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1. 发明授权

US4316932A Combating fungi with .alpha.-azolyl-keto derivatives 失效
标题翻译：抗真菌与α-唑基 - 酮衍生物
公开(公告)号：US4316932A
公开(公告)日：1982-02-23
申请号：US54067
申请日：1979-07-02
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/82
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxy-carbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.2 each independently represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or a physiologically acceptable acid addition salt or metal salt complex thereof, which possesses fungicidal properties.
摘要翻译：其中R 1表示任意取代的烷基或任意取代的苯基，R 2代表基团-CX 1 X 2 R 3或烷氧基 - 羰基，R 3表示卤素，卤代烷基或任意取代的苯基，R 4代表基团 -O-CO-R 5，-O（S）-R 6或-OS（O）n -R 7或烷基氨基，二烷基氨基，任选取代的苯基氨基或卤素，R 5表示烷基，卤代烷基，烯基，炔基，环烷基，任选取代的苯基，任选取代的苯基烷基，烷基氨基，二烷基氨基或任选取代的苯基氨基，R 6表示烷基，烯基，炔基，环烷基，任选取代的苯基或任选取代的苄基，R 7表示烷基，卤代烷基，任选取代的苯基或二烷基氨基，n表示1或2，和X2各自独立地表示氢或卤素，Y表示氮原子或CH基团，或生理上可接受的酸加成盐或金属盐c 其复合物具有杀真菌性能。

2. 发明授权

US4386088A Combating fungi with .alpha.-azolyl-keto derivatives 失效
标题翻译：抗真菌与α-唑基 - 酮衍生物
公开(公告)号：US4386088A
公开(公告)日：1983-05-31
申请号：US304128
申请日：1981-09-21
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/82
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.2 each independently represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or a physiologically acceptable acid addition salt or metal salt complex thereof, which possesses fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示分组-C X 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，R 4表示基团-O -CO-R 5，-O（S）-R 6或-OS（O）n -R 7或烷基氨基，二烷基氨基，任选取代的苯基氨基或卤素，R 5表示烷基，卤代烷基，烯基，炔基，环烷基，任选取代的苯基，取代的苯基烷基，烷基氨基，二烷基氨基或任选取代的苯基氨基，R 6表示烷基，烯基，炔基，环烷基，任选取代的苯基或任选取代的苄基，R 7表示烷基，卤代烷基，任选取代的苯基或二烷基氨基，n表示1或2，各自独立地表示氢或卤素，Y表示氮原子或CH基团，或生理上可接受的酸加成盐或金属盐共其复合物具有杀真菌性能。

3. 发明授权

US4291047A Combating fungi with .alpha.-azolyl-.beta.-hydroxy-ketones 失效
标题翻译：抗真菌与α-唑基-β-羟基酮
公开(公告)号：US4291047A
公开(公告)日：1981-09-22
申请号：US54061
申请日：1979-07-02
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： .alpha.-Azolyl-.beta.-hydroxy-ketones of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,X.sup.1 and X.sup.2, which may be identical or different, each represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or physiologically acceptable acid-addition salts or metal-salt complexes thereof which possess fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示基团-CX 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，X 1和X 2，其可以相同或不同，各自表示氢或卤素，Y表示具有杀真菌性质的氮原子或CH基团或其生理上可接受的酸加成盐或其金属盐络合物。

