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    • 3. 发明授权
    • Method of fabricating a nickel silicide on a substrate
    • 在衬底上制造硅化镍的方法
    • US06720258B2
    • 2004-04-13
    • US10319313
    • 2002-12-12
    • Jer-shen MaaDouglas J. TweetYoshi OnoFengyan ZhangSheng Teng Hsu
    • Jer-shen MaaDouglas J. TweetYoshi OnoFengyan ZhangSheng Teng Hsu
    • H01L2144
    • H01L21/28518H01L29/456
    • An integrated circuit device, and a method of manufacturing the same, comprises an epitaxial nickel silicide on (100) Si, or a stable nickel silicide on amorphous Si, fabricated with a cobalt interlayer. In one embodiment the method comprises depositing a cobalt (Co) interface layer between the Ni and Si layers prior to the silicidation reaction. The cobalt interlayer regulates the flux of the Ni atoms through the cobalt/nickel/silicon alloy layer formed from the reaction of the cobalt interlayer with the nickel and the silicon so that the Ni atoms reach the Si interface at a similar rate, i.e., without any orientation preference, so as to form a uniform layer of nickel silicide. The nickel silicide may be annealed to form a uniform crystalline nickel disilicide. Accordingly, a single crystal nickel silicide on (100) Si or on amorphous Si is achieved wherein the nickel silicide has improved stability and may be utilized in ultra-shallow junction devices.
    • 集成电路器件及其制造方法包括在(100)Si上的外延硅化镍,或者由钴中间层制造的在非晶Si上的稳定的硅化镍。 在一个实施方案中,该方法包括在硅化反应之前在Ni和Si层之间沉积钴(Co)界面层。 钴中间层通过由钴中间层与镍和硅的反应形成的钴/镍/硅合金层调节Ni原子的通量,使得Ni原子以相似的速率到达Si界面,即没有 任何取向偏好,从而形成均匀的硅化镍层。 可以将镍硅化物退火以形成均匀的结晶二硅化镍。 因此,实现了(100)Si或非晶Si上的单晶硅化镍,其中硅化镍具有改进的稳定性并可用于超浅结结器件中。
    • 5. 发明授权
    • Multilayered barrier metal thin-films
    • 多层阻隔金属薄膜
    • US08264081B2
    • 2012-09-11
    • US11311546
    • 2005-12-19
    • Wei PanYoshi OnoDavid R. EvansSheng Teng Hsu
    • Wei PanYoshi OnoDavid R. EvansSheng Teng Hsu
    • H01L23/48H01L23/52
    • H01L21/28562H01L21/76841H01L2221/1078
    • A multi-layered barrier metal thin film is deposited on a substrate by atomic layer chemical vapor deposition (ALCVD). The multi-layer film may comprise several different layers of a single chemical species, or several layers each of distinct or alternating chemical species. In a preferred embodiment, the multi-layer barrier thin film comprises a Tantalum Nitride layer on a substrate, with a Titanium Nitride layer deposited thereon. The thickness of the entire multi-layer film may be approximately fifty Angstroms. The film has superior film characteristics, such as anti-diffusion capability, low resistivity, high density, and step coverage, when compared to films deposited by conventional chemical vapor deposition (CVD). The multi-layered barrier metal thin film of the present invention has improved adhesion characteristics and is particularly suited for metallization of a Copper film thereon.
    • 通过原子层化学气相沉积(ALCVD)将多层阻挡金属薄膜沉积在衬底上。 多层膜可以包括单个化学物质的几个不同层,或者各个不同的或交替的化学物质的几个层。 在优选实施例中,多层阻挡薄膜包括在衬底上的氮化钽层,其上沉积有氮化钛层。 整个多层膜的厚度可以是大约50埃。 当与通过常规化学气相沉积(CVD)沉积的膜相比时,该膜具有优异的膜特性,例如抗扩散能力,低电阻率,高密度和台阶覆盖。 本发明的多层阻挡金属薄膜具有改善的粘合特性,特别适用于其上的铜膜的金属化。