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1. 发明授权

US5151329A Process for the production of patent leather and patent leather prepared therefrom 失效
标题翻译：制备专利皮革和专利皮革的方法
公开(公告)号：US5151329A
公开(公告)日：1992-09-29
申请号：US371357
申请日：1989-06-26
申请人： Klaus Noll , Josef Pedain , Bruno Zorn , Rosemarie Schmid
发明人： Klaus Noll , Josef Pedain , Bruno Zorn , Rosemarie Schmid
IPC分类号： C08G18/12 , C08G18/42 , C14C11/00
CPC分类号： C14C11/006 , C08G18/12 , C08G18/4202 , Y10T428/31558
摘要： The present invention is directed to a process for the production of high-gloss patent leather from two-component polyurethane compositions by reacting hydroxyl group-containing oligourethanes with polyisocyanates, characterized in that the oligourethanes have been synthesized fromA) at least 2 macrodiols in a molar ratio of about 1:6 to 6:1 wherein1) the first macrodiol has an average molecular weight of 254 to about 650 and contains an aromatic ring or a saturated or unsaturated cycloaliphatic ring and2) the second macrodiol has an average molecular weight of about 1,200 to 3,000, provided that the molecular weight of macrodiol A/2 is at least 3 times the molecular weight of macrodiol A/1, andB) at least one diisocyanate,wherein the macrodiol:diisocyanate molar ratio is about 1.0:0.9 to 1.0:0.3.The present invention is also directed to the high-gloss patent leather prepared in accordance with the above process.
摘要翻译：本发明涉及通过使含羟基的聚氨酯与多异氰酸酯反应从双组分聚氨酯组合物生产高光泽漆皮的方法，其特征在于所述低聚氨酯由A）至少2个大分子二醇在摩尔比为约1:6至6:1，其中1）第一大二醇的平均分子量为254至约650，并且包含芳环或饱和或不饱和脂环族环，和2）第二大二醇具有平均分子量约1,200至3,000，条件是大分子二醇A / 2的分子量至少为大分子二醇A / 1的分子量的3倍，B）至少一种二异氰酸酯，其中大二醇：二异氰酸酯摩尔比为约1.0:0.9 至1.0：0.3。本发明还涉及根据上述方法制备的高光泽漆皮。

2. 发明授权

US4829122A Process for the preparation of aqueous polyurethane dispersions and solutions 失效
标题翻译：制备水性聚氨酯分散体和溶液的方法
公开(公告)号：US4829122A
公开(公告)日：1989-05-09
申请号：US19902
申请日：1987-02-27
申请人： Josef Pedain , Klaus Nachtkamp , Klaus Noll , Jurgen Grammel
发明人： Josef Pedain , Klaus Nachtkamp , Klaus Noll , Jurgen Grammel
IPC分类号： C08G18/00 , C03C25/00 , C08G18/08 , C08G18/10
CPC分类号： C08G18/0804 , C03C25/00 , C08G18/10 , Y10T428/31551
摘要： The present invention therefore relates to a process for the preparation of aqueous solutions or dispersions of polyurethane-polyureas by the reaction in the aqueous phase of prepolymers which contain chemically built-in hydrophilic groups and/or external emulsifiers which are not bound chemically as well as at least two free isocyanate groups with organic compounds containing at least two primary and/or secondary amino groups, characterized in that the isocyanate prepolymer which has been hydrophilically modified and/or contains an external emulsifier is mixed, in the absence of water, with compounds containing at the most one free primary or secondary amino group and at least one blocked group which releases a free primary or secondary amino group in the presence of water and a total of at least two at least partially blocked primary and/or secondary amino groups, and the mixture is subsequently mixed with water.The invention also relates to the dispersions or solutions obtained by this process and to their use for coating flexible and rigid substrates.
摘要翻译：因此，本发明涉及一种制备聚氨酯 - 聚脲的水溶液或分散体的方法，所述水溶液或分散体是通过在水相中含有化学内置的亲水基团的预聚物和/或外部乳化剂的反应制成的，至少两个含有至少两个伯和/或仲氨基的有机化合物的游离异氰酸酯基团，其特征在于，在没有水的情况下将已经亲水改性和/或含有外部乳化剂的异氰酸酯预聚物与化合物含有最多一个游离的伯或仲氨基和至少一个在水存在下释放游离的伯或仲氨基并且总共至少两个至少部分封闭的伯和/或仲氨基的封闭基团，随后将混合物与水混合。本发明还涉及通过该方法获得的分散体或溶液及其用于涂覆柔性和刚性基材的用途。

