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1. 发明申请

WO2010106408A1 HYBRID, ORGANIC-INORGANIC, CRYSTALLINE, POROUS SILICATES AND METAL-SILICATES 审中-公开
标题翻译：混合有机无机，结晶，多孔硅酸盐和金属硅酸盐
公开(公告)号：WO2010106408A1
公开(公告)日：2010-09-23
申请号：PCT/IB2010/000407
申请日：2010-02-25
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , COZZOLINO, Mariangela , RIZZO, Caterina , ZANARDI, Stefano
发明人： BELLUSSI, Giuseppe , CARATI, Angela , COZZOLINO, Mariangela , RIZZO, Caterina , ZANARDI, Stefano
IPC分类号： C01B37/00
CPC分类号： C01B37/00 , C01P2002/72
摘要： The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
摘要翻译：本发明涉及新型混合有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于含有具有式（a）的结构单元的晶体结构，其中R是可能含有一种或多种选自IIIB族，IVB族元素的有机基团，VB和过渡金属。还描述了从用于制备所述材料的环状三硅烷开始的方法。这些材料可用作催化领域的分子筛，吸附剂，电子领域，传感器领域，纳米技术领域。

2. 发明申请

WO2011039595A2 MIXED OXIDES OF TRANSITION METAL, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A2
公开(公告)日：2011-04-07
申请号：PCT/IB2010/002392
申请日：2010-09-23
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) X a Y b Z c O d . pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) R I R II R III R IV NOH ( I ) wherein the groups R I -R IV , the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R 1 R 2 R 3 N (II) wherein R 1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R 2 and R 3 , the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R 1 , a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选从0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

3. 发明申请

WO2021094976A1 DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DI-SUBSTITUTED WITH THIENOTHIOPHENIC GROUPS 审中-公开
公开(公告)号：WO2021094976A1
公开(公告)日：2021-05-20
申请号：PCT/IB2020/060661
申请日：2020-11-12
申请人： ENI S.P.A.
发明人： SCHIMPERNA, Giuliana , ABBONDANZA, Luigi , PROTO, Antonio Alfonso , ZANARDI, Stefano
IPC分类号： H01L51/44
摘要： Diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia), wherein - Z represents a sulphur atom, an oxygen atom, a selenium atom; or an NR5 group wherein R5 is selected from C1-C20 alkyl groups, preferably C1-C8, linear or branched, or from optionally substituted aryl groups; - R1, R2 and R3, equal to or different from each other, represent a hydrogen atom; or are selected from C1-C20 alkyl groups, preferably C1-C8, linear or branched, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, C1-C20 alkoxy groups, preferably C1-C8, linear or branched, optionally substituted, -COOR6 groups wherein R6 is selected from C1-C20 alkyl groups, preferably C1-C8, linear or branched, or is a cyano group; - or R1 and R2, may optionally be bound together so as to form, together with the carbon atoms to which they are bound, a saturated, unsaturated, or aromatic, cycle or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - R4, equal to or different from each other, are selected from optionally substituted aryl groups. Said diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCs) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.

4. 发明申请

WO2012130728A1 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM AND PREPARATION PROCESS 审中-公开
标题翻译：过渡金属的混合氧化物，由其获得的加氢催化剂和制备方法
公开(公告)号：WO2012130728A1
公开(公告)日：2012-10-04
申请号：PCT/EP2012/055116
申请日：2012-03-22
申请人： ENI S.P.A. , CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
发明人： CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
IPC分类号： B01J23/00 , B01J23/888 , B01J37/20
CPC分类号： B01J23/8885 , B01J23/002 , B01J31/34 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/031 , B01J37/04 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G45/50 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite isostructural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.
摘要翻译：描述了新的硫化物金属催化剂，其包含Ni，Mo和W，选自Si，Al及其混合物的元素Z，以及可能的通过混合氧化物前体的硫化获得的有机残基，其也是新的，其特征在于它们包含无定形所述混合氧化物的结晶度高于0且低于100％，优选高于0且低于70％。本发明的催化剂可用作加氢处理催化剂，特别是加氢脱硫，加氢脱氮和/或加氢脱芳构化催化剂。

