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1. 发明授权

US4927526A Octane improvement of gasoline in catalytic cracking without decreasing total liquid yield 失效
标题翻译：汽油在催化裂化中的辛烷值改善，而不降低总液体产率
公开(公告)号：US4927526A
公开(公告)日：1990-05-22
申请号：US187099
申请日：1988-06-28
申请人： Conroy D. Anderson , Tai-Sheng Chou , William E. Cormier, Jr. , Francis G. Dwyer , Frederick J. Krambeck , Gary M. Pasquale , Paul H. Schipper , William A. Stover
发明人： Conroy D. Anderson , Tai-Sheng Chou , William E. Cormier, Jr. , Francis G. Dwyer , Frederick J. Krambeck , Gary M. Pasquale , Paul H. Schipper , William A. Stover
IPC分类号： B01J29/08 , B01J29/40 , B01J29/80 , B01J29/90 , C10G11/05 , C10G11/16 , C10G11/18
CPC分类号： B01J29/40 , B01J29/80 , B01J29/90 , C10G11/05 , C10G11/16 , C10G11/18 , C10G11/187 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/084
摘要： Modified ZSM-5 type zeolite catalyst is prepared by controlled aging in a moving bed catalytic cracking unit. The modified catalyst exhibits significant olefin isomerization activity and reduced paraffin cracking activity. Hydrocarbons are cracked to products boiling in the motor fuel range, e.g., gasoline, by using the modified catalyst mixture comprising a ZSM-5 type zeolite and a conventional cracking catalyst. The ZSM-5 type zeolite is treated with partial pressure steam under conditions which increase the gasoline octane number of the product fuel without decreasing gasoline plus distillate yield. A process for changing a catalytic cracking unit's inventory from a conventional catalyst to a modified ZSM-5 type containing catalyst is also disclosed.
摘要翻译：改性ZSM-5型沸石催化剂是通过在移动床催化裂化装置中控制老化来制备的。改性催化剂表现出显着的烯烃异构化活性和降低的链烷烃裂解活性。通过使用包含ZSM-5型沸石和常规裂化催化剂的改性催化剂混合物，将碳氢化合物裂解成在发动机燃料范围内沸腾的产物，例如汽油。在增加产品燃料的汽油辛烷值但不降低汽油加馏出物产率的条件下，用分压蒸汽处理ZSM-5型沸石。还公开了将催化裂化装置的库存从常规催化剂改变为含改性ZSM-5的催化剂的方法。

2. 发明授权

US4375458A Synthesis of large crystallite zeolites 失效
标题翻译：大型微晶沸石的合成
公开(公告)号：US4375458A
公开(公告)日：1983-03-01
申请号：US304725
申请日：1981-09-23
申请人： Francis G. Dwyer , Pochen Chu , William E. Cormier, Jr.
发明人： Francis G. Dwyer , Pochen Chu , William E. Cormier, Jr.
IPC分类号： B01J29/40 , B01J29/65 , B01J29/70 , C01B33/28
CPC分类号： C01B33/2876 , B01J29/40 , B01J29/65 , B01J29/70 , Y10S423/22 , Y10S423/23 , Y10S423/29 , Y10S423/33
摘要： The invention provides a method of making large crystallite zeolites by a method comprising forming the zeolite in a medium containing a combination of two different alkylammonium cations or a combination of an alkylammonium cation and a metallic cation. In the combination at least one of the cations will have an ionic radius of from about 1.40 to the pore size of the specific zeolite.
摘要翻译：本发明提供了一种通过包括在含有两种不同烷基铵阳离子或烷基铵阳离子和金属阳离子的组合的介质中形成沸石的方法来制备大型微晶沸石的方法。在组合中，至少一个阳离子的离子半径将比特定沸石的孔径大约为1.40。

