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1. 发明授权

US07384837B2 Method for isolating silicon germanium dislocation regions in strained-silicon CMOS applications 有权
标题翻译：在应变硅CMOS应用中分离硅锗位错区的方法
公开(公告)号：US07384837B2
公开(公告)日：2008-06-10
申请号：US11073185
申请日：2005-03-03
申请人： Sheng Teng Hsu , Jong-Jan Lee , Douglas J. Tweet , Jer-shen Maa
发明人： Sheng Teng Hsu , Jong-Jan Lee , Douglas J. Tweet , Jer-shen Maa
IPC分类号： H01L21/8238
CPC分类号： H01L29/1054 , H01L21/76224 , H01L21/823807 , H01L21/823842 , H01L21/823878 , H01L27/1203 , H01L29/78645
摘要： A dual gate strained-Si MOSFET with thin SiGe dislocation regions and a method for fabricating the same are provided. The method forms a first layer of relaxed SiGe overlying a substrate, having a thickness of less than 5000 Å; forms a second layer of relaxed SiGe overlying the substrate and adjacent to the first layer of SiGe, having a thickness of less than 5000 Å; forms a layer of strained-Si overlying the first and second SiGe layers; forms a shallow trench isolation region interposed between the first SiGe layer and the second SiGe layer; forms an p-well in the substrate and the overlying first layer of SiGe; forming forms a p-well in the substrate and the overlying second layer of SiGe; forms channel regions, in the strained-Si, and forms PMOS and NMOS transistor source and drain regions.
摘要翻译：提供具有薄SiGe位错区域的双栅应变Si MOSFET及其制造方法。该方法形成覆盖衬底的第一层松弛SiGe，厚度小于5000; 形成覆盖衬底并且邻近第一SiGe层的第二层松弛SiGe，其厚度小于5000; 形成层叠在第一和第二SiGe层上的应变层; 形成介于第一SiGe层和第二SiGe层之间的浅沟槽隔离区; 在衬底和SiGe的上覆第一层中形成p阱; 在衬底和SiGe的上覆第二层中形成p阱; 在应变Si中形成沟道区，并形成PMOS和NMOS晶体管的源极和漏极区。

2. 发明授权

US06699764B1 Method for amorphization re-crystallization of Si1-xGex films on silicon substrates 失效
标题翻译：硅衬底上Si1-xGex薄膜的非晶化再结晶方法
公开(公告)号：US06699764B1
公开(公告)日：2004-03-02
申请号：US10238146
申请日：2002-09-09
申请人： Douglas J. Tweet , Jer-shen Maa , Jong-Jan Lee , Sheng Teng Hsu
发明人： Douglas J. Tweet , Jer-shen Maa , Jong-Jan Lee , Sheng Teng Hsu
IPC分类号： H01L21336
CPC分类号： H01L21/263 , C30B1/023 , C30B1/04 , C30B29/52 , H01L21/02381 , H01L21/0245 , H01L21/02502 , H01L21/0251 , H01L21/02532 , H01L21/02694 , H01L29/1054 , H01L29/165 , Y10S438/933
摘要： A method of fabricating a Si1−XGeX film on a silicon substrate includes preparing a silicon substrate; epitaxially depositing a Si1−XGeX layer on the silicon substrate forming a Si1−XGeX/Si interface there between; epitaxially growing a silicon cap on the Si1−XGeX layer; implanting hydrogen ions through the Si1−XGeX layer to a depth of between about 3 nm to 100 nm below the Si1−XGeX/Si interface; amorphizing the Si1−XGeX layer to form an amorphous, graded SiGe layer; and annealing the structure at a temperature of between about 650° C. to 1100° C. for between about ten seconds and sixty minutes to recrystallize the SiGe layer.
摘要翻译：在硅衬底上制造Si1-XGeX膜的方法包括制备硅衬底; 在硅衬底上外延沉积形成Si1-XGeX / Si界面的Si1-XGeX层; 在Si1-XGeX层上外延生长硅帽; 通过Si1-XGeX层将氢离子注入Si1-XGeX / Si界面以下约3nm至100nm之间的深度; 将Si1-XGeX层非晶化以形成无定形的梯度SiGe层; 并在约650℃至1100℃的温度下对该结构退火约十秒至六十分钟以使SiGe层重结晶。

