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1. 发明授权

US06239060B1 Supported metallocene catalyst system and method for polymerizing olefins 失效
标题翻译：负载金属茂催化剂体系及烯烃聚合方法
公开(公告)号：US06239060B1
公开(公告)日：2001-05-29
申请号：US09224176
申请日：1998-12-31
申请人： David W. Dockter , Bryan E. Hauger , M. Bruce Welch , Randall S. Muninger
发明人： David W. Dockter , Bryan E. Hauger , M. Bruce Welch , Randall S. Muninger
IPC分类号： B01J3502
CPC分类号： B01J31/1616 , B01J31/128 , B01J31/143 , B01J31/1608 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10S526/943 , C08F4/65916
摘要： The present invention provides a new type of supported metallocene catalyst system. In one aspect of the invention, an inorganic oxide support, such as silica, is impregnated with a Group XIII element such as B, Al or GA. The support is then contacted with a liquid catalyst system prepared by combining in a liquid an organo aluminoxane and a metallocene having two cyclopetadienyl-type ligands selected from substituted or unsubstituted cyclopentadienyl, indenyl, benzoindenyl, tetrahdroindenyl, benzofluorenyl, octahydrofluorenyl, and fluorenyl ligands to form a supported metallocene catalyst system. In preferred embodiments the process further includes conducting prepolymerization of at least one olefin in the presence of the supported metallocene catalyst system to produce a prepolymerized metallocene catalyst system. The prepolymerized metallocene catalyst system prepared in this manner yields substantially increased activity for the polymerization of olefins. In another aspect, the present invention also provides a method for polymerization of olefins using the inventive supported metallocene catalyst system.
摘要翻译：本发明提供一种新型的负载型茂金属催化剂体系。在本发明的一个方面，无机氧化物载体如二氧化硅用第ⅩⅢ族元素如B，Al或GA浸渍。然后将载体与通过在液体中组合有机铝氧烷和具有选自取代或未取代的环戊二烯基，茚基，苯并茚基，四氢茚基，苯并芴基，八氢芴基和芴基配体的两个环戊二烯基型配体的金属茂接触而形成的液体催化剂体系形成负载金属茂催化剂体系。在优选的实施方案中，该方法还包括在负载的茂金属催化剂体系的存在下进行至少一种烯烃的预聚合，以产生预聚合的茂金属催化剂体系。以这种方式制备的预聚合的茂金属催化剂体系产生了烯烃聚合的显着提高的活性。另一方面，本发明还提供使用本发明的负载型茂金属催化剂体系聚合烯烃的方法。

2. 发明授权

US06992035B2 Metallocenes, polymerization catalyst systems, their preparation, and use 有权
公开(公告)号：US06992035B2
公开(公告)日：2006-01-31
申请号：US10251771
申请日：2002-09-23
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.

3. 发明授权

US06221981B1 Method for making and using a supported metallcene catalyst system 失效
标题翻译：制备和使用负载型金属催化剂体系的方法
公开(公告)号：US06221981B1
公开(公告)日：2001-04-24
申请号：US09152652
申请日：1998-09-14
申请人： Michael Jung , Helmut G. Alt , Bryan E. Hauger , M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Antoni Jurkiewicz
发明人： Michael Jung , Helmut G. Alt , Bryan E. Hauger , M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Antoni Jurkiewicz
IPC分类号： C08F444
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F4/65927
摘要： Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in a suitable liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.
摘要翻译：公开了用于制备高活性固体茂金属催化剂体系及其在烯烃聚合中的应用的方法。催化剂体系是通过在合适的液体中将铝氧烷与具有烯属不饱和键的取代基的茂金属组合形成液体催化剂体系，在液体催化剂体系中进行烯烃预聚合，并分离从反应混合物中得到固体茂金属的催化剂体系。还公开了使用本发明的固体催化剂体系的烯烃的聚合。

4. 发明授权

US06509427B1 Metallocenes, polymerization catalyst systems, their preparation, and use 有权
标题翻译：金属茂，聚合催化剂体系，其制备和用途
公开(公告)号：US06509427B1
公开(公告)日：2003-01-21
申请号：US09690858
申请日：2000-10-18
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： C08F202
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
摘要翻译：公开了具有由具有芳基取代基和末端不饱和烃基取代基的单个碳原子连接的两个环状二烯基的茂金属，由其制备的烯烃聚合催化剂体系，以及这种催化剂体系的用途。

