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1. 发明授权

US5171825A Preparation of polyphenylene ethers 失效
标题翻译：聚苯乙烯的制备
公开(公告)号：US5171825A
公开(公告)日：1992-12-15
申请号：US695385
申请日：1991-05-03
申请人： Carola Hedtmann-Rein , Bernhard Czauderna , Martina von Deessen , Karl Hennig
发明人： Carola Hedtmann-Rein , Bernhard Czauderna , Martina von Deessen , Karl Hennig
IPC分类号： C08G65/38 , C08G65/44
CPC分类号： C08G65/44
摘要： A process for preparing polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho positions and possibly also in one meta position but not in the para position, by oxidative coupling with oxygen-containing gases in the presence of an oxidation catalyst and of an electrically conducting compound which counteracts the electrostatic charge in the reaction mixture, in organic solution, comprises using as electrically conducting compound a salt of a carboxamide derivative of the formula I ##STR1## or mixtures of such salts, where R.sup.1 is a saturated or singly or multiply unsaturated aliphatic group which can have a terminal phenyl group and which contains a total of 8-30 carbon atoms, it also being possible for these carbon atoms to be interrupted by isolated oxygen atoms,R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl,A is an aliphatic, araliphatic or cycloaliphatic or aromatic bridge of up to 10 carbon atoms,n and m are each 1 to 3,Q.sup..sym. is ammonium, an alkali metal cation or the equivalent of an alkaline earth metal cation or a cation of a metal of groups IVb to VIIb of the periodic table.
摘要翻译：在氧化催化剂存在下，通过与含氧气体的氧化偶联和电化学反应，由一元酚制备聚苯醚的方法，它们在邻位和可能还在一个间位而不是在对位具有烷基取代基在有机溶液中抵抗反应混合物中的静电荷的导电化合物包括使用式I的羧酰胺衍生物或其混合物作为导电化合物的盐或其混合物，其中R1是饱和或单独或可以具有末端苯基并且含有总共8-30个碳原子的多重不饱和脂族基团，这些碳原子也可以被分离的氧原子中断，R2是氢或C1-C4-烷基，A 是至多10个碳原子的脂族，芳脂或脂环族或芳族桥，n和m各自为1至3，Q（+）为铵，碱金属阳离子或当量的碱金属阳离子或元素周期表IVb至VIIb族金属的阳离子。

2. 发明授权

US5237039A Preparation of polyphenylene ethers in the presence of defoamer 失效
标题翻译：在存在缺陷的情况下制备聚苯乙烯
公开(公告)号：US5237039A
公开(公告)日：1993-08-17
申请号：US876163
申请日：1992-04-30
申请人： Doris Zeltner , Peter Steieri , Heike Feldman , Klaus Muehlbach , Carola Hedtmann-Rein , Bernhard Czauderna , Karl Hennig
发明人： Doris Zeltner , Peter Steieri , Heike Feldman , Klaus Muehlbach , Carola Hedtmann-Rein , Bernhard Czauderna , Karl Hennig
IPC分类号： C08G65/40 , C08G65/44
CPC分类号： C08G65/44
摘要： Polyphenylene ethers are prepared from monohydric phenols by oxidative coupling with oxygen-containing gases in the presence of an oxidation catalyst in an organic solvent by carrying out the polycondensation in the presence of a defoamer.
摘要翻译：通过在有机溶剂中的氧化催化剂存在下，通过在消泡剂的存在下进行缩聚，通过与含氧气体的氧化偶联，由一元酚制备聚苯醚。

3. 发明授权

US4692373A Laminate bonded by adhesion promoting layer and adhesive layer 失效
标题翻译：通过粘合促进层和粘合剂层粘合的层压板
公开(公告)号：US4692373A
公开(公告)日：1987-09-08
申请号：US782929
申请日：1985-10-02
申请人： Martin Welz , Bernhard Czauderna , Karl-Heinz Stoffel
发明人： Martin Welz , Bernhard Czauderna , Karl-Heinz Stoffel
IPC分类号： B32B15/14 , B32B15/08 , B32B15/085 , B32B15/095 , B32B15/00
CPC分类号： B32B15/08 , Y10T428/31587 , Y10T428/31605 , Y10T442/66 , Y10T442/669 , Y10T442/681
摘要： A laminate consists of a layer A of a polyolefin, reinforced with from 10 to 50% of glass fiber mats, and a metal layer D, which are bonded to one another by means of a mechanically adhesion-promoting layer B and an adhesive layer C. The adhesive is a thermoplastic polyurethane elastomer, preferably having a melting range of from 110.degree. to 250.degree. C. The laminates are used as automobile components, and as housings and containers.
摘要翻译：层压材料由用10-50％的玻璃纤维垫增强的聚烯烃层A和通过机械粘合促进层B和粘合剂层C彼此结合的金属层D组成粘合剂是热塑性聚氨酯弹性体，优选熔点范围为110-250℃。层压体用作汽车部件以及壳体和容器。