3. 发明授权

US06992025B2 Strained silicon on insulator from film transfer and relaxation by hydrogen implantation 有权
标题翻译：绝缘体上的应变硅通过氢注入从膜转移和弛豫
公开(公告)号：US06992025B2
公开(公告)日：2006-01-31
申请号：US10755615
申请日：2004-01-12
申请人： Jer-shen Maa , Jong-Jan Lee , Douglas J. Tweet , David R. Evans , Allen W. Burmaster , Sheng Teng Hsu
发明人： Jer-shen Maa , Jong-Jan Lee , Douglas J. Tweet , David R. Evans , Allen W. Burmaster , Sheng Teng Hsu
IPC分类号： H01L21/26 , H01L21/42 , H01L21/324
CPC分类号： H01L21/76254
摘要： Transistors fabricated on SSOI (Strained Silicon On Insulator) substrate, which comprises a strained silicon layer disposed directly on an insulator layer, have enhanced device performance due to the strain-induced band modification of the strained silicon device channel and the limited silicon volume because of the insulator layer. The present invention discloses a SSOI substrate fabrication process comprising various novel approaches. One is the use of a thin relaxed SiGe layer as the strain-induced seed layer to facilitate integration and reduce processing cost. Another is the formation of split implant microcracks deep in the silicon substrate to reduce the number of threading dislocations reaching the strained silicon layer. And lastly is the two step annealing/thinning process for the strained silicon/SiGe multilayer film transfer without blister or flaking formation.
摘要翻译：包含直接设置在绝缘体层上的应变硅层的SSOI（应变绝缘体硅）基板上制造的晶体管由于应变诱导的应变硅器件通道的带隙修改而增加了器件性能，并且由于绝缘体层。本发明公开了一种包含各种新颖方法的SSOI衬底制造工艺。一个是使用薄的松弛SiGe层作为应变诱导的种子层，以促进整合并降低加工成本。另一个是在硅衬底深部形成分裂的植入物微裂纹，以减少到达应变硅层的穿透位错的数量。最后是对应变硅/ SiGe多层膜转移的两步退火/变薄处理，没有起泡或剥落形成。

4. 发明授权

US06703293B2 Implantation at elevated temperatures for amorphization re-crystallization of Si1-xGex films on silicon substrates 失效
标题翻译：在高温下植入硅衬底上的Si1-xGex膜的非晶化再结晶
公开(公告)号：US06703293B2
公开(公告)日：2004-03-09
申请号：US10194383
申请日：2002-07-11
申请人： Douglas J. Tweet , Sheng Teng Hsu , Jer-shen Maa , Jong-Jan Lee
发明人： Douglas J. Tweet , Sheng Teng Hsu , Jer-shen Maa , Jong-Jan Lee
IPC分类号： H01L21265
CPC分类号： H01L21/02381 , C30B25/02 , C30B29/52 , C30B31/22 , H01L21/0245 , H01L21/02502 , H01L21/0251 , H01L21/02532 , H01L21/02694 , Y10S438/933
摘要： A method of fabricating a Si1−XGeX film on a silicon substrate includes preparing a silicon substrate; epitaxially depositing a Si1−XGeX layer on the silicon substrate forming a Si1−XGeX/Si interface there between; amorphizing the Si1−XGeX layer at a temperature greater than Tc to form an amorphous, graded SiGe layer; and annealing the structure at a temperature of between about 650° C. to 1100° C. for between about ten seconds and sixty minutes to recrystallize the SiGe layer.
摘要翻译：在硅衬底上制造Si1-XGeX膜的方法包括制备硅衬底; 在硅衬底上外延沉积形成Si1-XGeX / Si界面的Si1-XGeX层; 在大于Tc的温度下使Si1-XGeX层非晶化以形成无定形的梯度SiGe层; 并在约650℃至1100℃的温度下对该结构退火约十秒至六十分钟以使SiGe层重结晶。

