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    • 2. 发明授权
    • Morpholinones as light stabilizers
    • 吗啉酮作为光稳定剂
    • US06562815B1
    • 2003-05-13
    • US09639906
    • 2000-08-16
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • A61K315375
    • C07C229/12C07D265/32C08K5/357
    • The invention relates to new compounds containing 1-8 active groups of the type 3,3,6,6-polysubstituted 2-morpholinone and having the formula F (A′—Z)m—X  (F), wherein m is a number from 1 to 8; X is an organic anchor group of valency m and in case that m is not 1, X may also be a direct bond, SO2, P or PO; A′ is a monovalent group of the formula E  containing one linking group; Z is a direct bond, —O—, —S—, —SO—, —SO2— or —NR′14—; provided that Z is —O—, —S—, —SO—, —SO2— or —NR′14— if m is 1 and the linking group in formula E is G3 or G5; G1 is hydrogen; C1-C18alkyl; C2-C18alkyl substituted by OH and/or phenyl; oxyl; OH; C2-C12cyanoalkyl; C2-C12cyanoalkoxy; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C3-C8alkenyloxy; C7-C12phenylalkyl; C7-C12phenylalkyl substituted by hydroxy, C1-C4alkyl and/or C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted by C1-C4alkyl and/or C1-C4alkoxy; or G1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; C3-C8epoxyalkyl; or G1 is the linking group —R10—; G2 and G4 are, independently of one another, C1-C18alkyl, C5-C12cycloalkenyl, C5-C12cycloalkyl, or an oligocyclic hydrocarbon residue of 6-12 carbon atoms; G3 is as defined for G2 or is C1-C8hydroxyalkyl; or G2 and G3 together are (CH2)e, where e is a number from 4 to 11; or G3 is the linking group —R5—; G5 is as defined for G4 or is C1-C8hydroxyalkyl; or G4 and G5 together are (CH2)e, where e is a number from 4 to 11; or G5 is the linking group —R5—; G6 is as defined for G4 or is hydrogen; or G6 is the linking group, which is a direct bond or —R5—; and other residues are as defined in claim 1. The new compounds are effective as stabilizers for organic material, especially coatings, against harmful effects of light, oxygen and/or heat.
    • 本发明涉及含有1,3,6,6-三取代的2-吗啉酮类型的1-8个活性基团并具有式F的新化合物,其中m为1至8的数; X为化合价m 并且在m不为1的情况下,X也可以是直接键合,SO 2,P或PO; A'是含有一个连接基团的式E的一价基团; Z是直接键,-O-,-S - , - SO - , - SO2-或-NR'14-; 条件是如果m是1,则Z是-O - , - S - , - SO - , - SO 2 - 或-NR'14-,式E中的连接基团是G 3或G 5; G 1是氢; C1-C18烷基; 由OH和/或苯基取代的C 2 -C 18烷基; 氧基 哦; C 2 -C 12氰基烷基; C2-C12氰基烷氧基; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C3-C8链烯氧基; C7-C12苯基烷基; 被羟基,C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 12苯基烷基; C7-C15苯基烷氧基; 被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 15苯基烷氧基; 或G1是C1-C8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; C3-C8环氧烷基; 或G1是连接基团-R10-; G 2和G 4彼此独立地是C 1 -C 18烷基,C 5 -C 12环烯基,C 5 -C 12环烷基或6-12个碳原子的低聚烃残基; G3如对于G2 或是C 1 -C 8羟烷基; 或G2和G3一起为(CH 2)e,其中e为4至11的数; 或G3是连接基团-R5-; G5如G4所定义或是C 1 -C 8羟烷基; 或G4和G5一起为(CH 2)e,其中e为4至11的数; 或G5为连接基团-R5-; G6如G4所定义或是氢;或G6是连接基团,其是直接键或-R 5 - ;其它残基如权利要求1中所定义。该新化合物作为有机材料的稳定剂是有效的,特别是涂料 ,防止光,氧和/或热的有害影响。
