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1. 发明授权

US07897539B2 Methods of preparing a polymerization catalyst 有权
标题翻译：制备聚合催化剂的方法
公开(公告)号：US07897539B2
公开(公告)日：2011-03-01
申请号：US11749663
申请日：2007-05-16
申请人： Max P. McDaniel , Elizabeth A. Benham , Randall S. Muninger
发明人： Max P. McDaniel , Elizabeth A. Benham , Randall S. Muninger
IPC分类号： B01J20/284 , C08F4/64 , C08F4/6592 , C08F4/02
CPC分类号： C08F10/00 , B01J21/04 , B01J27/053 , B01J35/1019 , B01J35/1047 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65922 , C08F4/025 , C08F2500/12
摘要： A method of preparing a composition comprising dry mixing commercial grade alumina and a solid sulfating agent to form a mixture and calcining the mixture to form a sulfated alumina support.
摘要翻译：一种制备组合物的方法，其包括将市售级氧化铝和固体硫酸盐干混，以形成混合物并煅烧所述混合物以形成硫酸化氧化铝载体。

2. 发明授权

US06239060B1 Supported metallocene catalyst system and method for polymerizing olefins 失效
标题翻译：负载金属茂催化剂体系及烯烃聚合方法
公开(公告)号：US06239060B1
公开(公告)日：2001-05-29
申请号：US09224176
申请日：1998-12-31
申请人： David W. Dockter , Bryan E. Hauger , M. Bruce Welch , Randall S. Muninger
发明人： David W. Dockter , Bryan E. Hauger , M. Bruce Welch , Randall S. Muninger
IPC分类号： B01J3502
CPC分类号： B01J31/1616 , B01J31/128 , B01J31/143 , B01J31/1608 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10S526/943 , C08F4/65916
摘要： The present invention provides a new type of supported metallocene catalyst system. In one aspect of the invention, an inorganic oxide support, such as silica, is impregnated with a Group XIII element such as B, Al or GA. The support is then contacted with a liquid catalyst system prepared by combining in a liquid an organo aluminoxane and a metallocene having two cyclopetadienyl-type ligands selected from substituted or unsubstituted cyclopentadienyl, indenyl, benzoindenyl, tetrahdroindenyl, benzofluorenyl, octahydrofluorenyl, and fluorenyl ligands to form a supported metallocene catalyst system. In preferred embodiments the process further includes conducting prepolymerization of at least one olefin in the presence of the supported metallocene catalyst system to produce a prepolymerized metallocene catalyst system. The prepolymerized metallocene catalyst system prepared in this manner yields substantially increased activity for the polymerization of olefins. In another aspect, the present invention also provides a method for polymerization of olefins using the inventive supported metallocene catalyst system.
摘要翻译：本发明提供一种新型的负载型茂金属催化剂体系。在本发明的一个方面，无机氧化物载体如二氧化硅用第ⅩⅢ族元素如B，Al或GA浸渍。然后将载体与通过在液体中组合有机铝氧烷和具有选自取代或未取代的环戊二烯基，茚基，苯并茚基，四氢茚基，苯并芴基，八氢芴基和芴基配体的两个环戊二烯基型配体的金属茂接触而形成的液体催化剂体系形成负载金属茂催化剂体系。在优选的实施方案中，该方法还包括在负载的茂金属催化剂体系的存在下进行至少一种烯烃的预聚合，以产生预聚合的茂金属催化剂体系。以这种方式制备的预聚合的茂金属催化剂体系产生了烯烃聚合的显着提高的活性。另一方面，本发明还提供使用本发明的负载型茂金属催化剂体系聚合烯烃的方法。

3. 发明申请

US20080287287A1 METHODS OF PREPARING A POLYMERIZATION CATALYST 有权
标题翻译：制备聚合催化剂的方法
公开(公告)号：US20080287287A1
公开(公告)日：2008-11-20
申请号：US11749663
申请日：2007-05-16
申请人： Max P. McDaniel , Elizabeth A. Benham , Randall S. Muninger
发明人： Max P. McDaniel , Elizabeth A. Benham , Randall S. Muninger
IPC分类号： B01J31/14 , C01B17/96 , C01F7/02
CPC分类号： C08F10/00 , B01J21/04 , B01J27/053 , B01J35/1019 , B01J35/1047 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65922 , C08F4/025 , C08F2500/12
摘要： A method of preparing a composition comprising dry mixing commercial grade alumina and a solid sulfating agent to form a mixture and calcining the mixture to form a sulfated alumina support.
摘要翻译：一种制备组合物的方法，其包括将市售级氧化铝和固体硫酸盐干混，以形成混合物并煅烧所述混合物以形成硫酸化氧化铝载体。

4. 发明授权

US06852660B2 Solid metallocene catalyst system 失效
公开(公告)号：US06852660B2
公开(公告)日：2005-02-08
申请号：US10348555
申请日：2003-01-21
申请人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
发明人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
IPC分类号： C08F2/00 , C08F4/06 , C08F4/42 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F110/02 , B01J31/16
CPC分类号： C08F110/02 , C08F4/6492 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： A solid metallocene-containing catalyst system of an organoaluminoxane, at least one metallocene having at least one olefinically unsaturated substituent and a polyolefin is disclosed. The polyolefin is formed from at least one olefin polymerized in the presence of a combination of a solution of the organoluminoxane in an aromatic liquid, the at least one metallocene, and an aliphatic liquid. The solid metallocene-containing catalyst system may also include one or more the particulate solids.

5. 发明授权

US06534609B2 Method for making and using a metallocene catalyst system 有权
公开(公告)号：US06534609B2
公开(公告)日：2003-03-18
申请号：US09805277
申请日：2001-03-13
申请人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
发明人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
IPC分类号： C08F442
CPC分类号： C08F110/02 , C08F4/6492 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in an aliphatic liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, preferably in multiple stages, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.

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