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1. 发明授权

US07794509B2 Tricationic dyes 有权
标题翻译：化学染料
公开(公告)号：US07794509B2
公开(公告)日：2010-09-14
申请号：US12308042
申请日：2007-06-04
申请人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
发明人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
IPC分类号： A61Q5/10 , C09B29/00
CPC分类号： A61Q5/10 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K8/4966 , C09B23/145 , C09B26/04 , C09B44/005 , C09B44/08 , C09B44/126 , C09B44/16 , C09B55/002 , C09B55/004 , C09B69/001
摘要： Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims. [D-E1=E2-K]3+(An1−) (An2−) (An3−) (1)
摘要翻译：公开了用于染发，羊毛，皮革，丝绸，纤维素或聚酰胺的化学染料化合物。染料化合物具有式（1），其中基团如说明书和权利要求中所定义。 [D-E1 = E2-K] 3+（An1-）（An2-）（An3-）（1）

2. 发明申请

US20090044345A1 Use of Metal Complex Compounds as Oxidation Catalysts 审中-公开
标题翻译：金属络合物作为氧化催化剂的应用
公开(公告)号：US20090044345A1
公开(公告)日：2009-02-19
申请号：US12223429
申请日：2006-02-06
申请人： Gunther Schlingloff , Kishor Ramachandra Nivalkar , Torsten Wieprecht , Marie-Josee Dubs , Nicole End
发明人： Gunther Schlingloff , Kishor Ramachandra Nivalkar , Torsten Wieprecht , Marie-Josee Dubs , Nicole End
IPC分类号： C11D3/39 , D06L3/00 , A01N59/00 , A01P1/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F1/08 , C07F7/28 , C07D401/14 , C02F1/68 , C02F103/00
CPC分类号： B01J31/1835 , A61L2/186 , A61L2/23 , A61L12/124 , A61L12/128 , A61L2202/17 , A61L2202/26 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/184 , B01J2231/70 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C02F1/683 , C02F1/722 , C02F1/725 , C02F2303/04 , C07D213/22 , C07D213/74 , C07D401/14 , C07D471/04 , C11D3/3932 , C11D17/0039 , C11D17/06 , D06M11/32 , D06M11/50 , D21C9/1036 , D21C9/163
摘要： The present invention relates to the use, as oxidation catalysts, of metal complex compounds having tetradentate ligands of formula (2) wherein all substitutents have the meanings as defined in Claim 1. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.
摘要翻译：本发明涉及作为氧化催化剂的具有式（2）的四齿配体的金属络合物的用途，其中所有取代基具有权利要求1中定义的含义。本发明还涉及包含这种金属络合物的制剂，新型金属络合物和新配体。

3. 发明申请

US20100011518A1 Tricationic dyes 有权
标题翻译：化学染料
公开(公告)号：US20100011518A1
公开(公告)日：2010-01-21
申请号：US12308042
申请日：2007-06-04
申请人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
发明人： Christian Cremer , Olof Wallquist , Victor Paul Eliu , Kishor Ramachandra Nivalkar
IPC分类号： A61K8/49 , C09B44/00 , C09B67/22 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K8/4966 , C09B23/145 , C09B26/04 , C09B44/005 , C09B44/08 , C09B44/126 , C09B44/16 , C09B55/002 , C09B55/004 , C09B69/001
摘要： Disclosed are compounds of formula D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, —CN, NO2, —NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are ═CH; or ═N—; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, —NR3R4, —N(R3)(CO)R4, —SO2NR1R2, —SONR1R2 or by one or more Z; or a radical of formula —NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6-C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, —NR5R6, —N(R5)—(CO)R5 or by Z; Z is a group of the formula (1a) *—X1—Y1—W1, wherein X1 is the direct bond; —NR7—; —O—; —NR7(C═O)—; —(CO)NR7—; —O(C═O)—; —(CO)O—; or —(C═O)—; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by —O—, —NR8, —S—, —(C═O)—, —O(C═O)—, (C═O)O—, —NR7(C═O)—, —(C═O)NR7—, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, —NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1−, An2− and An3− independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair.
摘要翻译：公开了式D的化合物是芳族或阳离子杂芳基，其任选被C 1 -C 14烷基，C 1 -C 14烷氧基，羟基-C 1 -C 14烷基，C 3 -C 8环烷基，-CN，NO 2，-NR 3 R 4，卤素， C10芳基，其为任选取代的或C 1 -C 14烷基，或一个或多个基团Z; E1和E2彼此独立地是-CH; 或-N-; K是任选被C 1 -C 14烷基，C 1 -C 14烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基，NO 2，-NR 3 R 4，-N（R 3）（CO）R 4，-SO 2 NR 1 R 2， -SONR1R2或一个或多个Z; 或式-NR1R2的基团; R1和R2彼此独立地是氢; C 1 -C 14烷基; 环C 1 -C 14烷基; C6-C10芳基; 任选被C 1 -C 14烷基，C 1 -C 14烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基，-NR 5 R 6，-N（R 5） - （CO）R 5或Z取代的芳族或杂芳族基团; Z是式（1a）* -X1-Y1-W1的基团，其中X1是直接键; -NR7-; -O-; -NR7（C-O） - ; - （CO）NR7-; -O（C-O） - ; - （CO）O-; 或 - （C-O） - ; Y1是直接键; （CO） - ， - （CO） - ，（CO）O - ， - NR7（CO） - ， - （CO） NR7-，其可以被C 1 -C 14烷基，羟基-C 1 -C 14烷基，羟基，-NR 9 R 10或卤素取代; 或可被C 1 -C 14烷基取代的C 6 -C 10亚芳基，羟基-C 1 -C 14烷基，羟基，氨基或卤素; W1是阳离子基团; 且R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10彼此独立地为氢; C 1 -C 14烷基; 或Z; 而An1-，An2-和An3-彼此独立地是阴离子。这些化合物可用于染色有机材料，例如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，更优选人发。

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