3. 发明授权

US4789718A Polyurethanes soluble or dissolved in aromatic hydrocarbons, a process for their preparation and their use 失效
标题翻译：可溶于或溶于芳烃的聚氨酯，其制备方法及其用途
公开(公告)号：US4789718A
公开(公告)日：1988-12-06
申请号：US730136
申请日：1985-05-03
申请人： Klaus Noll , Josef Pedain , Manfred Schonfelder
发明人： Klaus Noll , Josef Pedain , Manfred Schonfelder
IPC分类号： C08G18/65 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/66 , C09D175/04 , C08G18/16
CPC分类号： C08G18/12 , C08G18/0852 , C08G18/2805 , C08G18/6607 , C09D175/04
摘要： The present invention is directed to substantially linear polyurethanes obtained from 1 mol of relatively high molecular weight macrodiols such as polyesters, polyethers and polycarbonates having a molecular weight of 400 to 5000, preferably about 500 to 3000, about 1.5 to 16.5 mols of aromatic diisocyanates, optionally about 0.01 to 1 mol of chain breaking agents in the form of compounds which are monofunctional in their reaction with isocyanates, and about 0.5 to 15 mols of low molecular weight, difunctional chain lengthening agents, characterized in that at least 10 mol-% of the chain lengthening agents is 2,2,4-trimethylpentanediol-(1,3) and the remaining chain lengthening agents, having molecular weights of 62 to 399 (preferably 62 to 250), are preferably diols.The present invention also relates to a process for the preparation of these polyurethanes and to their use for the production of coatings on flexible or non-flexible substrates, wherein the coatings are optionally filled, preferably with magnetizable pigments, and are optionally cross-linked.
摘要翻译：本发明涉及从1mol相对高分子量的大分子量如聚酯，聚醚和聚碳酸酯获得的基本上线性的聚氨酯，其分子量为400至5000，优选约500至3000，约1.5至16.5摩尔的芳族二异氰酸酯，任选地约0.01至1摩尔的与异氰酸酯反应的单官能化合物形式的断链剂，以及约0.5至15摩尔的低分子量双功能链增长剂，其特征在于至少10摩尔％链延长剂是2,2,4-三甲基戊二醇 - （1,3），剩余的链延长剂的分子量为62〜399（优选为62〜250），优选为二醇。本发明还涉及制备这些聚氨酯的方法及其在柔性或非柔性基材上生产涂层的用途，其中涂层任选地被填充，优选可磁化的颜料，并且任选地是交联的。

