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1. 发明授权

US5100945A Emulsifiers and a process for the production of large particle size, homodisperse polymer dispersions using these emulsifiers 失效
标题翻译：乳化剂和生产大颗粒尺寸的方法，使用这些乳化剂的均聚聚合物分散体
公开(公告)号：US5100945A
公开(公告)日：1992-03-31
申请号：US679326
申请日：1991-04-02
申请人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： B01F17/00 , B01F17/36 , C07C69/593 , C07C69/75 , C07C69/753 , C08F2/26
CPC分类号： C08F2/26
摘要： Reaction products of 1 mol of a cycloaliphatic diol corresponding to formula IHO--R--OH Iwith 2 mols cycloaliphatic carboxylic anhydrides corresponding to formulae II and/or III ##STR1## in which R is a cycloaliphatic hydrocarbon radical having 6 to 20 carbon atoms onto which the hydroxy groups are bonded directly or via methylene groups and X represents ##STR2## chemical bond --obtainable obtainable by fusion of the cycloaliphatic diol and the cycloaliphatic carboxylic anhydride in an inert gas atmosphere at temperatures of from 100.degree. C. to 250.degree. C., and the alkali and ammonium salts of these reaction products, and their use as emulsifiers.

2. 发明授权

US5071946A Emulsifiers and a process for the production of large particle size, homodisperse polymer dispersions using these emulsifiers 失效
标题翻译：乳化剂和生产大颗粒尺寸的方法，使用这些乳化剂的均聚聚合物分散体
公开(公告)号：US5071946A
公开(公告)日：1991-12-10
申请号：US509514
申请日：1990-04-16
申请人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Adolf Schmidt , Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： B01F17/00 , B01F17/36 , C07C69/593 , C07C69/75 , C07C69/753 , C08F2/26
CPC分类号： C08F2/26
摘要： Reaction products of 1 mol of a cycloaliphatic diol corresponding to formula IHO--R--OH Iwith 2 mols cycloaliphatic carboxylic anhydrides corresponding to formulae II and/or III ##STR1## in which R is a cycloaliphatic hydrocarbon radical having 6 to 20 carbon atoms onto which the hydroxy groups are bonded directly or via methylene groups andX represents ##STR2## chemical bond obtainable by fusion of the cycloaliphatic diol and the cycloaliphatic carboxylic anhydride in an inert gas atmosphere at temperatures of from 100.degree. C. to 250.degree. C., and the alkali and ammonium salts of these reaction products, and their use as emulsifiers.
摘要翻译：对应于式I HO-R-OH I的1摩尔脂环族二醇与对应于式II和/或III的2摩尔脂环族羧酸酐的反应产物其中R是脂环族烃基，其中R是具有 6至20个碳原子，其上羟基直接或通过亚甲基键合，X代表通过脂环族二醇和脂环族羧酸酐在惰性气体气氛中熔融获得的化学键，温度为100℃ ℃至250℃，以及这些反应产物的碱和铵盐，以及它们作为乳化剂的用途。

3. 发明授权

US4920181A Polymeric emulsifiers based on amino telechelatic vinyl oligomers II 失效
标题翻译：基于氨基电泳乙烯基低聚物的聚合乳化剂II
公开(公告)号：US4920181A
公开(公告)日：1990-04-24
申请号：US133551
申请日：1987-12-16
申请人： Adolf Schmidt , Udo Hendricks , Bruno Bomer , Karl-Heinz Ott , Herbert Eichenauer , Alfred Pischtschan
发明人： Adolf Schmidt , Udo Hendricks , Bruno Bomer , Karl-Heinz Ott , Herbert Eichenauer , Alfred Pischtschan
IPC分类号： B01F17/22 , B01F17/52 , C07C67/00 , C07C301/00 , C07C307/02 , C07C309/17 , C08F2/24 , C08F8/10 , C08F8/34 , C08F8/44 , C08F8/46 , C08F26/00 , C08F226/02 , C08F291/00 , C08F291/02
CPC分类号： C08F8/44 , C08F8/46
摘要： Sulphosuccinamide acids and their salts corresponding to the following general formula ##STR1## wherein X denotes the residue of a hydrophobic, optionally branched vinyloligomer having an average molecular weight M.sub.n of from 200-5,000, preferably from 300-3,000,of the groups denoted byR.sup.1 R.sup.2, one is hydrogen and the other is --SO.sub.3 M, andn represents a number with a value of from 1.4-3.0, preferably form 1.6-2.3. andM denotes hydrogen, an alkali metal, or an ammonium, C.sub.1 -C.sub.4 -alkyl-ammonium or C.sub.2 -C.sub.3 -hydroxy alkyl-ammonium group.
摘要翻译：磺基琥珀酰胺酸及其盐对应于下列通式，其中X表示疏水性，任选支化的，具有200-5,000，优选为300-3,000，优选为300-3,000， R 1，R 2为氢，另一个为-SO 3 M，n为数值为1.4〜3.0，优选为1.6〜2.3的数。 M表示氢，碱金属或铵，C 1 -C 4 - 烷基 - 铵或C 2 -C 3 - 羟基烷基 - 铵基。

