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1. 发明授权

US4419524A Process for the preparation of dihalovinylcyclopropanecarboxylic acids 失效
标题翻译：二卤乙烯基环丙烷羧酸的制备方法
公开(公告)号：US4419524A
公开(公告)日：1983-12-06
申请号：US350424
申请日：1982-02-19
申请人： Ferenc Lindwurm , Jozsef Muskovits , Sandor Zoltan , Rezso Kolta , Rudolf Soos , Tivadar Puskas , Eva Somfai , Gyorgy Hidasi
发明人： Ferenc Lindwurm , Jozsef Muskovits , Sandor Zoltan , Rezso Kolta , Rudolf Soos , Tivadar Puskas , Eva Somfai , Gyorgy Hidasi
IPC分类号： C07C61/40 , B01J31/02 , C07B61/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00 , C07C69/743
CPC分类号： C07C51/09
摘要： The invention relates to a new process for the preparation of cyclopropanecarboxylic acids of the formula (I) ##STR1## wherein X and Y independently stand for halogen, by the alkaline hydrolysis of the corresponding alkyl esters having 1 to 6 carbon atoms in the alkyl moiety, in or without a water-miscible organic solvent, in the presence of a phase transfer catalyst. The hydrolysis is carried out with a 2 to 50% by weight aqueous alkali hydroxide solution. If desired, under suitable conditions the cis/trans ratio of the original ester can be altered in the end products. The cyclopropanecarboxylic acids of the formula (I) are obtained in a high purity and are useful intermediates of insecticidally active pyrethroids.
摘要翻译：本发明涉及一种制备式（I）的环丙烷羧酸的新方法，其中X和Y独立地代表卤素，通过碱性水解相应的具有1-6个碳原子的烷基酯在烷基部分，在或不与水混溶的有机溶剂中，在相转移催化剂的存在下。水解用2至50重量％的碱金属氢氧化物水溶液进行。如果需要，在合适的条件下，可以在最终产物中改变原始酯的顺式/反式比。式（I）的环丙烷羧酸以高纯度获得，是杀虫活性拟除虫菊酯的有用中间体。

2. 发明授权

US5013754A Insecticidal composition comprising more than one active ingredient 失效
标题翻译：包含多于一种活性成分的杀虫组合物
公开(公告)号：US5013754A
公开(公告)日：1991-05-07
申请号：US367546
申请日：1989-06-16
申请人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
发明人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
IPC分类号： C07C69/747 , A01N20060101 , A01N37/34 , A01N53/00 , A01N53/08 , A01P7/04 , C07B20060101 , C07B57/00 , C07B61/00 , C07B63/04 , C07C20060101 , C07C67/52 , C07C69/743 , C07C253/30 , C07C253/34 , C07C255/00 , C07C255/37 , C07C255/39
CPC分类号： A01N53/00
摘要： According to the present invention there is provided a synergistic insecticidal composition containing more than one active ingredients and being harmless to environment characterized by comprising in an amount of from 0.001 to 99% by weight a synthetic pyrethroid of the Formula /I/ ##STR1## namely substantially only the 1RtransS and 1StransR entantiomer-pair /Ib/ out from the possible eight isomers--optionally in admixture with an amount of up to 100% by weight of one or more activator/s/ and auxiliary agent/s/, particularly antioxidants, stabilizing agents, wetting agents, emulsifying agents, dispersing agents, antifoam agents, diluents and/or fillers.The enantiomer-pair Ib consisting of the 1RtransS and 1StransR isomers is new and the invention also relates to the said new enantiomer-pair and a process for the preparation thereof.The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.

