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    • 10. 发明专利
    • Composite metallic glass hydrogen separation membrane and manufacturing method therefor
    • 复合金属玻璃氢分离膜及其制造方法
    • JP2008264775A
    • 2008-11-06
    • JP2008077292
    • 2008-03-25
    • Fukuda Metal Foil & Powder Co LtdTohoku Univ国立大学法人東北大学福田金属箔粉工業株式会社
    • SHINPO YOICHIRONISHIDA MOTONORIYAMAMOTO KOICHIISHIDA MINEOKAJITA OSAMUINOUE AKIHISAKIMURA HISAMICHIYAMAURA SHINICHI
    • B01D71/02C01B3/56
    • PROBLEM TO BE SOLVED: To provide a composite metallic glass hydrogen separation membrane with excellent hydrogen permeability and hydrogen embrittlement resistance, and a manufacturing method therefor.
      SOLUTION: The hydrogen separation membrane is composed of a composite structure in which Nb, Ta, V and Ti particles with excellent hydrogen permeability are dispersed in a metallic glass matrix which has an amorphous structure with excellent hydrogen embrittlement resistance, and the hydrogen separation membrane contains at least one kind of elements with the excellent permeability to 5 to 80 wt.%. The manufacturing method therefor is characterized by using a powder metallurgical method and comprises: a step where metallic glass powder to be a matrix and additive elements such as Nb are mixed, the resulting mixture is heated at a temperature near the supercooled liquid region of the metallic glass, and compressed to manufacture a composite metallic glass bulk material; and step where the bulk material is thinned by rolling or the like at the temperature near the supercooled liquid region further.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有优异的氢渗透性和耐氢脆性的复合金属玻璃氢分离膜及其制造方法。 解决方案:氢分离膜由复合结构组成,其中具有优异氢渗透性的Nb,Ta,V和Ti颗粒分散在具有优异的耐氢脆性的非晶结构的金属玻璃基体中,氢 分离膜含有至少一种具有优异渗透性的元素至5至80重量%。 其制造方法的特征在于使用粉末冶金方法,包括:将金属玻璃粉末作为基质和添加元素如Nb混合的步骤,将所得混合物在接近金属的过冷液体区域的温度下加热 玻璃,并压缩以制造复合金属玻璃块状材料; 以及在过冷液体区域附近的温度下通过轧制等使体积材料变薄的步骤。 版权所有(C)2009,JPO&INPIT