4. 发明申请

US20060202373A1 Thermoplastic granulates 审中-公开
标题翻译：热塑性颗粒
公开(公告)号：US20060202373A1
公开(公告)日：2006-09-14
申请号：US10549098
申请日：2004-03-10
申请人： Norbert Guntherberg , Bernhard Czauderna , Michael Sauer , Rainer Bardon , Yohwan An
发明人： Norbert Guntherberg , Bernhard Czauderna , Michael Sauer , Rainer Bardon , Yohwan An
IPC分类号： B29B9/06
CPC分类号： B29B9/065 , B29B9/12 , B29C2045/0091
摘要： Pelletized materials based on at least one thermoplastically processable polymer, where the pellets have less than 10% of concave regions and otherwise are convex in every other region, this being determined by means of incident-light interference-contrast spectroscopy, by taking the average value for the ratios of the outline area to the entire outline area for an assembly of pellets.
摘要翻译：基于至少一种热塑性可加工聚合物的颗粒化材料，其中颗粒具有小于10％的凹陷区域，并且在另外的每个区域中是凸起的，这是通过入射光干涉对比度光谱法，通过取平均值对于组装颗粒的轮廓区域与整个轮廓区域的比率。

5. 发明申请

US20060034962A1 Device for extruding thermoplasts 审中-公开
标题翻译：用于挤压热塑性塑料的装置
公开(公告)号：US20060034962A1
公开(公告)日：2006-02-16
申请号：US10527929
申请日：2003-09-08
申请人： Norbert Guntherberg , Bernhard Czauderna , Michael Sauer , Rainer Bardon , YoHwan An
发明人： Norbert Guntherberg , Bernhard Czauderna , Michael Sauer , Rainer Bardon , YoHwan An
IPC分类号： B29C47/36
CPC分类号： B29B7/845 , B29B7/46 , B29B7/603 , B29B7/7495 , B29B7/842 , B29B9/065 , B29C48/07 , B29C48/09 , B29C48/12 , B29C48/761 , B29C48/763 , B29C48/766 , B29C48/767 , B29K2009/00 , B29K2021/00 , B29K2033/12 , B29K2055/02 , B29K2069/00 , B29K2077/00 , C08L51/04 , C08L25/12
摘要： An apparatus intended for extruding thermoplastics and having at least one devolatilization orifice and, if desired, also at least one dewatering orifice, which has been equipped with a metal-wire-mesh composite sheet, with a finely perforated metal sheet, or with a slit diaphragm.
摘要翻译：一种用于挤出热塑性塑料并具有至少一个脱挥发孔的装置，并且如果需要，还具有至少一个已经装配有金属丝网复合片的脱水孔，其具有精细穿孔的金属片或狭缝隔膜

6. 发明授权

US4289676A Binders, impregnating agents and coating agents based on an aqueous dispersion of an amide-containing copolymer 失效
标题翻译：基于含酰胺共聚物的水分散体的粘合剂，浸渍剂和包衣剂
公开(公告)号：US4289676A
公开(公告)日：1981-09-15
申请号：US145695
申请日：1980-05-01
申请人： Bernhard Czauderna , Andreas Einwiller , Kaspar Bott
发明人： Bernhard Czauderna , Andreas Einwiller , Kaspar Bott
IPC分类号： C08F8/00 , C08F8/28 , C08F220/58 , C08L9/00 , C08L21/02 , C08L25/00 , C08L25/10 , C08L27/06 , C08L31/04 , C08L33/04 , C08L33/06 , C08L33/18 , C08L33/20 , C09D201/02 , D04H1/4258 , D04H1/4334 , D04H1/435 , D04H1/587 , D04H1/645 , D04H1/65 , D04H1/74 , D06M15/29 , C08L33/24
CPC分类号： D04H1/587 , C08F220/58 , D04H1/4258 , D04H1/4334 , D04H1/435 , D04H1/645 , D04H1/65 , D04H1/74 , D06M15/29
摘要： Binders, impregnating agents and coating agents based on an aqueous dispersion of an amide-containing copolymer, wherein the copolymer contains recurring units of the general formula I ##STR1## where R is H and/or CH.sub.3, eliminate virtually no formaldehyde in use and may advantageously be used as binders for bonding nonwovens.
摘要翻译：基于含酰胺共聚物的水性分散体的粘合剂，浸渍剂和涂布剂，其中所述共聚物含有通式I的重复单元，其中R是H和/或CH 3，实际上在使用中消除了甲醛，并且可以有利地用作粘合无纺布的粘合剂。