3. 发明授权

US5110976A Insecticidal composition comprising more than one active ingredient 失效
标题翻译：包含超过一个活性成分的杀虫剂组合物
公开(公告)号：US5110976A
公开(公告)日：1992-05-05
申请号：US696580
申请日：1991-05-07
申请人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
发明人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
IPC分类号： C07C69/747 , A01N20060101 , A01N37/34 , A01N53/00 , A01N53/08 , A01P7/04 , C07B20060101 , C07B57/00 , C07B61/00 , C07B63/04 , C07C20060101 , C07C67/52 , C07C69/743 , C07C253/30 , C07C253/34 , C07C255/00 , C07C255/37 , C07C255/39
CPC分类号： A01N53/00
摘要： A process is disclosed for preparing a synergistic, crystalline product consisting of solely enantiomer pair 1RCisS and 1SCisR and enantiomer pair 1RTransS and 1STransR of cypermethrin in a 3:7 to 5:5 crystalline mixture, which comprises the steps of: (a) epimerizing an oily melt or a saturated solution of enantiomer pair 1RCisS and 1SCisR and enantiomer pair 1RTransS and 1STransR in a ratio other than 3:7 to 5:5, or a mixture of enantiomer pair 1RCisS and 1SCisR, enantiomer pair 1RTransS and 1STransR together with enantiomer pair 1RCisR and 1SCisS and enantiomer pair 1RTransR and 1STransS, said saturated solution including a protic or apolar, aprotic inert organic solvent by treating said oily melt or saturated solution with an organic or inorganic base at a temperature of -15.degree. C. to 30.degree. C. to precipitate crystals consisting solely of the 1RCisS and 1SCisR and the 1RTransS and 1RTransR enantiomer pairs in a 3:7 to 5:5 weight ratio; (b) isolating the precipitated crystals consisting solely of the enantiomer pairs 1RCisS and 1SCisR and 1RTransS and 1STransR at -10.degree. to 30.degree. C., optionally after inoculating the reaction mixture with a seeding crystal consisting of a mixture of the enantiomer pairs 1RCisS and 1SCisR and 1RTransS and 1STransR at a weight ratio of 3:7 to 5:5 before crystallization; and (c) repeating any of the above steps, if necessary.

4. 发明授权

US4845126A Insecticidal composition comprising more than one active ingredient 失效
标题翻译：包含多于一种活性成分的杀虫组合物
公开(公告)号：US4845126A
公开(公告)日：1989-07-04
申请号：US916546
申请日：1986-09-16
申请人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
发明人： Gyorgy Hidasi , Istvan Szekely , Bela Bertok , Sandor Zoltan , Lajos Nagy , Antal Gajari , Eva Somfai , Agnes Hegedus , Laszlo Pap , Rudolf Soos , Erzsebet Radvany , Sandor Botar , Tamas Szabolcsi
IPC分类号： C07C69/747 , A01N20060101 , A01N37/34 , A01N53/00 , A01N53/08 , A01P7/04 , C07B20060101 , C07B57/00 , C07B61/00 , C07B63/04 , C07C20060101 , C07C67/52 , C07C69/743 , C07C253/30 , C07C253/34 , C07C255/00 , C07C255/37 , C07C255/39
CPC分类号： A01N53/00
摘要： According to the present invention there is provided a synergistic insecticidal composition containing more than one active ingredients and being harmless to environment characterized by comprising in an amount of from 0.001 to 99% by weight a synthetic pyrethroid of the Formula /I/ ##STR1## namely substantially only the 1RtransS and 1StransR entantiomer-pair /Ib/ out from the possible eight isomers--optionally in admixture with an amount of up to 100% by weight of one or more activator/s/ and auxiliary agent/s/, particularly antioxidants, stabilizing agents, wetting agents, emulsifying agents, dispersing agents, antifoam agents, dileunts and/or fillers.The enantiomer-pair Ib consisting of the 1RtransS and 1StransR isomers is new and the invention also relates to the said new enantiomer-pair and a process for the preparation thereof.The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.
摘要翻译： PCT No.PCT / HU86 / 00004 Sec。 371日期1986年10月15日第 102（e）1986年10月15日日期PCT提交1986年1月16日PCT公布。第WO86 / 04216号公报日本1986年7月31日。根据本发明，提供了含有多于一种活性成分并且对环境无害的协同杀虫组合物，其特征在于包含0.001至99重量％的式（I）的合成拟除虫菊酯（I）即基本上只有可能的八个异构体中的1RtransS和1StransR对映异构体对/ Ib /出，任选地与至多100重量％的一种或多种活化剂/ 和助剂，特别是抗氧化剂，稳定剂，润湿剂，乳化剂，分散剂，消泡剂，二酸酐和/或填料。由1RtransS和1StransR异构体组成的对映体对1b是新的，本发明还涉及所述新的对映异构体对及其制备方法。本发明的杀虫组合物的优点在于它对温血动物和有用寄生虫的毒性较小，因此对环境的危害小得多。