4. 发明授权

US4764553A Water soluble or dispersible polyurethanes, a process for their preparation and their use for coating substrates 失效
标题翻译：水溶性或分散性聚氨酯，其制备方法及其用于涂布基材的用途
公开(公告)号：US4764553A
公开(公告)日：1988-08-16
申请号：US127340
申请日：1987-12-01
申请人： Jurgen Mosbach , Josef Pedain , Klaus Noll
发明人： Jurgen Mosbach , Josef Pedain , Klaus Noll
IPC分类号： C08G18/34 , C08G18/08 , C08G18/28 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/65 , C08G18/66 , C08G18/78 , C08G18/80 , C09D175/04 , D06N7/06
CPC分类号： C08G18/0823 , C08G18/2805 , C08G18/5042 , C08G18/7818 , C08G18/8061
摘要： The present invention is directed to water dispersible or soluble polyurethanes containing about 0.5 to 30% by weight, based on the weight of the polyurethanes, of ethylene oxide units present in lateral or terminal polyether chains, characterized in that in addition to these ethylene oxide units the polyurethanes contain, as further hydrophilic centers, about 0.1 to 120 milliequivalents, per 100 g of solids content, of carboxylate groups in the form of built-in structural units corresponding to the general formula ##STR1## wherein R denotes an alkyl group having 1 to 4 carbon atoms and the total quantity of carboxylate groups and ethylene oxide units present in lateral or terminal chains is calculated to ensure the solubility or dispersibility of the polyurethanes in water.The present invention also relates to a process for the preparation of these polyurethanes and to their use for coating substrates.
摘要翻译：本发明涉及水分散性或可溶性聚氨酯，其含有基于聚氨酯重量的约0.5至30重量％存在于侧链或末端聚醚链中的环氧乙烷单元，其特征在于除了这些环氧乙烷单元作为进一步的亲水中心，聚氨酯含有相对于通式为“IMAGE”的内置结构单元形式的羧酸酯基团的每100克固体含量约0.1至120毫当量，其中R表示具有1个至4个碳原子，并计算存在于侧链或末端链中的羧酸酯基和环氧乙烷单元的总量，以确保聚氨酯在水中的溶解度或分散性。本发明还涉及制备这些聚氨酯的方法及其用于涂布基材的方法。

5. 发明授权

US4728542A Ionically modified pur spreading pastes and their use 失效
标题翻译：离子改性的涂布膏及其用途
公开(公告)号：US4728542A
公开(公告)日：1988-03-01
申请号：US874326
申请日：1986-06-13
申请人： Klaus Nachtkamp , Wilhelm Thoma , Josef Pedain , Walter Schroer , Rolf Langel , Klaus Noll
发明人： Klaus Nachtkamp , Wilhelm Thoma , Josef Pedain , Walter Schroer , Rolf Langel , Klaus Noll
IPC分类号： C08G18/08 , C08G18/40 , C08G18/61 , C09D5/00 , C09D175/00 , C09D175/04 , C14C11/00 , D06M13/02 , D06M13/07 , D06M13/224 , D06M15/564 , D06N3/14 , B05D3/02 , C08F8/30 , C08F283/04
CPC分类号： D06N3/14 , C08G18/0804 , C08G18/4009 , C08G18/61 , C09D175/04 , C14C11/006
摘要： The present invention is directed to the preparation of optionally pigmented spreading paste based on multiphase mixtures of ionically-modified polyurethanes and/or polyurethane ureas which are prepared from special synthesis components based on silicone resins, aromatic hydroxypolyethers, aromatichydroxy polyesters, and perfluorocarbon resins, the multiphase mixtures additionally containing water and organic solvents for the polyurethanes and/or polyurethane ureas. The present invention is also directed to the preparation of these optionally pigmented spreading pastes and to their use for the production of coatings permeable to water vapor on fabric or leather substrates by the direct or transfer method using the technique of evaporation.
摘要翻译：本发明涉及基于由基于有机硅树脂，芳族羟基聚醚，芳基三羟基聚酯和全氟化碳树脂的特殊合成成分制备的基于离子改性聚氨酯和/或聚氨酯脲的多相混合物的任意着色的铺展浆料的制备，多相混合物另外含有聚氨酯和/或聚氨酯脲的水和有机溶剂。本发明还涉及这些任选着色的铺展糊剂的制备及其用于通过使用蒸发技术的直接或转移方法生产可渗透织物或皮革基底上的水蒸汽的涂层。