5. 发明授权

US06903384B2 System and method for isolating silicon germanium dislocation regions in strained-silicon CMOS applications 失效
标题翻译：在应变硅CMOS应用中分离硅锗位错区的系统和方法
公开(公告)号：US06903384B2
公开(公告)日：2005-06-07
申请号：US10345551
申请日：2003-01-15
申请人： Sheng Teng Hsu , Jong-Jan Lee , Douglas J. Tweet , Jer-shen Maa
发明人： Sheng Teng Hsu , Jong-Jan Lee , Douglas J. Tweet , Jer-shen Maa
IPC分类号： H01L21/322 , H01L21/762 , H01L21/8238 , H01L27/092 , H01L27/12 , H01L29/10 , H01L29/78 , H01L29/786 , H01L31/0312
CPC分类号： H01L29/1054 , H01L21/76224 , H01L21/823807 , H01L21/823842 , H01L21/823878 , H01L27/1203 , H01L29/78645
摘要： A dual gate strained-Si MOSFET with thin SiGe dislocation regions and a method for fabricating the same are provided. The method comprises: forming a first layer of relaxed SiGe overlying a substrate, having a thickness of less than 5000 Å; forming a second layer of relaxed SiGe overlying the substrate and adjacent to the first layer of SiGe, having a thickness of less than 5000 Å; forming a layer of strained-Si overlying the first and second SiGe layers; forming a shallow trench isolation region interposed between the first SiGe layer and the second SiGe layer; forming an n-well in the substrate and the overlying first layer of SiGe; forming a p-well in the substrate and the overlying second layer of SiGe; forming channel regions, in the strained-Si, and forming PMOS and NMOS transistor source and drain regions.
摘要翻译：提供具有薄SiGe位错区域的双栅应变Si MOSFET及其制造方法。该方法包括：形成覆盖衬底的第一层松弛SiGe，厚度小于5000; 形成第二层弛豫的SiGe，覆盖衬底并与第一层SiGe相邻，厚度小于5000; 形成层叠在第一和第二SiGe层上的应变层; 形成介于所述第一SiGe层和所述第二SiGe层之间的浅沟槽隔离区域; 在衬底和上覆的第一层SiGe中形成n阱; 在衬底和SiGe的上覆第二层中形成p阱; 在应变Si中形成沟道区，并形成PMOS和NMOS晶体管的源极和漏极区。

6. 发明授权

US07390725B2 Strained silicon on insulator from film transfer and relaxation by hydrogen implantation 有权
标题翻译：绝缘体上的应变硅通过氢注入从膜转移和弛豫
公开(公告)号：US07390725B2
公开(公告)日：2008-06-24
申请号：US11284326
申请日：2005-11-21
申请人： Jer-shen Maa , Jong-Jan Lee , Douglas J. Tweet , David R. Evans , Allen W. Burmaster , Sheng Teng Hsu
发明人： Jer-shen Maa , Jong-Jan Lee , Douglas J. Tweet , David R. Evans , Allen W. Burmaster , Sheng Teng Hsu
IPC分类号： H01L21/46 , H01L21/30
CPC分类号： H01L21/76254
摘要： Transistors fabricated on SSOI (Strained Silicon On Insulator) substrate, which comprises a strained silicon layer disposed directly on an insulator layer, have enhanced device performance due to the strain-induced band modification of the strained silicon device channel and the limited silicon volume because of the insulator layer. The present invention discloses SSOI substrate fabrication processes comprising various novel approaches. One is the use of a thin relaxed SiGe layer as the strain-induced seed layer to facilitate integration and reduce processing cost. Another is the formation of split implant microcracks deep in the silicon substrate to reduce the number of threading dislocations reaching the strained silicon layer. And lastly is a two step annealing/thinning process for the strained silicon/SiGe multilayer film transfer without blister or flaking formation.
摘要翻译：包含直接设置在绝缘体层上的应变硅层的SSOI（应变绝缘体硅）基板上制造的晶体管由于应变诱导的应变硅器件通道的带隙修改而增加了器件性能，并且由于绝缘体层。本发明公开了包含各种新颖方法的SSOI衬底制造工艺。一个是使用薄的松弛SiGe层作为应变诱导的种子层，以促进整合并降低加工成本。另一个是在硅衬底深部形成分裂的植入物微裂纹，以减少到达应变硅层的穿透位错的数量。最后是对应变硅/ SiGe多层膜转移进行两步退火/变薄处理，无需起泡或剥落形成。