3. 发明授权

US5182090A Synthesis of large crystal size ZSM-5 失效
标题翻译：大尺寸ZSM-5的合成
公开(公告)号：US5182090A
公开(公告)日：1993-01-26
申请号：US839731
申请日：1992-02-19
申请人： Francis G. Dwyer , Pochen Chu , William E. Cormier, Jr.
发明人： Francis G. Dwyer , Pochen Chu , William E. Cormier, Jr.
IPC分类号： B01J29/40 , B01J29/65 , B01J29/70 , B01J31/02 , C01B37/02 , C01B39/40 , C09D11/02
CPC分类号： B01J31/0254 , B01J29/40 , B01J31/0239 , C01B33/2876 , C01B37/02 , C01B39/40 , C09D11/03 , B01J29/65 , B01J29/70 , Y10S423/22
摘要： There is provided a method for making large crystal size ZSM-5. This method involves the use of two organic cations, specifically tetrapropylammonium (TPA) and tetramethylammonium (TMA) cations, in the reaction mixture. This method further involves the use of a source of deliberately added alumina, such as aluminum sulfate, in the reaction mixture.
摘要翻译：提供了制造大型晶体尺寸ZSM-5的方法。该方法涉及在反应混合物中使用两种有机阳离子，特别是四丙基铵（TPA）和四甲基铵（TMA）阳离子。该方法还涉及在反应混合物中使用有意添加的氧化铝源，例如硫酸铝。

4. 发明授权

US5254767A Highly siliceous porous crystalline material and its use in conversion of oxygenates 失效
标题翻译：高度硅质多孔结晶材料及其在含氧化合物转化中的应用
公开(公告)号：US5254767A
公开(公告)日：1993-10-19
申请号：US623585
申请日：1984-06-22
申请人： Francis G. Dwyer
发明人： Francis G. Dwyer
IPC分类号： B01J29/70 , C07C2/12 , C10G45/64 , C07C1/20
CPC分类号： B01J29/7042 , C07C2/12 , C10G3/49 , C10G3/57 , C07C2529/70 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/02 , Y02P30/20
摘要： A new zeolite, designated ZSM-22, is disclosed and claimed. The new zeolite has the composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(x)Q.sub.2 O:(y)M.sub.2/n O:(z)L.sub.2 O.sub.3 :100SiO.sub.2wherein Q.sub.2 O is the oxide form of an organic compound containing an element of Group 5-B (as defined in the Table of the Elements--National Bureau of Standards, Fischer Scientific Co. Catalog No. 5-702-10), e.g., N or P, preferably N, containing at least one alkyl or aryl group having at least 2 carbon atoms, M is an alkali or alkaline earth metal having a valence n, e.g., Na, K, Cs or Li and wherein x=0.01-2.0, y=0-2.0, z=0-5, and L=Al. The zeolite is useful in the process of catalytic conversion of alcohols and/or oxygenates to gasoline-grade hydrocarbons.
摘要翻译：公开并要求保护名为ZSM-22的新型沸石。新型沸石的组成为无水状态，以氧化物的摩尔比表示如下：（x）Q2O：（y）M2 / nO：（z）L2O3：100SiO2其中Q2O是有机物的氧化物形式含有5-B族元素的化合物（如元素 - 国家标准局表，Fischer Scientific Co.目录号5-702-10中所定义），例如N或P，优选N，至少含有一个具有至少2个碳原子的烷基或芳基，M是价数n的碱金属或碱土金属，例如Na，K，Cs或Li，其中x = 0.01-2.0，y = 0-2.0，z = 0-5，L = Al。沸石可用于将醇和/或含氧化合物催化转化成汽油级烃的方法。

