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1. 发明授权

US5248727A Vinyl chloride polymer based moulding compositions with reduced fogging 失效
标题翻译：基于氯乙烯聚合物的模塑组合物具有减少的雾化
公开(公告)号：US5248727A
公开(公告)日：1993-09-28
申请号：US892397
申请日：1992-05-18
申请人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
发明人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
IPC分类号： C08F2/26 , C08F291/02 , C08L27/06
CPC分类号： C08F291/02 , C08F2/26 , C08L27/06
摘要： Thermoplastic molding compositions of a vinyl chloride polymer and one or more emulsion polymers made with special emulsifiers have improved properties for technical application, such as reduced fogging. They are used for the production of molded articles, sheet products and films.
摘要翻译：氯乙烯聚合物和由特殊乳化剂制成的一种或多种乳液聚合物的热塑性模塑组合物具有改进的技术应用性能，例如减少雾化。它们用于生产模制品，片材和薄膜。

2. 发明授权

US5041485A Stabilizer dispersions 失效
标题翻译：稳定剂分散体
公开(公告)号：US5041485A
公开(公告)日：1991-08-20
申请号：US556622
申请日：1990-07-23
申请人： Herbert Eichenauer , Karl-Erwin Piejko , Christian Lindner , Adolf Schmidt , Karl-Heinz Ott
发明人： Herbert Eichenauer , Karl-Erwin Piejko , Christian Lindner , Adolf Schmidt , Karl-Heinz Ott
IPC分类号： B01F17/00 , B01F17/36 , C08K5/00 , C08K9/04
CPC分类号： C08K5/00 , C08K5/005
摘要： Dispersions of stabilizers for plastics in water which contain special reaction products of diols and carboxylic acid anhydrides as auxiliary emulsifiers, and which are characterized by simple preparation, stability and good effectiveness in chemical materials.
摘要翻译：塑料在水中的分散体含有二醇和羧酸酐作为辅助乳化剂的特殊反应产物，其特征在于制备简单，稳定性和化学物质的有效性。

3. 发明授权

US5674939A ABS moulding compounds with novel morphology 失效
标题翻译： ABS模塑料具有新颖的形态
公开(公告)号：US5674939A
公开(公告)日：1997-10-07
申请号：US557359
申请日：1995-11-13
申请人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08L51/04 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02
CPC分类号： C08L55/02 , C08F279/04
摘要： Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.
摘要翻译：成型化合物由至少一种树脂基质和分散在其中的颗粒状接枝橡胶聚合物组成的ABS类型，通过乳液聚合制备，其中至少70％的接枝橡胶颗粒（数量）表现出橡胶相的结构，其可以通过借助透射电子显微镜拍摄的照片进行检测，其中各个颗粒含有不规则的树脂形成性聚合物的细胞夹杂物，并且颗粒的表面呈现不规则的锯齿状结构，使得对于所示的每个颗粒为5〜30 存在这样的锯齿形突起，其与理想化的圆形颗粒（直径d）不同，其直径d = + d / x，x = 3〜15，以及制造所述模塑料的方法。

4. 发明授权

US5066717A Thermoplastic moulding compounds based on aromatic polycarbonates and vinyl polymers with improved thermostability 失效
标题翻译：基于具有改进的热稳定性的芳族聚碳酸酯和乙烯基聚合物的热塑性模塑化合物
公开(公告)号：US5066717A
公开(公告)日：1991-11-19
申请号：US511680
申请日：1990-04-20
申请人： Herbert Eichenauer , Dieter Wittmann , Adolf Schmidt , Karl-Heinz Ott
发明人： Herbert Eichenauer , Dieter Wittmann , Adolf Schmidt , Karl-Heinz Ott
IPC分类号： C08L25/00 , B01F17/36 , C08F2/24 , C08F2/26 , C08L51/00 , C08L69/00
CPC分类号： C08L69/00
摘要： This invention relates to thermostable thermoplastic moulding compounds consisting of a thermoplastic aromatic polycarbonate resin, a graft polymer and optionally a thermoplastic vinyl polymer wherein the graft or vinyl polymer is emulsion polymerized with an emulsifier which is the reaction product of 2 mols of certain carboxylic anhydrides and 1 mole of certain diols.
摘要翻译：本发明涉及由热塑性芳族聚碳酸酯树脂，接枝聚合物和任选的热塑性乙烯基聚合物组成的耐热性热塑性模塑料，其中接枝或乙烯基聚合物与乳化剂乳液聚合，乳化剂是2摩尔某些羧酸酐的反应产物和 1摩尔某些二醇。

