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    • 6. 发明授权
    • Antireflective bi-layer hardmask including a densified amorphous carbon layer
    • 包括致密非晶碳层的抗反射双层硬掩模
    • US06900002B1
    • 2005-05-31
    • US10299427
    • 2002-11-19
    • Marina V. PlatMarilyn I. WrightLu YouScott A. Bell
    • Marina V. PlatMarilyn I. WrightLu YouScott A. Bell
    • G03F7/00G03F7/09H01L21/027H01L21/3105H01L21/3213
    • H01L21/32139G03F7/091H01L21/0276H01L21/31058
    • An amorphous carbon layer of an antireflective bi-layer hardmask is processed to increase its density prior to patterning of an underlying polysilicon layer using the bi-layer hardmask. The increased density of the layer increases its resistance to polysilicon etch chemistry, thus reducing the likelihood of patterning inaccuracies resulting from amorphous carbon depletion during polysilicon etch, and enabling the patterning of thicker polysilicon layers than can be reliably patterned without densification. The increased density also reduces stresses, thus reducing the likelihood of delamination. Densification may be performed by UV or e-beam irradiation after formation of an overlying protective layer. Densification may also be performed by annealing the amorphous carbon layer in situ prior to formation of the overlying protective layer. In the latter case, annealing reduces the amount of outgassing that occurs during formation of the protective layer, thus reducing the formation of pin holes.
    • 在使用双层硬掩模对下面的多晶硅层进行图案化之前,处理抗反射双层硬掩模的无定形碳层以增加其密度。 层的增加的密度增加了其对多晶硅蚀刻化学性质的抵抗力,从而降低了在多晶硅蚀刻期间由无定形碳耗尽导致的不准确图案的可能性,并且使得能够在不致密化的情况下可靠地图案化更厚的多晶硅层的图案化。 增加的密度也降低了应力,从而降低了分层的可能性。 在形成上覆保护层之后,可以通过UV或电子束照射进行致密化。 还可以通过在形成上覆保护层之前将非晶碳层原位退火来进行致密化。 在后一种情况下,退火减少了在形成保护层期间发生的除气量,从而减少了针孔的形成。
    • 7. 发明授权
    • L-shaped spacer incorporating or patterned using amorphous carbon or CVD organic materials
    • 使用无定形碳或CVD有机材料结合或图案化的L形间隔物
    • US06893967B1
    • 2005-05-17
    • US10755911
    • 2004-01-13
    • Marilyn I. WrightDouglas J. BonserLu YouKay Hellig
    • Marilyn I. WrightDouglas J. BonserLu YouKay Hellig
    • H01L29/72
    • H01L29/6656
    • A multilayer L-shaped spacer is formed of a lower portion comprising a CVD organic material or amorphous carbon, and an upper portion comprised of a protective material. The upper portion is patterned using a photoresist mask. During that patterning, the underlying substrate is protected by a layer of CVD organic material or amorphous carbon. The CVD organic material or amorphous carbon is then patterned using the patterned protective material as a mask. The chemistry used to pattern the CVD organic material or amorphous carbon is relatively harmless to the underlying substrate. Alternatively, an L-shaped spacer is patterned without using a photoresist mask by forming an amorphous carbon spacer around a gate that is covered with a conformal layer of a conventional spacer material. The conventional spacer material is patterned using the amorphous carbon spacer as an etch mask. The amorphous carbon spacer is easily formed without the need for lithographic patterning, and therefore this method is preferable to methods using photoresist masks.
    • 多层L型间隔件由包含CVD有机材料或无定形碳的下部和由保护材料构成的上部形成。 使用光致抗蚀剂掩模对上部进行图案化。 在该图案化期间,下面的衬底被CVD有机材料层或无定形碳保护。 然后使用图案化的保护材料作为掩模对CVD有机材料或无定形碳进行图案化。 用于对CVD有机材料或无定形碳进行图案化学的化学物质对于底层基材相对无害。 或者,通过在被常规间隔物材料的共形层覆盖的栅极周围形成无定形碳隔离物,将L形间隔物图案化而不使用光致抗蚀剂掩模。 使用无定形碳间隔物作为蚀刻掩模来对传统的间隔物材料进行图案化。 非晶碳隔离物容易地形成而不需要平版印刷图案,因此该方法优于使用光致抗蚀剂掩模的方法。