    • 5. 发明授权
    • Polyglycidyl compounds
    • 聚缩水甘油基化合物
    • US06169158A
    • 2001-01-02
    • US09298573
    • 1999-04-23
    • Christoph RickertHugh Stephen Laver
    • Christoph RickertHugh Stephen Laver
    • C08G5902
    • C09D163/00C08G59/3218C08G59/3254C09D167/00Y10S525/934C08L2666/04C08L63/00C08L2666/18
    • The present invention is directed to a polyglycidyl compound having on average more than two, preferably more than two and a half, particularly preferably more than three, glycidyl groups per molecule and a Tg value (determined by DSC, heating rate=20° C./min) higher than 20° C., based on a polyfunctional 1,1′-spirobisindane of formula I or on a mixture of different polyfunctional 1,1′-spirobisindanes of the general formula I wherein Z is a direct single bond or —O—; more than two of R1, R2, R3 and R4 are —OH, —O—CO—R—CO—OH, —O—R—OH, —O—CO—NH—R—NH—CO—O—R—OH or —[O—CmH2m]n—OH, with the proviso that R1, R2, R3 and R4 are not —OH when Z is a direct single bond, wherein m is an integer from 2 to 4, n is an integer from 1 to 20, and R is C1-C8alkylene, C5-C8cycloalkylene, C6-C14arylene or partially hydrated C6-C14arylene, and the remaining R1, R2, R3 and R4 are a hydrogen atom or —O—C1-C8alkyl, —O—C5-C8cycloalkyl, —O—C6-C14aryl, partially hydrated —O—C6-C14aryl or (meth)acrylate; and R5, R6, R7 and R8 are each independently of one another C1-C8alkyl, C5-C8cycloalkyl, C6-C14aryl, partially hydrated C6-C14aryl or a hydrogen atom, for the production of moulded articles, coatings, matrix materials or adhesives. Also disclosed is the reaction product of a polyglycidyl compound based on a polyfunctional 1,1′-spirobisindane or mixture thereof with a less than stoichiometric amount of a compound containing two substitutents reacting with epoxy groups.
    • 本发明涉及每分子平均具有两个以上,优选多于两个半,特别优选多于三个缩水甘油基的聚缩水甘油基化合物,Tg值(通过DSC测定,加热速率= 20℃) /分钟),基于式I的多官能1,1'-螺双茚满或通式I的不同多官能1,1'-螺双茚满的混合物,其中Z是直接单键或-O- R1,R2,R3和R4中的两个以上是-OH,-O-CO-R-CO-OH,-OR-OH,-O-CO-NH-R-NH-CO-OR-OH或 - [O-CmH2m] n-OH,条件是当Z是直接单键时,R 1,R 2,R 3和R 4不是-OH,其中m是2至4的整数,n是1至20的整数, 并且R为C1-C8亚烷基,C5-C8亚环烷基,C6-C14亚芳基或部分水合的C6-C14芳烯,其余R1,R2,R3和R4为氢原子或-O-C1-C8烷基,-O-C5-C8环烷基,-O -C6-C14芳基,部分水合的-O-C6-C14芳基或(甲基)丙烯酸酯;和R5,R6,R7和 R 8各自独立地为C 1 -C 8烷基,C 5 -C 8环烷基,C 6 -C 14芳基,部分水合的C 6 -C 14芳基或氢原子,用于制备模制品,涂料,基质材料或粘合剂。 还公开了基于多官能1,1'-螺二茚满或其混合物的多缩水甘油基化合物与少于化学计量的含有两个与环氧基反应的取代基的化合物的反应产物。
    • 6. 发明授权
    • Morpholinones as light stabilizers
    • 吗啉酮作为光稳定剂
    • US6140326A
    • 2000-10-31
    • US152985
    • 1998-09-14
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • C07C229/12C07D265/32C07D403/12C07D413/10C07D413/12C07D413/14C08K5/357C08L101/00C09K15/30A61K31/535C07D265/00C07D265/30
    • C07C229/12C07D265/32C08K5/357
