 1,1,2-三烷氧基乙醚的制备
公开(公告)号：US4755625A
公开(公告)日：1988-07-05
申请号：US73999
申请日：1987-07-16
申请人： Robert Maerkl , Werner Bertleff , Rudolf Kummer
发明人： Robert Maerkl , Werner Bertleff , Rudolf Kummer
IPC分类号： C07B61/00 , B01J31/00 , B01J31/20 , B01J31/24 , C07C41/00 , C07C41/48 , C07C43/315 , C07C67/00 , C07D317/22 , C07D319/06 , C07D321/06
CPC分类号： C07C41/48
摘要： 1,1,2-trialkoxyethanes I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.8 -alkyl and R.sup.1 and R.sup.2 may furthermore be bonded to one another to form a 5-membered to 7-membered ring, are prepared by reacting a formaldehyde dialkyl acetal II with carbon monoxide and hydrogen, from 0.5 to 1.5 moles of hydrogen being used per mole of carbon monoxide, and with not less than 1 mole of alcohol R.sup.3 OH per mole of formaldehyde dialkyl acetal under superatmospheric pressure and at elevated temperatures in the presence of a catalyst which is formed from a cobalt carbonyl compound and a trivalent organic compound of the formula III ##STR2## where A is phosphorus, arsenic, antimony or bismuth and R.sup.4, R.sup.5 and R.sup.6 are each an organic radical.
摘要翻译：其中R 1，R 2和R 3各自是C 1 -C 8 - 烷基，R 1和R 2可以彼此键合形成5元至7元环，通过使甲醛二烷基缩醛II与一氧化碳和氢反应，每摩尔一氧化碳使用0.5至1.5摩尔氢，并且在超大气压下每摩尔甲醛二烷基缩醛不少于1摩尔醇R3OH，在由羰基钴化合物和式III的三价有机化合物形成的催化剂存在下，在升高的温度下，其中A是磷，砷，锑或铋，并且R 4，R 5和R 6各自是有机的激进。

5. 发明授权

US4740525A Preparation of ethylene glycol 失效
标题翻译：乙二醇的制备
公开(公告)号：US4740525A
公开(公告)日：1988-04-26
申请号：US900770
申请日：1986-08-26
申请人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
发明人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
IPC分类号： C07B61/00 , B01J31/00 , C07C29/158 , C07C27/06 , C07C31/20
CPC分类号： C07C29/158 , Y02P20/52
摘要： Ethylene glycol is prepared from carbon monoxide and hydrogen in homogeneous liquid phase under superatmospheric pressure and at elevated temperature in the presence of a rhodium-containing catalyst and in the presence of an organic solvent, the organic solvent used being a C.sub.2 -C.sub.20 -n-alkanol and the concentration of this alkanol, based on the total amount of the mixture, constantly being maintained at not less than 50% by weight.
摘要翻译：乙二醇由均一液相中的一氧化碳和氢气在超大气压和升高的温度下在含铑催化剂存在下制备，并且在有机溶剂存在下，所用的有机溶剂是C 2 -C 20正 - 链烷醇和该烷醇的浓度，基于混合物的总量，不断保持在不小于50重量％。

6. 发明授权

US4910328A Preparation of omega-formylalkanecarboxylic esters 失效
标题翻译： ω-甲酰基烷羧酸酯的制备
公开(公告)号：US4910328A
公开(公告)日：1990-03-20
申请号：US206752
申请日：1988-06-15
申请人： Werner Bertleff , Robert Maerkl , Michael Roeper
发明人： Werner Bertleff , Robert Maerkl , Michael Roeper
IPC分类号： C07B61/00 , B01J31/20 , C07C67/313 , C07C69/67
CPC分类号： C07C67/347
摘要： .omega.-Formylalkanecarboxylic esters are prepared by hydroformylation of an alkenecarboxylic ester with carbon monoxide and hydrogen at elevated tempertures and under superatmospheric pressure in the presence of a cobalt carbonyl complex by a process in which an .alpha.,.beta.-unsaturated alkenecarboxylic ester is hydroformylated in the presence of from 0.01 to 1 mol %, calculated as cobalt, of a cobalt carbonyl complex, while maintaining a conversion of from 10 to 70% of .alpha.,.beta.-unsaturated alkenecarboxylic esters.
摘要翻译：通过在钴羰基络合物存在下，在升高的温度和超大气压下，用一氧化碳和氢气将烯羧酸酯加氢甲酰化制备ω-甲酰基烷羧酸酯，其中α，β-不饱和烯烃羧酸酯在存在下加氢甲酰化 0.01至1摩尔％，钴计算为钴羰基络合物，同时保持10至70％的α，β-不饱和烯烃羧酸酯的转化率。