7. 发明授权

US06793731B2 Method for recrystallizing an amorphized silicon germanium film overlying silicon 失效
标题翻译：将硅非晶硅化硅膜再结晶的方法
公开(公告)号：US06793731B2
公开(公告)日：2004-09-21
申请号：US10098757
申请日：2002-03-13
申请人： Sheng Teng Hsu , Jong-Jan Lee , Jer-shen Maa , Douglas J. Tweet
发明人： Sheng Teng Hsu , Jong-Jan Lee , Jer-shen Maa , Douglas J. Tweet
IPC分类号： C30B3302
CPC分类号： H01L21/26506 , C30B1/023 , C30B29/52 , H01L21/02381 , H01L21/0245 , H01L21/02502 , H01L21/0251 , H01L21/02513 , H01L21/02532 , H01L21/02694
摘要： A method is provided for forming a relaxed single-crystal silicon germanium film on a silicon substrate. Also provided is a film structure with a relaxed layer of graded silicon germanium on a silicon substrate. The method comprises: providing a silicon (Si) substrate with a top surface; growing a graded layer of strained single-crystal Si1−xGex having a bottom surface overlying the Si substrate top surface and a top surface, where x increases with the Si1−xGex layer thickness in the range between 0.03 and 0.5, wherein the Si1−xGex layer has a thickness in the range of 2500 Å to 5000 Å; implanting hydrogen ions; penetrating the Si substrate with the hydrogen ions a depth in the range of 300 Å to 1000 Å; implanting heavy ions, such as Si or Ge, into the Si1−xGex; in response to the heavy ion implantation, amorphizing a first region of the Si1−xGex layer adjacent the Si substrate; annealing; in response to the annealing, forming a hydrogen platelets layer between the Si substrate and the Si1−xGex layer; forming a silicon layer with a high density of hydrogen underlying the hydrogen platelets layer; and, forming a relaxed single-crystal Si1−xGex region, free of defects.
摘要翻译：提供了一种在硅衬底上形成松弛的单晶硅锗膜的方法。还提供了在硅衬底上具有缓和的渐变硅锗层的膜结构。该方法包括：提供具有顶表面的硅（Si）衬底; 生长具有覆盖Si衬底顶表面的底表面和顶表面的应变单晶Si1-xGex的分级层，其中x随着Si1-xGex层厚度在0.03和0.5之间的范围增加，其中Si1-xGex 层的厚度在2500埃至5000埃的范围内; 植入氢离子; 用氢离子穿透Si衬底，深度在300埃至1000埃的范围内; 将诸如Si或Ge的重离子注入到Si1-xGex中; 响应于重离子注入，使与Si衬底相邻的Si1-xGex层的第一区域非晶化; 退火; 响应于退火，在Si衬底和Si1-xGex层之间形成氢血小板层; 在氢薄膜层下形成具有高密度氢的硅层; 并形成松弛的单晶Si1-xGex区域，没有缺陷。

8. 发明授权

US06720258B2 Method of fabricating a nickel silicide on a substrate 有权
标题翻译：在衬底上制造硅化镍的方法
公开(公告)号：US06720258B2
公开(公告)日：2004-04-13
申请号：US10319313
申请日：2002-12-12
申请人： Jer-shen Maa , Douglas J. Tweet , Yoshi Ono , Fengyan Zhang , Sheng Teng Hsu
发明人： Jer-shen Maa , Douglas J. Tweet , Yoshi Ono , Fengyan Zhang , Sheng Teng Hsu
IPC分类号： H01L2144
CPC分类号： H01L21/28518 , H01L29/456
摘要： An integrated circuit device, and a method of manufacturing the same, comprises an epitaxial nickel silicide on (100) Si, or a stable nickel silicide on amorphous Si, fabricated with a cobalt interlayer. In one embodiment the method comprises depositing a cobalt (Co) interface layer between the Ni and Si layers prior to the silicidation reaction. The cobalt interlayer regulates the flux of the Ni atoms through the cobalt/nickel/silicon alloy layer formed from the reaction of the cobalt interlayer with the nickel and the silicon so that the Ni atoms reach the Si interface at a similar rate, i.e., without any orientation preference, so as to form a uniform layer of nickel silicide. The nickel silicide may be annealed to form a uniform crystalline nickel disilicide. Accordingly, a single crystal nickel silicide on (100) Si or on amorphous Si is achieved wherein the nickel silicide has improved stability and may be utilized in ultra-shallow junction devices.
摘要翻译：集成电路器件及其制造方法包括在（100）Si上的外延硅化镍，或者由钴中间层制造的在非晶Si上的稳定的硅化镍。在一个实施方案中，该方法包括在硅化反应之前在Ni和Si层之间沉积钴（Co）界面层。钴中间层通过由钴中间层与镍和硅的反应形成的钴/镍/硅合金层调节Ni原子的通量，使得Ni原子以相似的速率到达Si界面，即没有任何取向偏好，从而形成均匀的硅化镍层。可以将镍硅化物退火以形成均匀的结晶二硅化镍。因此，实现了（100）Si或非晶Si上的单晶硅化镍，其中硅化镍具有改进的稳定性并可用于超浅结结器件中。