    • The invention relates to new compounds containing 1-8 active groups of the type 3,3,6,6-polysubstituted 2-morpholinone and having the formula F(A'--Z).sub.m --X (F),wherein m is a number from 1 to 8;X is an organic anchor group of valency m and in case that m is not 1, X may also be a direct bond, SO.sub.2, P or PO;A' is a monovalent group of the formula E ##STR1## containing one linking group; Z is a direct bond, --O--, --S--, --SO--, --SO.sub.2 -- or --NR'.sub.14 --; provided that Z is --O--, --S--, --SO--, --SO.sub.2 -- or --NR'.sub.14 -- if m is 1 and the linking group in formula E is G.sub.3 or G.sub.5 ;G.sub.1 is hydrogen; C.sub.1 -C.sub.18 alkyl; C.sub.2 -C.sub.18 alkyl substituted by OH and/or phenyl; oxyl; OH; C.sub.2 -C.sub.12 cyanoalkyl; C.sub.2 -C.sub.12 cyanoalkoxy; C.sub.1 -C.sub.18 alkoxy; C.sub.5 -C.sub.12 cycloalkoxy; C.sub.3 -C.sub.8 alkenyl; C.sub.3 -C.sub.8 alkynyl; C.sub.3 -C.sub.8 alkenyloxy; C.sub.7 -C.sub.12 phenylalkyl; C.sub.7 -C.sub.12 phenylalkyl substituted by hydroxy, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy; C.sub.7 -C.sub.15 phenylalkoxy; C.sub.7 -C.sub.15 phenylalkoxy, which is substituted by C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy; or G.sub.1 is C.sub.1 -C.sub.8 alkanoyl; C.sub.3 -C.sub.5 alkenoyl; C.sub.1 -C.sub.18 alkanoyloxy; C.sub.3 -C.sub.8 epoxyalkyl; or G.sub.1 is the linking group --R.sub.10 --;G.sub.2 and G.sub.4 are, independently of one another, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkenyl, C.sub.5 -C.sub.12 cycloalkyl, or an oligocyclic hydrocarbon residue of 6-12 carbon atoms;G.sub.3 is as defined for G.sub.2 or is C.sub.1 -C.sub.8 hydroxyalkyl; or G.sub.2 and G.sub.3 together are (CH.sub.2).sub.e, where e is a number from 4 to 11; or G.sub.5 is the linking group --R.sub.5 --;G.sub.5 is as defined for G.sub.4 or is C.sub.1 -C.sub.8 hydroxyalkyl; or G.sub.4 and G.sub.5 together are (CH.sub.2).sub.e, where e is number from 4 to 11; or G.sub.5 is the linking group --R.sub.5 --; G.sub.6 is as defined for G.sub.4 or is hydrogen;or G.sub.6 is the linking group, which is a direct bond or --R.sub.5 --;and other residues are as defined in claim 1. The new compounds are effective as stabilizers for organic material, especially coatings, against harmful effects of light, oxygen and/or heat.
    • 本发明涉及含有1,3,6,6-三取代的2-吗啉酮类的1-8个活性基团并具有式F(A'-Z)mX(F)的新化合物,其中m是1 到8 X是化合价m的有机锚定基团,在m不为1的情况下,X也可以是直接键合,SO 2,P或PO; A'是含有一个连接基团的式E的单价基团; Z是直接键,-O - , - S - , - SO - , - SO2-或-NR'14-; 条件是Z为-O - , - S - , - SO - , - SO 2 - 或-NR'14-,如果m为1且式E中的连接基团为G3或G5; G1是氢; C 1 -C 18烷基; 由OH和/或苯基取代的C 2 -C 18烷基; 氧基 哦; C 2 -C 12氰基烷基; C2-C12氰基烷氧基; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C3-C8链烯氧基; C7-C12苯基烷基; 被羟基,C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 12苯基烷基; C7-C15苯基烷氧基; 被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 15苯基烷氧基; 或G1是C1-C8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; C3-C8环氧烷基; 或G1是连接基团-R10-; G2和G4彼此独立地为C 1 -C 18烷基,C 5 -C 12环烯基,C 5 -C 12环烷基或6-12个碳原子的低聚烃残基; G3如对于G2所定义或为C1-C8羟烷基; 或G2和G3一起为(CH 2)e,其中e为4至11的数; 或G5为连接基团-R5-; G5如G4所定义或是C 1 -C 8羟烷基; 或G4和G5一起为(CH 2)e,其中e为4至11; 或G5为连接基团-R5-; G6如G4所定义或为氢; 或G6是连接基团,其是直接键或-R 5 - ; 和其它残基如权利要求1中所定义。新化合物作为有机材料的稳定剂,特别是涂料,有效地防止光,氧和/或热的有害影响。