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1. 发明申请

US20090100610A1 Mixture of Sulfide Dyes 有权
标题翻译：硫化物染料的混合物
公开(公告)号：US20090100610A1
公开(公告)日：2009-04-23
申请号：US11992929
申请日：2006-09-13
申请人： Christian Cremer , Victor Paul Eliu , Beate Frohling , Olof Wallquist
发明人： Christian Cremer , Victor Paul Eliu , Beate Frohling , Olof Wallquist
IPC分类号： A61K8/46 , C09B67/22
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译：公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。

2. 发明授权

US07794509B2 Tricationic dyes 有权
标题翻译：化学染料
公开(公告)号：US07794509B2
公开(公告)日：2010-09-14
申请号：US12308042
申请日：2007-06-04
申请人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
发明人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
IPC分类号： A61Q5/10 , C09B29/00
CPC分类号： A61Q5/10 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K8/4966 , C09B23/145 , C09B26/04 , C09B44/005 , C09B44/08 , C09B44/126 , C09B44/16 , C09B55/002 , C09B55/004 , C09B69/001
摘要： Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims. [D-E1=E2-K]3+(An1−) (An2−) (An3−) (1)
摘要翻译：公开了用于染发，羊毛，皮革，丝绸，纤维素或聚酰胺的化学染料化合物。染料化合物具有式（1），其中基团如说明书和权利要求中所定义。 [D-E1 = E2-K] 3+（An1-）（An2-）（An3-）（1）

3. 发明申请

US20100011518A1 Tricationic dyes 有权
标题翻译：化学染料
公开(公告)号：US20100011518A1
公开(公告)日：2010-01-21
申请号：US12308042
申请日：2007-06-04
申请人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
发明人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
IPC分类号： A61K8/49 , C09B44/00 , C09B67/22 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K8/4966 , C09B23/145 , C09B26/04 , C09B44/005 , C09B44/08 , C09B44/126 , C09B44/16 , C09B55/002 , C09B55/004 , C09B69/001
摘要： Disclosed are compounds of formula D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, —CN, NO2, —NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are ═CH; or ═N—; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, —NR3R4, —N(R3)(CO)R4, —SO2NR1R2, —SONR1R2 or by one or more Z; or a radical of formula —NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6-C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, —NR5R6, —N(R5)—(CO)R5 or by Z; Z is a group of the formula (1a) *—X1—Y1—W1, wherein X1 is the direct bond; —NR7—; —O—; —NR7(C═O)—; —(CO)NR7—; —O(C═O)—; —(CO)O—; or —(C═O)—; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by —O—, —NR8, —S—, —(C═O)—, —O(C═O)—, (C═O)O—, —NR7(C═O)—, —(C═O)NR7—, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, —NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1−, An2− and An3− independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair.
摘要翻译：公开了式D的化合物是芳族或阳离子杂芳基，其任选被C 1 -C 14烷基，C 1 -C 14烷氧基，羟基-C 1 -C 14烷基，C 3 -C 8环烷基，-CN，NO 2，-NR 3 R 4，卤素， C10芳基，其为任选取代的或C 1 -C 14烷基，或一个或多个基团Z; E1和E2彼此独立地是-CH; 或-N-; K是任选被C 1 -C 14烷基，C 1 -C 14烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基，NO 2，-NR 3 R 4，-N（R 3）（CO）R 4，-SO 2 NR 1 R 2， -SONR1R2或一个或多个Z; 或式-NR1R2的基团; R1和R2彼此独立地是氢; C 1 -C 14烷基; 环C 1 -C 14烷基; C6-C10芳基; 任选被C 1 -C 14烷基，C 1 -C 14烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基，-NR 5 R 6，-N（R 5） - （CO）R 5或Z取代的芳族或杂芳族基团; Z是式（1a）* -X1-Y1-W1的基团，其中X1是直接键; -NR7-; -O-; -NR7（C-O） - ; - （CO）NR7-; -O（C-O） - ; - （CO）O-; 或 - （C-O） - ; Y1是直接键; （CO） - ， - （CO） - ，（CO）O - ， - NR7（CO） - ， - （CO） NR7-，其可以被C 1 -C 14烷基，羟基-C 1 -C 14烷基，羟基，-NR 9 R 10或卤素取代; 或可被C 1 -C 14烷基取代的C 6 -C 10亚芳基，羟基-C 1 -C 14烷基，羟基，氨基或卤素; W1是阳离子基团; 且R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10彼此独立地为氢; C 1 -C 14烷基; 或Z; 而An1-，An2-和An3-彼此独立地是阴离子。这些化合物可用于染色有机材料，例如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，更优选人发。

4. 发明授权

US07828858B2 Mixture of sulfide dyes 有权
标题翻译：硫化染料的混合物
公开(公告)号：US07828858B2
公开(公告)日：2010-11-09
申请号：US11992929
申请日：2006-09-13
申请人： Christian Cremer , Victor Paul Eliu , Beate Fröhling , Olof Wallquist
发明人： Christian Cremer , Victor Paul Eliu , Beate Fröhling , Olof Wallquist
IPC分类号： A61Q5/10 , C07D277/26
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译：公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。

5. 发明申请

US20110107525A1 POLYMERIC HAIR DYES 有权
公开(公告)号：US20110107525A1
公开(公告)日：2011-05-12
申请号：US12812778
申请日：2009-01-07
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
IPC分类号： A61K8/89 , C08G73/04 , C08G77/38 , A61K8/84 , A61Q5/10
CPC分类号： C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
摘要： Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