5. 发明授权

US4521612A Process for the separation of esters 失效
标题翻译：分离酯的方法
公开(公告)号：US4521612A
公开(公告)日：1985-06-04
申请号：US659320
申请日：1984-10-10
申请人： Rudolf Soos , Rezso Kolta , Sandor Zoltan , Maria Tary
发明人： Rudolf Soos , Rezso Kolta , Sandor Zoltan , Maria Tary
IPC分类号： C07C69/743 , C07C67/60 , C07C68/08 , C07C69/003 , C07C69/747
CPC分类号： C07C67/60 , C07C2101/02
摘要： The present invention relates to a process for the selective separation of esters of the general formula IIA--COOR.sup.1 IIfrom mixtures containing the cyclopropane carboxylic acid esters of the general formula I ##STR1## in addition to the said esters of the general formula II by reacting the said mixture with an amine of the general formula III ##STR2## when removing the acid amides formed from the esters of the general formula II by washing the mixture with water of removing the esters of the general formula I by distillation.The compounds of the general formula I are the intermediates of herbicides. The requested purity of the herbicides can be achieved if pure intermediates are used.
摘要翻译：本发明涉及通式IIA-COOR1II的酯与含有通式ⅠI的环丙烷羧酸酯的混合物的选择性分离方法，除了所述通式II的酯当通过用除去通式I的酯的蒸馏物除去混合物，除去由通式II的酯形成的酸酰胺时，使所述混合物与通式III的胺III反应。通式I的化合物是除草剂的中间体。如果使用纯中间体，可以实现除草剂所要求的纯度。

6. 发明授权

US4843174A Process for separating pyethroid geometric isomers 失效
标题翻译：分离葡萄糖几何异构体的方法
公开(公告)号：US4843174A
公开(公告)日：1989-06-27
申请号：US902460
申请日：1986-09-26
申请人： Gyula Balogh , Iren Boros neee Gundar , Antal Gajary , Gyorgy Hidasi , Andras Rappi , Jozsef Rakoczi , Rudolf Soos , Istvan Szekely , Sandor Zoltan
发明人： Gyula Balogh , Iren Boros neee Gundar , Antal Gajary , Gyorgy Hidasi , Andras Rappi , Jozsef Rakoczi , Rudolf Soos , Istvan Szekely , Sandor Zoltan
IPC分类号： C07C61/37 , C07C51/487
CPC分类号： C07C51/487
摘要： The invention relates to the separation of the geometrical isomers of cyclopropane carboxylic acids of formula (I) ##STR1## wherein R represents alkyl having 1 to 4 carbon atoms or halogen.
摘要翻译： PCT No.PCT / HU85 / 00072 Sec。 371日期1986年9月26日第 102（e）1986年9月26日PCT PCT日期为1985年12月6日PCT公布。第WO86 / 03487号公报日本1986年6月19日。本发明涉及式（I）的环丙烷羧酸（I）的几何异构体的分离，其中R表示具有1至4个碳原子的烷基或卤素。