4. 发明授权

US4530715A Cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones as fungicides and plant growth regulators 失效
标题翻译：环烷基（α-三唑基-β-羟基） - 酮作为杀真菌剂和植物生长调节剂
公开(公告)号：US4530715A
公开(公告)日：1985-07-23
申请号：US438448
申请日：1982-11-02
申请人： Eckart Kranz , Karl H. Buchel , Udo Kraatz , Erik Regel , Wilhelm Brandes , Paul-Ernst Frohberger , Klaus Lurssen
发明人： Eckart Kranz , Karl H. Buchel , Udo Kraatz , Erik Regel , Wilhelm Brandes , Paul-Ernst Frohberger , Klaus Lurssen
IPC分类号： A01N43/653 , C07C45/63 , C07D249/08 , C07D521/00 , A01N43/64 , A01N55/02 , C07F3/00
CPC分类号： C07D231/12 , A01N43/653 , C07C45/63 , C07D233/56 , C07D249/08
摘要： Cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones of the general formula ##STR1## in which R.sup.1 represents an optionally substituted cycloalkyl group, andR.sup.2 represents a halogenoalkyl, halogenoalkenyl or alkoxycarbonyl group,and their physiologically acceptable acid addition salts and metal salt complexes are new, are prepared as described and find use as fungicides and plant growth regulators.
摘要翻译：其中R 1表示任选取代的环烷基，R 2表示卤代烷基，卤代烯基或烷氧基羰基，以及它们的生理上可接受的酸加成盐（Ⅰ）所示的环烷基（α-三唑基-β-羟基） - 酮和金属盐络合物是新的，按照描述制备并用作杀真菌剂和植物生长调节剂。

5. 发明授权

US5081265A Microbicidal substituted dioxolanes 失效
标题翻译：微生物取代的二氧化物
公开(公告)号：US5081265A
公开(公告)日：1992-01-14
申请号：US582581
申请日：1990-09-14
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylsulphinyl, optionally substituted arylsulphonyl, optionally substituted arylalkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted arylsulphinylalkyl, optionally substituted arylsulphonylalkyl, optionally substituted aralkyloxyalkyl, optionally substituted aralkylthioalkyl, optionally substituted aralkylsulphinylalkyl or optionally substituted aralkylsulphonylalkyl,R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##

6. 发明授权

US4988715A Microbicidal substituted dioxolanes 失效
标题翻译：杀菌剂取代二氧戊环
公开(公告)号：US4988715A
公开(公告)日：1991-01-29
申请号：US389032
申请日：1989-08-03
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, or other radicalsR.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##
摘要翻译：其中R 1表示任选取代的烷基或其它基团R 2，R 3，R 4，R 5和R 6彼此独立地表示的式（I）的杀真菌二氧戊环代表氢，烷基或环烷基，或者R 3和R 4一起代表二价烷二基和/或R 5和R 6一起表示二价烷二基，A表示氮或CH基，并且其与酸和金属盐的加成产物。（VIa）（VIIa）（VIIa）（VIIa）（VIIa）（VIIa）中的新颖的中间体

7. 发明授权

US4921967A Novel alkylcycloalkyl triazolylmethyl ketones as fungicide intermediates 失效
标题翻译：新型烷基环烷基三唑甲基酮作为杀真菌剂中间体
公开(公告)号：US4921967A
公开(公告)日：1990-05-01
申请号：US54551
申请日：1987-05-27
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/653 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56 , C07C2101/08
摘要： New alkylcycloalkyl triazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 and 7,are produced as described and find use as intermediate products for the preparation of cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones, which possess fungicidal and plant growth-regulating properties.
摘要翻译：其中R表示烷基且n为3,4,5,6和7的通式为“IMAGE”（I）的新的烷基环烷基三唑基甲基酮如所述制备，可用作制备环烷基的中间产物（ α-三唑基-β-羟基） - 酮，其具有杀真菌和植物生长调节性质。