5. 发明授权

US5254322A Method for reducing automotive NO.sub.x emissions in lean burn internal combustion engine exhaust using a transition metal-containing zeolite catalyst which is in-situ crystallized 失效
标题翻译：使用原位结晶的含过渡金属的沸石催化剂来减少贫燃内燃机废气中的汽车NOx排放的方法
公开(公告)号：US5254322A
公开(公告)日：1993-10-19
申请号：US927108
申请日：1992-08-10
申请人： Nazeer A. Bhore , Francis G. Dwyer , David O. Marler , John P. McWilliams
发明人： Nazeer A. Bhore , Francis G. Dwyer , David O. Marler , John P. McWilliams
IPC分类号： F01N3/24 , B01D53/56 , B01D53/86 , B01D53/94 , B01J29/40 , B01J29/44 , B01J29/46 , B01J29/48 , B01J8/00 , B01D47/00 , C01B21/00
CPC分类号： B01J29/46 , B01D53/9418 , B01J29/40 , B01D2251/208 , B01D2255/204 , B01D2255/20761 , B01D2255/504 , Y02T10/24
摘要： A method is provided for reducing NO.sub.x for high flow applications such as NO.sub.x abatement in an exhaust gas from an internal combustion engine operating under lean burn conditions wherein NO.sub.x is reduced by hydrocarbon reductants. The method employs a hydrothermally stable catalyst comprising transition metal-containing ZSM-5 which is prepared by in-situ crystallization of an aggregate comprising ZSM-5 seeds, silica, and a crystalline silicate.
摘要翻译：提供了一种用于减少用于高流量应用的NOx的方法，例如来自在贫燃条件下运行的内燃机的废气中的NOx的减少，其中NOx由烃还原剂还原。该方法采用包含含过渡金属的ZSM-5的水热稳定催化剂，其通过包含ZSM-5种子，二氧化硅和结晶硅酸盐的骨料的原位结晶而制备。

6. 发明授权

US4552648A Fluidized catalytic cracking process 失效
标题翻译：流化催化裂化工艺
公开(公告)号：US4552648A
公开(公告)日：1985-11-12
申请号：US577941
申请日：1984-02-08
申请人： Edward J. Rosinski , Albert B. Schwartz , Francis G. Dwyer
发明人： Edward J. Rosinski , Albert B. Schwartz , Francis G. Dwyer
IPC分类号： B01J29/08 , B01J29/40 , B01J29/80 , C10G11/05
CPC分类号： B01J29/80 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/08 , B01J29/084
摘要： A process for catalytically cracking a hydrocarbon feed in a reaction zone under catalytic cracking conditions in the absence of added hydrogen with a catalyst comprising a conventional cracking catalyst. The improvement comprises adding to the conventional cracking catalyst a thermally treated zeolite having a mole ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of about 10:1 to 100:1 and a constraint index of about 1 to 12. Thermal treatment reduces the additive zeolite's alpha activity to about 1 to 10 prior to use.
摘要翻译：在催化裂化条件下，在没有加入氢气的情况下，用含有常规裂化催化剂的催化剂，在反应区中催化裂化烃原料的方法。改进包括向常规裂化催化剂中加入具有约10:1至100:1摩尔比的SiO 2 :Al 2 O 3的热处理沸石，约1至12的约束指数。热处理将添加沸石的α活性降低至约使用前1至10。

7. 发明授权

US4049737A Propylation of toluene 失效
标题翻译：甲苯的丙基化
公开(公告)号：US4049737A
公开(公告)日：1977-09-20
申请号：US614731
申请日：1975-09-18
申请人： Francis G. Dwyer , Donald J. Klocke
发明人： Francis G. Dwyer , Donald J. Klocke
IPC分类号： C07C2/66 , C07C3/52
CPC分类号： C07C2/66 , C07C2521/04 , C07C2529/40
摘要： Propylation of toluene with selective production of cymene is accomplished by vapor phase reaction of toluene and propylene at a temperature between about 400.degree. and about 600.degree. F. in the presence of a catalyst comprising a crystalline aluminosilicate zeolite, said zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12.
摘要翻译：在选择性生产甲基异丙苯的情况下甲苯的丙基化是通过在包含结晶硅铝酸盐沸石的催化剂存在下，在约400至约600°F之间的温度下，甲苯和丙烯的气相反应完成的，所述沸石具有二氧化硅与氧化铝至少约12的比例和如下文所定义的约束指数在1至12的近似范围内。