7. 发明申请

US20100227965A1 PROCESS FOR THE PRODUCTION OF A GRAFT COPOLYMER HAVING A BIMODAL PARTICLE DISTRIBUTION 审中-公开
标题翻译：生产具有二次粒子分布的聚酯共聚物的方法
公开(公告)号：US20100227965A1
公开(公告)日：2010-09-09
申请号：US12063162
申请日：2006-08-03
申请人： Wil Duijzings , Davy Roger Suwier , Bernhard Czauderna , Norbert Niebner , Alexander Sauer , Michel Peper
发明人： Wil Duijzings , Davy Roger Suwier , Bernhard Czauderna , Norbert Niebner , Alexander Sauer , Michel Peper
IPC分类号： C08L51/06
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08L55/02 , C08L2666/02
摘要： A thermoplastic molding composition having reduced gloss sensitivity and no unpleasant odor is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, using an inorganic radical generating substance and a limited amount of chain transfer agent, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer using an inorganic radical generating substance while the use of a chain transfer agent is excluded. The thermoplastic polymer is a copolymer of a vinyl aromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of unpleasant odor coupled with reduced gloss sensitivity and good mechanical properties.
摘要翻译：由接枝共聚物和热塑性聚合物制备具有降低的光泽灵敏度和无异味的热塑性模塑组合物。接枝共聚物由软质弹性体颗粒接枝基质制得，该基质是通过使用无机自由基产生物质和有限量的链转移剂将共轭二烯单独或与少量单烯属不饱和单体进行乳液聚合而获得的，在不使用链转移剂的情况下，使用无机自由基产生物接枝乙烯基芳族单体和丙烯腈以及任选的另一种单烯属不饱和单体。热塑性聚合物是乙烯基芳族单体和丙烯腈和任选的另外的单烯属不饱和单体的共聚物。热塑性模塑组合物具有低水平的令人不快的气味，同时具有降低的光泽灵敏度和良好的机械性能。

8. 发明授权

US06852797B2 Method for producing polybutadiene latex with an optimized thermal current profile 失效
标题翻译：具有优化的热电流分布的聚丁二烯胶乳的生产方法
公开(公告)号：US06852797B2
公开(公告)日：2005-02-08
申请号：US10257717
申请日：2001-04-24
申请人： Sabine Oepen , Michael Breulmann , Norbert Güntherberg , Klaus-Dieter Hungenberg , Norbert Niessner , Bernhard Czauderna , Wil Duijzings
发明人： Sabine Oepen , Michael Breulmann , Norbert Güntherberg , Klaus-Dieter Hungenberg , Norbert Niessner , Bernhard Czauderna , Wil Duijzings
IPC分类号： C08F2/22 , C08F2/32 , C08F236/06 , C08F279/02 , C08F279/04
CPC分类号： C08F279/02 , C08F236/06 , Y10S525/942 , C08F2/22
摘要： A polybutadiene latex is prepared by a process in which butadiene is polymerized by free radical emulsion polymerization in the presence of initiator and, if required, dispersants and further conventional assistants, the polymerization being carried out in the presence of reactive comonomers in such a way that the heat flow of 43 watt/kg solids content of the polymerization mixture is not exceeded. Owing to the presence of reactive comonomers, the reaction rate at the beginning of the reaction is increased, with the result that an overall flatter heat flow profile is obtained. A preferred reactive comonomer is styrene. Preferably, the process is carried out by a semi-batch procedure in which (a) in a first stage, a portion of butadiene and at least one portion of reactive comonomer in the form of an aqueous emulsion are initially taken with a thermal polymerization initiator and, if required, dispersants and further conventional assistants and the polymerization is initiated, (b) in a second stage, the remaining amount of butadiene and, if required, the remaining amount of reactive comonomer are added undiluted or in the form of an aqueous emulsion, if required with dispersants and, if required, further conventional assistants, as a feed.
摘要翻译：聚丁二烯胶乳是通过一种方法制备的，其中丁二烯在引发剂存在下通过自由基乳液聚合聚合，如果需要的话，通过分散剂和其它常规助剂，聚合反应在反应性共聚单体的存在下进行，使得不超过聚合混合物的43瓦特/千克固体含量的热流。由于反应性共聚单体的存在，反应开始时的反应速率增加，结果得到整体平坦的热流分布。优选的反应性共聚单体是苯乙烯。优选地，该方法通过半间歇方法进行，其中（a）在第一阶段中，一部分丁二烯和至少一部分水性乳液形式的反应性共聚单体最初用热聚合引发剂并且如果需要，分散剂和其它常规助剂并开始聚合，（b）在第二阶段中，剩余量的丁二烯和如果需要的话，反应性共聚单体的剩余量未稀释或以水性形式加入乳液，如果需要与分散剂，并且如果需要，作为进料的其它常规助剂。

