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1. 发明申请

WO2011039595A2 MIXED OXIDES OF TRANSITION METAL, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A2
公开(公告)日：2011-04-07
申请号：PCT/IB2010/002392
申请日：2010-09-23
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) X a Y b Z c O d . pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) R I R II R III R IV NOH ( I ) wherein the groups R I -R IV , the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R 1 R 2 R 3 N (II) wherein R 1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R 2 and R 3 , the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R 1 , a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选从0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

2. 发明申请

WO2012130728A1 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM AND PREPARATION PROCESS 审中-公开
标题翻译：过渡金属的混合氧化物，由其获得的加氢催化剂和制备方法
公开(公告)号：WO2012130728A1
公开(公告)日：2012-10-04
申请号：PCT/EP2012/055116
申请日：2012-03-22
申请人： ENI S.P.A. , CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
发明人： CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
IPC分类号： B01J23/00 , B01J23/888 , B01J37/20
CPC分类号： B01J23/8885 , B01J23/002 , B01J31/34 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/031 , B01J37/04 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G45/50 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite isostructural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.
摘要翻译：描述了新的硫化物金属催化剂，其包含Ni，Mo和W，选自Si，Al及其混合物的元素Z，以及可能的通过混合氧化物前体的硫化获得的有机残基，其也是新的，其特征在于它们包含无定形所述混合氧化物的结晶度高于0且低于100％，优选高于0且低于70％。本发明的催化剂可用作加氢处理催化剂，特别是加氢脱硫，加氢脱氮和/或加氢脱芳构化催化剂。

4. 发明公开

EP2482977A2 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 有权
标题翻译：过渡金属混合氧化物物获得的加氢处理催化剂和方法的研究溶胶 - 凝胶法
公开(公告)号：EP2482977A2
公开(公告)日：2012-08-08
申请号：EP10782366.8
申请日：2010-09-23
申请人： ENI S.p.A.
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

5. 发明授权

EP2691172B1 MIXED OXIDES OF TRANSITION METALS AND PREPARATION PROCESS 有权
公开(公告)号：EP2691172B1
公开(公告)日：2019-11-20
申请号：EP12710085.7
申请日：2012-03-22
申请人： ENI S.p.A.
发明人： CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
IPC分类号： B01J23/00 , B01J23/888 , B01J37/20

6. 发明公开

EP2691172A1 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM AND PREPARATION PROCESS 有权
标题翻译： ÜBERGANGSMETALLMISCHOXIDE，DARAUS GEWONNENE HYDROTREATING-KATALYSATOREN UND HERSTELLUNGSVERFAHREN
公开(公告)号：EP2691172A1
公开(公告)日：2014-02-05
申请号：EP12710085.7
申请日：2012-03-22
申请人： ENI S.p.A.
发明人： CARATI, Angela , GAGLIARDI, Maria Federica , FERRARI, Marco Massimo , ZANARDI, Stefano , MARELLA, Marcello , TOMASELLI, Michele
IPC分类号： B01J23/00 , B01J23/888 , B01J37/20
摘要： New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite isostructural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.
摘要翻译：描述了含有Ni，Mo和W的新型硫化物金属催化剂，选自Si，Al及其混合物的元素Z，以及可能通过混合氧化物前体的硫化获得的有机残余物，其也是新的，其特征在于它们包含无定形所述混合氧化物的结晶度高于0且低于100％，优选高于0且低于70％。本发明的催化剂可用作加氢处理催化剂，特别是加氢脱硫，加氢脱氮和/或加氢脱芳构化催化剂。

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