4. 发明授权

US5420181A Composition of polycarbonate, ABS, a basic additive and a carboxylic and compound 失效
标题翻译：聚碳酸酯，ABS，碱性添加剂和羧酸和化合物的组成
公开(公告)号：US5420181A
公开(公告)日：1995-05-30
申请号：US320115
申请日：1994-10-07
申请人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08G64/06 , C08G64/00 , C08K5/00 , C08K5/09 , C08L55/00 , C08L55/02 , C08L69/00 , C08L101/00 , C08K5/092
CPC分类号： C08K5/0008 , C08L55/02 , C08L69/00
摘要： Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
摘要翻译：含有A）ABS型树脂，B）芳香族聚碳酸酯树脂的热塑性成型组合物，C）具有若干羧基的化合物或其混合物和任选的D）另外的聚合物树脂，其特征在于具有至少一种基本上作用的添加剂的ABS树脂是作为组分A，组分C选自分子中具有至少两个羧基（-COOH）的分子量为150至260的化合物，并且基本上作用的添加剂在A中的羧基中的重量比为从5：1到1：1。

5. 发明授权

US4960822A Thermoplastic moulding compounds with good processing properties and great toughness 失效
标题翻译：热塑性成型料具有良好的加工性能和较好的韧性
公开(公告)号：US4960822A
公开(公告)日：1990-10-02
申请号：US319275
申请日：1989-03-06
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott , Alfred Pischtschan
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： C08L25/04 , C08L7/00 , C08L25/12 , C08L33/00 , C08L33/04 , C08L51/04 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/04 , C08L69/00
CPC分类号： C08L25/12 , C08L51/04 , C08L69/005 , C08L69/00
摘要： Thermoplastic moulding compounds containing(A) from 5 to 90 parts by weight of one or more thermoplastic polymers,(B) from 5 to 90 parts by weight of one or more graft polymers and(C) from 0.25 to 40 parts by weight of a copolymer having a sequential structure corresponding to the idealized formula (I)(A-X-B).sub.n (I)whereinA=a polymer of a cyclic carbonate,B=a polymer of another cyclic ester andX=a middle member containing both partial structures of A and B.
摘要翻译：含有（A）5至90重量份的一种或多种热塑性聚合物的热塑性模塑料，（B）5至90重量份的一种或多种接枝聚合物和（C）0.25至40重量份的共聚物，其具有对应于理想化的式（I）（AXB）n（I）的顺序结构，其中A =环状碳酸酯的聚合物，B =另一种环状酯的聚合物，X =含有两种部分结构的中间构件和B.

6. 发明授权

US5028349A Moulding compositions having uniform particle size and improved thermal stability 失效
标题翻译：成型组合物具有均匀的粒度和改善的热稳定性
公开(公告)号：US5028349A
公开(公告)日：1991-07-02
申请号：US175053
申请日：1988-03-30
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08L51/04 , C08C1/00 , C08F8/34 , C08F279/02 , C08J3/00 , C08J3/16 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L55/00 , C08L55/02 , C08L57/00
CPC分类号： C08J3/005 , C08F279/02 , C08F279/04
摘要： Elastic-thermoplastic or thermoplastic powder-form moulding compositions having uniform particles size and improved thermal stability and processes for their manufacture.
摘要翻译：弹性热塑性或热塑性粉末成型组合物具有均匀的粒度和改善的热稳定性及其制造方法。

7. 发明授权

US4885337A Process for the preparation of thermoplastic moulding compositions 失效
标题翻译：制备热塑性模塑组合物的方法
公开(公告)号：US4885337A
公开(公告)日：1989-12-05
申请号：US69967
申请日：1987-07-06
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08F279/04 , C08F2/22 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/00 , C08L55/02
CPC分类号： C08L25/12 , C08F279/02 , C08L51/04
摘要： Process for the preparation of a thermoplastic moulding composition of 10 to 65% by weight of at least one graft polymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, in the presence of at least one rubber base, and the weight ratio of monomers employed to rubber polymer employed being 20:80 to 70:30, and 90 to 35% by weight of a copolymer of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, wherein, to prepare the graft polymer, the grafting monomers and 0.05 to 1.00 part by weight (per 100 parts by weight of grafting monomer) of a mercaptan are added stepwise to the latex of the rubber base over a period of time, the part amount of the monomer added in each time interval .DELTA.t.sub.n+1 being 0.30 to 0.95 times the amount of monomer added in the preceding time interval .DELTA.t.sub.n at least in the first half of the period of time, and the total period of time comprising n time intervals where n=3 to 30, and each time interval .DELTA.t being 5 to 100 minutes long.
摘要翻译：用于制备10至65重量％的至少一种接枝聚合物的热塑性模塑组合物的方法，所述接枝聚合物可以通过苯乙烯和丙烯腈的重量比为90:10至50:50的乳液聚合而获得，所有这些都可能或由至少一个橡胶基团存在下由α-甲基苯乙烯或甲基丙烯酸甲酯代替的一些苯乙烯，并且所用单体与橡胶聚合物的重量比为20:80至70:30和90至35 重量比为90:10至50:50的苯乙烯和丙烯腈的共聚物的重量比，可以用α-甲基苯乙烯或甲基丙烯酸甲酯代替全部或一些苯乙烯，其中制备接枝物聚合物，接枝单体和0.05至1.00重量份（每100重量份接枝单体）硫醇在一段时间内逐步添加到橡胶基料的胶乳上，每次加入单体的部分量时间间隔DELTA tn + 1 bei ng至少在上述时间段的前半部分中，在上述时间间隔DELTA tn中添加的单体量的0.30〜0.95倍，n = 3〜30的n个时间间隔的总时间，以及每个时间间隔长达5到100分钟。