5. 发明授权

US4920181A Polymeric emulsifiers based on amino telechelatic vinyl oligomers II 失效
标题翻译：基于氨基电泳乙烯基低聚物的聚合乳化剂II
公开(公告)号：US4920181A
公开(公告)日：1990-04-24
申请号：US133551
申请日：1987-12-16
申请人： Adolf Schmidt , Udo Hendricks , Bruno Bomer , Karl-Heinz Ott , Herbert Eichenauer , Alfred Pischtschan
发明人： Adolf Schmidt , Udo Hendricks , Bruno Bomer , Karl-Heinz Ott , Herbert Eichenauer , Alfred Pischtschan
IPC分类号： B01F17/22 , B01F17/52 , C07C67/00 , C07C301/00 , C07C307/02 , C07C309/17 , C08F2/24 , C08F8/10 , C08F8/34 , C08F8/44 , C08F8/46 , C08F26/00 , C08F226/02 , C08F291/00 , C08F291/02
CPC分类号： C08F8/44 , C08F8/46
摘要： Sulphosuccinamide acids and their salts corresponding to the following general formula ##STR1## wherein X denotes the residue of a hydrophobic, optionally branched vinyloligomer having an average molecular weight M.sub.n of from 200-5,000, preferably from 300-3,000,of the groups denoted byR.sup.1 R.sup.2, one is hydrogen and the other is --SO.sub.3 M, andn represents a number with a value of from 1.4-3.0, preferably form 1.6-2.3. andM denotes hydrogen, an alkali metal, or an ammonium, C.sub.1 -C.sub.4 -alkyl-ammonium or C.sub.2 -C.sub.3 -hydroxy alkyl-ammonium group.
摘要翻译：磺基琥珀酰胺酸及其盐对应于下列通式，其中X表示疏水性，任选支化的，具有200-5,000，优选为300-3,000，优选为300-3,000， R 1，R 2为氢，另一个为-SO 3 M，n为数值为1.4〜3.0，优选为1.6〜2.3的数。 M表示氢，碱金属或铵，C 1 -C 4 - 烷基 - 铵或C 2 -C 3 - 羟基烷基 - 铵基。

6. 发明授权

US5100945A Emulsifiers and a process for the production of large particle size, homodisperse polymer dispersions using these emulsifiers 失效
标题翻译：乳化剂和生产大颗粒尺寸的方法，使用这些乳化剂的均聚聚合物分散体
公开(公告)号：US5100945A
公开(公告)日：1992-03-31
申请号：US679326
申请日：1991-04-02
申请人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： B01F17/00 , B01F17/36 , C07C69/593 , C07C69/75 , C07C69/753 , C08F2/26
CPC分类号： C08F2/26
摘要： Reaction products of 1 mol of a cycloaliphatic diol corresponding to formula IHO--R--OH Iwith 2 mols cycloaliphatic carboxylic anhydrides corresponding to formulae II and/or III ##STR1## in which R is a cycloaliphatic hydrocarbon radical having 6 to 20 carbon atoms onto which the hydroxy groups are bonded directly or via methylene groups and X represents ##STR2## chemical bond --obtainable obtainable by fusion of the cycloaliphatic diol and the cycloaliphatic carboxylic anhydride in an inert gas atmosphere at temperatures of from 100.degree. C. to 250.degree. C., and the alkali and ammonium salts of these reaction products, and their use as emulsifiers.

7. 发明授权

US5071946A Emulsifiers and a process for the production of large particle size, homodisperse polymer dispersions using these emulsifiers 失效
标题翻译：乳化剂和生产大颗粒尺寸的方法，使用这些乳化剂的均聚聚合物分散体
公开(公告)号：US5071946A
公开(公告)日：1991-12-10
申请号：US509514
申请日：1990-04-16
申请人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： B01F17/00 , B01F17/36 , C07C69/593 , C07C69/75 , C07C69/753 , C08F2/26
CPC分类号： C08F2/26
摘要： Reaction products of 1 mol of a cycloaliphatic diol corresponding to formula IHO--R--OH Iwith 2 mols cycloaliphatic carboxylic anhydrides corresponding to formulae II and/or III ##STR1## in which R is a cycloaliphatic hydrocarbon radical having 6 to 20 carbon atoms onto which the hydroxy groups are bonded directly or via methylene groups andX represents ##STR2## chemical bond obtainable by fusion of the cycloaliphatic diol and the cycloaliphatic carboxylic anhydride in an inert gas atmosphere at temperatures of from 100.degree. C. to 250.degree. C., and the alkali and ammonium salts of these reaction products, and their use as emulsifiers.
摘要翻译：对应于式I HO-R-OH I的1摩尔脂环族二醇与对应于式II和/或III的2摩尔脂环族羧酸酐的反应产物其中R是脂环族烃基，其中R是具有 6至20个碳原子，其上羟基直接或通过亚甲基键合，X代表通过脂环族二醇和脂环族羧酸酐在惰性气体气氛中熔融获得的化学键，温度为100℃ ℃至250℃，以及这些反应产物的碱和铵盐，以及它们作为乳化剂的用途。