6. 发明申请

US20110061179A1 BLUE POLYMERIC HAIR DYES 有权
标题翻译：蓝色聚合物染发剂
公开(公告)号：US20110061179A1
公开(公告)日：2011-03-17
申请号：US12812781
申请日：2009-01-07
申请人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Frohling
发明人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist , Beate Frohling
IPC分类号： A61K8/81 , C08F8/34 , C08F8/30 , A61K8/84 , A61Q5/10
CPC分类号： C09B69/10 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/101 , C09B69/106
摘要： Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了具有h = 210°至330°的色相值为h = 210°至330°的阳离子聚合物染料，其包含：a）聚合物主链，b）有机染料的残基，和c）任选无色的有机基团，其中（b）和（c）共价结合到聚合物主链（a），并且其中阳离子电荷可以独立地是染料或无色有机基团的一部分。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

7. 发明授权

US08641783B2 Disulfide or thiol polymeric hair dyes 有权
标题翻译：二硫化物或硫醇聚合染发剂
公开(公告)号：US08641783B2
公开(公告)日：2014-02-04
申请号：US13816527
申请日：2011-08-15
申请人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
IPC分类号： A61Q5/10
CPC分类号： C09B67/0063 , A61K8/817 , A61K8/84 , A61K8/91 , A61Q5/10 , C09B62/78 , C09B69/101 , C09B69/106
摘要： The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
摘要翻译：本发明涉及（A）聚合物主链与（B）A发色团的反应产物; 和（C）至少一种含硫化物的化合物。使用这种新技术可以获得非常好的染色结果。

8. 发明申请

US20100192312A1 POLYMERIC DYES 有权
标题翻译：聚合染料
公开(公告)号：US20100192312A1
公开(公告)日：2010-08-05
申请号：US12598494
申请日：2008-04-25
申请人： Christian Cremer , Richard Lewis Riggs , Beate Frohling , Martin Muller
发明人： Christian Cremer , Richard Lewis Riggs , Beate Frohling , Martin Muller
IPC分类号： A61K8/89 , C08G77/04 , B32B1/00 , C09B27/00 , C07F7/10 , C09B67/22
CPC分类号： C08G77/26 , A61K8/11 , A61K8/26 , A61K8/898 , A61K2800/413 , A61K2800/43 , A61K2800/434 , A61Q5/065 , B82Y5/00 , C07F7/1804 , C08G77/22 , C08L83/08 , C09B69/008 , C09B69/101 , C09B69/103 , C09B69/106 , C09B69/107 , C09B69/109 , D06P1/0052 , D06P3/145 , Y10T428/29
摘要： A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.
摘要翻译：包含至少10个Si原子的高度交联的聚硅氧烷染料，包括至少一个式（I）部分，其开放的Si键各自连接到氧原子和开放的O形键，其余部分与硅原子连接聚硅氧烷，其中T为直接键或有机间隔基团，例如C 1 -C 18亚烷基，C 2 -C 12亚烯基，C 5 -C 10环亚烷基，C 5 -C 10亚芳基，-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - 各自可以是末端通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，SO2，C5-C10亚环烷基，C5-C10亚芳基与染料键合。 CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，-SO2 - ，C5-的亚烷基被中断并且任选地被端基连接到染料上， C 5 -C 10亚芳基; 或是CO; （CH 2 CH 2 -O）1-5; 首席运营官 N（R1）; CON（R1）; O; S; 所以; SO2; R1是氢; 直链或支链的单环或多环，中断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 染料是有机染料的残留物，可用于染色有机材料，如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。

9. 发明授权

US08992633B2 Disulfide dyes 有权
标题翻译：二硫化染料
公开(公告)号：US08992633B2
公开(公告)日：2015-03-31
申请号：US14114783
申请日：2012-05-02
申请人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
IPC分类号： A61Q5/10 , C09B33/00 , A61K8/49 , C09B26/04 , C09B29/08 , C09B43/18 , C09B43/44 , C09B44/10 , C09B49/00 , A61Q5/04 , A61Q5/06 , C09D15/00 , C09B29/36
CPC分类号： A61K8/4986 , A61K8/49 , A61K2800/884 , A61Q5/04 , A61Q5/065 , A61Q5/10 , C09B26/04 , C09B29/081 , C09B29/3691 , C09B43/18 , C09B43/44 , C09B44/10 , C09B49/00 , C09B62/78 , C09D15/00
摘要： Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2). A-(X1)p—(Csat)r—S—S—(Csat)q—(X2)p-D (1)
摘要翻译：公开了式（1）或式（2）的化合物。这些化合物可用于染色有机材料，例如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，优选毛发，更优选人发。（1）（2）。（X1）对 - （Csat）r-S-S-（Csat）q-（X2）p-D（1）

10. 发明申请

US20140157529A1 DISULFIDE DYES 有权
标题翻译： DISIFFIDE DYES
公开(公告)号：US20140157529A1
公开(公告)日：2014-06-12
申请号：US14114783
申请日：2012-05-02
申请人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
发明人： Sophie Marquais-Bienewald , Christian Cremer , Beate Frohling
IPC分类号： A61K8/49 , A61Q5/10 , C09B29/36
CPC分类号： A61K8/4986 , A61K8/49 , A61K2800/884 , A61Q5/04 , A61Q5/065 , A61Q5/10 , C09B26/04 , C09B29/081 , C09B29/3691 , C09B43/18 , C09B43/44 , C09B44/10 , C09B49/00 , C09B62/78 , C09D15/00
摘要： Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2). A-(X1)p—(Csat)r—S—S—(Csat)q—(X2)p-D (1)
摘要翻译：公开了式（1）或式（2）的化合物。这些化合物可用于染色有机材料，例如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，优选毛发，更优选人发。（1）（2）。（X1）对 - （Csat）r-S-S-（Csat）q-（X2）p-D（1）

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