8. 发明授权

US4526879A Synthesis of zeolite ZSM-5 失效
标题翻译：沸石ZSM-5的合成
公开(公告)号：US4526879A
公开(公告)日：1985-07-02
申请号：US520746
申请日：1983-08-05
申请人： Francis G. Dwyer , Pochen Chu
发明人： Francis G. Dwyer , Pochen Chu
IPC分类号： B01J29/40 , C01B39/40 , C01B33/28
CPC分类号： C01B39/40 , B01J29/40 , B01J2229/26 , B01J2229/42 , Y10S423/22
摘要： As synthesized by conventional technique, zeolite ZSM-5 is crystallized in the presence of substantial amount of tetraalkylammonium cations, the alkyl groups of which contain 2 to 5 carbon atoms, such as, for example, tetrapropylammonium. When synthesized in the conventional way, ZSM-5 contains tetraalkylammonium cations as well as a substantial amount of sodium ions. To obtain a more catalytically active form of ZSM-5, the sodium ions must be exchanged to very low levels. By synthesizing zeolite ZSM-5 according to the present method, i.e., in the presence of a combination of an amine and a halide in the presence of a mutual solvent and with a specifically defined reaction mixture composition, ZSM-5 having different organic nitrogen-containing cations but the same crystal structure as conventionally prepared ZSM-5 is obtained. The ZSM-5 prepared in accordance herewith is very low in sodium content as synthesized and has a crystal size of from about 0.05 microns to about 20 microns.
摘要翻译：如通过常规技术合成的，沸石ZSM-5在存在大量四烷基铵阳离子（其烷基含有2至5个碳原子的四烷基铵阳离子）存在下结晶，例如四丙基铵。当以常规方式合成时，ZSM-5含有四烷基铵阳离子以及大量的钠离子。为了获得更具催化活性的ZSM-5形式，钠离子必须交换到非常低的水平。通过根据本发明的方法合成沸石ZSM-5，即在相互溶剂存在下，在胺和卤化物的组合存在下，与特定定义的反应混合物组合物，具有不同有机氮气的ZSM-5，得到与常规制备的ZSM-5相同的晶体结构。根据本文制备的ZSM-5的钠含量非常低，并且具有约0.05微米至约20微米的晶体尺寸。

9. 发明授权

US4513092A Composite catalyst for halogenation and condensation of alkanes 失效
标题翻译：用于烷烃卤化和缩合的复合催化剂
公开(公告)号：US4513092A
公开(公告)日：1985-04-23
申请号：US594583
申请日：1984-03-29
申请人： Pochen Chu , Francis G. Dwyer
发明人： Pochen Chu , Francis G. Dwyer
IPC分类号： C07C1/26 , B01J29/76 , B01J37/04 , C07B61/00 , C07C1/00 , C07C17/00 , C07C17/10 , C07C17/152 , C07C17/154 , C07C67/00 , B01J29/30
CPC分类号： B01J37/04 , C07C17/10 , C07C17/152
摘要： A dual-function chlorination-condensation catalyst composition consisting essentially of (a) Deacon-type catalyst comprising cupric halide, alkaline earth halide and/or alkali metal halide, and/or rare earth metal halide and (b) crystalline aluminosilicate zeolite catalyst, such as ZSM-5 type.
摘要翻译：一种双功能氯化 - 缩合催化剂组合物，主要由（a）包含卤化铜，碱土金属卤化物和/或碱金属卤化物和/或稀土金属卤化物和（b）结晶硅铝酸盐沸石催化剂的Deacon型催化剂组成，作为ZSM-5型。

10. 发明授权

US4410452A Method of preparation of composite zeolite catalysts 失效
标题翻译：复合沸石催化剂的制备方法
公开(公告)号：US4410452A
公开(公告)日：1983-10-18
申请号：US375078
申请日：1982-05-05
申请人： Pochen Chu , Francis G. Dwyer , Albin Huss
发明人： Pochen Chu , Francis G. Dwyer , Albin Huss
IPC分类号： B01J29/40 , B01J29/65 , B01J29/70 , B01J37/06 , B01J29/06 , B01J29/28
CPC分类号： B01J29/40 , B01J37/06 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： A method of removing the organic cation from an organic cation-containing zeolite which comprises contacting the zeolite at low temperatures with an aqueous sodium hypochlorite solution.
摘要翻译：一种从含有机阳离子的沸石中除去有机阳离子的方法，其包括在低温下使沸石与次氯酸钠水溶液接触。

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