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    • 1. 发明申请
      US20110107525A1 POLYMERIC HAIR DYES 有权
    • POLYMERIC HAIR DYES
    • US20110107525A1
    • 2011-05-12
    • US12812778
    • 2009-01-07
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Frohling
    • A61K8/89 , C08G73/04 , C08G77/38 , A61K8/84 , A61Q5/10
    • C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
    • Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 4. 发明申请
      US20110088173A1 POLYMERIC HAIR DYES 有权
    • POLYMERIC HAIR DYES
    • US20110088173A1
    • 2011-04-21
    • US12812785
    • 2009-01-07
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Roberg Hochberg
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Roberg Hochberg
    • A61K8/41 , A61Q5/10 , C09B44/16
    • C09B69/106 , A61K8/4946 , A61K8/69 , A61K8/84 , A61K2800/57 , A61Q5/02 , A61Q5/065 , A61Q5/12
    • Disclosed are polymeric dyes obtained by the reaction of (a) a basic polycondensate with (b) an electrophilic dye of formula (2) P—X—Ya+ Ana−; wherein the basic polycondensate (a) is obtained by the reaction of (a1) an amine of formula (I) in the presence of an anhydrous solvent with an ammonium salt (a2) with a cyanamide; wherein R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl, which may be substituted by amino, hydroxy, cyano or C1-C4alkoxy; A is C2-C20alkylene, which may be substituted or interrupted by one or more than one hetero atoms; P is a reactive grouping capable of reacting with a nitrogen nucleophile; X is a linkage group selected from C1-C30alkylene, C2-C12alkenylene, C5-C10arylene, C5-C10cycloalkylene and C1-C10alkylene(C5-C10arylene) which may be interrupted and/or terminated at one or both ends by one or more than one —O—, —S—, —N═, —N(R5)—, —S(O)—, SO2, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OC(O)—, (II), —CON(R5)—, —C(NR5R6)2—, —(R5)NC(O)—, —C(S)R5— or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic bivalent radical optionally comprising at least one heteroatom; —O—; —S—; —N(R5)—; —S(O)—; —SO2—; —(CH2CH2—O)1-5—; —C(O)—; —C(O)O—, —OC(O)—; (III); —CON(R5)—; —SO2N(R5)—; —C(NR5R6)2—; —(R5)NC(O)—; —C(S)R5—; saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical optionally comprising at least one heteroatom; which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), halogen or hydroxy; or the direct bond; Y is a residue of an organic dye; R5 and R6 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted d-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); a is 1, 2 or 3; and An is an anion. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 9. 发明授权
      US08097045B2 Polymeric hair dyes 有权
    • Polymeric hair dyes
    • US08097045B2
    • 2012-01-17
    • US12812778
    • 2009-01-07
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Fröhling
    • Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Beate Fröhling
    • A61Q5/10 , C07D213/22
    • C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
    • Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
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