7. 发明授权

US4508919A Process for the preparation of optically active cyclopropane carboxylic acids 失效
标题翻译：光学活性环丙烷羧酸的制备方法
公开(公告)号：US4508919A
公开(公告)日：1985-04-02
申请号：US555187
申请日：1983-11-25
申请人： Elemer Fogassy , Laszlo Toke , Ferenc Faigl , Rudolf Soos , Jozsef Bozzay , Rezso Kolta , Jozsef Nemes , Peter Bencsik
发明人： Elemer Fogassy , Laszlo Toke , Ferenc Faigl , Rudolf Soos , Jozsef Bozzay , Rezso Kolta , Jozsef Nemes , Peter Bencsik
IPC分类号： C07C61/37 , C07B31/00 , C07B57/00 , C07C51/00 , C07C51/487 , C07C61/40 , C07C67/00 , C07B19/00
CPC分类号： C07C51/487
摘要： The invention relates to a process for the preparation of enantiomers of trans vinyl-cyclopropane carboxylic acids of the formula I, ##STR1## wherein R is a methyl group or chlorine atom, by resolution of racemic trans compound or mixture of racemic cis and trans compounds by using (+)- or (-)-N-(1-formamido-2,2,2-trichloroethyl)-piperazine as a resolving agent in a polar solvent then separating the crystallizing salt of (+)-trans carboxylic acid and (-)-resolving agent or (-)-trans carboxylic acid and (+)-resolving agent from the mother liquor by filtration and obtaining the enantiomers by acidifying the mother liquor or the salts suspended in water followed by extraction with a solvent and evaporation.The products so obtained may be used as starting materials for the preparation of insecticides.
摘要翻译：本发明涉及通过拆分外消旋反式化合物或外消旋的顺式和反式化合物的混合物制备式I的反式乙烯基 - 环丙烷羧酸的对映异构体的方法，其中R是甲基或氯原子通过在极性溶剂中使用（+） - 或（ - ） - N-（1-甲酰胺基-2,2,2-三氯乙基） - 哌嗪作为拆分剂，然后将（+） - 反式羧酸的结晶盐和（ - ） - 拆分剂或（ - ） - 反式羧酸和（+） - 拆分剂通过过滤从母液中获得对映异构体，通过酸化母液或悬浮在水中的盐，然后用溶剂萃取并蒸发。所得产物可用作制备杀虫剂的起始原料。

8. 发明授权

US4999454A Process for the preparation of trichloromethyl carbinols 失效
标题翻译：制备三氯甲基甲醇的方法
公开(公告)号：US4999454A
公开(公告)日：1991-03-12
申请号：US784692
申请日：1985-10-03
申请人： Rudolf Soos , Jozsef Nemes , Miklos Szelestei , Istvan Schler , Laszlo Vidra , Istvan Szekely
发明人： Rudolf Soos , Jozsef Nemes , Miklos Szelestei , Istvan Schler , Laszlo Vidra , Istvan Szekely
IPC分类号： C07C69/007 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/38 , C07C33/40 , C07C33/42 , C07C33/44 , C07C67/00 , C07C69/145
CPC分类号： C07C29/38 , C07C33/423 , C07C67/00 , C07C2101/16
摘要： The invention is directed to a new process for the preparation of carbinols of the general formula I ##STR1## by reaction chloral and olefins of the general formula ##STR2## and by optional acylation of the product comprising dissolving a catalyst of the general formula IIIFe.sub.n (NH.sub.4).sub.x Y.sub.m .multidot.A.sub.p IIIin chloral, then adding the olefin of the general formula II in order to produce a complex of the general formula IV ##STR3## from which a complex of the general formula V ##STR4## is formed, and from the reaction mixture a compound of the general formula I is obtained whereafter(a) the residual complex of the general formula V dissolved in the product is decomposed with an acidic solution and if desired the obtained product is distilled or(b) the product in the reaction mixture is acylated.The compounds prepared according to the invention can be utilized as intermediates when preparing e.g., permethrin and other pyrethroid insecticides.
摘要翻译：本发明涉及一种通过反应式I和通式II的烯烃制备通式I的甲醇的新方法，并通过产物的任意酰化，包括将通式 III Fen（NH4）xYmxAp III，然后加入通式II的烯烃以产生通式IV的复合物IV，其中形成通式V的复合物V，并且从反应混合物中获得通式I的化合物，之后（a）溶解在产物中的通式V的残余络合物用酸性溶液分解，如果需要，所得产物被蒸馏，或（b）产物在反应混合物中进行酰化。当制备例如氯菊酯和其他拟除虫菊酯杀虫剂时，根据本发明制备的化合物可以用作中间体。