9. 发明授权

US06723774B2 Method for producing caoutchouc particles 有权
标题翻译：橡胶颗粒的制备
公开(公告)号：US06723774B2
公开(公告)日：2004-04-20
申请号：US10221080
申请日：2002-09-10
申请人： Norbert Güntherberg , Bernhard Czauderna , Michael Breulmann , Sabine Oepen , Wil Duijzings , Norbert Niessner
发明人： Norbert Güntherberg , Bernhard Czauderna , Michael Breulmann , Sabine Oepen , Wil Duijzings , Norbert Niessner
IPC分类号： C08F3600
CPC分类号： C08F36/04 , Y10S525/902 , C08F2/24
摘要： The invention relates to a method for producing caoutchouc particles (K) by means of emulsion polymerisation in the presence of an emulsifier and a polymerisation initiator. Said particles contain A) 80 to 100 wt. % of one or more conjugated diene monomers (A) in relation to (K) and B) 0 to 20 wt. % of one or more monoethylenically unsaturated comonomers (B) in relation to (K) in the polymerised form. The inventive method is characterised in that 1) a mixture (M1) containing water and an emulsifier is provided, 2) a mixture (M2) containing one or more monomers in the monomer or polymerised form selected from styrole, &agr;-methylstyrole, butadiene, n-butylacrylate, MMA and acrylnitrile and optionally comonomers is added, 3) polymerisation of the obtained mixture starts in the presence of a polymerisation initiator at temperature of 5 to 95° C., 4) a mixture (M3) containing 0 to 100 wt. % of the comonomers (B) in relation to (B) and 0 to 25 wt. % of the diene monomers (A) in relation to (A) is added, 5) a mixture (M4) containing the (remaining) diene monomers (A) and the (remaining) comonomers (B) is proportioned and polymerised and 6) polymerisation is terminated when there is conversion of more than 90 and less than 95% in relation to the sum of the monomers.
摘要翻译：本发明涉及一种在乳化剂和聚合引发剂存在下，通过乳液聚合来生产酚醛树脂颗粒（K）的方法。所述颗粒包含A）80至100重量％一个或多个共轭二烯单体（A）相对于（K）和B）的％为0-20重量％％的一种或多种单烯属不饱和共聚单体（B）相对于聚合形式的（K）。本发明的方法的特征在于：1）提供含有水和乳化剂的混合物（M1），2）含有一种或多种选自苯乙烯，α-甲基苯甲醛，丁二烯的单体或聚合形式的单体的混合物（M2）丙烯酸正丁酯，MMA和丙烯腈和任选的共聚单体; 3）所得混合物的聚合在聚合引发剂存在下开始，温度为5至95℃，4）含有0-100重量份的混合物。共聚单体（B）的相对于（B）和0-25重量％加入相对于（A）的二烯单体（A）的％，5）含有（剩余的）二烯单体（A）和（剩余的）共聚单体（B）的混合物（M4）成比例和聚合，和6）当相对于单体的总和转化率大于90且小于95％时，聚合终止。

10. 发明授权

US06441062B1 Method for precipitating microsuspension polymers 失效
标题翻译：沉淀微悬浮聚合物的方法
公开(公告)号：US06441062B1
公开(公告)日：2002-08-27
申请号：US09600311
申请日：2000-08-18
申请人： Graham Edmund Mc Kee , Bernhard Czauderna , Harmut Heinen , Jürgen Koch
发明人： Graham Edmund Mc Kee , Bernhard Czauderna , Harmut Heinen , Jürgen Koch
IPC分类号： C08J300
CPC分类号： C08J3/16 , C08F6/24 , C08F265/06 , C08J3/005 , C08F2/18
摘要： In a process for precipitating microsuspension polymers from a suspension comprising them, a polymer dispersion prepared by emulsion polymerization is added to the suspension.
摘要翻译：在从包含它们的悬浮液中沉淀微悬浮聚合物的方法中，将通过乳液聚合制备的聚合物分散体加入到悬浮液中。

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