9. 发明授权

US06534871B2 Device including an epitaxial nickel silicide on (100) Si or stable nickel silicide on amorphous Si and a method of fabricating the same 失效
公开(公告)号：US06534871B2
公开(公告)日：2003-03-18
申请号：US09855391
申请日：2001-05-14
申请人： Jer-shen Maa , Douglas J. Tweet , Yoshi Ono , Fengyan Zhang , Sheng Teng Hsu
发明人： Jer-shen Maa , Douglas J. Tweet , Yoshi Ono , Fengyan Zhang , Sheng Teng Hsu
IPC分类号： H01L2348
CPC分类号： H01L21/28518 , H01L29/456
摘要： An integrated circuit device, and a method of manufacturing the same, comprises an epitaxial nickel silicide on (100) Si, or a stable nickel silicide on amorphous Si, fabricated with a cobalt interlayer. In one embodiment the method comprises depositing a cobalt (Co) interface layer between the Ni and Si layers prior to the silicidation reaction. The cobalt interlayer regulates the flux of the Ni atoms through the cobalt/nickel/silicon alloy layer formed from the reaction of the cobalt interlayer with the nickel and the silicon so that the Ni atoms reach the Si interface at a similar rate, i.e., without any orientation preference, so as to form a uniform layer of nickel silicide. The nickel silicide may be annealed to form a uniform crystalline nickel disilicide. Accordingly, a single crystal nickel silicide on (100) Si or on amorphous Si is achieved wherein the nickel silicide has improved stability and may be utilized in ultra-shallow junction devices.

10. 发明授权

US06583000B1 Process integration of Si1-xGex CMOS with Si1-xGex relaxation after STI formation 失效
标题翻译： STI形成后Si1-xGex CMOS与Si1-xGex弛豫过程的整合
公开(公告)号：US06583000B1
公开(公告)日：2003-06-24
申请号：US10072183
申请日：2002-02-07
申请人： Sheng Teng Hsu , Jong-Jan Lee , Jer-shen Maa , Douglas James Tweet
发明人： Sheng Teng Hsu , Jong-Jan Lee , Jer-shen Maa , Douglas James Tweet
IPC分类号： H01L218238
CPC分类号： H01L21/823807 , H01L21/76224 , H01L21/823878
摘要： A method of forming a CMOS device includes preparing a silicon substrate, including forming plural device regions on the substrate; epitaxially forming a strained SiGe layer on the substrate, wherein the SiGe layer has a germanium content of between about 20% and 40%; forming a silicon cap layer epitaxially on the SiGe layer; depositing a gate oxide layer; depositing a first polysilicon layer; implanting H+ ions to a depth below the SiGe layer; forming a trench by shallow trench isolation which extends into the substrate; annealing the structure at a temperature of between about 700° C. to 900° C. for between about five minutes to sixty minutes; depositing an oxide layer and a second polysilicon layer, thereby filling the trench; planarizing the structure to the top of the level of the portion of the second polysilicon layer which is located in the trench; and completing the CMOS device.
摘要翻译：形成CMOS器件的方法包括制备硅衬底，包括在衬底上形成多个器件区域; 在衬底上外延地形成应变SiGe层，其中SiGe层的锗含量在约20％和40％之间; 在SiGe层上外延地形成硅帽层; 沉积栅氧化层; 沉积第一多晶硅层; 将H +离子注入SiGe层以下的深度; 通过延伸到衬底中的浅沟槽隔离形成沟槽; 在约700℃至900℃的温度下退火结构约5分钟至60分钟; 沉积氧化物层和第二多晶硅层，从而填充沟槽; 将结构平面化到位于沟槽中的第二多晶硅层的部分的顶部的顶部; 并完成CMOS设备。

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