9. 发明授权

US4599444A Process for the separation of isomeric cyclopropane-carboxylic acids 失效
标题翻译：异构环丙烷羧酸分离方法
公开(公告)号：US4599444A
公开(公告)日：1986-07-08
申请号：US581081
申请日：1984-02-17
申请人： Elemer Foggassy , Ferenc Faigl , Rudolf Soos , Jozsef Rakoczi
发明人： Elemer Foggassy , Ferenc Faigl , Rudolf Soos , Jozsef Rakoczi
IPC分类号： C07C61/37 , C07B31/00 , C07B53/00 , C07B57/00 , C07C51/00 , C07C51/487 , C07C61/40 , C07C67/00
CPC分类号： C07C51/487
摘要： The invention relates to a new process for separating the four stereoisomers of the cyclopropanecarboxylic acids of the formula ##STR1## wherein R stands for a methyl group or a halogen atom.The process comprisesreacting a salt formed with an alkali hydroxide or an alkali carbonate of dl-cis-trans-2,2-dimethyl-3-(2,2-disubstituted vinyl)-cyclopropanecarboxylic acids containing the isomers in any ratio or the pure dl-cis and dl-trans-2,2-dimethyl-3-(2,2-disubstituted vinyl)-cyclopropanecarboxylic acids prepared therefrom by the means of a selective dissolution with aromatic and aliphatic hydrocarbon solvents (suitably with benzene, extraction petroleum ether, n-hexane) with N-benzyl-2-aminobutanol enantiomers or with the hydrochlorides thereof in an aqueous medium or aqueous acetone medium, obtaining the crystalline diastereomeric salt from the solution by filtration, decomposing said salt by using a mineral acid, then separating the thus obtained optically active cyclopropanecarboxylic acidand obtaining the other isomer or other mixture of isomers from the filtrate of the said diastereomeric salt similarly after acidifying by a mineral acid, if desired, purifying the said optically active 2,2-di-methyl-3-(2,2-disubstituted vinyl)-cyclopropane-carboxylic acid isomers obtained by the above-mentioned procedure by a selective precipitation and recovering the resolving agent.
摘要翻译：本发明涉及用于分离式（I）的环丙烷羧酸的四种立体异构体的新方法，其中R代表甲基或卤素原子。该方法包括使含有任何比例的异构体的dl-顺 - 反-2,2-二甲基-3-（2,2-二取代的乙烯基） - 环丙烷羧酸的碱金属氢氧化物或碱金属碳酸盐形成的盐或纯的 dl-顺式和dl-反式-2,2-二甲基-3-（2,2-二取代的乙烯基） - 环丙烷羧酸，其通过选择性溶解与芳族和脂族烃溶剂（适合于苯，萃取石油醚正己烷）与N-苄基-2-氨基丁醇对映体或其盐酸盐在水性介质或丙酮水溶液中反应，通过过滤从溶液中获得结晶非对映体盐，通过使用无机酸分解所述盐，然后分离由此获得的光学活性环丙烷羧酸，并从所述非对映异构体盐的滤液中得到其它异构体或其它异构体混合物，同样地在无机酸酸化后，如果需要，通过选择性沉淀获得的通过上述方法获得的光学活性的2,2-二甲基-3-（2,2-二取代的乙烯基） - 环丙烷 - 羧酸异构体并回收拆分剂。

10. 发明授权

US4450309A Process for the preparation of unsaturated geminal dihalogen compounds 失效
标题翻译：制备不饱和偕二卤化合物的方法
公开(公告)号：US4450309A
公开(公告)日：1984-05-22
申请号：US391866
申请日：1982-06-24
申请人： Rudolf Soos , Jozsef Nemes , Laszlo Vidra , Miklos Szelestei , Gabor Kovacs , Istvan Szekeley
发明人： Rudolf Soos , Jozsef Nemes , Laszlo Vidra , Miklos Szelestei , Gabor Kovacs , Istvan Szekeley
IPC分类号： C07C17/361 , B01J21/00 , B01J23/00 , B01J23/06 , B01J27/00 , C07B61/00 , C07C17/00 , C07C17/363 , C07C21/02 , C07C21/04 , C07C21/17 , C07C21/19 , C07C67/00 , C07C17/33
CPC分类号： C07C17/363
摘要： The invention relates to a new process for preparing unsaturated geminal dihalogen compounds. More particularly, the invention concerns a process for preparing compounds of the formula (I) ##STR1## wherein X is halogen,R.sup.1 is a straight or branched chained alkenyl group having 2 to 6 carbon atoms,by clearing the corresponding 1-substituted 2,2,2-trihaloethylesters.
摘要翻译：本发明涉及一种制备不饱和偕二卤化合物的新方法。更具体地，本发明涉及制备式（I）化合物的方法，其中X是卤素，R 1是具有2-6个碳原子的直链或支链链烯基，通过将相应的1-取代的2， 2,2-三卤乙基酯。

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