5. 发明申请

WO2013098261A1 PROCESS FOR PREPARING ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES WITH AN ORDERED STRUCTURE AND NEW HYBRID SILICATES AND METAL-SILICATES 审中-公开
标题翻译：具有有序结构和新型混合硅酸盐和金属硅酸盐的有机无机混合硅酸盐和金属硅酸盐的制备方法
公开(公告)号：WO2013098261A1
公开(公告)日：2013-07-04
申请号：PCT/EP2012/076748
申请日：2012-12-21
申请人： ENI S.P.A.
发明人： BELLUSSI, Giuseppe , CARATI, Angela , MILLINI, Roberto , RIZZO, Caterina , ZANARDI, Stefano
IPC分类号： C01B37/00
CPC分类号： C07F7/1836 , C01B37/00 , C01P2002/72 , C01P2002/74 , C01P2002/86
摘要： The present invention relates to a process for the preparation of organic-inorganic hybrid silicates and metal-silicates of the ECS type which uses as starting material the corresponding disilanes: said process is characterized by the presence of boric acid in the reagent mixture. With the process of the invention, ECS silicates and metal-silicates are obtained, characterized by an X-Ray diffractogram with reflections exclusively at angular values higher than 4.0° of 2Θ, and characterized by an ordered structure which contains: - structural units having formula (a), wherein R is an organic group: -boron - one or more elements T, different from boron, selected from groups IIIB, IVB, VB, and transition metals, with a molar ratio Si/ (Si + T) in said structure greater than 0.3 and lower than 1, wherein Si is the silicon contained in the structural unit having formula (a). The silicates and metal-silicates so obtained, containing both boron and at least one element T, are new. The process also allows new crystalline phases called ECS-13 and ECS-14 to be prepared.
摘要翻译：本发明涉及一种制备ECS型有机 - 无机杂化硅酸盐和金属硅酸盐的方法，该方法以起始原料为对应的二硅烷：所述方法的特征在于试剂混合物中存在硼酸。通过本发明的方法，获得ECS硅酸盐和金属硅酸盐，其特征在于具有专门在高于4.0°的2θ的角值的反射的X射线衍射图，其特征在于有序结构，其包含：具有式（a），其中R是有机基团 - 硼 - 选自IIIB，IVB，VB和过渡金属的一种或多种不同于硼的元素T，所述元素的摩尔比Si /（Si + T）在所述结构大于0.3且低于1，其中Si是包含在具有式（a）的结构单元中的硅。如此获得的含有硼和至少一种元素T的硅酸盐和金属硅酸盐是新的。该方法还允许制备称为ECS-13和ECS-14的新结晶相。

6. 发明申请

WO2012052947A1 WAVELENGTH CONVERTER 审中-公开
标题翻译：波长转换器
公开(公告)号：WO2012052947A1
公开(公告)日：2012-04-26
申请号：PCT/IB2011/054673
申请日：2011-10-19
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
发明人： BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
IPC分类号： C01B33/44 , C01B37/00 , C01B37/02
CPC分类号： C01B37/00 , C01B33/44 , C01B37/02 , C07F7/1836
摘要： The invention relates to a spectrum converter, capable of absorbing at least part of an incident radiation and re-emitting it to a longer wavelength, wherein said converter contains particular hybrid organic-inorganic silicates or metal-silicates. Said converter is particularly useful for transforming light with a higher energy of the solar spectrum into light with a lower energy for use in solar devices: its use coupled with a photovoltaic cell optimizes the portion of solar spectrum which can be used by the cell for conversion to electric current, and also avoids that light with an excessively high energy causes damaging the cell itself.
摘要翻译：本发明涉及能够吸收入射辐射的至少一部分并将其再发射到更长波长的光谱转换器，其中所述转换器包含特定的杂化有机 - 无机硅酸盐或金属硅酸盐。所述转换器特别适用于将具有较高能量的太阳光谱的光转换为具有较低能量的光用于太阳能装置：其与光伏电池耦合的使用优化了可被电池用于转换的部分太阳光谱并且也避免了具有过高能量的光会导致电池本身的损坏。

7. 发明申请

WO2008017513A2 ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 审中-公开
标题翻译：有机无机混合硅酸盐和具有订购结构的金属硅酸盐
公开(公告)号：WO2008017513A2
公开(公告)日：2008-02-14
申请号：PCT/EP2007/007132
申请日：2007-08-03
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , RIZZO, Caterina , DIAZ MORALES, Urbano , ZANARDI, Stefano , PARKER, Wallace, O'Neil , MILLINI, Roberto
发明人： BELLUSSI, Giuseppe , CARATI, Angela , RIZZO, Caterina , DIAZ MORALES, Urbano , ZANARDI, Stefano , PARKER, Wallace, O'Neil , MILLINI, Roberto
IPC分类号： C01B37/00 , C01B37/02 , C09C1/30 , C01B33/44
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1836
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/ (Si + T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.
摘要翻译：本发明涉及新的有机 - 无机杂化硅酸盐和称为ECS的金属硅酸盐，其特征在于X-射线粉末衍射图，其特征在于高于4.0°的角度值为2T，优选角度值高于4.7°的反射，以及含有具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（Si + T）的摩尔比高于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。

8. 发明公开

EP2054344A2 ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 有权
标题翻译：有机 - 无机HYBRIDSILICATE和-METALLSILICATE与有序结构
公开(公告)号：EP2054344A2
公开(公告)日：2009-05-06
申请号：EP07801626.8
申请日：2007-08-03
申请人： ENI S.p.A.
发明人： BELLUSSI, Giuseppe , CARATI, Angela , RIZZO, Caterina , DIAZ MORALES, Urbano , ZANARDI, Stefano , PARKER, Wallace, O'Neil , MILLINI, Roberto
IPC分类号： C01B37/00 , C01B37/02 , C09C1/30 , C01B33/44
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1836
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/ (Si + T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.

10. 发明公开

EP2482977A2 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 有权
标题翻译：过渡金属混合氧化物物获得的加氢处理催化剂和方法的研究溶胶 - 凝胶法
公开(公告)号：EP2482977A2
公开(公告)日：2012-08-08
申请号：EP10782366.8
申请日：2010-09-23
申请人： ENI S.p.A.
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

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