8. 发明授权

US4520165A ABS-moulding compositions 失效
标题翻译： ABS成型组合物
公开(公告)号：US4520165A
公开(公告)日：1985-05-28
申请号：US574870
申请日：1984-01-30
申请人： Karl Zabrocki , Karl-Heinz Ott , Adolf Schmidt , Alfred Pischtschan
发明人： Karl Zabrocki , Karl-Heinz Ott , Adolf Schmidt , Alfred Pischtschan
IPC分类号： C08F279/00 , C08L7/00 , C08L21/00 , C08L25/12 , C08L25/16 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L55/00 , C08L55/02
CPC分类号： C08L25/12 , C08L25/16 , C08L51/04 , C08L2205/02 , C08L55/02
摘要： This invention relates to thermoplastic moulding compositions of the ABS-type produced in emulsion and having improved properties in relation to known ABS-moulding compositions, particularly extreme toughness coupled with ready processibility and high surface gloss.
摘要翻译：本发明涉及在乳液中制备的ABS型热塑性模塑组合物，并且具有与已知的ABS-模塑组合物相比具有改进的性能，特别是具有良好的加工性和高表面光泽的极韧性。

9. 发明授权

US5719232A ABS type thermoplastic moulding compounds 失效
标题翻译： ABS型热塑性成型料
公开(公告)号：US5719232A
公开(公告)日：1998-02-17
申请号：US424656
申请日：1995-04-19
申请人： Adolf Schmidt , Herbert Eichenauer , Ulrich Jansen
发明人： Adolf Schmidt , Herbert Eichenauer , Ulrich Jansen
IPC分类号： C08F2/22 , C08L55/02
CPC分类号： C08L55/02 , Y10S525/902
摘要： ABS type thermoplastic moulding compounds obtainable by A) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. % B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced, C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt. % of the monomers are added within the first half of the total monomer introduction time, and D) mixing the polymer obtained in stage C, preferably after first converting it into a powder, with at least one thermoplastic vinyl resin.
摘要翻译： ABS型热塑性成型化合物，其可通过以下方法得到：A）制备平均粒径d50为30〜160nm，凝胶含量为75〜100重量％的橡胶胶乳。 B）一定量的丁二烯的乳液聚合和任选的至多50wt。在阶段A中获得的橡胶存在下，共聚单体的％（相对于阶段B中的单体的总量），使得平均粒径d 50 = 220〜330nm的橡胶胶乳（B）和凝胶含量为25〜70wt。产生％，C）乳液聚合40〜95重量份。的苯乙烯和丙烯腈的混合物，其任选地含有至多50重量％在5至60重量份存在下，一种或多种共聚单体的％（相对于阶段C中使用的单体的总量）。（相对于固体），通过以55〜90重量％的比例引入单体，得到阶段B中得到的橡胶。在全部单体引入时间的前半部分内加入％的单体，和D）将在阶段C中获得的聚合物，优选在首先将其转化为粉末之后，与至少一种热塑性乙烯基树脂混合。

10. 发明授权

US07060741B2 Polymer compositions with improved property constancy 有权
标题翻译：具有改善性能恒定性的聚合物组合物
公开(公告)号：US07060741B2
公开(公告)日：2006-06-13
申请号：US10204294
申请日：2001-02-12
申请人： Herbert Eichenauer , Adolf Schmidt , Ulrich Jansen
发明人： Herbert Eichenauer , Adolf Schmidt , Ulrich Jansen
IPC分类号： C08L51/04
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08L55/02 , C08L2666/24 , C08L2666/02
摘要： The present invention provides polymer compositions of special graft rubber polymers, in the production of which are employed rubbers with defined particle diameters obtained by seed polymerization using seed latex particles with defined particle diameters.
摘要翻译：本发明提供了特殊接枝橡胶聚合物的聚合物组合物，其生产使用具有确定的粒径的橡胶，其通过使用具有确定粒径的种子胶乳颗粒进行种子聚合获得。

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