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1. 发明申请

WO2010106408A1 HYBRID, ORGANIC-INORGANIC, CRYSTALLINE, POROUS SILICATES AND METAL-SILICATES 审中-公开
标题翻译：混合有机无机，结晶，多孔硅酸盐和金属硅酸盐
公开(公告)号：WO2010106408A1
公开(公告)日：2010-09-23
申请号：PCT/IB2010/000407
申请日：2010-02-25
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , COZZOLINO, Mariangela , RIZZO, Caterina , ZANARDI, Stefano
发明人： BELLUSSI, Giuseppe , CARATI, Angela , COZZOLINO, Mariangela , RIZZO, Caterina , ZANARDI, Stefano
IPC分类号： C01B37/00
CPC分类号： C01B37/00 , C01P2002/72
摘要： The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
摘要翻译：本发明涉及新型混合有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于含有具有式（a）的结构单元的晶体结构，其中R是可能含有一种或多种选自IIIB族，IVB族元素的有机基团，VB和过渡金属。还描述了从用于制备所述材料的环状三硅烷开始的方法。这些材料可用作催化领域的分子筛，吸附剂，电子领域，传感器领域，纳米技术领域。

2. 发明申请

WO2012052947A1 WAVELENGTH CONVERTER 审中-公开
标题翻译：波长转换器
公开(公告)号：WO2012052947A1
公开(公告)日：2012-04-26
申请号：PCT/IB2011/054673
申请日：2011-10-19
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
发明人： BELLUSSI, Giuseppe , BONOLDI, Lucia , CARATI, Angela , MONTANARI, Luciano , RIZZO, Caterina , ZANARDI, Stefano , FUSCO, Roberto
IPC分类号： C01B33/44 , C01B37/00 , C01B37/02
CPC分类号： C01B37/00 , C01B33/44 , C01B37/02 , C07F7/1836
摘要： The invention relates to a spectrum converter, capable of absorbing at least part of an incident radiation and re-emitting it to a longer wavelength, wherein said converter contains particular hybrid organic-inorganic silicates or metal-silicates. Said converter is particularly useful for transforming light with a higher energy of the solar spectrum into light with a lower energy for use in solar devices: its use coupled with a photovoltaic cell optimizes the portion of solar spectrum which can be used by the cell for conversion to electric current, and also avoids that light with an excessively high energy causes damaging the cell itself.
摘要翻译：本发明涉及能够吸收入射辐射的至少一部分并将其再发射到更长波长的光谱转换器，其中所述转换器包含特定的杂化有机 - 无机硅酸盐或金属硅酸盐。所述转换器特别适用于将具有较高能量的太阳光谱的光转换为具有较低能量的光用于太阳能装置：其与光伏电池耦合的使用优化了可被电池用于转换的部分太阳光谱并且也避免了具有过高能量的光会导致电池本身的损坏。

3. 发明申请

WO2008017513A2 ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 审中-公开
标题翻译：有机无机混合硅酸盐和具有订购结构的金属硅酸盐
公开(公告)号：WO2008017513A2
公开(公告)日：2008-02-14
申请号：PCT/EP2007/007132
申请日：2007-08-03
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , RIZZO, Caterina , DIAZ MORALES, Urbano , ZANARDI, Stefano , PARKER, Wallace, O'Neil , MILLINI, Roberto
发明人： BELLUSSI, Giuseppe , CARATI, Angela , RIZZO, Caterina , DIAZ MORALES, Urbano , ZANARDI, Stefano , PARKER, Wallace, O'Neil , MILLINI, Roberto
IPC分类号： C01B37/00 , C01B37/02 , C09C1/30 , C01B33/44
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1836
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/ (Si + T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.
摘要翻译：本发明涉及新的有机 - 无机杂化硅酸盐和称为ECS的金属硅酸盐，其特征在于X-射线粉末衍射图，其特征在于高于4.0°的角度值为2T，优选角度值高于4.7°的反射，以及含有具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（Si + T）的摩尔比高于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。

4. 发明申请

WO2011039595A2 MIXED OXIDES OF TRANSITION METAL, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A2
公开(公告)日：2011-04-07
申请号：PCT/IB2010/002392
申请日：2010-09-23
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) X a Y b Z c O d . pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) R I R II R III R IV NOH ( I ) wherein the groups R I -R IV , the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R 1 R 2 R 3 N (II) wherein R 1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R 2 and R 3 , the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R 1 , a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选从0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