5. 发明授权

US06384161B1 Method and catalyst system for producing polyolefins with broadened molecular weight distributions 失效
标题翻译：用于生产具有更宽分子量分布的聚烯烃的方法和催化剂体系
公开(公告)号：US06384161B1
公开(公告)日：2002-05-07
申请号：US09474864
申请日：1999-12-30
申请人： M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Bryan E. Hauger , David C. Rohlfing
发明人： M. Bruce Welch , David W. Dockter , Syriac J. Palackal , Bryan E. Hauger , David C. Rohlfing
IPC分类号： C08F402
CPC分类号： C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65927 , Y10S526/943 , C08F4/65916 , C08F2500/04 , C08F2500/12
摘要： The present invention provides a process for preparing a supported metallocene catalyst system that can be used to catalyze formation of polyolefins having a wide molecular weight range. In accordance with the process of the present invention, a first portion of an inorganic oxide is dried under a first set of conditions, wherein upon treatment with an organoaluminoxide and a metallocene, a first catalyst system is formed usable to produce a polyolefin product having a first molecular weight average distribution. A second portion of an inorganic oxide under a second set of conditions, wherein upon treatment with an organoaluminoxane and a metallocene, a second catalyst system is formed usable to produce polyolefin product having a second molecular weight distribution. An amount of the first portion is mixed with an amount of the second portion to produce a final inorganic oxide support. The final inorganic oxide support is combined with an organoaluminoxane and a metallocene to produce a supported metallocene catalyst system usable to catalyze formation of polyolefins with a broadened molecular weight average distribution. In another aspect, the present invention provides a process for polymerizing polyolefins using the inventive supported metallocene catalyst system. The process comprises preparing the final catalyst as mentioned above and then contacting an olefin with the final metallocene catalyst system under conditions supporting polymerization.
摘要翻译：本发明提供了一种制备负载型茂金属催化剂体系的方法，该体系可用于催化具有宽分子量范围的聚烯烃的形成。根据本发明的方法，在第一组条件下将无机氧化物的第一部分干燥，其中在用有机铝氧化物和茂金属处理时，形成可用于生产聚烯烃产品的第一催化剂体系，所述聚烯烃产物具有第一分子量平均分布。在第二组条件下的无机氧化物的第二部分，其中在用有机铝氧烷和茂金属处理时，形成可用于制备具有第二分子量分布的聚烯烃产物的第二催化剂体系。将第一部分的量与第二部分的量混合以产生最终的无机氧化物载体。最终的无机氧化物载体与有机铝氧烷和茂金属组合以产生可用于催化分子量平均分布扩大的聚烯烃形成的负载金属茂催化剂体系。另一方面，本发明提供使用本发明聚合聚烯烃的方法负载金属茂催化剂体系。该方法包括如上所述制备最终催化剂，然后在支持聚合的条件下使烯烃与最终茂金属催化剂体系接触。

6. 发明授权

US06187880B1 Process for producing an olefin polymer using a metallocene 有权
标题翻译：使用金属茂制备烯烃聚合物的方法
公开(公告)号：US06187880B1
公开(公告)日：2001-02-13
申请号：US09250963
申请日：1999-02-16
申请人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
发明人： M. Bruce Welch , Syriac J. Palackal , Bryan E. Hauger , David W. Dockter , Alexander Köppl , Helmut G. Alt
IPC分类号： C08F200
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6492 , C08F4/65927
摘要： Metallocene having two cyclic dienyl groups connected by a single carbon having an aryl substituent and a terminally unsaturated hydrocarbyl substituent, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
摘要翻译：公开了具有由具有芳基取代基和末端不饱和烃基取代基的单个碳原子连接的两个环状二烯基的茂金属，由其制备的烯烃聚合催化剂体系，以及这种催化剂体系的用途。