7. 发明授权

US5189182A Preparation of 5-methylbutyrolactone 失效
标题翻译： 5-甲基丁酰胺的制备
公开(公告)号：US5189182A
公开(公告)日：1993-02-23
申请号：US236199
申请日：1988-08-25
申请人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.
摘要翻译：通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

8. 发明授权

US5003102A Preparation of 5-formylvaleric esters 失效
标题翻译： 5-甲酰戊酸酯的制备
公开(公告)号：US5003102A
公开(公告)日：1991-03-26
申请号：US206751
申请日：1988-06-15
申请人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
发明人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
IPC分类号： C07B61/00 , C07C67/313 , C07C69/66 , C07C69/67
CPC分类号： C07C67/347
摘要： 5-Formylvaleric esters are prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a carbonyl complex of a metal of group 8 of the Periodic Table with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) Isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) Cleavage of the mixture essentially consisting of 4- and 3-formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of a catalyst to give pentenoic esters and(d) Recycling of the pentenoic esters to stage (a).
摘要翻译： 5-甲酰戊酸酯通过包括以下步骤的方法制备：（a）在升高的温度和超大气压下，在第8组的金属的羰基络合物存在下，通过与一氧化碳和氢气反应来进行戊烯基酯的加氢甲酰化的化合物，形成5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离5-甲酰基戊酸酯，基本上由4-和3-甲酰基戊酸酯组成，（c）在催化剂存在下，在50-400℃下将基本上由4-和3-甲酰基戊酸酯组成的混合物切割，得到戊烯酸酯和（d ）将戊烯酸酯循环回到（a）阶段。

9. 发明授权

US4950797A Preparation of carbonyl compounds by isomerization of allyl alcohols 失效
标题翻译：通过烯丙醇异构化制备羰基化合物
公开(公告)号：US4950797A
公开(公告)日：1990-08-21
申请号：US201064
申请日：1988-06-01
申请人： Rudolf Kummer , Werner Bertleff , Michael Roeper
发明人： Rudolf Kummer , Werner Bertleff , Michael Roeper
IPC分类号： C07C45/51 , C07C45/78 , C07C45/81 , C07C47/19
CPC分类号： C07C45/783 , C07C45/512 , C07C45/81 , C07C47/19
摘要： A process for the preparation of carbonyl compounds by catalyzed isomerization of allyl alcohols in a tertiary phosphine or phosphite ester in the presence of a rhodium compound at a temperature of from 80.degree. C. to 180.degree. C., a carrier gas being passed through the reaction mixture and the carbonyl compound being separated from the emergent gas mixture by cooling.
摘要翻译：在铑化合物存在下，在80℃〜180℃的温度下，通过在叔膦或亚磷酸酯中催化异构化烯丙醇来制备羰基化合物的方法，载气通过反应混合物和羰基化合物通过冷却与出气混合物分离。

10. 发明授权

US4931590A Preparation of adipic acid 失效
标题翻译：己二酸的制备
公开(公告)号：US4931590A
公开(公告)日：1990-06-05
申请号：US205340
申请日：1988-06-10
申请人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
发明人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
IPC分类号： B01J31/20 , C07B61/00 , C07C51/00 , C07C51/09 , C07C55/14 , C07C67/00 , C07C67/29 , C07C67/347 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/347 , C07C51/09 , C07C67/39
摘要： Adipic acid is prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a cobalt carbonyl or rhodium carbonyl complex with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) dehydrocarbonylation of the mixture consisting essentially of 4- and 3-formylvaleric esters in the presence of one or more elements of subgroup 8 of the Periodic Table at from 50.degree. to 400.degree. C. with formation of pentenoic esters, and recycling of the latter to stage (a) for hydroformylation,(d) oxidation of the 5-formylvaleric ester from stage (b) with molecular oxygen or a gas containing molecular oxygen to give a monoester of adipic acid, and(e) hydrolysis of the monoester of adipic acid to give adipic acid.
摘要翻译：己二酸通过包括以下步骤的方法制备：（a）在羰基或羰基铑羰基络合物的存在下，在一氧化碳和氢气下，在升高的温度和超大气压下与戊烯酸酯反应，加氢甲酰化形成 5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离出5-甲酰基戊酸酯，基本上由4-甲酰基戊酰胺剩余的酯，（c）在50℃至400℃下在元素周期表第8族的一种或多种元素存在下，基本上由4-甲酰基戊酸酯组成的混合物的脱氢羰基化，形成戊烯酸酯，并将后者再循环到步骤（a）进行加氢甲酰化，（d）用分子氧或含有分子氧的气体从阶段（b）氧化5-甲酰基戊酸酯，得到己二酸的单酯，和（e）水解己二酸的单酯得到己二酸。

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