5. 发明申请

WO2009149923A1 CATALYTIC SYSTEM AND PROCESS FOR THE HYDROCONVERSION OF HEAVY OIL PRODUCTS 审中-公开
标题翻译：催化体系和重油加氢工艺
公开(公告)号：WO2009149923A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/004193
申请日：2009-06-08
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
发明人： BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
IPC分类号： B01J23/28 , B01J23/883 , B01J29/70 , C10G45/04
CPC分类号： C10G45/04 , B01J23/882 , B01J23/883 , B01J27/051 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/166 , B01J29/7007 , B01J29/7615 , B01J35/0006 , B01J37/20 , C10G45/08 , C10G45/12 , C10G45/46 , C10G45/50 , C10G45/54 , C10G47/20 , C10G2300/1003 , C10G2300/1011 , C10G2300/1033 , C10G2300/1074 , Y02P30/20
摘要： Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS 2 or WS 2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle- sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
摘要翻译：催化体系，其可用于通过浆料相中的加氢处理加氢转化重油的方法，其特征在于其包含：具有包含MoS 2或WS 2的氢化剂或其混合物的层状功能的催化剂或其油溶性前体; 具有选自裂化和/或脱氮催化剂的纳米或微米粒径的助催化剂。助催化剂优选由具有小尺寸晶体并且在初级粒子之间具有低聚集度的沸石和/或与Mo和/或W的混合物中的Ni和/或Co的硫化物的硫化物或硫化物的前体组成。

6. 发明申请

WO2009147496A3 CRACKING PROCESS AND ENHANCED CATALYSTS FOR SAID PROCESS 审中-公开
公开(公告)号：WO2009147496A3
公开(公告)日：2009-12-10
申请号：PCT/IB2009/005786
申请日：2009-05-28
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , MILLINI, Roberto , RIZZO, Caterina , COLOMBO, Daniele
发明人： BELLUSSI, Giuseppe , MILLINI, Roberto , RIZZO, Caterina , COLOMBO, Daniele
IPC分类号： B01J29/70 , B01J29/80 , C10G11/05
摘要： The present invention concerns a new cracking process, preferably a fluid catalytic process, characterized in that it is carried out in the presence of a catalyst containing ERS-10 zeolite. The invention also relates to a new catalytic composition containing said ERS-10 zeolite, which can be used as catalyst in catalytic cracking processes, in particular in fluid catalytic cracking processes (FCC).

7. 发明申请

WO2004056943A1 PROCESS AND REACTOR FOR THE PRODUCTION OF OLEFINS BY THE STEAM CRACKING REACTION OF LIQUID HYDROCARBON FEEDS IN THE PRESENCE OF A CATALYST 审中-公开
标题翻译：通过催化剂存在下液体碳源的蒸汽破碎反应生产烯烃的方法和反应器
公开(公告)号：WO2004056943A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/014780
申请日：2003-12-11
申请人： POLIMERI EUROPA S.P.A. , ENITECNOLOGIE S.P.A. , ROMAGNOLI, Massimo , POLLESEL, Paolo , RIZZO, Caterina , BELLUSSI, Giuseppe , PEREGO, Carlo , CLERICI, Gabriele, Carlo, Ettore , GALIMBERTI, Francesca
发明人： ROMAGNOLI, Massimo , POLLESEL, Paolo , RIZZO, Caterina , BELLUSSI, Giuseppe , PEREGO, Carlo , CLERICI, Gabriele, Carlo, Ettore , GALIMBERTI, Francesca
IPC分类号： C10G11/00
CPC分类号： C10G9/14 , C10G11/00 , C10G11/10
摘要： A process for the production of light olefins by means of the steam cracking reaction of liquid hydrocarbon feeds, preferably selected from naphtha, kerosene, atmospheric gas oil, vacuum gas oil and oil residues, alone or mixed with each other, in the presence of a suitable catalyst, effected at a reaction temperature ranging from 700 to 850 °C, at a pressure ranging from 1.1 to 4.5 absolute Atm and for a contact time ranging from 0.02 to 0.3 sec, preferably from 0.05 to 0.15 sec, in a reactor comprising one or more cylindrical pipes, with the same or different section, consisting of a tubular core and a reaction zone whose transversal section is in the form of a circular crown, the ratio between the area of said circular crown and the circular section ranging from 0.35 to 0.99, preferably from 0.75 to 0.95.
摘要翻译：通过液体烃进料的蒸汽裂解反应生产轻质烯烃的方法，该方法优选选自石脑油，煤油，常压瓦斯油，减压瓦斯油和油残余物，单独或彼此混合，在合适的催化剂，在反应温度为700至850℃，压力范围为1.1至4.5，绝对的大气压下进行，接触时间为0.02至0.3秒，优选为0.05至0.15秒，或更多的具有相同或不同截面的圆柱形管，其由管状芯和横截面为圆形冠的形式的反应区组成，所述圆形冠部的面积与圆形截面之间的比率范围为0.35至 0.99，优选0.75至0.95。

