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    • 3. 发明授权
    • Dose control technique for plasma doping in ultra-shallow junction formations
    • 用于等离子体掺杂在超浅结结构中的剂量控制技术
    • US06403453B1
    • 2002-06-11
    • US09626837
    • 2000-07-27
    • Yoshi OnoYanjun MaSheng Teng Hsu
    • Yoshi OnoYanjun MaSheng Teng Hsu
    • H01L2126
    • H01L21/2236
    • A method of plasma doping substrates is provided. The substrate is covered with photoresist and placed within a plasma chamber. A doping gas is introduced into the chamber and ionized. A dilutant gas is also introduced to provide better control of the total amount of dosage associated with a given duration of exposure. The dilutant gas is preferably monatomic to reduce, or eliminate, affects associated with pressure variations within the chamber caused by dissociation of elements within the plasma chamber. The dilutant gas preferably contains lighter elements so as to reduce, or eliminate, damage to the photoresist caused by ion impacts. The dilutant gas is preferably neon or helium. The present method provides a means to better control the dosage and reduce photoresist damage and contamination.
    • 提供了一种等离子体掺杂衬底的方法。 衬底被光致抗蚀剂覆盖并置于等离子体室内。 将掺杂气体引入室并离子化。 还引入稀释气体以更好地控制与给定的暴露持续时间相关的剂量的总量。 稀释气体优选是单原子的,以减少或消除由等离子体室内的元素解离引起的室内压力变化的影响。 稀释气体优选含有较轻的元素,以便减少或消除由离子冲击引起的光致抗蚀剂的损伤。 稀释气体优选为氖气或氦气。 本方法提供了更好地控制剂量并减少光致抗蚀剂损伤和污染的方法。
    • 6. 发明授权
    • Multilayer dielectric stack and method
    • 多层电介质叠层及方法
    • US06407435B1
    • 2002-06-18
    • US09502420
    • 2000-02-11
    • Yanjun MaYoshi Ono
    • Yanjun MaYoshi Ono
    • H01L2976
    • H01L21/28185H01L21/28194H01L21/28202H01L29/513H01L29/517H01L29/518H01L29/66583
    • A multilayer dielectric stack is provided which has alternating layers of a high-k material and an interposing material. The presence of the interposing material and the thinness of the high-k material layers reduces or eliminate effects of crystallization within the high-k material, even at relatively high annealing temperatures. The high-k dielectric layers are a metal oxide of preferably zirconium or hafnium. The interposing layers are preferably amorphous aluminum oxide, aluminum nitride, or silicon nitride. Because the layers reduce the effects of crystalline structures within individual layers, the overall tunneling current is reduced. Also provided are atomic layer deposition, sputtering, and evaporation as methods of depositing desired materials for forming the above-mentioned multilayer dielectric stack.
    • 提供了具有高k材料和插入材料的交替层的多层电介质叠层。 插入材料的存在和高k材料层的薄度降低或消除了高k材料内的结晶效应,即使在较高的退火温度下也是如此。 高k电介质层是优选锆或铪的金属氧化物。 插层优选为无定形氧化铝,氮化铝或氮化硅。 因为这些层减少了单个层内晶体结构的影响,所以整个隧穿电流降低。 还提供了作为沉积用于形成上述多层电介质叠层的所需材料的方法的原子层沉积,溅射和蒸发。
    • 7. 发明授权
    • Doped zirconia, or zirconia-like, dielectric film transistor structure and deposition method for same
    • 掺杂的氧化锆或氧化锆样的电介质膜晶体管结构和沉积方法相同
    • US06297539B1
    • 2001-10-02
    • US09611356
    • 2000-07-06
    • Yanjun MaYoshi Ono
    • Yanjun MaYoshi Ono
    • H01L2976
    • H01L21/28185C23C14/083C23C16/405H01L21/28194H01L21/28211H01L21/31604H01L21/31641H01L21/31645H01L28/56H01L29/513H01L29/517
    • A high-k dielectric films is provided, which is doped with divalent or trivalent metals to vary the electron affinity, and consequently the electron and hole barrier height. The high-k dielectric film is a metal oxide of either zirconium (Zr) or hafnium (Hf), doped with a divalent metal, such as calcium (Ca) or strontium (Sr), or a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y). By selecting either a divalent or trivalent doping metal, the electron affinity of the dielectric material can be controlled, while also providing a higher dielectric constant material then silicon dioxide. Preferably, the dielectric material will also be amorphous to reduce leakage caused by grain boundaries. Also provided are sputtering, CVD, Atomic Layer CVD, and evaporation deposition methods for the above-mentioned, doped high dielectric films.
    • 提供了高k电介质膜,其掺杂有二价或三价金属以改变电子亲和力,从而电子和空穴势垒高度。 高k电介质膜是掺杂有二价金属如钙(Ca)或锶(Sr)的锆(Zr)或铪(Hf)的金属氧化物,或三价金属如铝(Al ),钪(Sc),镧(La)或钇(Y)。 通过选择二价或三价掺杂金属,可以控制介电材料的电子亲和力,同时还提供较高的介电常数材料,然后是二氧化硅。 优选地,电介质材料也将是非晶体的,以减少由晶界引起的泄漏。 还提供了用于上述掺杂的高介电膜的溅射,CVD,原子层CVD和蒸发沉积方法。
    • 9. 发明授权
    • Method of forming a doped metal oxide dielectric film
    • 形成掺杂金属氧化物电介质膜的方法
    • US06207589B1
    • 2001-03-27
    • US09515743
    • 2000-02-29
    • Yanjun MaYoshi Ono
    • Yanjun MaYoshi Ono
    • H01L2131
    • H01L21/28185H01L21/28194H01L28/56H01L29/513H01L29/517
    • A high-k dielectric film is provided which remains amorphous at relatively high annealing temperatures. The high-k dielectric film is a metal oxide of either Zr or Hf, doped with a trivalent metal, such as Al. Because the film resists the formation of a crystalline structure, interfaces to adjacent films have fewer irregularities. When used as a gate dielectric, the film can be made thin to support smaller transistor geometries, while the surface of the channel region can be made smooth to support high electron mobility. Also provided are CVD, sputtering, and evaporation deposition methods for the above-mentioned, trivalent metal doped high dielectric films.
    • 提供了一种高k电介质膜,其在相对高的退火温度下保持非晶态。 高k电介质膜是掺杂有三价金属如Al的Zr或Hf的金属氧化物。 由于膜抵抗晶体结构的形成,与相邻膜的界面具有较少的不规则性。 当用作栅极电介质时,可以使膜变薄以支持更小的晶体管几何形状,同时沟道区域的表面可以被制成平滑的以支持高电子迁移率。 还提供了用于上述三价金属掺杂的高介电膜的CVD,溅射和蒸发沉积方法。