会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 5. 发明申请
    • MULTIPLY SUBSTITUTED FERROCENES
    • 多取代二茂铁
    • WO2006114438A2
    • 2006-11-02
    • PCT/EP2006061861
    • 2006-04-27
    • SOLVIAS AGPUGIN BENOITFENG XIANGDONG
    • PUGIN BENOITFENG XIANGDONG
    • C07F17/02
    • C07F17/02
    • Disclosed are compounds of formulas (I) and (II) in the form of enantiomer-pure diastereomers o diastereomer mixtures. In said formulas (I) and (II), R' 1 represents C 1 -C 4 alkyl while n represents 0 or an integer from 1 to 5; R 1 represents a hydrogen atom, a hydrocarbon radical with 1 to 20 C atoms, secondary phosphino, a mercaptan radical with 1 to 20 C atoms in the hydrocarbon radical, or a silyl radical with 3 C 1 -C 12 hydrocarbon radicals; R 2 is the monovalent radical of an electrophilic organic compound; X 1 represents F, Cl, Br, or I; and Y represents vinyl, methyl, ethyl, -CH 2 -N(C 1 -C 4 -alkyl) 2 , -CH 2 -OR wherein R is a hydrocarbon radical, or a C-bonded, S-bonded, or P-bonded chiral group that directs metals of metallization reagents into the ortho position X 1 . The inventive compounds are coordinating ligands for metal complexes of transition metals as homogeneous catalysts for coupling reactions and intermediate products for producing bidentate ligands.
    • 式(I)和(II)化合物对映体纯非对映体的形式或者非对映体,其中R“ 1 C 1 -C 4 烷基,n是0或代表1〜5的整数; [R 1 代表氢原子,具有1至20个碳原子,仲膦基,具有在烃1至20个碳原子的硫醇,或具有图3C 1 甲硅烷基的烃基 -C 12 表示烃基; [R 2 是一价基团的亲电有机化合物的; X 1 是F,Cl,Br或I; 和Y是乙烯基,甲基,乙基,-CH 2 N(C 1 -C 4 烷基) 2 ,-CH 2 -OR,其中R是烃基,或C,S或在邻位金属化X的P-结合金属 1 引导手性基团 表示koordinerende是过渡金属作为用于偶联反应和中间体双齿配体的制备均相催化剂的金属配合物的配体。