8. 发明申请

WO2007028540A1 PROCESS FOR THE REOXIDATION, WITHOUT THE FORMATION OF NITROGEN OXIDES, OF FERROUS SOLUTIONS COMING FROM THE REMOVAL PROCESS IN CONTINUOUS OF HYDROGEN SULFIDE FROM GASEOUS STREAMS BY MEANS OF THE REDOX METHOD 审中-公开
标题翻译：在氧化还原过程中，无法形成氮氧化物，通过REDOX方法从连续流出的硫酸氢盐中除去过程中的有害溶剂
公开(公告)号：WO2007028540A1
公开(公告)日：2007-03-15
申请号：PCT/EP2006/008524
申请日：2006-08-31
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
IPC分类号： C10L3/10 , C01B17/05 , B01D53/14 , B01D53/52
CPC分类号： B01D53/1468 , B01D53/1418 , B01D53/1425 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the reoxidation, without the formation of ni¬ trogen oxides, of ferrous solutions used in the removal process in continuous of hydrogen sulfide from gaseous streams containing them, comprising: a) putting a gas containing H∑S in contact with an oxidiz¬ ing acid aqueous solution of ferric nitrate and containing a heteropolyacid having rjedox properties; b) filtrating and separating the sulfur produced; c) reoxidizing the ferrous nitrate to ferric nitrate with air as such or enriched in oxygen at a pressure higher than atmospheric pressure; d) recycling the solution containing ferric nitrate and the heteropolyacid to the oxidation step (a); and e) discharging the air.
摘要翻译：包括：a）将含有H 2 S的气体与氧化物接触，用于在不含氧化物的情况下，再次氧化从含有它们的气流中连续除去硫化氢中的亚铁溶液，酸式硝酸铁水溶液，含有具有杂聚性质的杂多酸; b）过滤和分离产生的硫; c）将空气中的硝酸亚铁还原为硝酸铁，或在高于大气压的压力下富集氧气; d）将含有硝酸铁和杂多酸的溶液再循环到氧化步骤（a）中; 和e）排出空气。

9. 发明申请

WO2011045657A1 GAS OIL COMPOSITION COMPRISING DIALKYL CARBONATE FROM BIOALCOHOL 审中-公开
标题翻译：包含来自生物醇的碳酸二烷基酯的气体油组合物
公开(公告)号：WO2011045657A1
公开(公告)日：2011-04-21
申请号：PCT/IB2010/002611
申请日：2010-10-11
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , NOTARI, Marcello , REBESCO, Elena, Maria , SAVARESE, Maria, Cristina , SCORLETTI, Pietro , COLLIA, Despina , SERBOLISCA, Luca Paolo
发明人： BELLUSSI, Giuseppe , NOTARI, Marcello , REBESCO, Elena, Maria , SAVARESE, Maria, Cristina , SCORLETTI, Pietro , COLLIA, Despina , SERBOLISCA, Luca Paolo
IPC分类号： C10L1/19 , C10L1/18
CPC分类号： C10L1/1905 , C10L1/19
摘要： Gas oil composition comprising: - at least one gas oil; - at least one dialkyl carbonate; wherein said dialkyl carbonate is obtained from bio- alcohol. Said composition can be advantageously used as fuel, for example, as fuel for burners, or for heating boilers. In particular, said composition can be advantageously used as fuel for diesel engines.
摘要翻译：瓦斯油组合物，其包含： - 至少一种瓦斯油; - 至少一种碳酸二烷基酯; 其中所述碳酸二烷基酯是从生物醇获得的。所述组合物可以有利地用作燃料，例如用作燃烧器的燃料或用于加热锅炉。特别地，所述组合物可以有利地用作柴油机的燃料。

10. 发明申请

WO2005014192A1 PROCESS FOR THE DISPOSAL OF SULFUR IN THE FORM OF COMPOUNDS LIQUID AT ROOM TEMPERATURE 审中-公开
标题翻译：化合物液体在室温下处理硫磺的方法
公开(公告)号：WO2005014192A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/007565
申请日：2004-07-06
申请人： ENI S.p.A. , ENITECNOLOGIE S.p.A. , DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
发明人： DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
IPC分类号： B09B1/00
CPC分类号： E21B41/0057 , B09B1/008 , B65G5/00
摘要： Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H 2 S n+1 , wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150°C.
摘要翻译：用于处理液态硫的方法，其包括：a）将元素硫转化为具有通式H 2 Sn + 1的硫烷，其中n为1至7的数; b）任选地将粉末形式的元素硫与液体硫烷混合，直至其浓度保证混合物的可泵送性; c）将室温下的硫烷液体注入温度低于150℃的地质构造中。

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