8. 发明授权

US4772668A Sulphur-containing graft products 失效
标题翻译：含硫移植产品
公开(公告)号：US4772668A
公开(公告)日：1988-09-20
申请号：US827390
申请日：1986-02-10
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08L51/00 , C08F2/38 , C08F279/00 , C08F279/02 , C08F291/02 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L55/00 , C08L55/02
CPC分类号： C08F279/02 , C08F291/02
摘要： Sulphur-containing elastic-thermoplastic graft products of styrene, .alpha.-methyl styrene, p-methyl styrene, vinyl toluene, acrylonitrile or methyl methacrylate or mixtures thereof on a particle-like rubber with an average particle diameter (d.sub.50) of from 0.05 to 20.0 .mu.m and a glass temperature .ltoreq.10.degree. C. with a total rubber content of from 1 to 80% by weight, whereby the graft products have a sulphur content of from 1.15 to 3.95% by weight and the thermoplast proportion of the polymerized monomers on the particle-like rubber has a limiting viscosity of from 2 to 15 ml/g (measured in dimethyl formamide at 25.degree. C.) and in which at least 90% by weight of the incorporated sulphur is present as a constituent of terminal C1-18-thioalkyl groups.
摘要翻译：苯乙烯，α-甲基苯乙烯，对甲基苯乙烯，乙烯基甲苯，丙烯腈或甲基丙烯酸甲酯或其混合物在平均粒径（d50）为0.05至20.0的颗粒状橡胶上的含硫弹性 - 热塑性接枝产物微米，玻璃温度为10℃，总橡胶含量为1〜80重量％，由此接枝产物的硫含量为1.15〜3.95重量％，聚合物的热塑性比例颗粒状橡胶上的单体的特性粘度为2至15ml / g（在25℃的二甲基甲酰胺中测量），并且其中至少90重量％的引入的硫作为末端的成分存在 C 1-18 - 硫烷基。

9. 发明授权

US4764557A Moulding compositions of uniform particle size and improved thermal stability 失效
标题翻译：均匀粒径和改善热稳定性的成型组合物
公开(公告)号：US4764557A
公开(公告)日：1988-08-16
申请号：US827639
申请日：1986-02-10
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08J3/12 , C08F8/34 , C08F279/02 , C08J3/00 , C08J3/16 , C08L55/00 , C08L55/02 , C08L39/04 , C08L51/04
CPC分类号： C08J3/005 , C08F279/04
摘要： Elastic-thermoplastic and thermoplastic powder-form moulding compositions of uniform particle size and improved thermal stability at made by incorporating a sulphur containing polymer.
摘要翻译：具有均匀粒径的弹性热塑性和热塑性粉末成型成型组合物，并且通过掺入含硫聚合物制成的热稳定性得到改善。

10. 发明授权

US5302664A ABS molding compounds 失效
标题翻译： ABS模塑料
公开(公告)号：US5302664A
公开(公告)日：1994-04-12
申请号：US74006
申请日：1993-06-08
申请人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
发明人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： C08L25/02 , C08L25/00 , C08L25/16 , C08L33/00 , C08L33/04 , C08L33/12 , C08L33/20 , C08L35/06 , C08L51/00 , C08L51/04 , C08L51/06 , C08L55/00 , C08L55/02 , C08L69/00 , C08L25/12
CPC分类号： C08L25/16 , C08L35/06 , C08L69/00 , C08L51/04
摘要： Thermoplastic molding compounds comprising three resin components with different molecular weights and two graft rubbers. The thermoplastic molding compounds have good toughness, high heat resistance, adjustable surface gloss and good thermoplastic processability. The invention also relates to a process for the production of the molding compounds.
摘要翻译：包含三种具有不同分子量的树脂组分和两种接枝橡胶的热塑性模塑料。热塑性成型化合物具有良好的韧性，高耐热性，可调表面光泽和良好的热塑性加工性。本发明还涉及一种用于生产模塑料的方法。

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