8. 发明授权

US4127728A Preparation of 1-phenyl-2,2,2-trihalogeno-ethanol esters 失效
标题翻译： 1-苯基-2,2,2-三卤代乙醇酯的制备
公开(公告)号：US4127728A
公开(公告)日：1978-11-28
申请号：US717302
申请日：1976-08-24
申请人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
发明人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
IPC分类号： C07C69/007 , C07C29/68 , C07C33/46 , C07C67/00 , C07C67/08 , C07C67/14 , C07C68/00 , C07C201/00 , C07C205/42 , C07C253/00 , C07C255/55 , C07C313/00 , C07C319/20 , C07C323/19 , C07C381/14 , C07D317/46 , C07D317/54
CPC分类号： C07C67/08 , C07C29/68 , C07C33/46 , C07C381/14 , C07C67/14
摘要： A process for the preparation of a substituted 1-phenyl-2,2,2-trihalo-ethanol ester of the formula ##STR1## in which R is alkyl, halogenoalkyl, alkoxy, cycloalkyl or optionally substituted phenyl, benzyl, phenoxy, or phenylsulfonyl,X is halogenoalkyl with 1-3 carbon atoms and 1-3 halogen atoms,Y is halogen, cyano, nitro, alkyl, alkoxy, alkylmercapto, sulfoalkoxy or optionally substituted methylenedioxy, andn is an integer from 0 to 3,Comprising reacting a compound of the formula ##STR2## WITH A HALOGENATED ALDEHYDE OF THE FORMULAX CHO in the presence of a Friedel-Crafts catalyst at a temperature of about -70 to +100.degree. C thereby to form a complex alcoholate, and reacting the complex alcoholate with an acid halide of the formula ##STR3## OR WITH A CORRESPONDING ACID ANHYDRIDE AT A TEMPERATURE OF ABOUT -70 TO +100.degree. C. The reaction with the acid halide or anhydride is preferably carried out in the presence of a solvent or diluent, sodium sulfate hydrate is added to the final reaction solution and the resulting mixture of sodium sulfate and basic aluminum halide is filtered off. The products are known insecticides.
摘要翻译：制备式“IMAGE”的取代的1-苯基-2,2,2-三卤代 - 乙醇酯的方法，其中R是烷基，卤代烷基，烷氧基，环烷基或任选取代的苯基，苄基，苯氧基或苯基磺酰基 X是具有1-3个碳原子和1-3个卤素原子的卤代烷基，Y是卤素，氰基，硝基，烷基，烷氧基，烷基巯基，磺基烷氧基或任选取代的亚甲二氧基，N是0至3的整数，包含反应A 在Fried-Crafts催化剂存在下，在约-70至+ 100℃的温度下，使用式（ⅩⅩⅩⅤ）化合物与式（ⅩⅤ）化合物反应，从而形成复合醇化物，并使复合醇化物与在-70至+ 100℃的温度下，与酰基卤或酸酐的反应优选在溶剂或稀释剂钠的存在下进行。将硫酸盐水合物加入到最终的反应物中并将所得的硫酸钠和碱式卤化铝的混合物滤出。产品是已知的杀虫剂。

9. 发明授权

US5010208A Novel alkylcycloalkyl triazolylmethyl ketones as fungicide intermediates 失效
标题翻译：新型烷基环烷基三唑甲基酮作为杀真菌剂中间体
公开(公告)号：US5010208A
公开(公告)日：1991-04-23
申请号：US482106
申请日：1990-02-16
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/653 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56 , C07C2101/08
摘要： New alkylcycloalkyl triazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 and 7,are produced as described and find use as intermediate products for the preparation of cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones, which possess fungicidal and plant growth-regulating properties.

10. 发明授权

US4492795A Alkylcycloalkyl imidazolylmethyl ketones as fungicide intermediates 失效
标题翻译：烷基环烷基咪唑甲基酮作为杀真菌剂中间体
公开(公告)号：US4492795A
公开(公告)日：1985-01-08
申请号：US438087
申请日：1982-11-01
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/50 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D233/60 , C07D521/00
CPC分类号： C07D249/08 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56
摘要： New alkylcycloalkyl imidazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 or 7,are produced as described and find use as intermediate products for the preparation of imidazolyl-vinyl-dithioacetals, which possess fungicidal properties.
摘要翻译：其中R表示烷基且n为3,4,5,6或7的通式为“IMAGE”的新的烷基环烷基咪唑基甲基酮如所述制备，可用作制备咪唑基 - 乙烯基 - 二硫代缩醛的中间产物，具有杀菌性。

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