6. 发明授权

US4716169A Imidazo[1,2a]pyridines and their use as cardiotonic agents 失效
标题翻译：咪唑并[1,2a]吡啶并用作强心剂
公开(公告)号：US4716169A
公开(公告)日：1987-12-29
申请号：US810008
申请日：1985-12-17
申请人： Joachim Heider , Norbert Hauel , Volkhard Austel , Klaus Noll , Andreas Bomhard , Jacques van Meel , Willi Diederen
发明人： Joachim Heider , Norbert Hauel , Volkhard Austel , Klaus Noll , Andreas Bomhard , Jacques van Meel , Willi Diederen
IPC分类号： A61K31/435 , A61K31/495 , A61P7/02 , A61P9/04 , C07D471/04 , C07D487/04 , A61K31/41
CPC分类号： C07D471/04 , C07D487/04
摘要： The invention relates to new imidazo derivatives of the formula ##STR1## wherein "A-D and R.sup.1 -R.sup.3 are as defined in the specification". The new compounds have valuable pharmacological properties, particularly antithrombotic and cardiovascular properties such as a cardiotonic activity and/or an effect on blood pressure, and can be prepared using methods known per se.
摘要翻译：本发明涉及式（I）的新的咪唑衍生物，其中“A-D和R 1 -R 3如说明书中所定义”。新化合物具有有价值的药理学性质，特别是抗血栓形成和心血管性质，例如强心剂活性和/或对血压的作用，并且可以使用本身已知的方法制备。

7. 发明授权

US4244967A Antiphlogistic pharmaceutical compositions containing a phenylethanolamine and methods of use 失效
标题翻译：含有苯乙醇胺的消炎药物组合物及其使用方法
公开(公告)号：US4244967A
公开(公告)日：1981-01-13
申请号：US72553
申请日：1979-09-04
申请人： Gunther Engelhardt , Johannes Keck , Gerd Kruger , Klaus Noll , Helmut Pieper , Rainer Zimmermann
发明人： Gunther Engelhardt , Johannes Keck , Gerd Kruger , Klaus Noll , Helmut Pieper , Rainer Zimmermann
IPC分类号： A61K31/135 , A61K31/17 , A61K31/275 , A61K31/325 , A61P29/00 , A61P43/00 , A61K31/27
CPC分类号： A61K31/135 , A61K31/17 , A61K31/275 , A61K31/325
摘要： The method of using compounds of the formula ##STR1## wherein R.sub.1 is hydrogen, fluorine, chlorine, bromine, iodine or cyano,R.sub.2 is fluorine, cyano, trifluoromethyl, nitro or alkyl of 1 to 4 carbon atoms,R.sub.3 is cycloalkyl or alkyl, each of 3 to 5 carbon atoms, andR.sub.4 is hydrogen or --CO--R.sub.5, whereR.sub.5 is alkoxy of 1 to 5 carbon atoms, alkenyloxy of 2 to 5 carbon atoms, aryloxy of 6 to 10 carbon atoms, aralkoxy of 7 to 11 carbon atoms, or amino which may be mono- or di-substituted by alkyl of 1 to 5 carbon atoms, alkenyl of 2 to 5 carbon atoms, aryl of 6 to 10 carbon atoms and/or aralkyl of 7 to 11 carbon atoms,and non-toxic, pharmacologically acceptable acid addition salts thereof as antirheumatics and antiphlogistics.
摘要翻译：使用下式化合物的方法其中R1是氢，氟，氯，溴，碘或氰基，R2是氟，氰基，三氟甲基，硝基或1-4个碳原子的烷基，R3是环烷基或烷基， 3〜5个碳原子，R4为氢或-CO-R5，R5为1〜5个碳原子的烷氧基，2〜5个碳原子的烯氧基，6〜10个碳原子的芳氧基，7〜11个芳氧基碳原子或可以被1至5个碳原子的烷基，2至5个碳原子的烯基，6至10个碳原子的芳基和/或7至11个碳原子的芳烷基单取代或二取代的氨基，以及无毒，药理学上可接受的酸加成盐作为抗风湿剂和消炎药。