7. 发明授权

US08535448B2 Methods of removing a protective layer 有权
标题翻译：去除保护层的方法
公开(公告)号：US08535448B2
公开(公告)日：2013-09-17
申请号：US13180163
申请日：2011-07-11
申请人： Dennis L. Holtermann , Tin-Tack Peter Cheung , Christopher D. Blessing , Lawrence E. Huff , Joseph Bergmeister, III , Robert L. Hise , Geoffrey E. Scanlon , David W. Dockter
发明人： Dennis L. Holtermann , Tin-Tack Peter Cheung , Christopher D. Blessing , Lawrence E. Huff , Joseph Bergmeister, III , Robert L. Hise , Geoffrey E. Scanlon , David W. Dockter
IPC分类号： B08B9/00 , C23G1/02 , C23G1/00
CPC分类号： C23G5/024 , C10G35/065 , C10G35/09 , C23F1/12 , C23F1/44 , C23G1/02
摘要： A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer with one or more chemical removal agents to remove at least a portion of the metal protective layer from the reactor component. A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer to remove the metal protective layer from the reactor component, and determining a thickness of the reactor component following treatment.
摘要翻译：从反应器组件的表面去除金属保护层的方法，包括用一种或多种化学去除剂处理金属保护层以从反应器组分中去除金属保护层的至少一部分。从反应器组件的表面除去金属保护层的方法，包括处理金属保护层以从反应器组分除去金属保护层，以及确定处理后反应器部件的厚度。

8. 发明申请

US20130014780A1 Methods of Removing a Protective Layer 有权
标题翻译：去除保护层的方法
公开(公告)号：US20130014780A1
公开(公告)日：2013-01-17
申请号：US13180163
申请日：2011-07-11
申请人： Dennis L. HOLTERMANN , Tin-Tack Peter CHEUNG , Christopher D. BLESSING , Lawrence E. HUFF , Joseph BERGMEISTER, III , Robert L. HISE , Geoffrey E. SCANLON , David W. Dockter
发明人： Dennis L. HOLTERMANN , Tin-Tack Peter CHEUNG , Christopher D. BLESSING , Lawrence E. HUFF , Joseph BERGMEISTER, III , Robert L. HISE , Geoffrey E. SCANLON , David W. Dockter
IPC分类号： C23G1/00 , C23G1/02
CPC分类号： C23G5/024 , C10G35/065 , C10G35/09 , C23F1/12 , C23F1/44 , C23G1/02
摘要： A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer with one or more chemical removal agents to remove at least a portion of the metal protective layer from the reactor component. A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer to remove the metal protective layer from the reactor component, and determining a thickness of the reactor component following treatment.
摘要翻译：从反应器组件的表面去除金属保护层的方法，包括用一种或多种化学去除剂处理金属保护层以从反应器组分中去除金属保护层的至少一部分。从反应器组件的表面除去金属保护层的方法，包括处理金属保护层以从反应器组分除去金属保护层，以及确定处理后反应器部件的厚度。

9. 发明授权

US06620776B2 Detergent additive composition and processes therefore and therewith 失效
公开(公告)号：US06620776B2
公开(公告)日：2003-09-16
申请号：US10173615
申请日：2002-06-19
申请人： Mitchell D. Refvik , David W. Dockter
发明人： Mitchell D. Refvik , David W. Dockter
IPC分类号： C11D334
CPC分类号： C07C323/25 , C11D3/3427
摘要： A novel composition having the formula: wherein R1 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group, and R2 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. The composition is made by combining an amine compound, a carbonyl compound, a solvent, and a sulfur-containing compound. The composition is used as a detergent additive in cleaning process.

10. 发明授权

US06506721B1 Detergent additive composition and processes therefore and therewith 失效
标题翻译：因此，洗涤剂添加剂组合物和工艺
公开(公告)号：US06506721B1
公开(公告)日：2003-01-14
申请号：US09667654
申请日：2000-09-22
申请人： Mitchell D. Refvik , David W. Dockter
发明人： Mitchell D. Refvik , David W. Dockter
IPC分类号： C11D334
CPC分类号： C07C323/25 , C11D3/3427
摘要： A novel composition having the formula: wherein R1 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group, and R2 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. The composition is made by combining an amine compound, a carbonyl compound, a solvent, and a sulfur-containing compound. The composition is used as a detergent additive in cleaning process.
摘要翻译：一种具有下式的新型组合物：其中R 1选自含有1至20个碳原子的烷基和芳基，R 2选自含有1至20个碳原子的烷基和芳基。组合物通过将胺化合物，羰基化合物，溶剂和含硫化合物组合而制成。该组合物在清洁过程中用作洗涤剂添加剂。

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