8. 发明授权

US4238378A Cationic electrolyte-stable dispersions and process for producing polyurethanes useful therein 失效
标题翻译：阳离子电解质稳定的分散体和用于生产其中有用的聚氨酯的方法
公开(公告)号：US4238378A
公开(公告)日：1980-12-09
申请号：US849689
申请日：1977-11-08
申请人： Peter Markusch , Klaus Noll , Dieter Dieterich
发明人： Peter Markusch , Klaus Noll , Dieter Dieterich
IPC分类号： C08G18/00 , C08G18/08 , C08G18/50 , C08G18/78 , C08L75/04 , C08G18/12 , C08G18/32 , C08L75/08 , C08L75/12
CPC分类号： C08G18/0809 , C08G18/5042 , C08G18/7818
摘要： The instant invention is directed to novel polyurethane cationic electrolyte-stable dispersions characterized by lateral or terminal polyalkylene oxide polyether chains containing from 2 to 10%, by weight, of ethylene oxide units, based on the total weight of the polyurethane; a content of ##STR1## groups of from 16 to 100 milliequivalents per 100 g of polyurethane; an average particle size of from 50 to 300 m.mu.; and a solids content of from 10 to 45%.
摘要翻译：本发明涉及新颖的聚氨酯阳离子电解质稳定的分散体，其特征在于以聚氨酯的总重量计含有2-10重量％的环氧乙烷单元的侧面或末端聚环氧烷聚醚链; 每100克聚氨酯的含量为16至100毫当量的组合物; 平均粒径为50〜300μm; 固体含量为10至45％。

9. 再颁专利

USRE29623E Polyurethane-ureas based on cis-trans-1,4-diaminocyclohexane 失效
标题翻译：基于顺式 - 反式-1,4-二氨基环己烷的聚氨酯 - 脲
公开(公告)号：USRE29623E
公开(公告)日：1978-05-02
申请号：US720183
申请日：1976-09-03
申请人： Harald Oertel , Bruno Zorn , Wilhelm Thoma , Klaus Noll
发明人： Harald Oertel , Bruno Zorn , Wilhelm Thoma , Klaus Noll
IPC分类号： C08G18/08 , C08G18/10 , C08G18/73 , C08G18/75 , C14C11/00 , D06M15/564 , D06N3/14
CPC分类号： D06N3/14 , C08G18/0852 , C08G18/10 , C08G18/73 , C08G18/75 , C14C11/006 , D06M15/564
摘要： Light stable polyurethane coatings with a considerably increased softening range and melting points coupled with improved resistance to perchlorethylene is obtained by using a chain extender comprising at least 80 mol % 1,4-diamino cyclohexane with a cis/transisomer ratio of from 10/90 to 60/40 .Iadd.and by using aliphatic or cycloaliphatic diisocyanates wherein such diisocyanates consist of at least 75 mol percent of 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethyl cyclohexane.Iaddend..

10. 发明授权

US5175157A Cyclic amine derivatives, pharmaceutical compositions containing these compounds and methods for preparing them 失效
标题翻译：环胺衍生物，含有这些化合物的药物组合物及其制备方法
公开(公告)号：US5175157A
公开(公告)日：1992-12-29
申请号：US725855
申请日：1991-07-03
申请人： Manfred Psiorz , Joachim Heider , Andreas Bomhard , Manfred Reiffen , Norbert Hauel , Klaus Noll , Berthold Narr , Christian Lillie , Walter Kobinger , Jurgen Dammgen
发明人： Manfred Psiorz , Joachim Heider , Andreas Bomhard , Manfred Reiffen , Norbert Hauel , Klaus Noll , Berthold Narr , Christian Lillie , Walter Kobinger , Jurgen Dammgen
IPC分类号： C07D223/16 , C07D401/06 , C07D401/14 , C07D403/06 , C07D403/14 , C07D405/14 , C07D409/14 , C07D491/04
CPC分类号： C07D223/16 , C07D401/06 , C07D401/14 , C07D403/06 , C07D403/14 , C07D405/14 , C07D409/14 , C07D491/04
摘要： Disclosed are new cyclic amine derivatives of the formula I ##STR1## wherein the substituents are defined in the specification. These compounds are useful as for treating sinus tachycardia.
摘要翻译：公开了式I（I）的新的环胺衍生物，其中取代基在说明书中定义。这些化合物可用于治疗窦性心动过速。

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